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MSDS Material Safety Data Sheet
CAS

109-99-9 89-32-7 89-05-4

File Name: 109-99-9_89-32-7_89-05-4.asp

                                   ADDENDUM
TO
MATERIAL SAFETY DATA SHEET (MSDS)

This Addendum is part of the Material Safety Data Sheet (MSDS) referred to below.
This addendum should be stored and read in conjunction with the MSDS.
Identification
Product Name: M-Bond Curing Agent 600/610
Product Code(s): VMMMBOND600-2
Manufacturer: Vishay Micro-Measurements
Product Use: Adhesive
Supplier Details
AUSTRALIA NEW ZEALAND
Biolab (Aust) Limited Biolab Limited
5 Caribbean Drive, Scoresby, 244 Bush Road, Albany
VIC 3179, Australia Auckland, New Zealand
Ph: 03 9757 4300 Ph: 09 980 6700
Fax: 03 9763 1169 Fax: 09 980 6788
Email: AUinfo@thermofisher.com Email: NZinfo@thermofisher.com
Emergency Contact: Emergency Contact:
National Poisons Information Centre (24 hr): 13 11 26 CHEMCALL (24hr): 0800 243 622
Hazard Identification
NOHSC: Classified as Hazardous according to the criteria of the NOHSC.
ADG Code: Classified as Dangerous Goods according to the Australian Dangerous Goods
Code.
Risk Phrases: R11 Highly flammable.
R36/37 Irritating to eyes and respiratory system.
R42/43 May cause sensitisation by inhalation and skin contact
R66 Repeated exposure may cause skin dryness and cracking.
R67 Vapours may cause drowsiness and dizziness.
Safety Phrases: S9 Keep container in a well ventilated place.
S16 Keep away from sources of ignition - No smoking.
S24 Avoid contact with skin.
S26 In case of contact with eyes, rinse immediately with plenty of water and
seek medical advice.
S29 Do not empty into drains.
S33 Take precautionary measures against static discharges.
S37/39 Wear suitable gloves and eye/face protection.
Transport Information
UN No.: 1993
Shipping Name: FLAMMABLE LIQUID, N.O.S. Contains Tetrahydrofuran
Class: 3
Subsidiary Risk: -
Packing Group: II
Hazchem Code: 3YE
Other Information
Poisons Schedule: S5
MATERIAL SAFETY DATA SHEET

SECTION 1: CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

PRODUCT: M-Bond Curing Agent 600/610 October 8, 2008

Vishay Micro-Measurements MSDS # MGM013M
Post Office Box 27777
Raleigh, NC 27611

919-365-3800

CHEMTREC 1-800-424-9300 (U.S.)
703-527-3887 (Outside U.S.)

NOTE: CHEMTREC numbers to be used only in the event of chemical emergencies involving a spill, leak, fire,
exposure or accident involving chemicals.

SECTION 2: HAZARDOUS INGREDIENTS / IDENTITY INFORMATION

CAS NUMBER CHEMICAL IDENTITY %

109-99-9 Tetrahydrofuran 88.25

89-32-7 1,2,4,5-Benzenetetracarboxylic Dianhydride 8.8

89-05-4 1,2,4,5-Benzenetetracarboxylic Acid 2.95

SECTION 3: HEALTH HAZARD DATA

Routes of Entry:

Inhalation: YES Skin: YES Ingestion: YES

Health Hazards (Acute and Chronic): Chronic over-exposure may include kidney and/or liver damage. Acute
over-exposure may induce narcosis and/or loss of consciousness. May be a skin sensitizer to some individuals.

Carcinogenicity: NTP: Not listed
IARC Monographs: Not listed
OSHA Regulated: Not listed




DOCUMENT NO.: 14035 805-FRM011
M-Bond Curing Agent 600/610 MSDS # MGM013M

Signs and Symptoms of Exposure:

INHALATION: May cause headache, dizziness, irritation of the nose and throat.

EYE CONTACT: May cause severe irritation or burns, tearing, and redness.

SKIN CONTACT: May cause redness and pain.

INGESTION: May cause sore throat and abdominal pain.

Medical Conditions Generally Aggravated by Exposure: Pre-existing skin or eye problems, impaired liver or
kidney function.

SECTION 4: EMERGENCY AND FIRST AID PROCEDURES

INHALATION: Remove to fresh air. If breathing is difficult, administer oxygen. If breathing has stopped,
administer artificial respiration and/or oxygen. Get medical attention if needed.

EYE CONTACT: Immediately flush eyes with copious amounts of water for 15 minutes while holding eyelids open.

SKIN CONTACT: Immediately flush thoroughly while removing contaminated clothing. Wash affected area with
soap and water. Wash contaminated clothing before reuse.

INGESTION: If swallowed wash out mouth with water provided person is conscious. Continue to give large
quantities of water. Do NOT induce vomiting unless directed to do so by medical personnel. Get medical attention.

SECTION 5: FIRE AND EXPLOSION HAZARD DATA

Flash Point (Method Used): 6癋 (-14癈) COC

Flammable limits: LEL: 1.8 UEL: 11.8

Extinguishing Media: Dry chemical, foam, carbon dioxide. Water spray may be used to cool fire exposed
containers.

Special Firefighting Procedures: Firefighters should wear proper protective equipment and self-contained
breathing apparatus operated in positive pressure mode.

Unusual Fire and Explosion Hazards: Vapors may flow along surfaces to distant ignition sources and flash back.
Explosive organic peroxides form from aging or light.

SECTION 6: ACCIDENTAL RELEASE MEASURES

Steps to be taken if material is released or spilled: Ventilate area. Remove all sources of ignition. Wipe up with
absorbent material such as sand or vermiculite. Flush affected area with water.




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DOCUMENT NO.: 14035 805-FRM011
M-Bond Curing Agent 600/610 MSDS # MGM013M

SECTION 7: EXPOSURE CONTROLS -- PERSONAL PROTECTION

Respiratory Protection: Respiratory protection required if airborne concentration exceeds TLV.

Ventilation:

Local Exhaust: Preferred because it can control the emissions of contaminants into the work area.
Mechanical: Keep below TLV
Special: N/E
Other: N/E

Protective Gloves: Rubber or neoprene gloves are recommended.

Eye Protection: Chemical splash goggles are recommended.

Other Protective Clothing or Equipment: Impervious over-clothing as needed. Safety shower and eye wash
station in local area.

Work / Hygienic Practices: Wash thoroughly after using and before eating, drinking or smoking.

SECTION 8: HANDLING AND STORAGE

Precautions to be taken in handling and storing: Store below 80癋 (27癈) in a dry, well ventilated, flammable
liquid area away from light, heat and oxidizers.

Other Precautions: Keep containers tightly sealed when not in use. Avoid prolonged exposure to vapors and skin
contact.

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES

Boiling Point: 151癋 (66癈)
Vapor Pressure (mmHg): 145 @ 59癋 (15癈)
Vapor Density (Air = 1): 2.5
Specific Gravity (H2O = 1): 0.9
Melting Point: N/A
Evaporation Rate (BuAc = 1): >1
Volatile Organic Compounds: 705 g/liter
Solubility in Water: Complete

Appearance and Odor: Colorless to amber colored liquid; ether-like odor.




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DOCUMENT NO.: 14035 805-FRM011
M-Bond Curing Agent 600/610 MSDS # MGM013M

SECTION 10: STABILITY AND REACTIVITY DATA

Stability: Stable under normal conditions of use and storage.

Conditions to Avoid: Heat, sources of ignition, light.

Incompatibility (Materials to Avoid): Strong oxidizing agents.

Hazardous Decomposition or By-products: Oxides of carbon, explosive peroxides.

Hazardous Polymerization: Will not occur.

SECTION 11: TOXICOLOGICAL INFORMATION

Tetrahydrofuran

OSHA PEL: 200 ppm (TWA) 250 ppm STEL
ACGIH TLV: 200 ppm (TWA) 250 ppm STEL
OTHER: LDLO ORAL (RAT) 3000 mg/kg

1,2,4,5-Benzenetetracarboxylic Anhydride

OSHA PEL: Not known
ACGIH TLV: Not known
OTHER: LD50 ORAL (MUS) 2400 mg/kg

1,2,4,5-Benzenetetracarboxylic Acid

OSHA PEL: Not known
ACGIH TLV: Not known
OTHER: 0.25 mg/m3 Respirable Dust per manufacturer

SECTION 12: DISPOSAL CONSIDERATIONS

Waste Disposal Method: Dispose of in accordance with local, state, and federal regulations.

SECTION 13: TRANSPORTATION INFORMATION

SHIPPING NAME CLASS PACKING GROUP UN NUMBER

Flammable Liquids, N.O.S.
(Tetrahydrofuran) 3 II 1993




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DOCUMENT NO.: 14035 805-FRM011
M-Bond Curing Agent 600/610 MSDS # MGM013M

SECTION 14: REGULATORY INFORMATION

SECTION 313 SUPPLIER NOTIFICATION:

This product contains a toxic chemical or chemicals (as listed below) subject to the reporting requirements of
Section 313 Title III of the Superfund Amendment and Reauthorization Act of 1986 and 40 CFR Part 372.

CAS NUMBER CHEMICAL NAME % BY WEIGHT

NONE

TSCA NOTIFICATION:

All components of this product are listed in the Toxic Substance Control Act Chemical Substance Inventory (TSCA).

SECTION 15: OTHER INFORMATION

To the best of our knowledge, the information provided above meets the requirements of the United States
Occupational Safety and Health Act and regulations established under 29 CFR 1910.1200 (g)(2)(c)(1)-(4) for a
mixture of hazardous chemicals which has not been tested as a whole. The data provided on this Material Safety
Data Sheet is from manufacturers of the original components. Vishay Micro-Measurements specifically disclaims
any and all form of liability and/or responsibility for the application of this product.




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DOCUMENT NO.: 14035 805-FRM011

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