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Hitachi Industrial Equipment Systems Co., Ltd JP-K83 Version 2.00 issue 2009.3.31 revision 2009.11.10
MATERIAL SAFETY DATA SHEET
1 IDENTIFICATION
Product name :JP-K83
Name of company :Hitachi Industrial Equipment Systems Co., Ltd
Address :1-1,Higashitaga-cho 1-chome, Hitachi-shi, Ibaraki-ken, Japan
Tel :+81-294-36-8682
Fax :+81-294-36-8975
Recommended use of the chemical
and restrictions on use :Printing Ink for industrial Marking
2 HAZARDS IDENTIFICATION
Physico-chemical endpoints :Flammable liquid Category 2
Acute toxicity - oral :Category 5
Acute toxicity - dermal :Not available
Acute toxicity - inhalation air :Not identified
Acute toxicity - inhalation vapors :Not available
Acute toxicity - inhalation dust, mist :Not identified
Skin corrosion/irritation :Not available
Eye damage/irritation : Category 2
Sensitization - respiratory : Not identified
Sensitization - skin : Not identified
Germ cell mutagenicity : Not available
Carcinogenicity : Not available
Toxic to reproduction : Category 1
Effects on or via lactation : Not identified
Specific target organ systemic toxicity (Single exposure)
Category 1 Sensory system
Category 1 Systemic toxicity
Category 1 Central nervous system
Category 2 Kidney
Category 3 Respiratory system
:(Repeated exposure)
Category 1 Sensory system
Category 1 Central nervous system
Category 1 Peripheral nervous system
Aspiration toxicity : Category 2
Hazardous to the aquatic environment
-Acute hazard : Not available
-Chronic hazard : Not available
To the best of our knowledge, the information contained here in is accurate. However, neither the above
named supplier nor any of its subsidiaries assumes any liability whatsoever for the accuracy or
completeness of the information contained herein. Final determination of suitability of any material is the
sole responsibility of the user. All materials may present unknown hazards and should be used with caution.
Although certain hazards are described herein, we cannot guarantee that these are the only hazards that
exist.
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Hitachi Industrial Equipment Systems Co., Ltd JP-K83 Version 2.00 issue 2009.3.31 revision 2009.11.10
GHS label elements
Hazard symbols:
Signal word: Danger
Hazard statement and precautionary statement
?Highly flammable liquid and vapour
?May be harmful if swallowed
?Causes skin irritation
?Causes damage to Sensory system,systemic toxicity and central nervous system-single exposure
?May cause damage to kidney-single exposure
?May cause respiratory irritation-single exposure
?Causes damage to sensory system, central nervous system and peripheral nervous system
through prolonged or repeated exposure.
Precautionary statements:
?Keep out of reach of children. Read label before use. If medical advice is needed: Have product
container or label at hand.
Prevention
?Keep away from ignition sources such as heat/sparks/open flame?No smoking.
?Take precautionary measures against static discharge.
?Wear protective gloves and eye/face protection as specified by the competent authority.
?Do not breathe dust/mist/vapors.
?Use only in a well-ventilated area. Call a doctor/physician if you feel unwell.
?Do not eat, drink or smoke when using this product.
?Avoid contact during pregnancy/while nursing.
?Wash hands thoroughly after handling.
Response
?In case of fire, use dry chemical, CO2, water splay (fog) or form for extinction.
?IF SWALLOWED: Call a doctor/physician if you feel unwell. Rinse mouth.
?IF ON SKIN: Gently wash with plenty of soap and water.
?Wash/Decontaminate removed clothing before reuse.
?If skin irritation occurs, seek medical advice/attention.
?IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.
?IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and
easy to do. Continue rinsing. Immediately call a doctor/physician.
?Collect spillage.
Storage
?Store in cool/well-ventilated place. Store locked up.
?Call a doctor/physician if exposed or you feel unwell.
To the best of our knowledge, the information contained here in is accurate. However, neither the above
named supplier nor any of its subsidiaries assumes any liability whatsoever for the accuracy or
completeness of the information contained herein. Final determination of suitability of any material is the
sole responsibility of the user. All materials may present unknown hazards and should be used with caution.
Although certain hazards are described herein, we cannot guarantee that these are the only hazards that
exist.
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Hitachi Industrial Equipment Systems Co., Ltd JP-K83 Version 2.00 issue 2009.3.31 revision 2009.11.10
Disposal
?Waste must be disposed of according to applicable regulations.
3 Composition/information on ingredients
Substance or mixture; mixture
Composition;
Chemical name concentration (%) CAS number
2-butanone 30-40 78-93-3
Methanol 30-40 67-56-1
1-Methoxy-2-propanol 1-10 107-98-2
4 First-aid measures
Inhalation;
Remove the victim from the contamination immediately to fresh air. Keep the victim warm and quiet and
arrange for transport to the neatest medial facility for examination and treatment by a physician as soon
as possible.
Skin contact;
Remove all contaminated clothing, shoes and socks from the affected areas as quickly as possible.
Wash the affected area under running water using a mild soap. If irritation persists, arrange for transport
to the nearest medical facility for examination and treatment by a physician as son as possible.
Eye contact;
Gently rinse the affected eyes with clean water for at least 15 minutes. Remove contact lenses if easily
possible. and refer for medical attention.
Ingestion;
Never give anything by mouth to someone who is unconscious or convulsing. If the victim is responsive,
give him one or two glasses of water. And refer for medial attention.
5 Fire-fighting measures
Suitable extinguishing media;
Use dry chemical, CO2, water splay (fog) or form.
Fire fighting procedures;
Use water spray to cool fire-exposed surfaces and to protect personnel. Shut off "fuel" to fire. If a leak
or spill has not ignited, use water spray to disperse the vapors.
Avoid spraying water directly into storage containers due to danger of boil over.
Unusual fire/explosion hazard;
Flammable liquid, can release vapors that form flammable mixtures at temperatures at or above the
flashpoint.
Special protective equipment and precautions for fire fighters;
Fire fighters should wear boots, overalls, gloves, eye and face protection and breathing apparatus.
6 Accidental release measures
Shut off all sources of ignition; No smoking or flames in area. Absorb spill with inert material (e.g.,
To the best of our knowledge, the information contained here in is accurate. However, neither the above
named supplier nor any of its subsidiaries assumes any liability whatsoever for the accuracy or
completeness of the information contained herein. Final determination of suitability of any material is the
sole responsibility of the user. All materials may present unknown hazards and should be used with caution.
Although certain hazards are described herein, we cannot guarantee that these are the only hazards that
exist.
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Hitachi Industrial Equipment Systems Co., Ltd JP-K83 Version 2.00 issue 2009.3.31 revision 2009.11.10
dry sand or earth), then place in closed containers using non-sparking tools. Flush residual spill
(area) with copious amounts of water.
7 Handling and storage
Handling;
Use only in the well-ventilated areas.
Make available in the work area emergency shower and eyes wash.
Avoid contact with skin or eyes.
Storage;
Close up the container and keep it in dark cool(0~20 ) place.
Keep away from combustible materials and sources of ignition.
8 Exposure controls/personal protection
Exposure guidelines;
ACGIH TLV-TWA (ppm)
2-butanone :200
Methanol :200(skin)
1-Methoxy-2-propanol :100
ACGIH STEL(ppm)
2-butanone :300
Methanol :250(skin)
1-Methoxy-2-propanol :150
9 Physical and chemical properties
Appearance
Physical state :Liquid
Color :Black
Odor :Solvent odor
Boiling point :65 to 80
Flash point :-2.0 closed cup
Upper/lower flammability or explosive limits :Lower 1.8 vol Upper 36 vol
Vapor pressure :11.2kPa (20 )
Vapor density (Air 1) :None known
Relative density :0.81(20 )
Solubility Water :None known
Partition coefficient: n-octanol/water :None known
Auto-ignition temperature :470
Decomposition temperature :No data
10 Stability and reactivity
Stability: The product is stable.
Conditions and materials to avoid: Not available
Hazardous decomposition products: These products are carbon oxides
To the best of our knowledge, the information contained here in is accurate. However, neither the above
named supplier nor any of its subsidiaries assumes any liability whatsoever for the accuracy or
completeness of the information contained herein. Final determination of suitability of any material is the
sole responsibility of the user. All materials may present unknown hazards and should be used with caution.
Although certain hazards are described herein, we cannot guarantee that these are the only hazards that
exist.
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Hitachi Industrial Equipment Systems Co., Ltd JP-K83 Version 2.00 issue 2009.3.31 revision 2009.11.10
11 Toxicological information
Acute toxicity;
2-butanone
LD50(orl,rat): 2737mg/kg(TXAPA9 19, 699, 1971)
LCLo(ihl,rat): 23500mg/m3/8H(AIHAAP 20, 364, 1959)
LD50(skin,rabbit): 6480mg/kg(SHELL* MSDS-5390-4)
TCLo(ihl,human): 1000mg/m3(VCVGK* -, 417, 1994)
LDLo(orl,human): 714.3mg/kg(VCVGK* -, 417, 1994)
Methanol
LD50(orl,rat): 5628mg/kg(GTPZAB 19(11),27,1975)
LC50(ihl,rat): 64000ppm/4H(NPIRI* 1,74,1974)
TDLo(orl,man): 9450礚/kg(AJEMEN 16,538,1998)
TCLo(ihl,human): 300ppm(NPIRI* 1,74,1974)
1-Methoxy-2-propanol
LD50(orl,rat): 6600mg/kg (RTECS)
TCLo(ihl,human): 3000ppm (RTECS)
Skin corrosion/irritation;
2-butanone
Skin; rabbit; 402mg/24H; Mild(TXAPA9 19, 276, 1971)
Methanol
Skin; rabbit; 20mg/24H; Moderate(85JCAE -,187,1986)
1-Methoxy-2-propanol
Skin; rabbit; 500mg open; Mild (RTECS)
Serious eye damage/irritation;
2-butanone
Eye; rabbit; 80mg(TXAPA9 19, 276, 1971)
Methanol
Eye; rabbit; 100mg/24H; Moderate(85JCAE -,187,1986)
1-Methoxy-2-propanol
Eye; rabbit; 500mg/24H; Mild (RTECS)
human; ; Severe(SIDS, 2001)(ACGIH, 2001)(PATTY, 1994)
Respiratory or skin sensitization;
2-butanone
Methanol
Allergic dermatitis; human, skin(PATTY 4th,1994)
No skin sensitization ;Magnusson-Kligman maximization test, guinea pig(EHC 196,1997: DFGOT
vol. 16,2001)
1-Methoxy-2-propanol
Not available
Germ cell mutagenicity;
2-butanone
Reverse mutation assay in S.typhimuriun and E.coli; Negative
Sex chromosome loss and nondisjunction; S.cerevisiae; 33800ppm(MUREAV 149, 339, 1985)
Methanol
Mutation in microorganisms; mouse; lymphocyte; 7900mg/L(ENMUDM 7(Suppl 3),10,1985)
To the best of our knowledge, the information contained here in is accurate. However, neither the above
named supplier nor any of its subsidiaries assumes any liability whatsoever for the accuracy or
completeness of the information contained herein. Final determination of suitability of any material is the
sole responsibility of the user. All materials may present unknown hazards and should be used with caution.
Although certain hazards are described herein, we cannot guarantee that these are the only hazards that
exist.
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Hitachi Industrial Equipment Systems Co., Ltd JP-K83 Version 2.00 issue 2009.3.31 revision 2009.11.10
1-Methoxy-2-propanol
Not available
Carcinogenicity;
2-butanone
Not available
Methanol
Not available
1-Methoxy-2-propanol
Not available
Reproductive toxicity;
2-butanone
TCLo(ihl,rat): 2900mg/m3(female 6-10 D preg); Specific Developmental Abnormalities -
craniofacial(VCVGK* -, 418, 1994)
Methanol
TCLo(ihl,rat): 10000ppm/7H(7-15 D preg)(FAATDF 5,727,1985)
TDLo(orl,rat): 5200礚/kg(10 D preg)(REPTED 11,503,1997)
1-Methoxy-2-propanol
TCLo(ihl,rat): 3000ppm/6H(female 6-15D preg)(RTECS)
TDLo(orl,mouse): 115.5gm/kg(male 7D preg)(RTECS)
STOST-single exposure;
2-butanone
The influence of the central nervous system, rat/mouse(EHC 143, 1992; PATTY 4th, 1994;
IRIS 2003)
The influence of kidny, oral, rat(DFGOT vol 12,1999; IRIS 2003; ATSDR 1992)
The respiratory tract irritation, human (ACGIH 7th, 2001; DFGOT vol 12,1999; PATTY 4th,
1994; ATSDR 1992)
Methanol
The restraint of central nervous system and damage of the visual organ, human,
oral or ihl(EHC 196,1997; ACGIH, 7th,2001; DFGOT vol.16, 2001),
The respiratory tract irritation, rat,(EHC 196,1997; PATTY 4th,1994),
Anesthesia, rat , mouse and rhesus monkey(EHC 196,1997;PATTY 4th,1994)
1-Methoxy-2-propanol
Rat, mouse; ihl, and Rabbit; skin, disappearance of reflection and get up(SIDS, 2001)
STOST-repeated exposure;
2-butanone
The sensory paralysis of hand and arm, human(EHC 143, 1992; DFGOT vol 12, 1999; IRIS 2003)
The dmade of central nervous system, human(DFGOT vol 12, 1999; IRIS 2003)
Methanol
The restraint of central nervous system and damage of the visual organ, human,
oral or ihl(EHC 196,1997; ACGIH, 7th,2001; DFGOT vol.16, 2001),
The respiratory tract irritation, rat,(EHC 196,1997; PATTY 4th,1994),
Anesthesia, rat , mouse and rhesus monkey(EHC 196,1997;PATTY 4th,1994)
1-Methoxy-2-propanol
Not available
Aspiration hazard.
2-butanone
Not available
To the best of our knowledge, the information contained here in is accurate. However, neither the above
named supplier nor any of its subsidiaries assumes any liability whatsoever for the accuracy or
completeness of the information contained herein. Final determination of suitability of any material is the
sole responsibility of the user. All materials may present unknown hazards and should be used with caution.
Although certain hazards are described herein, we cannot guarantee that these are the only hazards that
exist.
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Hitachi Industrial Equipment Systems Co., Ltd JP-K83 Version 2.00 issue 2009.3.31 revision 2009.11.10
Methanol
Not available
1-Methoxy-2-propanol
Not available
12 Ecological information
Toxicity
2-butanone
Methanol
1-Methoxy-2-propanol
Persistence and degradability:
2-butanone
Not available
Methanol
This material is biodegradable.
1-Methoxy-2-propanol
This material is biodegradable.
Bioaccumulative potential:
2-butanone
Not available
Methanol
Not available
1-Methoxy-2-propanol
Not available
Mobility in soil:
2-butanone
Not available
Methanol
Not available
1-Methoxy-2-propanol
Not available
13 Disposal considerations
Scrap materials may be disposed by licensed contractor or burn in an approved incinerator.
Do not dump into sewer, on the ground or into any body of water.
To the best of our knowledge, the information contained here in is accurate. However, neither the above
named supplier nor any of its subsidiaries assumes any liability whatsoever for the accuracy or
completeness of the information contained herein. Final determination of suitability of any material is the
sole responsibility of the user. All materials may present unknown hazards and should be used with caution.
Although certain hazards are described herein, we cannot guarantee that these are the only hazards that
exist.
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Hitachi Industrial Equipment Systems Co., Ltd JP-K83 Version 2.00 issue 2009.3.31 revision 2009.11.10
Follow national and local regulations.
14 Transport information
Follow all regulations in your country.
UN Number :1210
UN Proper Shipping Name :Printing ink, flammable
Transport hazard class :Class 3(Flammable liquid)
Packing Group :
Environmental hazards :No
15 Regulatory information
Follow all regulations in your country.
Content of RoHS Directive material Cd<100ppm Pb, Hg, Hexavalent Cr, PBB, PBDE<1000ppm
16 References
1) Solvent, dye MSDS
2) Results of Eco-toxicity tests of chemicals conducted by Ministry of the Environment in Japan (-2006)
3) International Chemical Safety Cards
To the best of our knowledge, the information contained here in is accurate. However, neither the above
named supplier nor any of its subsidiaries assumes any liability whatsoever for the accuracy or
completeness of the information contained herein. Final determination of suitability of any material is the
sole responsibility of the user. All materials may present unknown hazards and should be used with caution.
Although certain hazards are described herein, we cannot guarantee that these are the only hazards that
exist.
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