MATERIAL SAFETY DATA SHEET
AEROSOL LUBRICANTS & PENETRANTS
10/12/05
PRODUCTS COVERED: AB-S, AC-G, AG-R, AG-W, AR-4, AR-B, AR-T, AS-H, AT-L
SECTION I MANUFACTURER
Crest Industries, Inc., 1337 King Road, Trenton, MI 48183 Phone: (734) 479-4141 FAX: (734) 479-4040
24 HOUR EMERGENCY TELEPHONE (CHEMTEL): (800) 255-3924 INTERNATIONAL CALLS: (813) 248-0585
SECTION II PRODUCTS
Stock Numbers of Ingredients HMIS RATING Solubility Volatile
Number Product Name on Label in Products HFR Appearance and Odor % in Water Volume%
AB-S Red Battery Terminal Protector 1, 11, 18, 20, 34, 36 3* 3 0 Red liquid, strong solvent 10 60 to 70
AC-G Clear Cheetah Grease 1, 9, 11, 18, 27, 28, 30 3* 4 0 Clear liquid, strong solvent 24 75 to 85
AG-R Red Lube 1, 2, 5, 25, 37 3* 1 0 Red liquid, strong solvent 20 50 to 60
AG-W White Lithium Grease 8, 14, 17, 31, 37, 38 3* 3 0 White paste, mild solvent <1 50 to 60
AR-4 Rustek Plus 4 12, 13, 16, 32, 36 330 Amber liquid, mild solvent <1 40 to 50
AR-B Rustek Penetrant Lubricant 4, 7, 31, 35 240 Gray liquid, mild solvent <1 15 to 25
AR-T RusTerminator Cyberlube
Penetrant 5, 19, 21, 22, 23, 24 320 Yellow liquid, strong solvent 30 65 to 70
AS-H Hi-Viscosity Silicone Spray 1, 10, 29, 31 240 Clear liquid, strong solvent 35 95 to 98
AT-L Dry Lubricant 3, 10, 26, 30, 31, 33 240 Cloudy liquid, mild solvent <3 95 to 99
*Chronic health effects may occur from ingredients 11, 37. See NOTES in SECTION VI.
SECTION III HAZARDOUS INGREDIENTS
Exposure Limits* Flash Vapor Pres- Evap. Rate Boiling Flammable Autoigni-
in ppm (parts Point sure (mm Hg (n-Butyl Point Limits in % tion Pt.
癋 癈 at 20癈) 癋 癈 癋 癈
Ingredients CAS Number per million) Acetate=1) Lower Upper
1. Acetone 67-64-1 750 A, O -4 -20 185 7.7 132 56 2.6 12.8 869 465
0.5 mg/m3 A, O
2. Antimony Metal Salt Unknown -NA- NA NA -NA- -NA- -NA-
3. Butane (or n-Butane) 106-97-8 1000 A, 800 N <-40 >1500 114 31 -1 1.8 8.4 860 460
4. Calcium Dinonyl- >200 >93
naphthalene Sulfonate 57855-77-3 NE <0.01 <0.01 1120 605 Unknown Unknown
5. Carbon Dioxide 124-38-9 5000 A,10000 O None >45000 NA -108 -78 -NA- None
6. Cyclohexane 110-82-7 300 A, O -7 -22 95 6.1 177 81 1.3 8.3 473 245
68551-20-2 5 mg/m3 A mist
7. Heavy Aliphatic Naphtha >200 >93 <0.01 <0.1 Unknown Unknown Unknown
8. Heavy Naphthenic
5 mg/m3 A mist
Petroleum Oil 64742-52-5 >200 >93 <0.01 <0.1 Unknown Unknown Unknown
9. Heavy Paraffinic
3
Petroleum Distillate 64742-65-0 5 mg/m A mist >200 >93 <0.01 <0.1 Unknown Unknown Unknown
10. Heptane (or n-Heptane) 142-82-5 400 A, 500 O 25 4 45 4.5 201 94 1.2 6.7 433 223
11. Hexane (or n-Hexane)** 110-54-3 50 A, 500 O** -7 -22 140 8.1 156 69 1.2 7.4 437 225
100 mg/m3 N
12. Hydrotreated Kerosene 64742-47-8 148 64 0.4 Unknown 350 177 1.0 8.0 Unknown
13. Hydrotreated, Severe,
64742-52-5 5 mg/m3 A mist
Lt. Naphthenic Distillate >200 >93 <0.01 <0.1 Unknown Unknown Unknown
14. Isobutane 75-28-5 1000 A, 800 N <-40 >1500 >114 11 -12 1.8 8.4 860 460
15. Isohexane Isomers 107-83-5 500 A, O -32 -36 <200 16.2 140 60 1.0 7.0 507 264
8008-20-6 100 mg/m3 N
16. Kerosene 148 64 0.4 Unknown 350 177 1.0 8.0 Unknown
17. Light Petroleum Distillate 64742-89-8 400 E <20 <-7 60 3.9 206 97 1.2 6.8 536 280
18. Liquid (or Liquefied)
Petroleum Gas 68476-86-8 1000 A, O <-40 >760 >164 -45 -43 2.1 9.5 842 450
19. Medium Aromatic
3
Hydrocarbons 64742-94-5 5 mg/m A mist >200 >93 0.12 <0.1 Unknown Unknown Unknown
20. Metalworking Fluid Additive (Mixture) 100 A, O >200 >93 <0.01 <0.01 Unknown Unknown Unknown
21. 2-Methoxymethyl-
ethoxypropanol 34590-94-8 100 (Skin) A, O >200 >93 0.4 <0.1 Unknown Unknown Unknown
22. Methyl Acetate 79-20-9 200 A, O 4 -15 180 6.2 132 56 3.1 16.0 934 501
23. Mineral Spirits 140-Flash 64742-88-7 100 A, O 140 60 0.5 <0.01 355 179 1.4 6.8 Unknown
24. Naphthalene 91-20-3 10 A, O 189 87 <1 <1 424 218 0.9 5.9 979 526
5 mg/m3 A mist
25. Paraffin Oil 8012-95-1 >200 >93 <0.01 <0.01 Unknown Unknown Unknown
26. Pentane 109-66-0 600 A, 1000 O -57 -49 425 >10 97 36 1.4 7.8 496 258
5 mg/m3 A mist
27. Petrolatum 8009-03-8 >200 >93 <0.01 <0.1 Unknown Unknown Unknown
5 mg/m3 A mist
28. Petroleum Oil 64742-52-5 >200 >93 <0.01 <0.1 Unknown Unknown Unknown
5 mg/m3 A mist
29. Polydimethylsiloxane 63148-62-9 >200 >93 <1 <0.1 Unknown Unknown Unknown
30. Polytetrafluoroethylene
(PTFE) 9002-84-0 NE -NA- NA NA -NA- -NA- -NA-
31. Propane 74-98-6 1000 A, O <-40 >1500 >114 -44 -42 2.1 9.5 919 493
32. Propane/Isobutane/
68476-86-8 1000 A, O <-40 >760 >164 -45 -43 2.1 9.5 842 450
n-Butane
33. 2-Propanol 67-63-0 400 A, O 53 12 31 1.7 180 82 2.0 12.0 750 399
34. Severely Hydrotreated
5 mg/m3 A mist
Mineral Oil 64742-52-5 >200 >93 <0.01 <0.1 Unknown Unknown Unknown
35. Solvent-Dewaxed
Heavy Paraffinic
Petroleum Distillate
64742-65-0 5 mg/m3 A mist
Mineral Oil >200 >93 <0.01 <0.1 Unknown Unknown Unknown
36. Stoddard Solvent 8052-41-3 100 A, 500 O 104 40 3 0.2 318 159 0.7 6.0 >394 >201
37. Tetrachloroethylene** 127-18-4 50 A, 25 O** None 13 2.1 250 121 None None
1314-13-2 10 mg/m3 A,
38. Zinc Oxide -NA- NA NA -NA- -NA- -NA-
10 (5 Respirable
Dust Fraction) O
*A means ACGIH TLV, N means NIOSH, O means OSHA PEL. Other abbreviations: > means greater than, < means less than, Lt. Means Light,
NA means Not Applicable, NE means Not Established. **See NOTES in SECTION VI.
Aerosol Lubricants & Penetrants MSDS 10/12/05 page 2
SECTION IV PHYSICAL DATA breathing the solvent vapors from AG-R and AG-W. Use products out-
Pressure of Can Contents: Maximum pressure less than 140 PSI doors, if possible. If you must use indoors, open all windows and doors or
GAUGE @ 130癋 (54癈). Evaporation Rate: See SECTIONS II, III. use other means to assure fresh air movement during application and
Vapor Density: Heavier than air. Solubility in Water (Wt%): See SEC- drying. If properly used, a respirator (NIOSH/MSHA TC23C or equivalent)
TION II. Volatile Volume %: See SECTION II. may offer additional protection. Get professional advice for respirator use.
Approximate Boiling Point: See SECTIONS II, III. A dust mask does not provide protection against vapors! Clean up
Product Density (water=1): Less than 1 (AGR and AGW are greater rags and other waste immediately and allow solvent vapors to evaporate
than 1). Ingredients (except 2, 37, 38): Less than 1. outdoors. DO NOT use in basement or other unventilated area!
Appearance and Odor: See SECTION II. SECTION VII EMERGENCY AND FIRST AID
SECTION V FIRE AND EXPLOSION DATA PROCEDURES
Flash Point (Tag Closed Cup Method): See SECTIONS II, III. INHALATION: Move to an area free from risk of further exposure. Ad-
Approximate Flammable Limits: See SECTIONS II, III. minister oxygen or artificial respiration as needed. Obtain medical atten-
Autoignition Temperature: See SECTIONS II, III. tion.
Extinguishing Media: Foam, carbon dioxide, dry chemical. SKIN CONTACT: Remove contaminated clothing immediately. Wash
Special Fire Fighting Procedures: Full protective equipment, including affected areas thoroughly with soap and water. Wash contaminated cloth-
self-contained breathing apparatus, is recommended because highly toxic ing thoroughly before reuse. Seek medical attention if irritation develops
gasses may be generated by combustion or thermal decomposition. Wa- or persists.
ter from fog nozzles may be used to cool closed containers to prevent EYE CONTACT: Flush with clean, lukewarm water (low pressure) for at
pressure build up (containers may leak or burst when heated). least 15 minutes while lifting eyelids. Refer person to physician for imme-
Unusual Fire and Explosion Hazards: Vapors are heavier than air and diate attention.
may travel along the ground or be moved by ventilation and ignited by INGESTION: DO NOT INDUCE VOMITING! Consult physician, hospital
pilot lights, other flames, sparks, heaters, electric motors, smoking or emergency room or poison control center immediately. Have list of ingre-
other ignition sources at locations far from material handling point. At ele- dients available.
vated temperatures [130癋 (54癈) or over] containers may vent, rupture NOTES TO PHYSICIAN:
or burst. Inhalation: Treat as for solvent vapor inhalation. Bronchodilators, ex-
SECTION VI HEALTH HAZARD DATA pectorants and antitussives may help.
PRIMARY ROUTES OF EXPOSURE: Inhalation, Skin contact, Eye con- Skin: Treat as any contact dermatitis.
tact. Eyes: May cause conjunctivitis. Stain for evidence of corneal injury.
SIGNS AND SYMPTOMS OF EXPOSURE: Ingestion: Treat as for solvent ingestion. Inducing vomiting is contrain-
INHALATION: dicated because of the possibility of chemical pneumonia caused by aspi-
Acute Exposure: Solvent vapors at concentrations above the TLV can ration of solvent liquid.
irritate the respiratory tract (nose, throat, lungs) causing a burning sensa- SECTION VIII EMPLOYEE RECOMMENDATIONS
tion, runny nose, sore throat, coughing, chest discomfort (tightness). May VENTILATION AND RESPIRATORY PROTECTION: If exhaust ventila-
cause central nervous system depression with the following progressive tion sufficient to keep the airborne concentrations of solvents and propel-
symptoms: headache, dizziness, nausea, staggering gait, confusion, un- lants below their respective TLV's is not possible, an OSHA/MSHA ap-
consciousness, cessation of breathing and death. NOTE: Do not smoke proved TC23C Paint Spray Respirator with Particulate Prefilter or TC19C
Air Supplied Respirator must be used. Observe OSHA regulations (29
while using Dry Lube (AT-L). Wash hands thoroughly before smoking.
CFR 1910.134) for respirator use.
Heating particles of 30. Polytetrafluoroethylene (PTFE) (contained
NOTE: THERE MUST ALWAYS BE ENOUGH VENTILATION
in AT-L) in burning tobacco will result in fumes which, when inhaled with
the tobacco smoke, can cause a temporary influenza-like condition called TO KEEP VAPOR CONCENTRATION BELOW THE LOWER
polymer fume fever. FLAMMABLE LIMIT!
Chronic Exposure: Reports have associated repeated and prolonged SKIN PROTECTION: Cover as much of the skin as possible with ap-
occupational overexposure to solvents with permanent brain and nervous propriate clothing. Wear solvent resistant gloves.
system damage. Symptoms include: loss of memory, loss of intellectual EYE PROTECTION: Desirable during use of aerosol products. Wear
ability and loss of coordination. NOTE: Prolonged and/or repeated safety glasses, splash goggles or face shield. Contact lenses should not
overexposure to 11. Hexane (n-Hexane) that is contained in AB-S be worn.
and AC-G may cause Peripheral Neuropathy (damage to nerve tissue of OTHER PROTECTIVE MEASURES: Eyewash stations should be
the arms or legs) resulting in muscular weakness and loss of sensation in available. Educate and train employees in safe use of products. Follow all
some or all of the following: fingers, hands, arms, toes, feet or legs. label instructions.
NOTE: INTENTIONAL MISUSE BY DELIBERATELY CONCENTRAT- SECTION IX REACTIVITY DATA
STABILITY: Stable under normal room conditions.
ING AND INHALING ANY SOLVENT VAPORS MAY BE HARMFUL OR
HAZARDOUS POLYMERIZATION: Will not occur.
FATAL.
INCOMPATIBILITY (Materials to Avoid): Strong oxidizers.
SKIN CONTACT:
HAZARDOUS DECOMPOSITION PRODUCTS: By high heat and fire:
Acute Exposure: Repeated or prolonged skin contact with solvents
carbon dioxide, carbon monoxide, hydrocarbon fumes, smoke. AG-R and
can result in dry, defatted and cracked skin causing increased susceptibil-
AG-W will also give off hydrogen chloride, chlorine, phosgene and chlo-
ity to infection. Skin irritation may develop into contact dermatitis.
rinated hydrocarbon vapors.
Chronic Exposure: Exposure to small amounts of solvent over long
SECTION X SPILL OR LEAK PROCEDURES
periods of time may cause some or all of the symptoms as in acute expo-
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR
sure to solvents.
SPILLED: Put on protective equipment including respiratory protection.
EYE CONTACT:
Prevent further spillage. Evacuate nonessential personnel. Remove all
Acute Exposure: Irritation of the eyes with itching, burning, redness
sources of ignition and ventilate the area. Keep spill from reaching sewers
and even permanent tissue damage if sprayed directly into the eyes and
and waterways. Cover the spill with sawdust, vermiculite, Fuller's Earth or
not flushed out immediately.
other absorbent material. Collect material with non-sparking tools and put
Chronic Exposure: Irritation of the eyes with itching, burning, redness.
in a tightly sealed container. Remove container to a safe place.
INGESTION:
WASTE DISPOSAL METHOD: Follow all federal, state and local envi-
Acute Exposure: (Not likely unless deliberately sprayed into mouth.)
ronmental control regulations. Incineration is the preferred method. DO
Irritation to the mouth, and if swallowed, to the esophagus, stomach tis-
sue and digestive tract. If swallowed, vomiting may cause breathing of NOT PUT AEROSOL CONTAINERS IN A HOME TRASH COMPAC-
liquid solvent resulting in chemical pneumonia. TOR! DO NOT INCINERATE (OR BURN) AEROSOL CONTAINERS
Chronic Exposure: Unknown. EVEN WHEN EMPTY! Containers may become pressurized and burst
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: (See even if they will not spray. Containers must be handled with care due to
NOTES) None specifically known to Crest Industries, Inc. but it is possi- toxic and/or flammable and pressure producing residue.
ble that eye, respiratory tract, skin, liver, kidney, blood cell formation, nerv- RCRA STATUS: Since these products are ignitable and toxic they are
ous system and brain diseases may be aggravated by overexposure to hazardous when discarded.
the products on this MSDS. SECTION XI SPECIAL PRECAUTIONS &
CARCINOGENICITY: Products not listed by NTP, IARC or OSHA. STORAGE DATA
NOTE: 37. Tetrachloroethylene (contained in AG-R and AG-W) has STORAGE TEMPERATURE
been designated a carcinogen by OSHA. Risk to health depends on MINIMUM / MAXIMUM: 50癋 (10癈) / 120癋 (49癈)
level and duration of exposure. Be especially careful to minimize RECOMMENDED SHELF LIFE: One year
Aerosol Lubricants & Penetrants MSDS 10/12/05 page 3
PRECAUTIONS TO BE TAKEN IN HANDLING, STORAGE AND USE: before eating, drinking, smoking or using the toilet.
Keep away from heat, sparks and open flame. Do not store in tempera- Employee education and training in the safe use and handling of these
tures above 120癋 (49癈) or in direct sunlight. Do not inhale vapors or materials are required under the OSHA Hazard Communication Standard
spray mist. Avoid contact with skin and eyes. Wash hands after use and (29 CFR 1910.1200).
KEEP OUT OF THE REACH OF CHILDREN
SECTION XII ENVIRONMENTAL PROTECTION AGENCY (EPA) REGULATORY INFORMATION
The following percentage table is to be used to meet Environmental Protection Agency (EPA) Regulations:
1. 40 CFR Part 370 Emergency and Hazardous Chemical Inventory Forms and Community Right-to-Know Reporting Requirements.
2. Title III Section 313 Toxic Chemical Release Reporting Requirements. Note: All the chemicals listed must be considered for 1. above. Only the
ones marked with an asterisk (*) fall under 2. The numbers in the following tables are good for all shipments until further notice.Note: This page is
legally required to be sent with the previous two pages of this MSDS.
HAZARDOUS INGREDIENTS IN AEROSOL LUBRICANTS & PENETRANTS APPROXIMATE PERCENTAGES BY WEIGHT
Ingredients CAS Number ABS ACG AGR AGW AR4 ARB ART ASH ATL
1. Acetone 67-64-1 10 24 20 35
*2. Antimony Metal Salt Unknown 01
3. Butane (or n-Butane) 106-97-8 31
4. Calcium Dinonylnaphthalene Sulfonate 57855-77-3 01
5. Carbon Dioxide 124-38-9 02 03
*6. Cyclohexane 110-82-7
7. Heavy Aliphatic Naphtha 68551-20-2 75
8. Heavy Naphthenic Petroleum Oil 64742-52-5 26
9. Heavy Paraffinic Petroleum Distillate 64742-65-0 13
10. Heptane (or n-Heptane) 142-82-5 45 16
*11. Hexane (or n-Hexane)** 110-54-3 30 23
12. Hydrotreated Kerosene 64742-47-8 20
13. Hydrotreated, Severe, Lt. Naphthenic Distillate 64742-52-5 20
14. Isobutane (Methylpropane) 75-28-5 07
15. Isohexane Isomers 107-83-5
16. Kerosene 8008-20-6 25
17. Light Petroleum Distillate 64742-89-8 06
18. Liquid (or Liquefied) Petroleum Gas 68476-86-8 15 24
19. Medium Aromatic Hydrocarbons 64742-94-5 46
20. Metalworking Fluid Additive (Mixture) 05
21. 2-Methoxymethylethoxypropanol 34590-94-8 06
22. Methyl Acetate 79-20-9 24
23. Mineral Spirits 140-Flash 64742-88-7 17
*24. Naphthalene 91-20-3 04
25. Paraffin Oil 8012-95-1 28
26. Pentane 109-66-0 34
27. Petrolatum 8009-03-8 07
28. Petroleum Oil 64742-52-5 03
29. Poly (dimethylsilioxane) 63148-62-9 05
30. Polytetrafluoroethylene (PTFE) 9002-84-0 01 03
31. Propane 74-98-6 08 10 15 14
32. Propane/Isobutane/n-Butane 68476-86-8 20
33. 2-Propanol 67-63-0 02
34. Severely Hydrotreated Mineral Oil 64742-52-5 40
35. Solvent-Dewaxed Heavy Paraffinic
Petroleum Distillate Mineral Oil 64742-65-0 12
36. Stoddard Solvent 8052-41-3 05 15
*37. Tetrachloroethylene (Perchloroethylene) 127-18-4 49 48
38. Zinc Oxide 1314-13-2 02
Physical Hazard-Fire 60 71 20 21 80 10 24 95 97
Physical Hazard-Pressure Release 15 24 02 15 20 10 03 15 45
Health Hazard-Acute 100 100 100 100 100 100 100 100 100
Health Hazard-Chronic 30 23 49 48
Physical Hazard-Reactivity NONE OF THE AEROSOL LUBRICANTS HAVE THIS HAZARD.
Aerosol Level 3 3 1 2 3 3 3 3 3
Ingredients CAS Number ABS ACG AGR AGW AR4 ARB ART ASH ATL
SECTION XIII VOLATILE ORGANIC COMPOUND (V.O.C.) CONTENT OF
AEROSOL LUBRICANTS ACCORDING TO THE FEDERAL EPA
Stock Number ABS ACG AGR AGW AR4 ARB ART ASH ATL
Percent by Weight 49.3 48.0 0 22.0 48.8 85.3 50.0 60.0 98.7
Pounds per Gallon 3.00 2.82 0 1.81 3.12 5.52 3.61 3.49 5.01
Grams per Liter 359 338 0 216 373 661 4.33 418 600
Pounds per Can 0.362 0.39 0 0.179 0.374 0.667 0.375 0.384 0.62
SECTION XIV CALIFORNIA PROPOSITION 65 WARNINGS
According to the California Safe Drinking Water and Toxic Enforcement Act (PROPOSITION 65) "No person in the course of doing business shall
knowingly and intentionally expose any individual to a chemical known to the State of California to cause cancer, birth defects or reproductive toxicity
without first giving clear and reasonable warning to such individuals of such an exposure". The following warnings apply:
Tetrachloroethylene containing products (AG-R and AG-W):
WARNING: This product contains a chemical known to the State of California to cause cancer.
SECTION XV OZONE DEPLETION IN THE UPPER ATMOSPHERE
None of the products on this MSDS contain Upper Atmosphere ozone depleting substances.
DISCLAIMER: The information contained in this MSDS is believed to be accurate and reliable as of the date indicated.
Crest Industries, Inc. assumes no legal responsibility and makes no representation, warranty or guarantee, expressed or
implied, as to the completeness or accuracy of the information. It is offered solely for your consideration, investigation and
verification. The user is ultimately responsible for the safe use of the material in accordance with applicable federal, state,
provincial and local laws and regulations.
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