MATERIAL SAFETY DATA SHEET
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SECTION 1 - PRODUCT INFORMATION
PRODUCT NAME: NAXONAC?690-70 ISSUE DATE: 07/13/05
CHEMICAL NAME: Poly(oxy-1,2-ethanediyl), alpha-(nonylphenyl) SUPERSEDES: 04/12/05
-omega-hydroxy-, branched phosphates
CAS NUMBER: 68412-53-3
PRODUCT CODE: 3007
MSDS NO.: 1-13100
SECTION 2 - HAZARD IDENTIFICATION
Appearance & Odor: Slightly hazy, viscous liquid. Bland odor.
Primary Routes of Exposure: Skin, Eyes and Respiratory tract.
Health Hazard Warnings: DANGER! Corrosive. Causes severe burns to eyes and skin. Eye contact may cause
blindness. Overexposure to vapors or mists is extremely destructive to the mucous membranes and upper
respiratory tract. Reacts with metal to form flammable hydrogen gas.
Inhalation: Prolonged or repeated overexposure to vapors or mists can cause severe irritation to mucous membranes
and upper respiratory tract.
Skin Contact: Can cause severe burns. Material is extremely destructive to skin. May aggravate existing dermatitis.
Eye Contact: Can cause burns unless immediately and thoroughly flushed with water. May cause permanent eye
damage.
Ingestion: Material is harmful if swallowed. Can cause burns of the mouth and digestive tract.
SECTION 3 - COMPOSITION/INFORMATION ON INGREDIENTS
CHEMICAL NAME CAS REGISTRY NO. PERCENT
Ethoxylated nonyl phenol phosphate 68412-53-3 50 ?65
ester/Ethoxylated alcohol 9016-45-9
Phosphoric acid 7664-38-2 <6
Polyethylene glycol 25322-68-3 <2
Water 7732-18-5 30 - 40
SECTION 4 - FIRST AID MEASURES
Eyes: Immediately wash eyes with water for 15-20 minutes. Hold eyelids apart and roll eyes up and down to assure
complete washing. Seek immediate medical attention.
Skin: Thoroughly flush the affected area with plenty of water for at least 15 minutes. Remove contaminated clothing
and equipment. Seek medical attention.
Inhalation: Immediately move the patient to fresh air and call a physician. If breathing is difficult, give oxygen. If not
breathing, begin artificial respiration.
MATERIAL SAFETY DATA SHEET
Page 2 of 4 MSDS No.: 1-13100
SECTION 4 - FIRST AID MEASURES (CONT.)
Ingestion: If swallowed, call a physician immediately. Only induce vomiting at the instruction of a physician. Never
give anything by mouth to an unconscious person.
Other Specific Instructions: In the event of exposure, seek medical attention immediately. Do not give chemical
antidotes unless directed to do so by the physician.
SECTION 5 - FIRE FIGHTING MEASURES
Flash Point: > 400 oF (open cup) Auto Ignition: No data available
Explosive Limits; UEL/LEL: No data available
Extinguishing Agents: Use water spray, dry chemical, carbon dioxide, or foam extinguishing agents.
Fire & Explosion Hazards: As in any fire prevent human exposure to fire, smoke, fumes or products of combustion.
Firefighters should wear recommended exposure control equipment including a self-contained breathing apparatus.
Cool containers with water that are exposed to flames.
Hazardous Combustion Products: Thermal decomposition produces oxides of carbon and phosphorous.
SECTION 6 - ACCIDENTAL RELEASE MEASURES
Personal Protective Equipment: Appropriate protective equipment must be worn when handling a spill of
NAXONAC?690-70. See Section 8 - Exposure Control, for recommendations.
Spill or Leak Information: Absorb spill material with an inert material (i.e. vermiculite, soil, etc.). Sweep or scoop
material into containers for disposal. Flush spill area with plenty of water to a chemical sewer. Collect water for
proper disposal. Prevent discharge to bodies of water.
SECTION 7 - HANDLING AND STORAGE
Handling Conditions: Prevent all skin and eye contact. Use local exhaust ventilation to prevent exposure to vapors
and mists. Emptied container may retain product residues. Follow all warnings and precautions even after container
is emptied.
Storage Conditions: Keep container tightly closed when not in use. Store in cool and well ventilated area. Do not
store in unlined metal containers as the phosphoric acid will react with the metal to liberate flammable hydrogen
gas.
SECTION 8 - EXPOSURE CONTROL
Exposure Limits: 1.0 mg/m3; TWA (Phosphoric acid)
Eye Protection: Use chemical splash goggles. Wear face shield when transferring material.
Skin Protection: Skin contact with material should be minimized through the use of suitable impervious gloves. Butyl
rubber or neoprene gloves are recommended. Use chemical resistant protective clothing or apron when handling this
material.
Respiratory Protection: Use a NIOSH approved full-facepiece, air-purifying respirator with acid gas cartridges and
the appropriate particulate prefilters for the gas/mists concentrations at the point of use.
MATERIAL SAFETY DATA SHEET
Page 3 of 4 MSDS No.: 1-13100
SECTION 8 - EXPOSURE CONTROL (CONT.)
Ventilation: Good local exhaust ventilation should be provided.
Other Protective Equipment: Safety showers and eye wash stations where material is being handled. Wash hands
and face before eating, using tobacco products or using the washroom. Smoke or eat only in designated areas.
Take a warm shower and change clothing daily. Clothing and shoes used while handling this material should not be
worn or taken away from the workplace.
SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES
Appearance: Slightly hazy viscous liquid Odor: Bland odor
Melting Point: Approximately -10 oC Boiling Point: > 500 oF
Evaporation Rate (butyl acetate=1): No data available pH: Approximately 2
Vapor Pressure: No data available Vapor Density (Air=1): No data available
Specific Gravity/Density: 1.13 @ 20 oC Solubility in Water: Soluble
Flash Point: > 400 oF (open cup)
Viscosity: 1104-1578 cps.
SECTION 10 - STABILITY AND REACTIVITY
Stability: Stable under normal conditions of storage and handling.
Incompatibility: Avoid strong oxidizers, strong bases and metals. Phosphoric acid reacts with metals to liberate
flammable hydrogen gas.
Polymerization: Not expected to occur.
Decomposition: When heated to decomposition, will emit toxic oxides of carbon and phosphorous.
SECTION 11 - TOXICOLOGICAL INFORMATION
Acute Data: The information shown in Section 3 - Hazard Identification, is based on toxicity profiles of similar
materials or on the components present in this material.
Sensitization: Ethoxylated nonyl phenol phosphate ester is not known to be a sensitizer.
Carcinogenicity/Mutagenicity: Ethoxylated nonyl phenol phosphate ester is not known to be a human or animal
carcinogen.
Teratogenicity/Reproductive Toxicity: Ethoxylated nonyl phenol phosphate ester is not known to cause
teratogenicityor reproductive toxicity.
SECTION 12 - ECOLOGICAL INFORMATION
Ecological Toxicity: No information available. The material should be considered to be toxic to fish.
MATERIAL SAFETY DATA SHEET
Page 4 of 4 MSDS No.: 1-13100
SECTION 13 - DISPOSAL CONSIDERATIONS
Waste Disposal: This product if discarded as supplied is considered a hazardous waste as defined by RCRA.
Characteristic; Corrosive, D002. Dispose of in accordance with local, state and federal regulations.
SECTION 14 - TRANSPORT CONSIDERATIONS
Shipping Description: Corrosive Liquid, Acidic, Inorganic, N.O.S (Phosphoric acid)
Hazard Class: 8 ID No.: UN3264 PG: III Labels: Corrosive
SECTION 15 - REGULATORY CONSIDERATIONS
OSHA Regulatory Status: This product is a hazardous chemical under 29 CFR 1910.1200.
SARA Title III
Section 311/312: This product is categorized as an immediate health hazard according to EPA under Section
311/312 of SARA.
Section 313: This product contains the following chemicals subject to 313 reporting:
None above De Minimis limit
CERCLA: Phosphoric acid 7664-38-2
Pennsylvania Right-to-Know: Phosphoric acid 7664-38-2 Environmental
California Proposition 65: This product may contain trace chemicals known to the State of California to cause cancer.
Acetaldehyde 75-07-0
1,4-Dioxane 123-91-1
Formaldehyde 50-00-0
This product may contain trace chemicals known to the State of California to cause cancer and reproductive effects.
Ethylene oxide, 75-21-8
Chemical Control Law Status:
This product is in compliance with the inventory listing requirements of the Chemical Control Laws in the following
countries: United States of America, Canada, Europe, Australia, Korea
WHMIS Ingredient Disclosure List: Phosphoric acid 7664-38-2
HMIS Health Rating: 3 HMIS Fire Rating: 0
HMIS Physical Hazards Rating: 0 HMIS Other: NA
SECTION 16 - OTHER CONSIDERATIONS
Prepared by Regulatory Staff Phone No.: (814) 238-2424 MSDS No.: 1-13100
Issue Date: 7/13/05
Emergency Phone No.: CHEMTREC 800-424-9300
This information is furnished free of charge and is based on technical data that Nease Corporation believes to be reliable. It is intended for use by trained persons having technical skill and at their
own discretion and risk. Since conditions of use are outside our control, we make no warranties, expressed or implied, and assume no liability in connection with any use of this information. Nothing
herein is to be taken as a license to operate under or a recommendation to infringe any patents.
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