Safety Data Sheet
Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - Germany
1. Identification of the substance/preparation and of the
company/undertaking
Identification of the substance or preparation
Product name or Trade name :
Sika-Trocal C 300
Use of the substance/preparation : Chemical product for construction and industry
Company/undertaking identification
Manufacturer/Distributor : Sika Deutschland GmbH
Street/postbox : Kornwestheimer Str. 103-107
Town/City and Post Code : 70439 Stuttgart
Country : Germany
Telephone no. : +4971180090
Fax no. : +497118009321
e-mail address of person : EHS@de.sika.com
responsible for this SDS
Emergency telephone number : +49-(0)173-6774799 (Only out of office hour)
2. Hazards identification
The preparation is classified as dangerous according to Directive 1999/45/EC and its amendments.
: F; R11
Classification
Xi; R36
R42/43, R67
N; R51/53
Physical/chemical hazards : Highly flammable.
: Irritating to eyes. May cause sensitisation by inhalation and skin contact. Vapours
Human health hazards
may cause drowsiness and dizziness.
: Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic
Environmental hazards
environment.
: Contains isocyanates. See information supplied by the manufacturer.
Additional warning phrases
See section 11 for more detailed information on health effects and symptoms.
3. Composition/information on ingredients
Chemical family/ : Polyisocyanate, containing solvent
Characteristics
Ingredient name CAS number % EC number Classification
methyl acetate 79-20-9 10-15 201-185-2 F; R11 [1] [2]
Xi; R36
R66, R67
F; R11 [1] [2]
cyclohexane 110-82-7 5-10 203-806-2
Xn; R65
Xi; R38
R67
N; R50/53
Xn; R20 [1]
Diphenylmethanediisocyanate, isomeres and 9016-87-9 1-5
Xi; R36/37/38
homologues
R42/43
See section 16 for the full text of the R-
phrases declared above
Date of issue : 13.11.2007. MSDS no. : 29773 1/6
Sika-Trocal C 300 13.11.2007 2/6
3. Composition/information on ingredients
[1] Substance classified with a health or environmental hazard
[2] Substance with a workplace exposure limit
Occupational exposure limits, if available, are listed in section 8.
4. First-aid measures
First-aid measures
: If it is suspected that fumes are still present, the rescuer should wear an appropriate
Inhalation
mask or self-contained breathing apparatus. Get medical attention if adverse health
effects persist or are severe. Get medical attention if symptoms appear.
: Do not induce vomiting unless directed to do so by medical personnel. Maintain an
Ingestion
open airway. Seek immediate medical attention.
: Flush contaminated skin with plenty of water. Remove contaminated clothing and
Skin contact
shoes. Wash contaminated clothing thoroughly with water before removing or wear
gloves. Continue to rinse for at least 10 minutes. Obtain medical attention if
symptoms occur.
: Immediately flush eyes with plenty of water, occasionally lifting the upper and lower
Eye contact
eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10
minutes. Get medical attention.
: No specific treatment. Treat symptomatically. Contact poison treatment specialist
Notes to physician
immediately if large quantities have been ingested or inhaled.
See section 11 for more detailed information on health effects and symptoms.
5. Fire-fighting measures
Extinguishing media
: Use dry chemical, CO2, water spray (fog) or foam.
Suitable
: Do not use water jet.
Not suitable
: Highly flammable liquid. In a fire or if heated, a pressure increase will occur and the
Special exposure hazards
container may burst, with the risk of a subsequent explosion. Runoff to sewer may
create fire or explosion hazard.
: Decomposition products may include the following materials:
Hazardous combustion
carbon oxides
products
: Fire-fighters should wear appropriate protective equipment and self-contained
Special protective
breathing apparatus (SCBA) with a full face-piece operated in positive pressure
equipment for fire-fighters
mode.
6. Accidental release measures
: Keep unnecessary and unprotected personnel from entering. Do not touch or walk
Personal precautions
through spilt material. Shut off all ignition sources. No flares, smoking or flames in
hazard area. Put on appropriate personal protective equipment (see section 8).
Evacuate surrounding areas.
: Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains
Environmental precautions
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air). Water polluting material. May be harmful to
the environment if released in large quantities.
: Stop leak if without risk. Move containers from spill area. Prevent entry into sewers,
Large spill
water courses, basements or confined areas. Wash spillages into an effluent
treatment plant or proceed as follows. Contain and collect spillage with non-
combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth
and place in container for disposal according to local regulations (see section 13).
Use spark-proof tools and explosion-proof equipment.
: Stop leak if without risk. Move containers from spill area. Absorb with an inert
Small spill
material and place in an appropriate waste disposal container. Use spark-proof tools
and explosion-proof equipment.
Date of issue : 13.11.2007. MSDS no. : 29773 2/6
Sika-Trocal C 300 13.11.2007 3/6
7. Handling and storage
: Put on appropriate personal protective equipment (see section 8). Eating, drinking
Handling
and smoking should be prohibited in areas where this material is handled, stored and
processed. Workers should wash hands and face before eating, drinking and
smoking. Persons with a history of asthma, allergies or chronic or recurrent
respiratory disease should not be employed in any process in which this product is
used. Do not get in eyes or on skin or clothing. Do not breathe vapour or mist. Avoid
release to the environment. Refer to special instructions/safety data sheet. Use only
with adequate ventilation. Wear appropriate respirator when ventilation is inadequate.
Do not enter storage areas and confined spaces unless adequately ventilated. Keep
in the original container or an approved alternative made from a compatible material,
kept tightly closed when not in use. Store and use away from heat, sparks, open
flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting
and material handling) equipment. Use non-sparking tools. Take precautionary
measures against electrostatic discharges. To avoid fire or explosion, dissipate static
electricity during transfer by earthing and bonding containers and equipment before
transferring material. Empty containers retain product residue and can be hazardous.
: Store in accordance with local regulations. Store in a segregated and approved area.
Storage
Store in original container protected from direct sunlight in a dry, cool and well-
ventilated area, away from incompatible materials (see section 10) and food and
drink. Eliminate all ignition sources. Separate from oxidizing materials. Keep
container tightly closed and sealed until ready for use. Containers that have been
opened must be carefully resealed and kept upright to prevent leakage. Do not store
in unlabelled containers. Use appropriate containment to avoid environmental
contamination.
Packaging materials
: Use original container.
Recommended
8. Expose controls/personal protection
Exposure limit values
Ingredient name Occupational exposure limits
methyl acetate TRGS900 AGW (Germany, 1/2006).
PEAK: 2440 mg/m? 0 times per shift, 15 minute(s).
PEAK: 800 ppm, 0 times per shift, 15 minute(s).
TWA: 610 mg/m? 0 times per shift, 8 hour(s).
TWA: 200 ppm, 0 times per shift, 8 hour(s).
cyclohexane TRGS900 AGW (Germany, 1/2006).
PEAK: 2800 mg/m?15 minute(s).
PEAK: 800 ppm 15 minute(s).
TWA: 700 mg/m?8 hour(s).
TWA: 200 ppm 8 hour(s).
Recommended monitoring : If this product contains ingredients with exposure limits, personal, workplace
atmosphere or biological monitoring may be required to determine the effectiveness
procedures
of the ventilation or other control measures and/or the necessity to use respiratory
protective equipment. Reference should be made to European Standard EN 689 for
methods for the assessment of exposure by inhalation to chemical agents and
national guidance documents for methods for the determination of hazardous
substances.
Exposure controls
Occupational exposure : Use only with adequate ventilation. Use process enclosures, local exhaust ventilation
or other engineering controls to keep worker exposure to airborne contaminants
controls
below any recommended or statutory limits. The engineering controls also need to
keep gas, vapour or dust concentrations below any lower explosive limits. Use
explosion-proof ventilation equipment.
: Wash hands, forearms and face thoroughly after handling chemical products, before
Hygiene measures
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Wash contaminated clothing before reusing.
Date of issue : 13.11.2007. MSDS no. : 29773 3/6
Sika-Trocal C 300 13.11.2007 4/6
8. Expose controls/personal protection
: Use a properly fitted, air-purifying or air-fed respirator complying with an approved
Respiratory protection
standard if a risk assessment indicates this is necessary. Respirator selection must
be based on known or anticipated exposure levels, the hazards of the product and the
safe working limits of the selected respirator.
: hemical-resistant, impervious gloves complying with an approved standard should be
Hand protection
worn at all times when handling chemical products if a risk assessment indicates
this is necessary. Recommended: Butyl rubber/nitrile rubber gloves.
: Safety eyewear complying with an approved standard should be used when a risk
Eye protection
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts.
: Personal protective equipment for the body should be selected based on the task
Skin protection
being performed and the risks involved and should be approved by a specialist before
handling this product. Recommended: Use barrier skin cream.
: Emissions from ventilation or work process equipment should be checked to ensure
Environmental exposure
they comply with the requirements of environmental protection legislation. In some
controls
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels.
9. Physical and chemical properties
General information
Appearance
Form : Liquid.
Colour : Tan.
: Hydrocarbon. Characteristic.
Odour
Important health, safety and environmental information
Flash point : Open cup: <0癈 (<32癋)
: Lower: 3.1%
Explosion limits
Upper: 16%
Vapour pressure : 22 kPa (165 mm Hg)
: ~1.08 g/cm 3 [20癈 (68癋)]
Density
Solubility : Insoluble in the following materials: water
: Dynamic: 4600 mPa穝 (4600 cP)
Viscosity
10. Stability and reactivity
: The product is stable. Under normal conditions of storage and use, hazardous
Stability
polymerisation will not occur.
: Avoid all possible sources of ignition (spark or flame). Do not pressurise, cut, weld,
Conditions to avoid
braze, solder, drill, grind or expose containers to heat or sources of ignition. Avoid
release to the environment. Refer to special instructions/safety data sheet.
: Highly reactive or incompatible with the following materials: oxidizing materials
Materials to avoid
Hazardous decomposition : Under normal conditions of storage and use, hazardous decomposition products
products should not be produced.
11. Toxicological information
Potential acute health effects
: Vapours may cause drowsiness and dizziness. May cause sensitisation by inhalation.
Inhalation
May cause irritation.
Ingestion : Can cause gastrointestinal disturbances.
: May cause skin irritation. May cause sensitisation by skin contact.
Skin contact
Eye contact : Irritating to eyes.
Date of issue : 13.11.2007. MSDS no. : 29773 4/6
Sika-Trocal C 300 13.11.2007 5/6
11. Toxicological information
Product name List name Name on list Classification Notes
diphenylmethanediisocyanate, Germany TRGS905 K3
Techn. (''Polymeres'')
isomeres and homologues MDI; pMDI
: Once sensitized, a severe allergic reaction may occur when subsequently exposed to
Chronic effects
very low levels.
12. Ecological information
: Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic
Environmental effects
environment.
13. Disposal considerations
: Completely emptied packagings can be given for recycling. Packaging containing
Methods of disposal
remains of dangerous substances, as well as packagings disposed of remains can be
unharmed eliminated in accordance with the regulations.
: ompletely emptied packagings may be given for recycling. Empty packaging may still
Packaging
contain hazardous residues. Empty packaging should be removed by a licensed
waste contractor.
14. Transport information
International transport regulations
ADR
: UN1133
ADR Class :3
Classification code : F1
: III
Packing group
Proper shipping name : Adhesives
Label No. :3
: 640H
Special provisions
IMDG
UN number : UN1133
IMDG Class :3
Packing group : III
Proper shipping name : Adhesives
Emergency schedules : F-E, S-D
(EmS)
Marine pollutant : No.
Label no. :3
IATA
UN number : UN1133
IATA Class :3
Packing group : III
Proper shipping name : Adhesives
Label no. :3
Date of issue : 13.11.2007. MSDS no. : 29773 5/6
Sika-Trocal C 300 13.11.2007 6/6
15. Regulatory information
EU regulations
Classification and labeling have been determined according to EU Directives 67/548/EEC and 1999/45/EC
(including amendments) and take into account the intended product use.
: F, Xn, N
Hazard symbol or symbols
Highly flammable, Harmful, Dangerous for the environment
Contains : Diphenylmethanediisocyanate, isomeres and homologues
: R11- Highly flammable.
Risk phrases
R36- Irritating to eyes.
R42/43- May cause sensitisation by inhalation and skin contact.
R67- Vapours may cause drowsiness and dizziness.
R51/53- Toxic to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.
: S23- Do not breathe gas/fumes/vapour/spray
Safety phrases
S24- Avoid contact with skin.
S37- Wear suitable gloves.
S45- In case of accident or if you feel unwell, seek medical advice immediately (show
the label where possible).
: Contains isocyanates. See information supplied by the manufacturer.
Additional warning phrases
: VOC (w/w): 17.8%
VOC content (EU)
National regulations
: 1 Appendix No. 4
Hazard class for water
16. Other information
Full text of classifications : R11- Highly flammable.
referred to in sections 2 and R20- Harmful by inhalation.
3 R65- Harmful: may cause lung damage if swallowed.
R36- Irritating to eyes.
R38- Irritating to skin.
R36/37/38- Irritating to eyes, respiratory system and skin.
R42/43- May cause sensitisation by inhalation and skin contact.
R66- Repeated exposure may cause skin dryness or cracking.
R67- Vapours may cause drowsiness and dizziness.
R50/53- Very toxic to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.
R51/53- Toxic to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.
: F - Highly flammable
Full text of classifications
Xn - Harmful
referred to in sections 2 and
Xi - Irritant
3
N - Dangerous for the environment
History
Date of printing : 15.11.2007
: 13.11.2007.
Date of issue
Date of previous issue : No previous validation.
Indicates information that has changed from previously issued version.
Notice to reader
The information contained in this Safety Data Sheet corresponds to our level of knowledge at the time of
publication. All warranties are excluded. Our most current General Sales Conditions shall apply. Please consult
Technical Data Sheet prior to any use and processing.
Date of issue : 13.11.2007. MSDS no. : 29773 6/6
|