MATERIAL SAFETY DATA SHEET
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1. Chemical Product and Company Identification
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Identification of the Q7456A
preparation
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Use of the preparation Inkjet printing
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Manufacturer information Hewlett-Packard Company
1000 NE Circle Boulevard
Corvallis, OR 97330-4239 US
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Hewlett-Packard health effects line
(Toll-free within the US) 1-800-457-4209
(Direct) 1-503-494-7199
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General information telephone number
HP Customer Care Line 1-800-474-6836
(Toll-free) 1-800-474-6836
(Direct) 1-208-323-2551
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Date prepared Jun 12, 2007
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MSDS number 146863
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2. Composition / Information on Ingredients
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Component/substance CAS number % by weight
Water 7732-18-5 > 70
2-pyrrolidone 616-45-5 < 15
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Carbon black 1333-86-4 <5
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Isopropyl Alcohol 67-63-0 <5
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Composition comments This ink supply contains an aqueous ink formulation.
This product has been evaluated using criteria specified in 29 CFR 1910.1200 (Hazard
Communication Standard).
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3. Hazards Identification
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Emergency overview Contact with skin and eyes may result in irritation.
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Acute health effects Any potential hazards are presumed to be due to exposure to the components.
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Skin contact space
2-pyrrolidone
Contact with skin may result in irritation.
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Eye contact space
2-pyrrolidone
Contact with eyes may result in irritation.
Isopropyl Alcohol
Contact with eyes may result in severe irritation.
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Inhalation space
2-pyrrolidone
Inhalation may result in respiratory irritation.
Isopropyl Alcohol
Inhalation may cause drowsiness or dizziness.
Material name Q7456A MSDS US
Creation date Apr 30, 2003 Version number 5 1/ 6
MATERIAL SAFETY DATA SHEET
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Ingestion space
2-pyrrolidone
Ingestion may result in nausea, vomiting and diarrhea.
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Potential health effects
Routes of exposure Potential routes of overexposure to this product are skin and eye contact
Inhalation of vapor and ingestion are not expected to be significant routes of exposure for this
product under normal use conditions.
Complete toxicity data are not available for this specific formulation
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Chronic health effects Carbon Black: Chronic inhalation studies performed with fine dust particles resulted in lung
tumors in animals. The IARC classification was based upon these results. IARC also concluded
"there is inadequate evidence in humans for the carcinogenicity of carbon black." Inhalation
of fine dust particles is not expected to occur during normal conditions of use of this ink.
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Carcinogenicity Carbon black is classified by the IARC as a Group 2B carcinogen (the substance is possibly
carcinogenic to humans).
None of the other ingredients in this preparation are classified as carcinogens according to
ACGIH, EU, IARC, MAK, NTP or OSHA.
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Other information space
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4. First Aid Measures
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First aid procedures
Skin Wash affected areas thoroughly with mild soap and water. If irritation persists get medical
attention. Wash affected areas thoroughly with mild soap and water and Get medical attention
if irritation develops or persists.
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Eye Do not rub eyes. Immediately flush with large amounts of clean, warm water (low pressure)
for at least 15 minutes or until particles are removed. If irritation persists get medical
attention. Do not rub eyes, Immediately flush with large amounts of clean, warm water (low
pressure) for at least 15 minutes or until particles are removed, If irritation persists get
medical attention.
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Inhalation Move to fresh air. If symptoms persist, get medical attention. Move to fresh air, If symptoms
persist, get medical attention.
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Ingestion If ingestion of a large amount does occur, seek medical attention. If ingestion of a large
amount does occur, seek medical attention.
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5. Fire Fighting Measures
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Flash point and method 131 - 136 癋 (55 - 57.8 癈); Pensky-Martens Closed Cup; No ignition, sustained combustion or
flashing detected using the Sustained Combustibility Test (method in US 49CFR173, Appendix
H).
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Hazardous combustion Refer to section 10. Carbon monoxide and carbon dioxide.
products
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Extinguishing media CO2, water, dry chemical, or foam Dry chemical, CO2, water spray or regular foam.
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Unsuitable extinguishing None known. None known.
media
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Unusual fire and explosion None known. Flammable Liquid and Will burn if involved in a fire and Vaporizes easily at
hazard normal temperatures and Vapors may travel to a source of ignition and flash back.
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Special firefighting None established.
procedures
Material name Q7456A MSDS US
Creation date Apr 30, 2003 Version number 5 2/ 6
MATERIAL SAFETY DATA SHEET
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6. Accidental Release Measures
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Personal precautions Wear appropriate personal protective equipment. Wear appropriate personal protective
equipment and Ensure adequate ventilation and Remove all sources of ignition.
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Environmental precautions Do not let product enter drains. Do not flush into surface water or sanitary sewer system. Do
not let product enter drains and Do not flush into surface water or sanitary sewer system.
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Procedures if material is Soak up with inert absorbent material. Slowly vacuum or sweep the material into a bag or
released or spilled other sealed container. Dispose of in compliance with federal, state, and local regulations. See
also section 13 Disposal considerations. Soak up with inert absorbent material, Clean
remainder with a damp cloth or vacuum cleaner, Dispose of in compliance with federal, state,
and local regulations, See also section 13 Disposal considerations.
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7. Handling and Storage
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Handling Avoid contact with skin, eyes and clothing. Keep away from heat and sources of ignition and
Avoid contact with skin and eyes Use this product with adequate ventilation.
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Storage Keep out of the reach of children. Keep away from excessive heat or cold. Keep away from
excessive heat, sparks, and open flames.
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8. Exposure Controls/Personal Protection
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Exposure limit values Exposure limits have not been established for this product.
ACGIH - Threshold Limits Values - Time Weighted Averages (TLV-TWA)
Isopropyl Alcohol 67-63-0 200 ppm TWA
ACGIH - Threshold Limits Values - Time Weighted Averages (TLV-TWA)
Carbon black 1333-86-4 3.5 mg/m3 TWA
OSHA - Final PELs - Time Weighted Averages (TWAs)
Carbon black 1333-86-4 3.5 mg/m3 TWA
OSHA - Final PELs - Time Weighted Averages (TWAs)
Isopropyl Alcohol 67-63-0 400 ppm TWA; 980 mg/m3 TWA
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Personal protective equipment
General Use personal protective equipment to minimize exposure to skin and eye. Use personal
protective equipment to minimize exposure to skin and eye.
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Hygiene measures Handle in accordance with good industrial hygiene and safety practice. Handle in accordance
with good industrial hygiene and safety practice.
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Exposure guidelines Use in a well ventilated area. Use in a well ventilated area.
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9. Physical & Chemical Properties
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pH 7.8 - 8.4
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Vapor pressure Not determined
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Boiling point > 200 癋 (> 93.3 癈)
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Solubility Soluble in water
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Specific gravity 1 - 1.2 g/mL
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VOC content <3%
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Flash point 131 - 136 癋 (55 - 57.8 癈)
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Viscosity > 2 cp
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Vapor density > 1 (air = 1.0)
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Evaporation rate Not determined
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Oxidizing properties Not determined No information available.
Material name Q7456A MSDS US
Creation date Apr 30, 2003 Version number 5 3/ 6
MATERIAL SAFETY DATA SHEET
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Color Black
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10. Chemical Stability & Reactivity Information
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Stability Stable under recommended storage conditions. Stable under recommended storage
conditions.
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Hazardous polymerization Will not occur. Will not occur.
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Hazardous decomposition Upon decomposition, this product may yield gaseous nitrogen oxides, carbon monoxide,
products carbon dioxide and/or low molecular weight hydrocarbons. Carbon monoxide and carbon
dioxide.
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Incompatibility Incompatible with strong bases and oxidizing agents. Incompatible with strong acids and
bases.
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11. Toxicological Information
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Complete toxicity data are not available for this specific formulation.
Refer to Section 3 for potential health effects and Section 4 for first aid measures. Complete toxicity data are not available for this
specific formulation Refer to Section 3 for potential health effects and Section 4 for first aid measures.
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Carcinogenicity space
OSHA - Hazard Communication Carcinogens
Carbon black 1333-86-4 Present
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Symptoms and target organs space
NIOSH - Pocket Guide - Target Organs
Isopropyl Alcohol 67-63-0 eyes, skin, respiratory system
NIOSH - Pocket Guide - Target Organs
Carbon black 1333-86-4 respiratory system, eyes (lymphatic cancer in presence of PAHs)
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12. ECOLOGICAL INFORMATION
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Aquatic toxicity LC50/96h/Fathead minnows =>750 mg/L LC50/96h/Fathead minnows =9460 mg/L.
EC50/48h/daphnia =13299 mg/L.
EC50/72h/algae =/> 1000 mg/L.
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13. Disposal Considerations
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Disposal instructions Dispose of in compliance with federal, state, and local regulations.
HP's Planet Partners (trademark) supplies recycling program enables simple, convenient
recycling of HP original inkjet and LaserJet supplies. For more information and to determine if
this service is available in your location, please visit http://www.hp.com/recycle. Dispose of in
compliance with federal, state, and local regulations.
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14. Transportation Information
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General Not a regulated article under United States DOT, IATA, ADR, IMDG, or RID.
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IATA
Proper shipping name Not applicable
Hazard class Not applicable
Packaging exceptions None
Identification number None
(UN)
Packing group N/A
Material name Q7456A MSDS US
Creation date Apr 30, 2003 Version number 5 4/ 6
MATERIAL SAFETY DATA SHEET
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15. Regulatory Information
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International regulations All chemical substances in this HP product have been notified or are exempt from notification
under chemical substances notification laws in the following countries: US (TSCA), EU
(EINECS/ELINCS), Switzerland, Canada (DSL/NDSL), Australia, Japan, Philippines, South
Korea, New Zealand, and China. All chemical substances in this HP product have been notified
or are exempt from notification under chemical substances notification laws in the following
countries: US (TSCA), EU (EINECS/ELINCS), Switzerland, Canada (DSL/NDSL), Australia,
Japan, Philippines, South Korea, New Zealand, and China.
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US federal regulations US TSCA 12(b): Contains tetrahydrofuran (CASRN 109-99-9), subject to export notification
requirements.
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HMIS ratings Health: 1
Flammability: 2
Physical hazard: 0
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NFPA ratings Health: 1
Flammability: 2
Instability: 0
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Superfund Amendments and Reauthorization Act of 1986 (SARA)
Section 302 extremely No
hazardous substance
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Section 311 hazardous No
chemical
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Hazard categories Immediate Hazard - No
Delayed Hazard - No
Fire Hazard - No
Pressure Hazard - No
Reactivity Hazard - No
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16. Other Information
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Other information This MSDS was prepared in accordance with USA OSHA Hazard Communications regulation
(29 CFR 1910.1200).
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Issue date Jun 12 2007 6:56AM
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Revision 5
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Replaces sheet dated Jan 26 2007 10:57PM
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Disclaimer This Safety Data Sheet document is provided without charge to customers of Hewlett-Packard
Company. Data is the most current known to Hewlett-Packard Company at the time of
preparation of this document and is believed to be accurate. It should not be construed as
guaranteeing specific properties of the products as described or suitability for a particular
application. This document was prepared to the requirements of the jurisdiction specified in
Section 1 above and may not meet regulatory requirements in other countries.
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MSDS sections updated Chemical Product and Company Identification: Alternate Trade Names - SKU Numbers
Composition / Information on Ingredients: Ingredients
3. Hazards Identification: Chronic health effects
3. Hazards Identification: Carcinogenicity
15. Regulatory Information: Canadian regulations
Material name Q7456A MSDS US
Creation date Apr 30, 2003 Version number 5 5/ 6
MATERIAL SAFETY DATA SHEET
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Explanation of abbreviations
ACGIH American Conference of Governmental Industrial Hygienists
CAS Chemical Abstracts Service
CERCLA Comprehensive Environmental Response Compensation and Liability Act
CFR Code of Federal Regulations
COC Cleveland Open Cup
DOT Department of Transportation
EPCRA Emergency Planning and Community Right-to-Know Act (aka SARA)
IARC International Agency for Research on Cancer
NIOSH National Institute for Occupational Safety and Health
NTP National Toxicology Program
OSHA Occupational Safety and Health Administration
PEL Permissible Exposure Limit
RCRA Resource Conservation and Recovery Act
REC Recommended
REL Recommended Exposure Limit
SARA Superfund Amendments and Reauthorization Act of 1986
STEL Short-Term Exposure Limit
TCLP Toxicity Characteristics Leaching Procedure
TLV Threshold Limit Value
TSCA Toxic Substances Control Act
VOC Volatile Organic Compounds
Material name Q7456A MSDS US
Creation date Apr 30, 2003 Version number 5 6/ 6
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