MATERIAL SAFETY DATA SHEET COMPUBLEND(tm) II BASE R 05/20/2008
Material Safety Data Sheet
Copyright, 2008, 3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly
utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is
obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit
thereon.
SECTION 1: PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: COMPUBLEND(tm) II BASE R
MANUFACTURER: 3M
DIVISION: Building & Commercial Services Division
ADDRESS: 3M Center
St. Paul, MN 55144-1000
EMERGENCY PHONE: 1-800-364-3577 or (651) 737-6501 (24 hours)
Issue Date: 05/20/2008
Supercedes Date: 05/14/2008
Document Group: 11-2037-7
Product Use:
Specific Use: 3M (TM) CompuBlend (TM) II Cleaning System Base Chemical
Intended Use: Hard Surface Cleaner
SECTION 2: INGREDIENTS
Ingredient C.A.S. No. % by Wt
1-METHOXY-2-PROPANOL 107-98-2 40 - 70
2-BUTOXYETHANOL 111-76-2 30 - 60
WATER 7732-18-5 <2
2-methoxy-1-propanol 1589-47-5 < 0.5
ETHYLENE GLYCOL 107-21-1 < 0.5
SECTION 3: HAZARDS IDENTIFICATION
3.1 EMERGENCY OVERVIEW
Specific Physical Form: Liquid
Odor, Color, Grade: Clear blue color, fruity solvent odor
General Physical Form: Liquid
Immediate health, physical, and environmental hazards: Combustible liquid and vapor. Closed containers exposed to heat from
fire may build pressure and explode. Vapors may travel long distances along the ground or floor to an ignition source and flash back.
May cause severe eye irritation. May cause severe skin irritation. May cause target organ effects. Contains a chemical or
chemicals which can cause birth defects or other reproductive harm.
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MATERIAL SAFETY DATA SHEET COMPUBLEND(tm) II BASE R 05/20/2008
3.2 POTENTIAL HEALTH EFFECTS
Eye Contact:
Severe Eye Irritation: Signs/symptoms may include significant redness, swelling, pain, tearing, cloudy appearance of the cornea, and
impaired vision.
Skin Contact:
May be harmful or fatal if absorbed through skin.
Severe Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, dryness, cracking, blistering, and pain.
Inhalation:
May be harmful or fatal if inhaled.
Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and
throat pain.
May be absorbed following inhalation and cause target organ effects.
Ingestion:
May be harmful if swallowed.
Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea.
May be absorbed following ingestion and cause target organ effects.
Target Organ Effects:
Blood Effects: Signs/symptoms may include generalized weakness and fatigue, skin pallor, changes in blood clotting time, internal
bleeding, and/or hemoglobinemia.
Central Nervous System (CNS) Depression: Signs/symptoms may include headache, dizziness, drowsiness, incoordination, nausea,
slowed reaction time, slurred speech, giddiness, and unconsciousness.
Prolonged or repeated exposure may cause:
Kidney/Bladder Effects: Signs/symptoms may include changes in urine production, abdominal or lower back pain, increased
protein in urine, increased blood urea nitrogen (BUN), blood in urine, and painful urination.
Liver Effects: Signs/symptoms may include loss of appetite, weight loss, fatigue, weakness, abdominal tenderness and
jaundice.
Contains a chemical or chemicals which can cause birth defects or other reproductive harm.
SECTION 4: FIRST AID MEASURES
4.1 FIRST AID PROCEDURES
The following first aid recommendations are based on an assumption that appropriate personal and industrial hygiene practices are
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MATERIAL SAFETY DATA SHEET COMPUBLEND(tm) II BASE R 05/20/2008
followed.
Eye Contact: Immediately flush eyes with large amounts of water for at least 15 minutes. Get immediate medical attention.
Skin Contact: Remove contaminated clothing and shoes. Immediately flush skin with large amounts of water. Get medical
attention. Wash contaminated clothing and clean shoes before reuse.
Inhalation: Remove person to fresh air. If signs/symptoms develop, get medical attention.
If Swallowed: Do not induce vomiting unless instructed to do so by medical personnel. Give victim two glasses of water. Never
give anything by mouth to an unconscious person. Get medical attention.
SECTION 5: FIRE FIGHTING MEASURES
5.1 FLAMMABLE PROPERTIES
102 篎 [Test Method: Tagliabue Closed Cup]
Flash Point
Class II Combustible Liquid
OSHA Flammability Classification:
5.2 EXTINGUISHING MEDIA
Use fire extinguishers with class B extinguishing agents (e.g., dry chemical, carbon dioxide).
5.3 PROTECTION OF FIRE FIGHTERS
Special Fire Fighting Procedures: Water may not effectively extinguish fire; however, it should be used to keep fire-exposed
containers and surfaces cool and prevent explosive rupture. Wear full protective equipment (Bunker Gear) and a self-contained
breathing apparatus (SCBA).
Unusual Fire and Explosion Hazards: Combustible liquid and vapor. Closed containers exposed to heat from fire may build
pressure and explode. Vapors may travel long distances along the ground or floor to an ignition source and flash back.
Note: See STABILITY AND REACTIVITY (SECTION 10) for hazardous combustion and thermal decomposition
information.
SECTION 6: ACCIDENTAL RELEASE MEASURES
Accidental Release Measures: Refer to other sections of this MSDS for information regarding physical and health hazards,
respiratory protection, ventilation, and personal protective equipment. Call 3M-HELPS line (1-800-364-3577) for more information
on handling and managing the spill. Evacuate unprotected and untrained personnel from hazard area. The spill should be cleaned up
by qualified personnel. Remove all ignition sources such as flames, smoking materials, and electrical spark sources. Use only non-
sparking tools. Ventilate the area with fresh air. Contain spill. For larger spills, cover drains and build dikes to prevent entry into
sewer systems or bodies of water. Cover spill area with a fire-extinguishing foam designed for use on solvents, such as alcohols and
acetone, that can dissolve in water. An AR - AFFF type foam is recommended. Working from around the edges of the spill inward,
cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears
dry. Remember, adding an absorbent material does not remove a toxic, corrosivity or flammability hazard. Collect as much of the
spilled material as possible using non-sparking tools. Clean up residue with water. Collect the resulting residue containing solution.
Place in a metal container approved for transportation by appropriate authorities. Seal the container. Dispose of collected material as
soon as possible.
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MATERIAL SAFETY DATA SHEET COMPUBLEND(tm) II BASE R 05/20/2008
In the event of a release of this material, the user should determine if the release qualifies as reportable according to
local, state, and federal regulations.
SECTION 7: HANDLING AND STORAGE
7.1 HANDLING
Keep out of the reach of children. This product is not intended to be used without prior dilution as specified on the product label.
Avoid breathing of vapors, mists or spray. Avoid skin contact. Avoid eye contact. Do not eat, drink or smoke when using this
product. Wash exposed areas thoroughly with soap and water. Keep away from heat, sparks, open flame, pilot lights and other sources
of ignition. No smoking while handling this material.
7.2 STORAGE
Store away from areas where product may come into contact with food or pharmaceuticals. Store away from heat. Store out of direct
sunlight.
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
8.1 ENGINEERING CONTROLS
Use in a well-ventilated area. Do not use in a confined area or areas with little or no air movement. NOTE: When used as directed
and diluted and dispensed with a COMPUBLEND (TM) Chemical Dispenser, special ventilation is not required.
8.2 PERSONAL PROTECTIVE EQUIPMENT (PPE)
8.2.1 Eye/Face Protection
Avoid eye contact.
NOTE: When used as directed and diluted and dispensed with a COMPUBLEND (TM) Chemical Dispenser, eye contact with the
concentrate is not expected to occur.
If the product is not used with the Twist 'n Fill system or if there is an accidental release, the following eye protection is
recommended: Indirect Vented Goggles.
8.2.2 Skin Protection
Avoid skin contact.
NOTE: When used as directed and diluted and dispensed with a COMPUBLEND (TM) Chemical Dispenser, skin contact with
the concentrate is not expected to occur.
If the product is not used with the Twist 'n Fill system or if there is an accidental release, select and use gloves and/or protective
clothing to prevent skin contact based on the results of an exposure assessment. Consult with your glove and/or protective clothing
manufacturer for selection of appropriate compatible materials. Gloves made from the following material is recommended: Butyl
Rubber. The following protective clothing material(s) are recommended: Apron - Neoprene.
8.2.3 Respiratory Protection
Avoid breathing of vapors, mists or spray.
NOTE: When used as directed and diluted and dispensed with a COMPUBLEND (TM) Chemical Dispenser, respiratory protection
is not required.
If the product is not used with the COMPUBLEND (TM) system or if there is an accidental release, select one of the following
NIOSH approved respirators based on airborne concentration of contaminants and in accordance with OSHA regulations: Half
facepiece or fullface air-purifying respirator with organic vapor cartridges . Consult the current 3M Respiratory Selection Guide for
additional information or call 1-800-243-4630 for 3M technical assistance.
8.2.4 Prevention of Swallowing
Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water.
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MATERIAL SAFETY DATA SHEET COMPUBLEND(tm) II BASE R 05/20/2008
8.3 EXPOSURE GUIDELINES
Ingredient Authority Type Limit Additional Information
1-METHOXY-2-PROPANOL ACGIH TWA 100 ppm
1-METHOXY-2-PROPANOL ACGIH STEL 150 ppm
1-METHOXY-2-PROPANOL OSHA TWA 100 ppm Table Z-1A
1-METHOXY-2-PROPANOL OSHA STEL 150 ppm Table Z-1A
2-BUTOXYETHANOL ACGIH TWA 20 ppm Table A3
2-BUTOXYETHANOL OSHA TWA, Vacated 25 ppm Skin Notation*
2-BUTOXYETHANOL OSHA TWA 50 ppm Skin Notation*; Table Z-1
ETHYLENE GLYCOL ACGIH CEIL, as aerosol 100 mg/m3 Table A4
ETHYLENE GLYCOL CMRG CEIL, as vapor and 100 mg/m3
aerosol
ETHYLENE GLYCOL OSHA CEIL 50 ppm Table Z-1A
* Substance(s) refer to the potential contribution to the overall exposure by the cutaneous route including mucous membrane and eye,
either by airborne or, more particularly, by direct contact with the substance. Vehicles can alter skin absorption.
VAC Vacated PEL:Vacated Permissible Exposure Limits [PEL] are enforced as the OSHA PEL in some states. Check with your local
regulatory agency.
SOURCE OF EXPOSURE LIMIT DATA:
ACGIH: American Conference of Governmental Industrial Hygienists
CMRG: Chemical Manufacturer Recommended Guideline
OSHA: Occupational Safety and Health Administration
AIHA: American Industrial Hygiene Association Workplace Environmental Exposure Level (WEEL)
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
Liquid
Specific Physical Form:
Clear blue color, fruity solvent odor
Odor, Color, Grade:
Liquid
General Physical Form:
102 篎 [Test Method: Tagliabue Closed Cup]
Flash Point
Approximately 190 篎
Boiling point
<=27 psia [@ 131 篎]
Vapor Pressure
Approximately 0.9 [Ref Std: WATER=1]
Specific Gravity
Approximately 5.3
pH
Complete
Solubility in Water
Approximately 100 % weight [Test Method: calculated per CARB
Volatile Organic Compounds
title 2]
Approximately 100 % weight
Percent volatile
Approximately 1000 g/l [Test Method: calculated per CARB title 2]
VOC Less H2O & Exempt Solvents
< 100 centipoise
Viscosity
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MATERIAL SAFETY DATA SHEET COMPUBLEND(tm) II BASE R 05/20/2008
SECTION 10: STABILITY AND REACTIVITY
Stability: Stable.
Materials and Conditions to Avoid: Sparks and/or flames
Hazardous Polymerization: Hazardous polymerization will not occur.
Hazardous Decomposition or By-Products
Substance Condition
Carbon monoxide Not Specified
Carbon dioxide Not Specified
Hazardous Decomposition: Under recommended usage conditions, hazardous decomposition products are not expected. Hazardous
decomposition products may occur as a result of oxidation, heating, or reaction with another material.
SECTION 11: TOXICOLOGICAL INFORMATION
Please contact the address listed on the first page of the MSDS for Toxicological Information on this material and/or its
components.
SECTION 12: ECOLOGICAL INFORMATION
ECOTOXICOLOGICAL INFORMATION
A 3M Product Environmental Data Sheet (PED) is available.
CHEMICAL FATE INFORMATION
A 3M Product Environmental Data Sheet (PED) is available.
SECTION 13: DISPOSAL CONSIDERATIONS
Waste Disposal Method: Incinerate in a permitted hazardous waste incinerator. As a disposal alternative, dispose of waste product
in a permitted hazardous waste facility.
EPA Hazardous Waste Number (RCRA): D001 (Ignitable)
Since regulations vary, consult applicable regulations or authorities before disposal.
SECTION 14:TRANSPORT INFORMATION
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MATERIAL SAFETY DATA SHEET COMPUBLEND(tm) II BASE R 05/20/2008
Please contact the emergency numbers listed on the first page of the MSDS for Transportation Information for this
material.
SECTION 15: REGULATORY INFORMATION
US FEDERAL REGULATIONS
311/312 Hazard Categories:
Fire Hazard - Yes Pressure Hazard - No Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - Yes
Section 313 Toxic Chemicals subject to the reporting requirements of that section and 40 CFR part 372 (EPCRA):
Ingredient C.A.S. No % by Wt
2-BUTOXYETHANOL (GLYCOL ETHERS) 111-76-2 30 - 60
STATE REGULATIONS
CHEMICAL INVENTORIES
The components of this product are in compliance with the chemical notification requirements of TSCA.
All applicable chemical ingredients in this material are listed on the European Inventory of Existing Chemical Substances (EINECS),
or are exempt polymers whose monomers are listed on EINECS.
The components of this product are listed on the Australian Inventory of Chemical Substances.
The components of this product are listed on the Canadian Domestic Substances List.
INTERNATIONAL REGULATIONS
This MSDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200.
SECTION 16: OTHER INFORMATION
NFPA Hazard Classification
Health: 2 Flammability: 2 Reactivity: 0 Special Hazards: None
National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are
presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the
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MATERIAL SAFETY DATA SHEET COMPUBLEND(tm) II BASE R 05/20/2008
inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to
be generated in significant quantities.
HMIS Hazard Classification
Health: 2 Flammability: 2 Reactivity: 0 Protection: X - See PPE section.
Hazardous Material Identification System (HMIS(r)) hazard ratings are designed to inform employees of chemical hazards in the workplace. These
ratings are based on the inherent properties of the material under expected conditions of normal use and are not intended for use in emergency
situations. HMIS(r) ratings are to be used with a fully implemented HMIS(r) program. HMIS(r) is a registered mark of the National Paint and
Coatings Association (NPCA).
Revision Changes:
Section 9: Property description for optional properties was modified.
Section 2: Ingredient table was modified.
DISCLAIMER: The information in this Material Safety Data Sheet (MSDS) is believed to be correct as of the date issued. 3M
MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY
OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF
TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of
use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely
within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a
particular purpose and suitable for user's method of use or application.
3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may
have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy.
In addition, information obtained from a database may not be as current as the information in the MSDS available directly from 3M.
3M MSDSs are available at www.3M.com
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