Safety data sheet
Page: 1/9
Elastogran Safety data sheet according to 91/155/EEC
Date / Revised: 19.09.2005 Version: 1.0
Product: LINE-X XS-100 RESIN
(30158046/SDS_GEN_GB/EN)
Date of print 19.09.2005
1. Substance/preparation and company identification
LINE-X XS-100 RESIN
Use: Chemical
Company:
Elastogran GmbH
Postfach 1140
D-49440 Lemfoerde
Telephone: +49-5443/122121
Telefax number: +49-5443/122090
Emergency information:
BASF Werkfeuerwehr Ludwigshafen
Telephone: +49-621/60-43333
Telefax number: +49-621/60-92664
2. Composition/information on ingredients
Chemical nature
Preparation based on: polyol, catalyst, additives
Hazardous ingredients
diethylmethylbenzenediamine
Content (W/W): >= 5 % - < 10 %
CAS Number: 68479-98-1
EC-Number: 270-877-4
INDEX-Number: 612-130-00-0
Hazard symbol(s): Xn, N
R-phrase(s): 21/22, 36, 48/22, 50/53
Polyetherdiamin
Content (W/W): >= 10 % - < 20 %
CAS Number: 9046-10-0
Hazard symbol(s): C
R-phrase(s): 34, 22, 52/53
Page: 2/9
Elastogran Safety data sheet according to 91/155/EEC
Date / Revised: 19.09.2005 Version: 1.0
Product: LINE-X XS-100 RESIN
(30158046/SDS_GEN_GB/EN)
Date of print 19.09.2005
ethyleneglycol
Content (W/W): >= 3 % - <= 10 %
CAS Number: 107-21-1
EC-Number: 203-473-3
INDEX-Number: 603-027-00-1
Hazard symbol(s): Xn
R-phrase(s): 22
Diethylene glycol
Content (W/W): >= 3 % - <= 10 %
CAS Number: 111-46-6
EC-Number: 203-872-2
Hazard symbol(s): Xn
R-phrase(s): 22
The wording of the hazard symbols and R-phrases is specified in chapter 16 if dangerous ingredients
are mentioned.
3. Hazard identification
Harmful if swallowed.
Causes burns.
Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
4. First-aid measures
General advice:
Remove contaminated clothing.
If inhaled:
If difficulties occur after vapour/aerosol has been inhaled, remove to fresh air and seek medical
attention.
On skin contact:
Wash thoroughly with soap and water.
On contact with eyes:
Immediately wash affected eyes for at least 15 minutes under running water with eyelids held open,
consult an eye specialist.
On ingestion:
Immediately rinse mouth and then drink plenty of water, do not induce vomiting, seek medical
attention.
Page: 3/9
Elastogran Safety data sheet according to 91/155/EEC
Date / Revised: 19.09.2005 Version: 1.0
Product: LINE-X XS-100 RESIN
(30158046/SDS_GEN_GB/EN)
Date of print 19.09.2005
5. Fire-fighting measures
Suitable extinguishing media:
water, dry extinguishing media, foam, carbon dioxide
Specific hazards:
carbon monoxide, carbon dioxide, nitrogen oxides
The substances/groups of substances mentioned can be released in case of fire.
Special protective equipment:
Wear a self-contained breathing apparatus.
Further information:
Dispose of fire debris and contaminated extinguishing water in accordance with official regulations.
6. Accidental release measures
Personal precautions:
Use personal protective clothing.
Environmental precautions:
Do not empty into drains. Do not discharge into the subsoil/soil.
Methods for cleaning up or taking up:
For large amounts: Pump off product.
For residues: Pick up with suitable absorbent material (e.g. sand, sawdust, general-purpose binder,
kieselguhr). Dispose of contaminated material as prescribed.
Additional information: High risk of slipping due to leakage/spillage of product.
7. Handling and storage
Handling
Ensure thorough ventilation of stores and work areas.
Protection against fire and explosion:
No special precautions necessary.
Storage
Segregate from foods and animal feeds. Segregate from acids. Segregate from oxidants.
Further information on storage conditions: Containers should be stored tightly sealed in a dry place.
Information concerning the compliance to the Packaging (Essential Requirements) Regulations 1998
and their amendments may be obtained from the manufacturer.
Page: 4/9
Elastogran Safety data sheet according to 91/155/EEC
Date / Revised: 19.09.2005 Version: 1.0
Product: LINE-X XS-100 RESIN
(30158046/SDS_GEN_GB/EN)
Date of print 19.09.2005
8. Exposure controls and personal protection
Components with workplace control parameters
107-21-1: ethyleneglycol
TWA value 52 mg/m3 ; 20 ppm (OEL (EU))
STEL value 104 mg/m3 ; 40 ppm (OEL (EU))
Skin Designation (OEL (EU))
The substance can be absorbed through the skin.
TWA value 10 mg/m3 (EH40 (UK))
TWA value 52 mg/m3 ; 20 ppm (EH40 (UK))
STEL value 104 mg/m3 ; 40 ppm (EH40 (UK))
Skin Designation (EH40 (UK))
The substance can be absorbed through the skin.
Skin Designation (EH40 (UK))
The substance can be absorbed through the skin.
111-46-6: Diethylene glycol
TWA value 101 mg/m3 ; 23 ppm (EH40 (UK))
Personal protective equipment
Respiratory protection:
Wear respiratory protection if ventilation is inadequate.
Hand protection:
Suitable chemical resistant safety gloves (EN 374) also with prolonged, direct contact
(Recommended: Protective index 6, corresponding > 480 minutes of permeation time according to
EN 374): E.g. nitrile rubber (0.4 mm), chloroprene rubber (0.5 mm), polyvinylchloride (0.7 mm) and
other
Eye protection:
Safety glasses with side-shields (frame goggles) (EN 166)
General safety and hygiene measures:
Avoid contact with the skin, eyes and clothing. Wearing of closed work clothing is required
additionally to the stated personal protection equipment. When using, do not eat, drink or smoke.
Hands and/or face should be washed before breaks and at the end of the shift. At the end of the shift
the skin should be cleaned and skin-care agents applied.
9. Physical and chemical properties
Form: liquid
Colour: bronze to gold, clear
Odour: mild, almost odourless
solidification temperature: < 0 癈
Flash point: approx. 93.3 癈 (Unspecified)
Page: 5/9
Elastogran Safety data sheet according to 91/155/EEC
Date / Revised: 19.09.2005 Version: 1.0
Product: LINE-X XS-100 RESIN
(30158046/SDS_GEN_GB/EN)
Date of print 19.09.2005
Ignition temperature:
No data available.
Vapour pressure: < 10 mbar
(20 癈)
Density: > 1.0 g/cm3 (DIN 51757)
(20 癈)
Miscibility with water:
moderately soluble
Viscosity, dynamic: 912 mPa.s
(25 癈)
10. Stability and reactivity
Thermal decomposition: No decomposition if stored and handled as
prescribed/indicated.
Substances to avoid:
acids, oxidizing agent, isocyanates
11. Toxicological information
Information on: diethylmethylbenzenediamine
LD50/oral/rat: 738 mg/kg (OECD Guideline 401)
Information on: Polyetherdiamin
LD50/oral/rat: 480 mg/kg
----------------------------------
Information on: Polyetherdiamin
Primary skin irritation/rabbit: Corrosive. (Draize test)
----------------------------------
Information on: diethylmethylbenzenediamine
Primary irritations of the mucous membrane/rabbit: Irritant.
Information on: Polyetherdiamin
Primary irritations of the mucous membrane/rabbit: Irritant. (Draize test)
----------------------------------
Page: 6/9
Elastogran Safety data sheet according to 91/155/EEC
Date / Revised: 19.09.2005 Version: 1.0
Product: LINE-X XS-100 RESIN
(30158046/SDS_GEN_GB/EN)
Date of print 19.09.2005
Additional information:
The product has not been tested. The statement has been derived from products of a similar
structure and composition.
12. Ecological information
Ecotoxicity
Information on: diethylmethylbenzenediamine
Toxicity to fish:
DIN 38412 Part 15
Leuciscus idus/LC50 (48 h): 194 mg/l
----------------------------------
Information on: diethylmethylbenzenediamine
Aquatic invertebrates:
OECD Guideline 202, part 1
Daphnia magna/EC50 (48 h): < 1 mg/l
----------------------------------
Information on: diethylmethylbenzenediamine
Microorganisms/Effect on activated sludge:
DIN 38412 Part 8
Pseudomonas sp./EC50 (16 h): 170 mg/l
----------------------------------
Persistence and degradability
Elimination information
Evaluation: Poorly biodegradable.
Information on: diethylmethylbenzenediamine
Test method: OECD 301D; EEC 92/69, C.4-E
Degree of elimination: < 1.0 % (28 d)
Evaluation: Not readily biodegradable (by OECD criteria).
----------------------------------
Other adverse effects
Adsorbable organically-bound halogen (AOX):
This product contains no organically-bound halogen.
Additional information
Page: 7/9
Elastogran Safety data sheet according to 91/155/EEC
Date / Revised: 19.09.2005 Version: 1.0
Product: LINE-X XS-100 RESIN
(30158046/SDS_GEN_GB/EN)
Date of print 19.09.2005
Other ecotoxicological advice:
Do not allow to enter soil, waterways or waste water channels. Inhibition of degradation activity in
activated sludge is not to be anticipated during correct introduction of low concentrations. The
product has not been tested. The statement has been derived from products of a similar structure
and composition.
13. Disposal considerations
Incinerate in suitable incineration plant, observing local authority regulations.
The UK Environmental Protection (Duty of Care) Regulations (EP) and amendments should be noted
(United Kingdom).
When disposed of the product will have the hazardous properties H5, H8, H14, as defined in the
Special Waste Regulations and amendments.
Waste key:
07 02 08?other still bottoms and reaction residues
Contaminated packaging:
Contaminated packaging should be emptied as far as possible; then it can be passed on for
recycling after being thoroughly cleaned.
14. Transport information
Not classified as hazardous under transport regulations ( ADR RID ADNR IMDG/GGVSee
ICAO/IATA )
15. Regulatory information
Regulations of the European union (Labelling) / National legislation/Regulations
Directive 1999/45/EC ('Preparation Directive'):
Hazard symbol(s)
C Corrosive.
N Dangerous for the environment.
R-phrase(s)
R22 Harmful if swallowed.
R34 Causes burns.
R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.
S-phrase(s)
Page: 8/9
Elastogran Safety data sheet according to 91/155/EEC
Date / Revised: 19.09.2005 Version: 1.0
Product: LINE-X XS-100 RESIN
(30158046/SDS_GEN_GB/EN)
Date of print 19.09.2005
S36/37/39 Wear suitable protective clothing, gloves and eye/face protection.
S26 In case of contact with eyes, rinse immediately with plenty of water and
seek medical advice.
S27 Take off immediately all contaminated clothing.
S28.1 After contact with skin, wash immediately with plenty of water and soap.
S45 In case of accident or if you feel unwell, seek medical advice
immediately (show the label where possible).
S61 Avoid release to the environment. Refer to special instructions/safety
data sheets.
Hazard determinant component(s) for labelling: diethylmethylbenzenediamine, Polyetherdiamin
Other regulations
The data should be considered when making any assessment under the Control of Substances
Hazardous to Health Regulations (COSHH), and related guidance, for example, 'COSHH Essentials'
(United Kingdom).
This product is classified under the Chemicals (Hazard Information and Packaging) Regulations,
(CHIP) (United Kingdom).
This product is not classified as dangerous for transport according to Carriage of Dangerous Goods
and Use of Transportable Pressure 2004.
16. Other information
Recommended use: polyurethane component
Full text of hazard symbols and R-phrases if mentioned as hazardous components in chapter 2:
Xn Harmful.
N Dangerous for the environment.
C Corrosive.
21/22 Harmful in contact with skin and if swallowed.
36 Irritating to eyes.
48/22 Harmful: danger of serious damage to health by prolonged exposure if
swallowed.
50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in
the aquatic environment.
34 Causes burns.
22 Harmful if swallowed.
52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.
Vertical lines in the left hand margin indicate an amendment from the previous version.
Page: 9/9
Elastogran Safety data sheet according to 91/155/EEC
Date / Revised: 19.09.2005 Version: 1.0
Product: LINE-X XS-100 RESIN
(30158046/SDS_GEN_GB/EN)
Date of print 19.09.2005
The data contained in this safety data sheet are based on our current knowledge and
experience and describe the product only with regard to safety requirements. The data
do not describe the product's properties (product specification). Neither should any
agreed property nor the suitability of the product for any specific purpose be deduced
from the data contained in the safety data sheet. It is the responsibility of the recipient of
the product to ensure any proprietary rights and existing laws and legislation are
observed.
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