Henkel KGaA
Material Safety Data Sheet according to 91/155/EEC - ISO 11014-1
Page 1 of 9
SDS no. : 43180
V001.6
Pattex Power Spray permanent
Revision: 14.12.2006
printing date: 28.10.2008
1. Identification of the substance/preparation and of the company/undertaking
Trade name:
Pattex Power Spray permanent
Intended use:
Spray adhesive
Company name:
Henkel AG & Co. KGaA
Henkelstr. 67
40191 D黶seldorf
Phone: +49 (211) 797-0
Emergency information:
The Henkel information service also provides an around-the-clock telephone service on phone no.++49-(0)211-
797-3350 for exceptional cases.
The product is notified at the "Information Centers for Cases of Poisoning in Germany". These centers provide
information by telephone day and night in poisoning cases. Central emergency phone number: ++49 (0) 30
19240
Information office (content SDS):
UA Safety, Health, Environment TEL: +49-(0)211-797-3044 FAX:+49-(0)211-798-8520
EMAIL: AAT-SHEQ@henkel.com
2. Composition / information on ingredients
General chemical description:
Spray adhesive
Base substances of preparation:
Styrene-butadiene copolymer
in a mixture of organic solvents
Propellant gas base: propane/butane
Declaration of ingredients:
20 - 30 % Methyl acetate
EINECS 201-185-2
CAS 79-20-9
Symbol F, Xi
R-phrases R11, R36, R66, R67
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<2 % Cyclohexane
EINECS 203-806-2
CAS 110-82-7
Symbol F, Xn, N
R-phrases R11, R38, R65, R67, R50/53
10 - 15 % Propane
EINECS 200-827-9
CAS 74-98-6
Symbol F+
R-phrases R12
25 - 30 % Butane
EINECS 203-448-7
CAS 106-97-8
Symbol F+
R-phrases R12
10 - 15 % Naphtha (petroleum), hydrotreated light
EINECS 265-151-9
CAS 64742-49-0
Symbol Xn, N
R-phrases R10, R65, R66, R67, R51/53
<2 % Ethyl acetate
EINECS 205-500-4
CAS 141-78-6
Symbol F, Xi
R-phrases R11, R36, R66, R67
For full text of the R-Phrases indicated by codes see section 16 'Other Information'.
3. Hazards identification
The product is classified as hazardous within the meaning of the valid (EU) preparation guideline.
F+ - Extremely flammable
Xi - Irritant
R12 Extremely flammable.
R36 Irritating to eyes.
R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
R66 Repeated exposure may cause skin dryness or cracking.
R67 Vapours may cause drowsiness and dizziness.
The solvent vapors are heavier than air and may collect in high concentrations at floor level. In use, may form
explosive or highly flammable vapor-air mixtures
4. First-aid measures
General information:
In case of adverse health effects seek medical advice.
After inhalation:
Move to fresh air.
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V001.6
After skin contact:
Rinse with running water and soap. Skin care. Remove contaminated clothes immediately.
After eye contact:
Rinse immediately with plenty of running water, seek medical advice from a specialist.
After ingestion:
Rinse the mouth. Drink 1-2 glasses of water.
Do not induce vomiting.
5. Fire-fighting measures
Suitable extinguishing media:
Carbon dioxide.
extinguishing powder
Sand
Extinguishing media which must not be used for safety reasons:
water
Special protection equipment for firefighters:
Wear protective equipment.
Wear self-contained breathing apparatus.
Special hazards by the product itself:
Can form explosive gas/air mixtures.
Additional information:
In case of fire, keep containers cool with water spray.
Remove product from danger zone.
6. Accidental release measures
General information:
Sort out leaking cans, spray until empty and destroy.
Personal precautions:
Ensure adequate ventilation.
Avoid contact with skin and eyes.
Keep away from sources of ignition.
Wear protective equipment.
Environmental precautions:
Do not empty into drains / surface water / ground water.
Process for cleaning and take-up:
Remove with liquid-absorbing material (sand, peat, sawdust).
Dispose of contaminated material as waste according to item 13.
7. Handling and storage
Handling:
Ventilate working rooms thoroughly. Avoid naked flames, sparking and sources of ignition. Switch off electrical
devices. Do not smoke, do not weld. Do not empty waste into waste water drains.
Avoid skin and eye contact.
Transport by automobile: leave the container wrapped in a cloth in the trunk, never in the passenger area.
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Storage:
The storage regulations for aerosols apply.
Ensure that storage and workrooms are adequately ventilated.
Store protected from heat influence.
Store in a cool place, max. storage temperature 30癈.
Do not store together with food or other consumables (coffee, tea, tobacco, etc.).
8. Exposure controls / personal protection
Components with specific control parameters for workplace:
Valid for
Germany
mg/m3
Ingredient ppm Type Category Remarks
methyl acetate 200 610
methyl acetate 200 610 Occupational Exposure 4 If in compliance with the MAK
Limit (OEL). and BAT values, then there
should be no risk to the fetus.
methyl acetate Short Term Exposure Category II: substances with a
Classification. resorptive effect.
cyclohexane 200 700 Occupational Exposure 4
Limit (OEL).
cyclohexane Short Term Exposure Category II: substances with a
Classification. resorptive effect.
cyclohexane 200 700 Time Weighted Average
(TWA).
propane 1.000 1.800 Occupational Exposure 4
Limit (OEL).
propane Listed.
propane Short Term Exposure Category II: substances with a
Classification. resorptive effect.
butane 1.000 2.400 Occupational Exposure 4
Limit (OEL).
butane Short Term Exposure Category II: substances with a
Classification. resorptive effect.
ethyl acetate 400 1.500 Occupational Exposure 2 If in compliance with the MAK
Limit (OEL). and BAT values, then there
should be no risk to the fetus.
ethyl acetate Short Term Exposure Category I: substances for
Classification. which the localized effect has
an assigned OEL or for
substances with a sensitizing
effect in respiratory passages.
ethyl acetate Listed.
Additional information for system design:
Ensure good ventilation/extraction.
Respiratory protection:
Suitable breathing mask when there is inadequate ventilation.
Filter : AX
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Hand protection:
For shorttime contact (e.g. as protection against splashes) protective gloves made from butyl rubber are
recommended according to EN 374.
material thickness > 0.4 mm
Perforation time > 60 minutes
Manufacturer e.g. German company KCL, type Butoject 898.
In the case of longer and repeated contact please note that in practice the penetration times may be considerably
shorter than those determined according to EN 374. The protective gloves must always be checked for their
suitability for use at the specific workplace (e.g. mechanical and thermal stress, product compatibility, antistatic
effects, etc.). The gloves must be replaced immediately at the first signs of wear and tear. The information
provided by the manufacturers and given in the relevant trade association regulations for industrial safety must
always be observed. We recommend that a hand care plan is drawn up in cooperation with a glove manufacturer
and the trade association in accordance with the local operating conditions.
Eye protection:
Goggles which can be tightly sealed.
Body protection:
suitable protective clothing
General protection and hygiene measures:
Do not breathe solvent vapors.
Avoid skin and eye contact.
Do not eat, drink or smoke while working.
When using the product avoid alcohol consumption.
Keep away from food, beverages and animal feed.
Wash hands before work breaks and after finishing work.
9. Physical and chemical properties
General characteristics
State: aerosol
Odor: of solvent
Color(s): colourless
Phys./chem. properties:
Vapor pressure 8300 mbar
(20 癈) Values referring to propellant
Vapor pressure 17000 mbar
(50 癈) Values referring to propellant
Density 0,70 - 74 g/cm3
(20 癈)
Solubility (qualitative) low solubility
(20 癈; Solvent: water)
Explosion limit
lower 1,7 %(V)
upper 10,8 %(V)
Values referring to propellant
Explosion limit The product is not explosive. The formation of explosive
vapor/air mixtures is possible.
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10. Stability and reactivity
Conditions to avoid:
Container may burst when heated to over 50'C. The contents may form explosive, combustible mixture.
Avoid ignition sources and naked flames. Comply with warming on container label.
Materials to avoid:
None if used for intended purpose.
Dangerous decomposition products:
None known
11. Toxicological information
Acute inhalative toxicity:
The toxicity of the product is due to its narcotic effect after inhalation.
Danger of serious damage to health by prolonged exposure by inhalation.
Skin irritation:
Prolonged or repeated skin contact can lead to skin degreasing and hence to skin irritation.
Eye irritation:
Primary eye irritation: irritating
12. Ecological information
General ecological information:
Do not empty into drains, soil or bodies of water.
Ultimate biodegradation:
The product is poorly biodegradable.
13. Disposal considerations
Product disposal:
Waste incineration or treatment plant with the approval of the responsible local authority.
The valid EEC waste code numbers are not product-related but are largely source-related. The manufacturer is
therefore unable to specify EEC waste codes for the articles or products used in the various sectors. These can be
requested from the manufacturer.
Disposal of uncleaned packages:
Completely empty pressurized gas containers (including propellant gas).
Use packages for recycling only when totally empty.
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V001.6
14. Transport information
Road transport ADR:
Class: 2
Packaging group:
Classification code: 5F
Hazard ident. number:
UN no.: 1950
Label: 2.1
Propper shipping name: AEROSOLS
Railroad transport RID:
Class: 2
Packaging group:
Classification code: 5F
Hazard ident. number: 23
UN no.: 1950
Label: 2.1
Propper shipping name: AEROSOLS
Inland water transport ADN:
Class: 2
Packaging group:
Classification code: 5F
Hazard ident. number:
UN no.: 1950
Label: 2.1
Propper shipping name: AEROSOLS
Marine transport IMDG:
Class: 2.1
Packaging group:
EmS: F-D ,S-U
Seawater pollutant: -
UN no.: 1950
Label: 2.1
Propper shipping name: AEROSOLS
Air transport IATA:
Class: 2.1
Packaging group:
Packaging instructions (cargo): 203
Packaging instructions (passenger) 203
UN no.: 1950
Label: 2.1
Propper shipping name: Aerosols, flammable
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15. Regulations - classification and identification
Symbols of danger:
F+ - Extremely flammable
Xi - Irritant
R-phrases
R12 Extremely flammable.
R36 Irritating to eyes.
R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
R66 Repeated exposure may cause skin dryness or cracking.
R67 Vapours may cause drowsiness and dizziness.
S-phrases :
S2 Keep out of the reach of children.
S9 Keep container in a well-ventilated place.
S16 Keep away from sources of ignition - No smoking.
S23 Do not breathe spray.
S24/25 Avoid contact with skin and eyes.
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S29 Do not empty into drains.
S51 Use only in well-ventilated areas.
Special declaration:
Pressurized container: protect from sunlight and do not expose to temperatures exceeding 50 癈. Do not pierce
or burn, even after use. Do not spray on a naked flame or any incandescent material. Keep away from sources of
ignition - No smoking. Keep out of the reach of children
National regulations/information:
WGK: 1, slightly water-endangering product. (German VwVwS of May 17,
1999 )
Classification in conformity with the calculation method
BG regulations, rules, infos:
BG data sheet: BGI 621 Solvents
BG regulation: BGV B 1 Handling hazardous substances
Storage class VCI: 2B
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16. Other information
Full text of the R-phrases indicated by codes in this safety data sheet. The labeling of the product is indicated in
Section 15.
R10 Flammable.
R11 Highly flammable.
R12 Extremely flammable.
R36 Irritating to eyes.
R38 Irritating to skin.
R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
R65 Harmful: may cause lung damage if swallowed.
R66 Repeated exposure may cause skin dryness or cracking.
R67 Vapours may cause drowsiness and dizziness.
Further information:
This information is based on our current level of knowledge and relates to the product in the state in which it is
delivered. It is intended to describe our products from the point of view of safety requirements and is not
intended to guarantee any particular properties.
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