Material Safety
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Data Sheet
Section 1 - Product and Company Identification
Product namePhoto-Resist Thinner/Dilution AgentPP-82
Other names--
Product usephotoresist thinner, photoresist detergent
Supplier's nameSan Fu Chemical Co., Ltd., Shan Hua Plant
Supplier's address340 Hsiao Hsin Li, Shan Hua Town, Tainan Hsien, Taiwan, R.O.C.
Supplier's phone06-5837608 Emergency phone06-5837608
FAX.06-5839498
Section 2 - Hazards Identification
Classification
1. Inflammable Liquids (Category 3)
2. Serious Eye Damage/Eye Irritation (Category 2)
The Most Important Hazards and effect
Label element
Hazard symbol Flame, Exclamation Mark
Signal wordDanger
Hazard statement
1. Inflammable liquid and vapor/mist
2. May cause eye irritation
Precautionary statement
1. Place the containers in well-ventilated area.
2. Keep away from heat or any source of ignition.
3. Avoid contacting with eyes.
Others Hazard--
Section 3 - Composition/Information On Ingredients
Mixture
Component or impurities Concentration or concentration CAS No.
contributing to the hazard range
Propylene Glycol 80% 107-98-2
Monomethyl Ether
Propylene Glycol 20% 108-65-6
Monomethyl Ether Acetate
Section 4 - First Aid Measures
The First-aid Information
InhalationIf you experience nauseated, headaches, or dizzy, leave area of exposure to
breath fresh air immediately. Give oxygen; keep warm; and artificial respiration if
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Data Sheet
necessary. Get medical attention.
Skin ContactRemove contaminated clothing as needed. Wash affected skin thoroughly
with soap and water. Flush with water for at least 15 minutes. Seek urgent medical
attention.
Eye ContactImmediately flush the eyes with large amounts of clean low-pressure water
for at least 15 minutes, occasionally lifting the upper and lower lids. If pain or irritation
persists, promptly obtain medical attention. Remove contact lenses, if worn. DO NOT use
counteractive to flush eyes.
Ingestion DO NOT induce vomiting. If conscious, give large quantities of water. Seek
immediate medical attention. Never give anything by mouth to an unconscious person.
The Most Important Symptoms and Hazardous Effects
1. Inter-limb development coordination disorder
2. Lose of consciousness
Protection of First-aiders
1. To avoid contacting with the poisonous substance
2. Wear appropriate chemical protective equipments.
Notes to a Physician
1. Treat symptomatically.
2. To avoid contacting with the poisonous substance.
3. Wear appropriate chemical protective equipments.
Section 5 - Fire Fighting Measures
Extinguishing Media
1. Small fire: use carbon dioxidedry chemicalfoam
2. Large fire: use water, fog or spray, foam
Specific Hazards when Fire-fight Vapor or gas may spread to distance ignition sources and
flash back. Vapors or gas may accumulate or concentrate along the ground in low areas or in
confined area. Indoor or outdoor vapors or gas, or vapors in the sewer may create explosion
hazard. Burning may produce oxidant, sparkle, or droplet.
Specific Fire-fighting Procedure
1. Apply proper extinguishing media.
2. May cause anoxia in confined space.
Specific Protection of FirefightersDo not enter fire area without proper protection. Wear
positive pressure self-contained breathing apparatus (SCBA). Structural firefighters protective
clothing will only provide limited protection.
Section 6 - Accidental Release Measures
Personal Precautions
1. Evacuate all unnecessary and unprotected personnel.
2. Keep upwind and keep away from low or confined area.
3. Wear appropriate personal protective equipment as specified in Section 8.
Environmental Precautions
1. Remove all sources of ignition.
2. Stop leak if safe to do so.
Methods for Cleaning up
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DO NOT touch spilled material. Stop leak if without risk.
Small Spill:
1. Absorb with dry sand and earth or other non-combustible materials. Collect the spilled
material in the proper covered disposal containers with labels. .
2. Use plenty of water to rinse the area.
Large Spill:
1. Dike and disposal according to the regulations.
Section 7 - Handling and Storage
Handling
1. Keep away from heat or any source of ignition.
2. Keep away from any incompatibles such as oxidizing agents.
3. Bond and ground transfer containers and equipment to avoid static electricity.
4. Well ventilation.
5. Store in proper covered containers with labels.
Storage
1. Keep away from sunshine.
2. Keep temperature below 35.
3. Keep in a well-ventilated area.
4. Keep away from any sources of ignition.
5. Separated storage, outdoor is recommended.
Section 8 - Exposure Controls & Personal Protection
Engineering measures
1. Use adequate general or local exhaust ventilation to keep airborne concentrations below
the permissible exposure limits.
Control parameters
TWA STEL Ceiling Biological standards
-- -- -- --
Personal protective equipment
Respiratory Protection
If repeated overexposure, appropriate personal respiratory protective equipment is highly
recommended.
Different equipments are required when expose in different concentration.
Wear a full-face organic vapor respirator or chemical cartridge respirator.
For emergency and other conditions where the exposure limit may be greatly exceeded,
use an approved positive-pressure, self-contained breathing apparatus or positive-pressure
airline with auxiliary self-contained air supply.
Hand ProtectionWear chemical protective gloves.
Eye ProtectionSafety glasses should be worn whenever working with chemicals.
Goggles or a face shield are required if there is a chance of splashing. Emergency shower
and eyewash facility nearby.
Skin and Body ProtectionProtective equipment (Level C).
Hygiene measures
1. Immediately change contaminated clothing after work. Appropriate warning before cleaning.
2. Wash hands thoroughly after handling.
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Data Sheet
3. Smoking and eating are prohibited in the work places.
4. Maintain cleanness in the work places.
Section 9 - Physical & Chemical Properties
AppearanceLiquid OdorEster odor
Melting Point: --
ColorTransparent
pH value-- Boiling point/boiling range120
Flammability: -- Flash point 34.5
Decomposition temp-- Test methodclosed
Auto ignition temp-- Explosion properties--
Vapor pressure14.7psi Vapor density--
Density0.93g/cm3(20) SolubilitySoluble in cold water.
log Kow/ Evaporation Rate--
Section 10 - Stability & Reactivity Data
StabilityStable under normal temperature and pressure
Possible hazardous reactions under specific conditions
Oxidizer (strong): may cause fire or explosion.
Conditions to avoid
Static electricity, spark, air, sunshine, moisture
Materials to avoid
Oxidizers
Hazardous decomposition products--
Section 11 - Toxicological Information
Route of exposureInhalationSkinEyeIngestion
Symptomsirritation, headache, vomiting, dizzy
Immediate Toxicity
1. Skin: May be absorbed through skin rapidly.
2. Inhalation: Irritation to eye, nose and throat. Suppression of the nerves system, may
cause headaches, nausea, dizziness, fatigue, body dysfunction, or even unconsciousness.
3. Eye: cause severe irritation, and tear production.
4. Ingestion: Irritation to eye, nose and throat. Suppression of the nerves system may cause
headaches, nausea, dizziness, fatigue, body dysfunction, or even unconsciousness.
Propylene glycol monomethyl ether acetate LD50: 8500 mg/kg (Oralrat)
Propylene glycol monomethyl ether LD50: 5660 mg/kg (Oralrat)
Specific effects --
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Data Sheet
Section 12 - Ecological Information
Ecotoxicology
LC50(fish)--
EC50(Aquatic Invertebrates)--
Bioconcentration factor (BCF)--
Persistence and degradability
Half-Life (Air)--
Half-Life (Water surface)--
Half-Life (Groundwater)--
Half-Life (Soil)--
Bioaccumulative potential--
Mobility in soil--
Other adverse effects--
Section 13 - Disposal Considerations
Methods of disposal
1. Incineration
2. Sanitary Landfill
3. Follow ROC Environmental Laws and Regulations.
Section 14 - MSDS Transport Information
UN classification number1993
Proper D.O.T Shipping Name--
Hazard Class--
Packing Group--
Marine pollution--
Specific precautionary transport measures and conditions--
Section 15 - Regulatory Information
Regulations
1. Regulations for Labor Safety and Health Installations
2. Regulations for Chemical Hazard Communication
3. Road Traffic Safety Regulations
4. Industrial Waste Storage and Disposal Regulations
5. Facility Standards
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Data Sheet
Section 16 - Other Information
1. MSDS from manufacturers or suppliers
2. Chemistry DictionaryGau Lih Book Co., Ltd. 1993-05
3. 1996 North American Emergency Response GuidebookCLA 2000-05
Literature
4. MSDS DatabaseITRI 2000-07
references
5. Class Materials from the Advanced Chemical Hazard Communication for
ExecutorsCLA 2000-08
6. 62000 TLVs and BEIsACGIH
SupplerSan Fu Chemical Co., Ltd. Shan Hua Plant
Address340 Hsiao Hsin Li, Shan Hua Town, Tainan Hsien, Taiwan, R.O.C.
Prepared by
TEL06-5837608 FAX06-5839498
NameChunfel Chang
Issue date 2009/3/19 Revision 1
Symbols Explanations:
"--" No information is available at this time.
Remarks
"/" Not applicable to this substance.
This information above is believed to be accurate and represents the best information
currently available to us. However, we make no warranty of merchantability or any other
warranty, expressed or implied, with respect to such information, and we assume no liability
resulting from its use. Users should make their own investigation to determine the suitability
of the information for their particular purposes. In no event shall San Fu liable for any claims,
losses, or damages of any third party or for lost profits or any special, indirect, incidental,
consequential, or exemplary damages howsoever arising, even if San Fu has been advised of
the possibility of such damages.
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