Page 1/8
Safety Data Sheet
according to 1907/2006/EC, Article 31
Printing date 26.08.2008 Revision: 26.08.2008
1 Identification of the substance/preparation and of the company/undertaking
?Product details
?Trade name: SR101-SR104 Fast Reducer
?Article number: SR101, SR104
?Application of the substance / the preparation diluent
?Manufacturer/Supplier:
SEM Products Inc.
651 Michael Wylie Dr.
Charlotte, NC 28217
(704)522-1006
?Further information obtainable from:
labsupport@sem.ws : SEM Products 651 Michael Wylie Dr. Charlotte, NC 28217 : phone 1-704-522-1006, M -
TH 7am - 4pm EDT
?Information in case of emergency: 24 HR EMERGENCY CHEMTREC 1-800-424-9300
2 Hazards identification
?Hazard description:
Xn Harmful
F Highly flammable
?Information concerning particular hazards for human and environment:
The product has to be labelled due to the calculation procedure of the "General Classification guideline for
preparations of the EU" in the latest valid version.
Has a narcotizing effect.
R 11 Highly flammable.
R 36/37/38 Irritating to eyes, respiratory system and skin.
R 48 Danger of serious damage to health by prolonged exposure.
R 63 Possible risk of harm to the unborn child.
R 65 Harmful: may cause lung damage if swallowed.
R 67 Vapours may cause drowsiness and dizziness.
?Classification system:
The classification is according to the latest editions of the EU-lists, and extended by company and literature data.
?GHS label elements
Danger
2.6/2 - Highly flammable liquid and vapour.
Danger
3.10/1 - May be fatal if swallowed and enters airways.
3.7/2 - Suspected of damaging fertility or the unborn child.
Warning
3.2/2 - Causes skin irritation.
3.3/2A - Causes serious eye irritation.
3.8/3 - May cause respiratory irritation. May cause drowsiness or dizziness.
(Contd. on page 2)
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Page 2/8
Safety Data Sheet
according to 1907/2006/EC, Article 31
Printing date 26.08.2008 Revision: 26.08.2008
Trade name: SR101-SR104 Fast Reducer
(Contd. of page 1)
?Prevention:
Obtain special instructions before use.
Do not handle until all safety precautions have been read and understood.
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
Keep container tightly closed.
Ground/bond container and receiving equipment.
Use explosion-proof electrical/ventilating/lighting/ equipment.
Use only non-sparking tools.
Take precautionary measures against static discharge.
Avoid breathing dust/fume/gas/mist/vapours/spray.
Wash thoroughly after handling.
Use only outdoors or in a well-ventilated area.
Wear protective gloves/protective clothing/eye protection/face protection.
Use personal protective equipment as required.
?Response:
IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
IF ON SKIN: Wash with plenty of soap and water.
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
IF exposed or concerned: Get medical advice/attention.
Call a POISON CENTER or doctor/physician if you feel unwell.
Specific treatment (see label).
Do NOT induce vomiting.
If skin irritation occurs: Get medical advice/attention.
If eye irritation persists: Get medical advice/attention.
Take off contaminated clothing and wash before reuse.
In case of fire: Use for extinction: CO2, powder or water spray.
?Storage:
Store in a well-ventilated place. Keep container tightly closed.
Store in a well-ventilated place. Keep cool.
Store locked up.
?Disposal:
Dispose of contents/container in accordance with local/regional/national/international regulations.
3 Composition/information on ingredients
?Chemical characterization
?Description: Mixture of substances listed below with nonhazardous additions.
?Dangerous components:
CAS: 123-86-4 n-butyl acetate 40 - 60%
EINECS: 204-658-1 R 10-66-67
Warning: 2.6/3; 3.8/3
CAS: 108-65-6 2-methoxy-1-methylethyl acetate 13 - 30%
EINECS: 203-603-9 Xi; R 10-36
Warning: 2.6/3; 3.3/2A
(Contd. on page 3)
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Safety Data Sheet
according to 1907/2006/EC, Article 31
Printing date 26.08.2008 Revision: 26.08.2008
Trade name: SR101-SR104 Fast Reducer
(Contd. of page 2)
CAS: 108-88-3 toluene 10 -13%
EINECS: 203-625-9 Xn, Xi, F; R 11-36/37/38-48-63-65-67
Danger: 2.6/2; 3.10/1, 3.7/2
Warning: 3.2/2, 3.3/2A, 3.8/3
CAS: 67-64-1 acetone 10 -13%
EINECS: 200-662-2 Xi, F; R 11-36-66-67
Danger: 2.6/2
Warning: 3.3/2A, 3.8/3
CAS: 107-98-2 1-methoxy-2-propanol 5 - 7%
EINECS: 203-539-1 R 10
Warning: 2.6/3
?Additional information: For the wording of the listed risk phrases refer to section 16.
4 First aid measures
?After inhalation: In case of unconsciousness place patient stably in side position for transportation.
?After skin contact: Immediately wash with water and soap and rinse thoroughly.
?After eye contact:
Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor.
?After swallowing: If symptoms persist consult doctor.
5 Fire-fighting measures
?Suitable extinguishing agents: CO2, sand, extinguishing powder. Do not use water.
?For safety reasons unsuitable extinguishing agents: Water with full jet
?Protective equipment: No special measures required.
6 Accidental release measures
?Person-related safety precautions: Wear protective equipment. Keep unprotected persons away.
?Measures for environmental protection:
Do not allow product to reach sewage system or any water course.
Inform respective authorities in case of seepage into water course or sewage system.
Do not allow to enter sewers/ surface or ground water.
?Measures for cleaning/collecting:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Dispose contaminated material as waste according to item 13.
Ensure adequate ventilation.
Do not flush with water or aqueous cleansing agents
7 Handling and storage
?Handling:
?Information for safe handling:
Ensure good ventilation/exhaustion at the workplace.
Prevent formation of aerosols.
?Information about fire - and explosion protection:
Keep ignition sources away - Do not smoke.
(Contd. on page 4)
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Safety Data Sheet
according to 1907/2006/EC, Article 31
Printing date 26.08.2008 Revision: 26.08.2008
Trade name: SR101-SR104 Fast Reducer
(Contd. of page 3)
Protect against electrostatic charges.
?Storage:
?Requirements to be met by storerooms and receptacles: Store in a cool location.
?Information about storage in one common storage facility: Not required.
?Further information about storage conditions:
Keep container tightly sealed.
Store in cool, dry conditions in well sealed receptacles.
8 Exposure controls/personal protection
?Additional information about design of technical facilities: No further data; see item 7.
?Ingredients with limit values that require monitoring at the workplace:
123-86-4 n-butyl acetate
WEL Short-term value: 966 mg/m? 200 ppm
Long-term value: 724 mg/m? 150 ppm
108-65-6 2-methoxy-1-methylethyl acetate
WEL Short-term value: 548 mg/m? 100 ppm
Long-term value: 274 mg/m? 50 ppm
Sk
108-88-3 toluene
WEL Short-term value: 384 mg/m? 100 ppm
Long-term value: 191 mg/m? 50 ppm
Sk
67-64-1 acetone
WEL Short-term value: 3620 mg/m? 1500 ppm
Long-term value: 1210 mg/m? 500 ppm
107-98-2 1-methoxy-2-propanol
WEL Short-term value: 560 mg/m? 150 ppm
Long-term value: 375 mg/m? 100 ppm
Sk
?Additional information: The lists valid during the making were used as basis.
?Personal protective equipment:
?General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing
Wash hands before breaks and at the end of work.
Avoid contact with the eyes and skin.
?Respiratory protection:
In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use
self-contained respiratory protective device.
?Protection of hands:
Protective gloves
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
(Contd. on page 5)
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Safety Data Sheet
according to 1907/2006/EC, Article 31
Printing date 26.08.2008 Revision: 26.08.2008
Trade name: SR101-SR104 Fast Reducer
(Contd. of page 4)
Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the
chemical mixture.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation
?Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and
varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance
of the glove material can not be calculated in advance and has therefore to be checked prior to the application.
?Penetration time of glove material
The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be
observed.
?Eye protection:
Tightly sealed goggles
9 Physical and chemical properties
?General Information
Liquid
Form:
According to product specification
Colour:
Characteristic
Odour:
?Change in condition
Melting point/Melting range: Undetermined.
Boiling point/Boiling range: 56癈
-19癈
?Flash point:
270癈
?Ignition temperature:
Product is not selfigniting.
?Self-igniting:
In use, may form flammable/explosive vapour-air mixture.
?Danger of explosion:
?Explosion limits:
1.2 Vol %
Lower:
13.0 Vol %
Upper:
233 hPa
?Vapour pressure at 20癈:
0.887 g/cm?br>
?Density at 20癈:
?Solubility in / Miscibility with
Not miscible or difficult to mix.
water:
?Solvent content:
100.0 %
Organic solvents:
900.4 g/l
VOC (EC)
900.4 g/l
10 Stability and reactivity
?Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications.
(Contd. on page 6)
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Safety Data Sheet
according to 1907/2006/EC, Article 31
Printing date 26.08.2008 Revision: 26.08.2008
Trade name: SR101-SR104 Fast Reducer
(Contd. of page 5)
?Dangerous reactions No dangerous reactions known.
?Dangerous decomposition products: No dangerous decomposition products known.
11 Toxicological information
?Acute toxicity:
?LD/LC50 values relevant for classification:
108-88-3 toluene
Oral LD50 5000 mg/kg (rat)
Dermal LD50 12124 mg/kg (rabbit)
Inhalative LC50/4 h 5320 mg/l (mouse)
?Primary irritant effect:
?on the skin: Irritant to skin and mucous membranes.
?on the eye: Irritating effect.
?Sensitization: No sensitizing effects known.
?Additional toxicological information:
The product shows the following dangers according to the calculation method of the General EU Classification
Guidelines for Preparations as issued in the latest version:
Irritant
12 Ecological information
?General notes:
Water hazard class 2 (German Regulation) (Self-assessment): hazardous for water
Do not allow product to reach ground water, water course or sewage system.
Danger to drinking water if even small quantities leak into the ground.
13 Disposal considerations
?Product:
?Recommendation
Must not be disposed together with household garbage. Do not allow product to reach sewage system.
?Uncleaned packaging:
?Recommendation: Disposal must be made according to official regulations.
14 Transport information
?Land transport ADR/RID (cross-border)
3 Flammable liquids.
?ADR/RID class:
?Danger code (Kemler): 33
1263
?UN-Number:
(Contd. on page 7)
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Safety Data Sheet
according to 1907/2006/EC, Article 31
Printing date 26.08.2008 Revision: 26.08.2008
Trade name: SR101-SR104 Fast Reducer
(Contd. of page 6)
II
?Packaging group:
3
?Hazard label:
?Description of goods: 1263 PAINT, special provision 640D
?Maritime transport IMDG:
3
?IMDG Class:
1263
?UN Number:
3
?Label
II
?Packaging group:
F-E,S-E
?EMS Number:
No
?Marine pollutant:
?Proper shipping name: PAINT
?Air transport ICAO-TI and IATA-DGR:
3
?ICAO/IATA Class:
1263
?UN/ID Number:
3
?Label
II
?Packaging group:
?Proper shipping name: PAINT
?UN "Model Regulation": UN1263, PAINT, 3, II
15 Regulatory information
?Labelling according to EU guidelines:
The product has been classified and marked in accordance with EU Directives / Ordinance on Hazardous
Materials.
?Code letter and hazard designation of product:
Xn Harmful
F Highly flammable
?Hazard-determining components of labelling:
toluene
?Risk phrases:
11 Highly flammable.
36/37/38 Irritating to eyes, respiratory system and skin.
48 Danger of serious damage to health by prolonged exposure.
63 Possible risk of harm to the unborn child.
65 Harmful: may cause lung damage if swallowed.
67 Vapours may cause drowsiness and dizziness.
(Contd. on page 8)
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Safety Data Sheet
according to 1907/2006/EC, Article 31
Printing date 26.08.2008 Revision: 26.08.2008
Trade name: SR101-SR104 Fast Reducer
(Contd. of page 7)
?Safety phrases:
2 Keep out of the reach of children.
29/56 Do not empty into drains, dispose of this material and its container at hazardous or special waste
collection point.
36/37 Wear suitable protective clothing and gloves.
46 If swallowed, seek medical advice immediately and show this container or label.
16 Other information
This information is based on our present knowledge. However, this shall not constitute a guarantee for any
specific product features and shall not establish a legally valid contractual relationship.
?Relevant R-phrases
10 Flammable.
11 Highly flammable.
36 Irritating to eyes.
36/37/38 Irritating to eyes, respiratory system and skin.
48 Danger of serious damage to health by prolonged exposure.
63 Possible risk of harm to the unborn child.
65 Harmful: may cause lung damage if swallowed.
66 Repeated exposure may cause skin dryness or cracking.
67 Vapours may cause drowsiness and dizziness.
?Department issuing MSDS: Environment protection department.
?Contact: Steve Gaver
?Abbreviations and acronyms:
ADR: Accord europ閑n sur le transport des marchandises Dangereuses par Route (European Agreement concerning the International
Carriage of Dangerous Goods by Road)
RID: Reglement internationale concernent le transport des merchandises dangereuses par chemin de fer (Regulations Concerning the
International Transport of Dangerous Goods by Rail)
IMDG: International Maritime Code for Dangerous Goods
IATA: International Air Transport Association
IATA-DGR: Dangerous Goods Regulations by the "International Air Transport Association" (IATA)
ICAO: International Civil Aviation Organization
ICAO-TI: Technical Instructions by the "International Civil Aviation Organization" (ICAO)
GHS: Globally Harmonized System of Classification and Labelling of Chemicals
VOC: Volatile Organic Compounds (USA, EU)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
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