MIRATHANE APU 100 MATTE, "A" COMPONENT
CROSSFIELD PRODUCTS CORPORATION
3000 E. Harcourt St 140 Valley Rd.
Rancho Dominguez, CA 90221 (Headquarters) Roselle Park, NJ 07204
(310)-886-9100 (8:00 AM ?5:00 PM Pacific Time) (908)-245-2800 (8:00 AM ?5: PM Eastern Time)
www.crossfieldproducts.com
MATERIAL SAFETY DATA SHEET
PART I. What is the material and what do I need to know in an emergency?
1. PRODUCT IDENTIFICATION
MIRATHANE APU 100 MATTE, "A" COMPONENT
TRADE NAME (AS LABELED):
CHEMICAL NAME/CLASS: Polyester Resin
PRODUCT USE: Decking Topcoat Resin
SUPPLIER/MANUFACTURER'S NAME: Crossfield Products Corp.
ADDRESS (WEST COAST): 3000 E. Harcourt Street (Headquarters)
Rancho Dominguez, CA 90221
ADDRESS (EAST COAST): 140 Valley Rd.
Roselle Park, NJ 07204
EMERGENCY PHONE: CHEMTREC: 800-424-9300
DATE OF PREPARATION: March 16, 2007
REVISION DATE: March 16, 2007
Si usted no entiende las Hojas de Informacion de Seguridad sobre Materials, busque a alguien para que se la explique a usted en
detalle. (If you do not understand the Material Safety Data Sheet, find someone to explain it to you in detail.)
S
2. COMPOSITION AND INFORMATION ON INGREDIENTS
CHEMICAL NAME CAS # %w/w EXPOSURE LIMITS IN AIR
ACGIH OSHA
TLV STEL PEL STEL IDLH OTHER
3 3 3 3 3
mg/m ppm mg/m mg/m mg/m mg/m
Acetic Acid, Methyl Ester 79-20-9 10 - 30 NE 250 610 NE NE Note 1
Propylene Glycol Monomethyl 108-65-6 10 - 30 NE NE NE NE NE MFR TWA:100
Ether AcetateI ppm
MFR STEL: 150
ppm
Xylene 1330-20-7 3-7 (TWA) 150 435 NE NE
100 ppm (100 ppm)
Methanol 67-56-1 0.1 - 1 (TWA) 250 260 NE NE Note 2
200 ppm
Ethyl Benzene 100-41-4 0.1 - 1 (TWA) 125 435 NE NE
100 ppm (100 ppm)
The components present in the balance of this product do not contribute any significant,
Water and other ingredients. The other ingredients Balance
additional hazards. All hazard information pertinent to this product has been presented in the
are each present in less than 1 percent concentration
remaining sections of this Material Safety Data Sheet, per the requirements of Federal
in this product.
Occupational Safety and Health Hazard Communication Standard (29 CFR 1910.1200).
VOC Component = 207 g/L As Applied (Part of multi-component system) = 96 g/L
Note 1: US. California Code of Regulations, Title 8, Section 5155, Airborne Contaminants Time Weighted Average (TWA) Permissable Exposure Limit (PEL): 200
3 3
ppm, 610 mg/m . Short Term Exposure Limit (STEL): 250 ppm, 760 mg/m
Note 2: US. California Code of Regulations, Title 8, Section 5155, Airborne Contaminants Time Weighted Average (TWA) Permissable Exposure Limit (PEL): 200
3 3
ppm, 610 mg/m . Ceiling Limit Value: 1,000 ppm. Short Term Exposure Limit (STEL): 250 ppm, 325 mg/m . Skin designation: Can be absorbed through the skin.
3
US OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) PEL: 200 ppm, 260 mg/m .
NE = Not Established. ND = No Data NA = Not Applicable C = Ceiling Limit. See Section 16 for Definitions of Terms Used.
NOTE: All WHMIS required information is included. It is located in appropriate sections based on the ANSI Z400.1-1993 format.
PAGE 1 OF 9
MIRATHANE APU 100 MATTE, "A" COMPONENT
3. HAZARD IDENTIFICATION
EMERGENCY OVERVIEW: This product is a clear to pale yellow liquid solution. This solution is extremely flammable,
and can be damaging to contaminated tissue. Ingestion of large quantities can be fatal. In the event of fire or spill, adequate
precautions must be taken. If involved in a fire, this product may decompose to produce toxic or irritating combustion products
and a variety of other compounds (i.e. carbon monoxide and carbon dioxide). Emergency responders must wear the proper
personal protective equipment suitable for the situation to which the are responding.
SYMPTOMS OF OVER-EXPOSURE BY ROUTE OF EXPOSURE: This
WHMIS HAZARDOUS MATERIAL
solution can damage skin, eyes, mucous membranes, and other contaminated
SYSTEM INFORMATION
tissue.
INHALATION: May cause respiratory tract irritation with symptoms of
HEALTH 2
(BLUE
coughing, sore throat and runny nose. Inhalation of the solvents may cause
central nervous system depression with symptoms of nausea,
lightheadedness, drowsiness, dizziness, headache, numbness and loss of
co-ordination. Prolonged occupational overexposure to solvents may cause
FLAMMABILITY (RED) 3
liver, kidney, brain and nervous system damage. Intentional misuse by
deliberately concentrating and inhaling solvents may be harmful or fatal.
CONTACT WITH SKIN: May cause irritation with symptoms of reddening
and itching.
REACTIVITY (YELLOW 0
CONTACT WITH EYES: Causes irritation with symptoms of reddening,
tearing, stinging, and swelling.
SKIN ABSORPTION: May cause irritation with symptoms of reddening and
PROTECTIVE D
itching. Chronic: May cause defatting of the skin with symptoms of dryness
Q
and cracking.
EYES HANDS BODY
RESPIRATORY
INGESTION: Though ingestion is not anticipated to be a significant route of
over-exposure to this product, if ingestion does occur it can result in
SEE SECTION 8
nervous system effects which can include symptoms of dizziness, loss of
co-ordination, headache, numbness, and/or confusion. Vomiting may
cause aspiration of solvent resulting in chemical pneumonitis. For routine industrial applications
INJECTION: Though injection is not anticipated to be a significant route of
over-exposure to this product, if it occurs, may cause local reddening, tissue swelling, and discomfort.
HEALTH EFFECTS OR RISKS FROM EXPOSURE: A Brief Explanation in Lay Terms.
ACUTE: This solution can burn and damage eyes, skin, mucous membranes, and any other exposed tissue. If inhaled, irritation of
the respiratory system may occur, with coughing, and breathing difficulty. Though unlikely to occur during occupational use,
ingestion of large quantities may be fatal.
CHRONIC: Repeated skin contact with this product may result in dermatitis (inflammation and reddening of the skin), skin
sensitization, and cause defatting of the skin with symptoms of dryness and cracking.
PAGE 2 OF 9
MIRATHANE APU 100 MATTE, "A" COMPONENT
PART II What should I do if a hazardous situation occurs?
4. FIRST-AID MEASURES
SKIN EXPOSURE: If the product contaminates the skin, immediately begin decontamination with running water. Minimum flushing
is for 15 minutes. Remove contaminated clothing, taking care not to contaminate eyes. Victim must seek medical attention.
EYE EXPOSURE: If this product enters the eyes, open victim's eyes while under gentle running water. Use sufficient force to open
eyelids. Have victim "roll" eyes. Minimum flushing is for 15 minutes. Oils or ointments should not be used at this time. Victim must
seek immediate medical attention.
INHALATION: If vapors, mists, or sprays of this product are inhaled, remove victim to fresh air. If necessary, use artificial
respiration to support vital functions. Remove or cover gross contamination to avoid exposure to rescuers.
INGESTION: If this product is swallowed, CALL PHYSICIAN OR POISON CONTROL CENTER FOR MOST CURRENT
INFORMATION. If professional advice is not available, do not induce vomiting. Victim should drink 1 ?2 glasses of water or milk.
Never induce vomiting or give diluents (milk or water) to someone who is unconscious, having convulsions, or who cannot swallow.
Victims of chemical exposure must be taken for medical attention. Rescuers should be taken for medical attention, if necessary.
Take copy of label and MSDS to health professional with victim.
5. FIRE-FIGHTING MEASURES
FLASH POINT, 癈 (method): -13 癈 (9 癋)
AUTOIGNITION TEMPERATURE, 癈: ND
Lower (LEL): ND
FLAMMABLE LIMITS (in air by volume, %, butyil acetate): NFPA RATING
Upper (UEL): ND
FIRE EXTINGUISHING MATERIALS: (Class IIIB Combustible Liquid) FLAMMABILITY
Water Spray: YES Carbon Dioxide: YES
Foam: YES Dry Chemical: YES 3
Halon: YES Other: Any "ABC" Class.
0
2
UNUSUAL FIRE AND EXPLOSION HAZARDS: May generate toxic or irritating HEALTH REACTIVITY
combustion products, sudden reactions and fire may result if product is mixed with
oxidizing agent. Solvent vapors may be heavier than air. Under conditions of
stagnant air, vapors may build up and travel along the ground to an ignition source. If
combined with phosphorus compounds, trimethylolpropanephosphate (TMPP), a
known neurotoxin, can be given off in the event of a fire. OTHER
Explosion Sensitivity to Mechanical Impact: Not sensitive.
Explosion Sensitivity to Static Discharge: Not sensitive.
SPECIAL FIRE-FIGHTING PROCEDURES: Structural fire fighters must wear Self-Contained Breathing Apparatus and full
protective equipment. If possible, prevent run-off water from entering storm drains, bodies of water, or other environmentally
sensitive areas.
6. ACCIDENTAL RELEASE MEASURES
SPILL AND LEAK RESPONSE: Uncontrolled releases should be responded to by trained personnel using pre-planned
procedures. Proper protective equipment should be used. In case of a spill, clear the affected area, protect people, and
respond with trained personnel.
The proper personal protective equipment for incidental releases (e.g.-1 L of the product released in a well-ventilated area)
use impermeable gloves, specific for the material handled, goggles, face shield, and appropriate body protection. In the event
of a large release, use impermeable gloves, specific for the material handled, chemically resistant suit and boots, and hard-
hat. Self Contained Breathing Apparatus or respirator may be required where engineering controls are not adequate or
conditions for potential exposure exist. When respirators are required, Select NIOSH/MSHA approved based on actual or
potential airborne concentrations in accordance with latest OSHA and/or ANSI recommendations.
Absorb spilled liquid with inert material (e.g., dry sand or earth), polypads or other suitable absorbent materials. Shut off
sources of ignition immediately. Decontaminate the area thoroughly. Test area with litmus paper to confirm neutralization.
Place all spill residue in metal containers for recovery or disposal. Dispose of in accordance with Federal, State, and local
hazardous waste disposal regulations (see Section 13, Disposal Considerations). Prevent entry into sewers, storm drains
and waterways.
PAGE 3 OF 9
MIRATHANE APU 100 MATTE, "A" COMPONENT
PART III How can I prevent hazardous situations from occurring?
7. HANDLING and STORAGE
WORK PRACTICES AND HYGIENE PRACTICES: As with all chemicals, avoid getting this product ON YOU or IN YOU. Wash
hands after handling this product. Do not eat or drink while handling this material. Remove contaminated clothing immediately.
Discard contaminated clothing items, or launder before re-use. Inform anyone handling such contaminated laundry of the hazards
associated with this product. Use ventilation and other engineering controls to minimize potential exposure to this product.
STORAGE AND HANDLING PRACTICES: Keep away from oxidizers, heat or flame. Store in well-ventilated areas. Keep
cool, dry and in closed containers.
For Non-Bulk Containers: Open containers slowly, on a stable surface. Containers of this product must be properly labeled. Store
containers in a cool, dry location, away from direct sunlight, sources of intense heat, or where freezing is possible. Material should
be stored in secondary containers, or in a diked area, as appropriate. Store containers away from incompatible chemicals. Keep
container tightly closed when not in use. Wash thoroughly after using this material. Storage areas should be made of fire-resistant
materials. If appropriate, post warning signs in storage and use areas. Inspect all incoming containers before storage, to ensure
containers are properly labeled and not damaged. Empty containers may contain residual liquid, therefore, empty containers should
be handled with care.
Bulk Containers: All tanks and pipelines which contain this material must be labeled. Perform routine maintenance on tanks or
pipelines which contain this product. Report all leaks immediately to the proper personnel.
Tank Car Shipments: Tank cars carrying this product should be loaded and unloaded in strict accordance with tank-car
manufacturer's recommendation and all established on-site safety procedures. Appropriate personal protective equipment must be
used (see Section 8, Engineering Controls and Personal Protective Equipment.). All loading and unloading equipment must be
inspected, prior to each use. Loading and unloading operations must be attended, at all times. Tank cars must be level, brakes must
be set or wheels must be locked or blocked prior to loading or unloading. Tank car (for loading) or storage tank (for unloading) must
be verified to be correct for receiving this product and be properly prepared, prior to starting the transfer operations. Hoses must be
verified to be clean and free of incompatible chemicals, prior to connection to the tank car or vessel. Valves and hoses must be
verified to be in the correct positions, before starting transfer operations. A sample (if required) must be taken and verified (if required)
prior to starting transfer operations. All lines must be blown-down and purged before disconnecting them from the tank car or vessel.
PROTECTIVE PRACTICES DURING MAINTENANCE OF CONTAMINATED EQUIPMENT: Follow practices indicated in
Section 6 (Accidental Release Measures). Make certain application equipment is locked and tagged-out safely. Always use
this product in areas where adequate ventilation is provided. Decontaminate equipment before maintenance. Begin by a
triple-rinse with water followed, if necessary, with an additional rinse. Collect all rinsates and dispose of according to
applicable Federal, State, or local procedures.
8. EXPOSURE CONTROLS - PERSONAL PROTECTION
VENTILATION AND ENGINEERING CONTROLS: If required use a corrosion-resistant ventilation system separate from other
exhaust ventilation systems to ensure that there is no potential for overexposure to sprays, or mists of this product and that
exposures are below those in section 2 (Composition and Information on Ingredients). Ensure eyewash/safety shower stations are
available near areas where this product is used.
RESPIRATORY PROTECTION: Maintain airborne contaminant concentrations below exposure limits listed in Section 2
(Composition and Information on Ingredients). If respiratory protection is needed, use only protection authorized in 29 CFR
1910.134, or applicable State regulations. If adequate ventilation is not available or if there is potential for airborne exposure above
the exposure limits (listed in Section 2) a respirator may be worn up to respirator exposure limitations, check with respirator
equipment manufactures recommendations/limitations. For a higher level of protection use positive pressure supplied air respiration
protection or Self Contained Breathing Apparatus or if oxygen levels are below 19.5% or are unknown.
EMERGENCY OR PLANNED ENTRY INTO UNKNOWN CONCENTRATIONS OR IDLH CONDITIONS:
(Up to 1ppm) Positive pressure, full-facepiece Self Contained Breathing Apparatus; or positive pressure, full-facepiece
Self Contained Breathing Apparatus with an auxiliary positive pressure Self Contained Breathing Apparatus.
PAGE 4 OF 9
MIRATHANE APU 100 MATTE, "A" COMPONENT
EYE PROTECTION: Splash goggles or safety glasses. Face-shields are recommended when the operation can generate splashes,
sprays or mists.
HAND PROTECTION: Wear appropriate gloves for routine industrial use. Use appropriate gloves or nitrile rubber gloves for spill
response, as stated in Section 6 of this MSDS (Accidental Release Measures).
BODY PROTECTION: Use body protection appropriate for task. Long-sleeved shirts and trousers. Cover-all, rubber aprons, or
chemical protective clothing made from natural rubber are generally acceptable, depending upon the task.
9. PHYSICAL and CHEMICAL PROPERTIES
RELATIVE VAPOR DENSITY (air = 1): ND EVAPORATION RATE (n-BuAc=1): ND
SPECIFIC GRAVITY (water = 1): 1.01 MELTING/FREEZING POINT: ND
SOLUBILITY IN WATER: Slight BOILING POINT: >138 篊 (280 篎)
VAPOR PRESSURE, mm Hg @ 50 癈: ND pH: ND
ODOR THRESHOLD: ND
LOG WATER/OIL DISTRIBUTION COEFFICIENT: Not available.
APPEARANCE AND COLOR: This is a clear to pale yellow liquid with a solvent odor.
HOW TO DETECT THIS SUBSTANCE (warning properties): Not established.
10. STABILITY and REACTIVITY
STABILITY: Stable.
DECOMPOSITION PRODUCTS: Thermal decomposition products of this solution can include carbon monoxide, carbon dioxide,
and other toxic or irritating compounds, including oxides of nitrogen.
MATERIALS WITH WHICH SUBSTANCE IS INCOMPATIBLE: This product may react with oxidizers (perchlorates, nitrates), strong
acids, hypochlorites, and peroxides. It should not be combined with phosphorous containing materials becaue highly toxic fumes
can be emitted in a fire situation.
HAZARDOUS POLYMERIZATION: Will not occur.
CONDITIONS TO AVOID: Avoid exposure or contact to extreme temperatures and incompatible chemicals.
PART IV Is there any other useful information about this material?
11. TOXICOLOGICAL INFORMATION
TOXICITY DATA: Additional toxicology information for components greater than 1 percent in concentration is provided below.
Propylene Glycol Monomethyl Ether Acetate Xylene
Acute Oral LD50 (rat) : > 5,000 mg/kg Acute Oral LD50 (rat) : 4,300 mg/kg
Acute Dermal LD50 (rat) : >5000 mg/kg Acute Dermal LD50 (rabbit) : >4,350 mg/kg
Acute Inhalation LC50 (rat): 4345 ppm, vapor, 6 hrs. Acute Inhalation LC50 (rat): 5,000 ppm, 4 hrs.
Skin Irritation (rabbit): Non-irritatiing Skin Irritation (rabbit,Draize): Moderately irritatiing
NOAEL (rat): 300 ppm, 2 wks inhalation Eye irritation (rabbit): Exposure time 24 hrs, Severely irritating
LOAEL (rat): 1000 ppm, 2 wks inhalation NOAEL (rat): 810 ppm, 90 Days inhalation
(No adverse effects seen at highest dose tested.)
LOAEL (rat): 150 mg/kg, 90 Days oral
Ethyl Benzene
Acute Oral LD50 (rat) : 3,500 mg/kg
Acute Dermal LD50 (rabbit) : 17,8000 mg/kg
Acute Inhalation LC50 (rat): 17.2 mg/l, 4 hrs.
Skin Irritation (rabbit,Draize): Exposure Time 24 hrs. Slightly-irritatiing
Eye irritation (rabbit,Draize): Severely irritating
Sensitization Dermal (Human, patch test): Non-sensitizer
NOAEL (rabbit): 3.4 mg/l, 28 Days inhalation
NOAEL (rat, Male/Female, daily): 0.47 mg/l, 90 Days inhalation
Mutagenicity: Genetic Toxicity in Vitro:
Ames: negative (Salmonella typhimurium, Metabolic Activation: with/without)
Positive and negative results were seen in various in vitro studies.
Genetic Toxicity in Vivo:
Drosophila SLRL test: negative (Drosophila melanogaster)
Micronucleus Assay: negative (mouse, Male/Female, inhalation)
PAGE 5 OF 9
MIRATHANE APU 100 MATTE, "A" COMPONENT
Ethyl Benzene continued
Carcinogenicity: Ethylene benzene was tested by inhalation exposure in mice and rats. In mice, there was an increased incidence of lung adenomas
males and liver adenomas in females. In male rats, there was an increased incidence of renal tubule adenomas and carcinomas.
Two studies of workers potentially exposed to ethyl benzene in a production plant and a styrene polymerization plant showed no excess
cancer incidence and no excess cancer mortality during a 15-year follow-up.
Toxicity to Reproduction/Fertility:
Other method, inhalation, (Monkey, male)
Reproductive effects have been observed in animal studies.
One generation study, inhalation, (rat, female) NOAEL (parental): 100 ppm, NOAEL (F2): 100 ppm
Developmental Toxicity/Teratogenicity
Rat, female, inhalation, gestaqtion, daily, NOAEL (teratogenicity): 100 ppm, NOAEL (maternal): 100 ppm
Teratogenic effects seen only with maternal toxicity. Fetotoxicity seen only with maternal toxicity.
Rabbit, female, inhalation, gestation, daily, NOAEL (teratogenicity): <1000 mg/m3, NOAEL (Maternal): <1000 mg/m3.
Teratongenic effects seen ohly with maternal toxicity. Fetotoxicity seen only with maternal toxicity.
Acetic acid, methyl ester
Acute Oral LD50 (rat) : >5,000 mg/kg (highest dose tested)
Acute Inhalation LC50 (rat): >16,000 ppm, 4 hrs
Acute Dermal LD50 (rabbit) : >5,000 mg/kg (highest dose tested)
Skin Irritation (rabbit): Slightly-irritatiing
Eye irritation (rabbit): Severely irritating
SUSPECTED CANCER AGENT: IARC: Ethyl Benzene ?Overall evaluation: 2B Possible carcinogen.
IRRITANCY OF PRODUCT: This product is severely irritating to contaminated tissue.
SENSITIZATION TO THE PRODUCT: This product is reported to be a pulmonary and skin sensitizer.
REPRODUCTIVE TOXICITY INFORMATION: Listed below is information concerning the effects of this product and its
components on the human reproductive system.
Mutagenicity: This product is not reported to produce mutagenic effects in humans.
Embryotoxicity: This product is not reported to produce embryotoxic effects in humans.
Teratogenicity: This product is not reported to cause teratogenic effects in humans.
Reproductive Toxicity: This product is not reported to cause reproductive effects in humans.
A mutagen is a chemical which causes permanent changes to genetic material (DNA) such that the changes will propagate
through generational lines. An embryotoxin is a chemical which causes damage to a developing embryo (i.e. within the first eight
weeks of pregnancy in humans), but the damage does not propagate across generational lines. A teratogen is a chemical which
causes damage to a developing fetus, but the damage does not propagate across generational lines. A reproductive toxin is
any substance which interferes in any way with the reproductive process.
BIOLOGICAL EXPOSURE INDICES: Currently there are no Biological Exposure Indices (BEIs) associated with the components of
this product.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE Asthma and other respiratory disorders, skin allergies, eczema.
RECOMMENDATIONS TO PHYSICIANS: Treat symptoms and eliminate over-exposure to this product.
12. ECOLOGICAL INFORMATION
ALL WORK PRACTICES MUST BE AIMED AT ELIMINATING ENVIRONMENTAL CONTAMINATION.
ENVIRONMENTAL STABILITY: The components of this product are relatively stable in the environment; they may degrade,
after time, into other organic and inorganic constituents.
EFFECT OF MATERIAL ON PLANTS or ANIMALS: This product is harmful to plant and animal life if this product is released into
the environment. As with all chemicals, work practices should be aimed at eliminating environmental releases.
EFFECT OF CHEMICAL ON AQUATIC LIFE This product is harmful to an aquatic environment and can be toxic to fish and aquatic
plants. As with all chemicals, work practices should be aimed at eliminating environmental releases.
Propylene Glycol Monomethyl Ether Acetate:
Biodegradation: Aerobic, 100%, Exposure time: 8 Days
Acute and Prolonged Exposure to Fish: LC50: 161 mg/l (Fathead minnow {Pimephales promelas}, 96 hrs)
Acute Toxicity to Aquatic Invertebrates: EC50: 408 mg/l (Water flea(Daphnia magna), 48 hrs)
PAGE 6 OF 9
MIRATHANE APU 100 MATTE, "A" COMPONENT
Xylene:
Biological Oxygen Demand (BOD): 5 Days, 80%
Chemical Oxygen Demand (COD): 83 mg/g
Acute and Prolonged Toxicity to Fish: LC50: 13.5-17.3 mg/l (Rainbow {Donaldson} Trout {Oncorhynchus mykiss}, 96 hrs)
Acute Toxicity to Aquatic Invertebrates: 600 ug/L (Gammaurs sp., 48 hrs)
Ethyl Benzene:
Biodegradation: Aerobic, 50%, Exposure time: 28 Days
Biological Oxygen Demand (BOD): 5 Days, 2.8% -- 35 Days, 1,780 mg/g
Theoretical Biological Oxygen Demand (ThBOD): 3.17 mg/g
Bioaccumulation: Carp, 15 BCF
Acute and Prolonged Toxicity to Fish: LC50: 4.2 mg/l (Rainbow {Donaldson} Trout {Oncorhynchus mykiss}, 96 hrs)
LC50: 12.1 mg/l (Fathead minnow {Pimephales promelas}, 96 hrs)
LC50: 4.3 mg/l (Hybrid striped bass {Morone saxatilis x chrysops}, 96 hrs)
Acute Toxicity to Aquatic Invertebrates: EC50: 1.8 ?2.9 mg/l (Water flea {Daphnia magna}, 48 hrs)
Toxicity to Aquatic Plants: EC50: 4.6 mg/l, (Green algae {Selenastrum capricornutum}, 72 hrs)
Toxicity to Microorganisms: EC50: 130 mg/l (Activated sludge microorganisms, 48 hrs)
EC50: 9.68 ppm, (Photobacterium phosphoreum, 30 min)
Acetic Acid, Methyl Ester:
Biological Oxygen Demand (BOD-5):393 mg/g
Theoretical Biological Oxygen Demand (ThBOD): 1.510 mg/g
Acute and Prolonged Toxicity to Fish: LC50: 320 ?399 mg/l (fathead minnow) 96 hrs
13. DISPOSAL CONSIDERATIONS
PREPARING WASTES FOR DISPOSAL: Incineration is a preferred method. Waste disposal must be in accordance with
appropriate Federal, State, and local regulations. This product, if unaltered by use, may be disposed of by treatment at a
permitted facility or as advised by your local hazardous waste regulatory authority.
EPA WASTE NUMBER: D001 (Characteristic, ignitability), applicable to wastes consisting only of this solution. When discarded in
its purchased form, this product meets the criteria if ignitability, and should be managed as a hazardous waste under 40 CFR 261.
14. TRANSPORTATION INFORMATION
PROPER SHIPPING NAME: Resin solution, liquid, (contains Xylene, Propylene Glycol
Monomethyl Ether Acetate, Methyl Acetate)
HAZARD CLASS NUMBER and DESCRIPTION: 3 (Flammable Liquid)
UN IDENTIFICATION NUMBER: UN 1866
PACKING GROUP: II
DOT LABEL(S) REQUIRED: Flammable Liquid
NORTH AMERICAN EMERGENCY RESPONSE GUIDEBOOK NUMBER (2000): 156
MARINE POLLUTANT: This product does not contain any components which are designated by the Department of Transportation
to be Marine Pollutants. (49 CFR 172.101, Appendix B).
TRANSPORT CANADA TRANSPORTATION OF DANGEROUS GOODS REGULATIONS: THIS MATERIAL IS NOT
CONSIDERED AS DANGEROUS GOODS. This product contains the following chemical(s) listed on the WHMIS Ingredient
Disclosure List at or above the specified concentration limit: Ethyl Benzene. Use the above information for the preparation of
Canadian Shipments.
ICAO/IATA SHIPPING DATA: Resin solution, Hazard Class 3, UN1866, Packing Group 2, Flammable Liquid.
PASSENGER AIR MAX. QUANTITY: 6OL
PASSENGER PACKING INSTRUCTIONS: 309
CARGO AIR ?MAX. QUANTITY: 220L
CARGO AIR ?PACKING INSTRUCTION: 310
Note: The latest DOT information is provided, please verify all DOT information as it subject to change without notice.
PAGE 7 OF 9
MIRATHANE APU 100 MATTE, "A" COMPONENT
15. REGULATORY INFORMATION
SARA REPORTING REQUIREMENTS: The components of this product subject to the reporting requirements of Sections
302, 304 and 313 of Title III of the Superfund Amendments and Reauthorization Act are as follows.
COMPONENT SARA 302 SARA 304 SARA 313
Xylene Yes (RQ 100 lbs) No Yes
Ethyl Benzene Yes (RQ 1000 lbs) Yes Yes
SARA Threshold Planning Quantity: Not applicable.
TSCA INVENTORY STATUS: The components of this product are listed on the TSCA Inventory.
DOT REGULATED COMPONENT (RQ): Xylene RQ ?2,352 lb.
CERCLA REPORTABLE QUANTITY (RQ): Xylene 100 lbs. Ethyl Benzene 1000 lbs.
OTHER FEDERAL REGULATIONS: Not applicable.
STATE REGULATORY INFORMATION: Components of this product are covered under specific State regulations, as
denoted below:
Massachusetts, New Jersey or Pennsylvania Right to Know Substance Lists:
Weight % Components CAS No.
>= 1% Polyester Polyol 61842-72-6
10 - 30 % Propylene Glycol Monomethyl Ether Acetate 108-65-6
10 - 30 % Methyl Acetate 79-20-9
3 ?7% Xylene 1330-20-7
New Jersey Environmental Hazardous Substances List and/or New Jersey RTK Special Hazardous Substances Lists:
Weight Components CAS No.
3 ?7% Xylene 1330-20-7
0.1 ?1% Ethyl Benzene 100-41-4
CALIFORNIA PROPOSITION 65: Components of this product are known to the state of California to cause cancer, birth defects or
other reproductive harm. Ethyl Benzene
LABELING (Precautionary Statements): DANGER! FLAMMABLE MATERIAL! LIQUID AND MIST CAUSE SEVERE DAMAGE
TO ALL BODY TISSUE. MAY BE FATAL IF SWALLOWED. HARMFUL IF INHALED. MAY CAUSE LUNG DAMAGE. REACTS
WITH WATER TO GENERATE HEAT. AVOID SPATTERING BY SLOWLY ADDING TO SOLUTION. Do not get into eyes, on
skin or clothing. Avoid breathing spray or mist. Do not take internally. Use with adequate ventilation and employ respiratory
protection when exposed to the mist or spray. When handling, wear chemical splash goggles, face shield, rubber gloves and
protective clothing. Do not transfer to unlabeled containers. Use with adequate ventilation. Wash thoroughly after handling, Keep
container closed when not in use. FIRST-AID: In case of contact, immediately flush skin or eyes for at least 15 minutes. If inhaled,
move to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Do not induce vomiting. IN CASE
OF FIRE: Use dry chemical, CO2, or alcohol foam. IN CASE OF SPILL: Dike area to contain spill. Only trained personnel
equipped full acid- protective gear should be permitted in this area. Spilled material may be absorbed into an appropriate absorbent
material. Spills should be removed using a vacuum truck. Do not wash into storm or sanitary sewer system.
TARGET ORGANS: Skin, eyes, liver, kidney, and respiratory system.
WHMIS SYMBOLS: B2, D2A, D2B
Class B ?Flammable and Combustible Material Class D - Poisonous and Infectious Material
Division 2 Materials Causing Other Toxic Effect
PAGE 8 OF 9
MIRATHANE APU 100 MATTE, "A" COMPONENT
16. OTHER INFORMATION
PREPARED BY: Bill Beach, CROSSFIELD PRODUCTS CORP.
THIS INFORMATION IS DRAWN FROM RECOGNIZED SOURCES BELIEVED TO BE RELIABLE. CROSSFIELD PRODUCTS MAKES NO
GUARANTEES NOR ASSUMES ANY LIABILITY IN CONNECTION WITH THIS INFORMATION. THE USER SHOULD BE AWARE OF CHANGING
TECHNOLOGY, RESEARCH, REGULATIONS AND ANALYTICAL PROCEDURES THAT MAY REQUIRE CHANGES HEREIN. THE ABOVE DATA IS
SUPPLIED UPON THE CONDITION THAT PERSONS WILL EVALUATE THIS INFORMATION AND THEN DETERMINE ITS SUITABILITY FOR THEIR
USE.
DEFINITIONS OF TERMS
A large number of abbreviations and acronyms appear on a MSDS. TOXICOLOGICAL INFORMATION:
Some of these which are commonly used include the following: Possible health hazards as derived from human data, animal studies, or
from the results of studies with similar compounds are presented.
CAS #: This is the Chemical Abstract Service Number which uniquely
Definitions of some terms used in this section are: LD50 - Lethal Dose
identifies each constituent. It is used for computer-related searching.
(solids & liquids) which kills 50% of the exposed animals; LC50 - Lethal
EXPOSURE LIMITS IN AIR: Concentration (gases) which kills 50% of the exposed animals; ppm
ACGIH - American Conference of Governmental Industrial Hygienists, a concentration expressed in parts of material per million parts of air or
3
professional association which establishes exposure limits. water; mg/m concentration expressed in weight of substance per volume
TLV - Threshold Limit Value - an airborne concentration of a substance of air; mg/kg quantity of material, by weight, administered to a test
which represents conditions under which it is generally believed that subject, based on their body weight in kg. Data from several sources are
nearly all workers may be repeatedly exposed without adverse effect. used to evaluate the cancer-causing potential of the material. The
The duration must be considered, including the 8-hour Time Weighted sources are: IARC - the International Agency for Research on Cancer;
Average (TWA), the 15-minute Short Term Exposure Limit, and the NTP - the National Toxicology Program, RTECS - the Registry of Toxic
instantaneous Ceiling Level. Skin adsorption effects must also be Effects of Chemical Substances, OSHA and CAL/OSHA. IARC and NTP
considered. rate chemicals on a scale of decreasing potential to cause human cancer
OSHA - U.S. Occupational Safety and Health Administration. with rankings from 1 to 4. Subrankings (2A, 2B, etc.) are also used.
PEL - Permissible Exposure Limit - This exposure value means exactly Other measures of toxicity include TDLo, the lowest dose to cause a
the same as a TLV, except that it is enforceable by OSHA. The OSHA symptom and TCLo the lowest concentration to cause a symptom; TDo,
Permissible Exposure Limits are based in the 1989 PELs and the June, LDLo, and LDo, or TC, TCo, LCLo, and LCo, the lowest dose (or
1993 Air Contaminants Rule (Federal Register: 58: 35338-35351 and 58: concentration) to cause death. BEI - Biological Exposure Indices,
40191). Both the current PELs and the vacated PELs are indicated. The represent the levels of determinants which are most likely to be observed
phrase, "Vacated 1989 PEL," is placed next to the PEL which was in specimens collected from a healthy worker who has been exposed to
vacated by Court Order. chemicals to the same extent as a worker with inhalation exposure to the
IDLH - Immediately Dangerous to Life and Health - This level TLV.
represents a concentration from which one can escape within 30-minutes
REGULATORY INFORMATION:
without suffering escape-preventing or permanent injury. The DFG - MAK
This section explains the impact of various laws and regulations on the
is the Republic of Germany's Maximum Exposure Level, similar to the
material. EPA is the U.S. Environmental Protection Agency. WHMIS is
U.S. PEL. NIOSH is the National Institute of Occupational Safety and
the Canadian Workplace Hazardous Materials Information System. DOT
Health, which is the research arm of the U.S. Occupational Safety and
and TC are the U.S. Department of Transportation and the Transport
Health Administration (OSHA). NIOSH issues exposure guidelines called
Canada, respectively. Other acronyms used are: Superfund
Recommended Exposure Levels (RELs). When no exposure guidelines
Amendments and Reauthorization Act (SARA); the Toxic Substance
are established, an entry of NE is made for reference.
Control Act (TSCA); Marine Pollutant status according to the DOT;
FLAMMABILITY LIMITS IN AIR: California's Safe Drinking Water Act (Proposition 65); the
Much of the information related to fire and explosion is derived from the Comprehensive Environmental Response, Compensation, and
National Fire Protection Association (NFPA). LEL - the lowest percent of Liability Act (CERCLA or Superfund); and various state regulations.
vapor in air, by volume, that will explode or ignite in the presence of an This section also includes information on the precautionary warnings
ignition source. UEL - the highest percent of vapor in air, by volume, that which appear on the materials package label.
will explode or ignite in the presence of an ignition source.
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