3M MATERIAL SAFETY DATA SHEET 3M(TM) General Trim Adhesive P.N. 08088 06/14/2006
Material Safety Data Sheet
Copyright, 2006, 3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly
utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is
obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit
thereon.
SECTION 1: PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: 3M(TM) General Trim Adhesive P.N. 08088
MANUFACTURER: 3M
DIVISION: Automotive Aftermarket
ADDRESS: 3M Center
St. Paul, MN 55144-1000
EMERGENCY PHONE: 1-800-364-3577 or (651) 737-6501 (24 hours)
Issue Date: 06/14/2006
Supercedes Date: 12/05/2005
Document Group: 16-6445-7
Product Use:
Intended Use: Adhesive
Limitations on Use: Not recommended for bonding polystyrene foam.
Specific Use: Automotive trim adhesive.
General Use: High strength adhesive for bonding automotive materials (carpeting, fabrics, plastics) to
metal and other surfaces.
SECTION 2: INGREDIENTS
Ingredient C.A.S. No. % by Wt
DIMETHYL ETHER 115-10-6 30 - 60
METHYL ACETATE 79-20-9 15 - 40
CYCLOHEXANE 110-82-7 7 - 13
BICYCLO[3.1.1]HEPT-2-ENE,2,6,6-TRIMETHYL-,POLYMER WITH 6,6- 31393-98-3 5 - 10
DIMETHYL-2-METHYLENEBICYCLO[3.1.1]HEPTANE
BENZENE, 1-ETHENYL-4-METHYL-, POLYMER WITH (1- 100199-62-0 1- 5
METHYLETHENYL)BENZENE
1,1-DIFLUOROETHANE 75-37-6 1- 5
HYDROTREATED LIGHT PETROLEUM DISTILLATES 64742-47-8 1- 5
NONVOLATILE COMPONENTS - TRADESECRET Trade Secret 1- 5
PETROLEUM DISTILLATE 64742-48-9 1- 5
SECTION 3: HAZARDS IDENTIFICATION
3.1 EMERGENCY OVERVIEW
_________________________________________________________________________________________________
Page 1 of 8
3M MATERIAL SAFETY DATA SHEET 3M(TM) General Trim Adhesive P.N. 08088 06/14/2006
Specific Physical Form: Aerosol
Odor, Color, Grade: Liquid in aerosol, clear, sweet fruity odor
General Physical Form: Liquid
Immediate health, physical, and environmental hazards: Closed containers exposed to heat from fire may build pressure and
explode. Extremely flammable liquid and vapor. Vapors may travel long distances along the ground or floor to an ignition source and
flash back. Aerosol container contains flammable material under pressure. May cause target organ effects. May cause
frostbite.
3.2 POTENTIAL HEALTH EFFECTS
Eye Contact:
Mild Eye Irritation: Signs/symptoms may include redness, pain, and tearing.
Frostbite: Signs/symptoms may include intense pain, clouding of the cornea, redness, swelling, and blindness.
Skin Contact:
Mild Skin Irritation: Signs/symptoms may include localized redness, swelling, and itching.
Frostbite: Signs/symptoms may include intense pain, discoloration of skin, and tissue destruction.
Inhalation:
Intentional concentration and inhalation may be harmful or fatal.
Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and
throat pain.
Cardiac Sensitization: Signs/symptoms may include irregular heartbeat (arrhythmia), faintness, chest pain, and may be fatal.
Single exposure, above recommended guidelines, may cause:
Simple Asphyxiation: Signs/symptoms may include increased heart rate, rapid respirations, drowsiness, headache,
incoordination, altered judgement, nausea, vomiting, lethargy, seizures, coma, and may be fatal.
May be absorbed following inhalation and cause target organ effects.
Ingestion:
Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea.
May be absorbed following ingestion and cause target organ effects.
Target Organ Effects:
May cause blindness.
Central Nervous System (CNS) Depression: Signs/symptoms may include headache, dizziness, drowsiness, incoordination, nausea,
slowed reaction time, slurred speech, giddiness, and unconsciousness.
Prolonged or repeated exposure may cause:
Liver Effects: Signs/symptoms may include loss of appetite, weight loss, fatigue, weakness, abdominal tenderness and
_________________________________________________________________________________________________
Page 2 of 8
3M MATERIAL SAFETY DATA SHEET 3M(TM) General Trim Adhesive P.N. 08088 06/14/2006
jaundice.
Kidney/Bladder Effects: Signs/symptoms may include changes in urine production, abdominal or lower back pain, increased
protein in urine, increased blood urea nitrogen (BUN), blood in urine, and painful urination.
Blood Effects: Signs/symptoms may include generalized weakness and fatigue, skin pallor, changes in blood clotting time,
internal bleeding, and/or hemoglobinemia.
SECTION 4: FIRST AID MEASURES
4.1 FIRST AID PROCEDURES
The following first aid recommendations are based on an assumption that appropriate personal and industrial hygiene practices are
followed.
Eye Contact: Flush eyes with large amounts of water. If signs/symptoms persist, get medical attention.
Skin Contact: Wash affected area with soap and water. If signs/symptoms develop, get medical attention.
Inhalation: Remove person to fresh air. Get immediate medical attention.
If Swallowed: Do not induce vomiting unless instructed to do so by medical personnel. Give victim two glasses of water. Never
give anything by mouth to an unconscious person. Get medical attention.
4.2 NOTE TO PHYSICIANS
Exposure may increase myocardial irritability. Do not administer sympathomimetic drugs unless absolutely necessary.
SECTION 5: FIRE FIGHTING MEASURES
5.1 FLAMMABLE PROPERTIES
No Data Available
Autoignition temperature
-40 篎 [Test Method: Tagliabue Closed Cup]
Flash Point
No Data Available
Flammable Limits - LEL
No Data Available
Flammable Limits - UEL
Class IA Flammable Liquid
OSHA Flammability Classification:
5.2 EXTINGUISHING MEDIA
Use fire extinguishers with class B extinguishing agents (e.g., dry chemical, carbon dioxide).
5.3 PROTECTION OF FIRE FIGHTERS
Special Fire Fighting Procedures: Water may not effectively extinguish fire; however, it should be used to keep fire-exposed
containers and surfaces cool and prevent explosive rupture. Wear full protective equipment (Bunker Gear) and a self-contained
breathing apparatus (SCBA).
Unusual Fire and Explosion Hazards: Closed containers exposed to heat from fire may build pressure and explode. Extremely
_________________________________________________________________________________________________
Page 3 of 8
3M MATERIAL SAFETY DATA SHEET 3M(TM) General Trim Adhesive P.N. 08088 06/14/2006
flammable liquid and vapor. Vapors may travel long distances along the ground or floor to an ignition source and flash back. Aerosol
container contains flammable material under pressure.
Note: See STABILITY AND REACTIVITY (SECTION 10) for hazardous combustion and thermal decomposition
information.
SECTION 6: ACCIDENTAL RELEASE MEASURES
Accidental Release Measures: Remove all ignition sources such as flames, smoking materials, and electrical spark sources. Use only
non-sparking tools. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to
disperse or exhaust vapors, in accordance with good industrial hygiene practice. Warning! A motor could be an ignition source and
could cause flammable gases or vapors in the spill area to burn or explode. Contain spill. Cover spill area with a fire-extinguishing
foam. An aqueous film forming foam (AFFF) is recommended. Working from around the edges of the spill inward, cover with
bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry.
Remember, adding an absorbent material does not remove a toxic, corrosivity or flammability hazard. Clean up residue with an
appropriate solvent selected by a qualified and authorized person. Ventilate the area with fresh air. Read and follow safety precautions
on the solvent label and MSDS. Collect the resulting residue containing solution. Place in a closed container approved for
transportation by appropriate authorities. Seal the container. Dispose of collected material as soon as possible.
In the event of a release of this material, the user should determine if the release qualifies as reportable according to
local, state, and federal regulations.
SECTION 7: HANDLING AND STORAGE
7.1 HANDLING
Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. Keep away from heat,
sparks, open flame, pilot lights and other sources of ignition. Do not pierce or burn container, even after use. No smoking while
handling this material. Do not spray near flames or sources of ignition. Avoid breathing of vapors, mists or spray. Avoid prolonged
or repeated skin contact. Aerosol container contains flammable gas under pressure. Avoid static discharge. Avoid eye contact with
vapors, mists, or spray. Keep out of the reach of children. For industrial or professional use only.
7.2 STORAGE
Store away from heat. Store out of direct sunlight.
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
8.1 ENGINEERING CONTROLS
Do not use in a confined area or areas with little or no air movement. Use in a well-ventilated area. If exhaust ventilation is not
available, use appropriate respiratory protection. Use with appropriate local exhaust ventilation. Use general dilution ventilation
and/or local exhaust ventilation to control airborne exposures to below Occupational Exposure Limits and/or control mist, vapor, or
spray. If ventilation is not adequate, use respiratory protection equipment.
8.2 PERSONAL PROTECTIVE EQUIPMENT (PPE)
8.2.1 Eye/Face Protection
Avoid eye contact with vapors, mists, or spray.
The following eye protection(s) are recommended: Safety Glasses with side shields, Indirect Vented Goggles.
8.2.2 Skin Protection
Gloves not normally required. Avoid skin contact. Avoid prolonged or repeated skin contact.
_________________________________________________________________________________________________
Page 4 of 8
3M MATERIAL SAFETY DATA SHEET 3M(TM) General Trim Adhesive P.N. 08088 06/14/2006
Select and use gloves and/or protective clothing to prevent skin contact based on the results of an exposure assessment. Consult with
your glove and/or protective clothing manufacturer for selection of appropriate compatible materials.
Gloves made from the following material(s) are recommended: Neoprene, Nitrile Rubber.
8.2.3 Respiratory Protection
Avoid breathing of vapors, mists or spray.
Select one of the following NIOSH approved respirators based on airborne concentration of contaminants and in accordance with
OSHA regulations: Half facepiece or fullface air-purifying respirator with organic vapor cartridges and P95 particulate prefilters.
Consult the current 3M Respiratory Selection Guide for additional information or call 1-800-243-4630 for 3M technical assistance.
8.2.4 Prevention of Swallowing
Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water.
8.3 EXPOSURE GUIDELINES
Ingredient Authority Type Limit Additional Information
1,1-DIFLUOROETHANE AIHA TWA 1000 ppm
1,1-DIFLUOROETHANE CMRG TWA 1000 ppm
CYCLOHEXANE ACGIH TWA 100 ppm
CYCLOHEXANE OSHA TWA 300 ppm Table Z-1
DIMETHYL ETHER AIHA TWA 1000 ppm
DIMETHYL ETHER CMRG TWA 1000 ppm
PETROLEUM DISTILLATE 3M TWA 100 ppm
PETROLEUM DISTILLATE CMRG TWA 300 ppm
HYDROTREATED LIGHT PETROLEUM CMRG TWA 300 ppm
DISTILLATES
METHYL ACETATE ACGIH TWA 200 ppm
METHYL ACETATE ACGIH STEL 250 ppm
METHYL ACETATE OSHA TWA 200 ppm Table Z-1A
METHYL ACETATE OSHA STEL 250 ppm Table Z-1A
SOURCE OF EXPOSURE LIMIT DATA:
ACGIH: American Conference of Governmental Industrial Hygienists
CMRG: Chemical Manufacturer Recommended Guideline
OSHA: Occupational Safety and Health Administration
AIHA: American Industrial Hygiene Association Workplace Environmental Exposure Level (WEEL)
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
Aerosol
Specific Physical Form:
Liquid in aerosol, clear, sweet fruity odor
Odor, Color, Grade:
Liquid
General Physical Form:
No Data Available
Autoignition temperature
-40 篎 [Test Method: Tagliabue Closed Cup]
Flash Point
No Data Available
Flammable Limits - LEL
No Data Available
Flammable Limits - UEL
No Data Available
Boiling point
0.781 g/ml [Details: Refers to density of the liquid]
Density
2.97 [Ref Std: AIR=1]
Vapor Density
No Data Available
Vapor Pressure
0.781 [Ref Std: WATER=1]
Specific Gravity
Not Applicable
pH
_________________________________________________________________________________________________
Page 5 of 8
3M MATERIAL SAFETY DATA SHEET 3M(TM) General Trim Adhesive P.N. 08088 06/14/2006
No Data Available
Melting point
Nil
Solubility in Water
1.90 [Ref Std: ETHER=1]
Evaporation rate
<=0.4 % weight
Hazardous Air Pollutants
53.62 % [Test Method: calculated SCAQMD rule 443.1]
Volatile Organic Compounds
53.62 % weight
Percent volatile
553.61 g/l [Test Method: calculated SCAQMD rule 443.1]
VOC Less H2O & Exempt Solvents
SECTION 10: STABILITY AND REACTIVITY
Stability: Stable.
Materials and Conditions to Avoid: Heat; Sparks and/or flames
Hazardous Polymerization: Hazardous polymerization will not occur.
Hazardous Decomposition or By-Products
Substance Condition
Carbon monoxide Not Specified
Carbon dioxide Not Specified
Toxic Vapor, Gas, Particulate Not Specified
SECTION 11: TOXICOLOGICAL INFORMATION
Please contact the address listed on the first page of the MSDS for Toxicological Information on this material and/or its
components.
SECTION 12: ECOLOGICAL INFORMATION
ECOTOXICOLOGICAL INFORMATION
Not determined.
CHEMICAL FATE INFORMATION
Not determined.
SECTION 13: DISPOSAL CONSIDERATIONS
Waste Disposal Method: Incinerate in an industrial or commercial facility in the presence of a combustible material. Incinerate in a
permitted hazardous waste incinerator. Facility must be capable of handling aerosol cans.
_________________________________________________________________________________________________
Page 6 of 8
3M MATERIAL SAFETY DATA SHEET 3M(TM) General Trim Adhesive P.N. 08088 06/14/2006
Since regulations vary, consult applicable regulations or authorities before disposal.
SECTION 14:TRANSPORT INFORMATION
ID Number(s):
60-9800-4516-9, 60-9801-0537-7
Please contact the emergency numbers listed on the first page of the MSDS for Transportation Information for this
material.
SECTION 15: REGULATORY INFORMATION
US FEDERAL REGULATIONS
Contact 3M for more information.
311/312 Hazard Categories:
Fire Hazard - Yes Pressure Hazard - Yes Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - Yes
Section 313 Toxic Chemicals subject to the reporting requirements of that section and 40 CFR part 372 (EPCRA):
Ingredient C.A.S. No % by Wt
CYCLOHEXANE 110-82-7 7 - 13
This material contains a chemical which requires export notification under TSCA Section 12[b]:
Ingredient (Category if applicable) C.A.S. No Regulation Status
CYCLOHEXANE 110-82-7 Toxic Substances Control Act (TSCA) 4 Test Applicable
Rule Chemicals
METHYL ACETATE 79-20-9 Toxic Substances Control Act (TSCA) 4 Test Applicable
Rule Chemicals
STATE REGULATIONS
Contact 3M for more information.
CHEMICAL INVENTORIES
The components of this product are in compliance with the chemical notification requirements of TSCA.
All applicable chemical ingredients in this material are listed on the European Inventory of Existing Chemical Substances (EINECS),
or are exempt polymers whose monomers are listed on EINECS.
Contact 3M for more information.
_________________________________________________________________________________________________
Page 7 of 8
3M MATERIAL SAFETY DATA SHEET 3M(TM) General Trim Adhesive P.N. 08088 06/14/2006
INTERNATIONAL REGULATIONS
Contact 3M for more information.
WHMIS: Hazardous
This MSDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200.
SECTION 16: OTHER INFORMATION
NFPA Hazard Classification
Health: 2 Flammability: 4 Reactivity: 0 Special Hazards: None
Aerosol Storage Code: 2
National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are
presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the
inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to
be generated in significant quantities.
Revision Changes:
Copyright was modified.
Section 9: Property description for optional properties was modified.
DISCLAIMER: The information in this Material Safety Data Sheet (MSDS) is believed to be correct as of the date issued. 3M
MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY
OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF
TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of
use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely
within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a
particular purpose and suitable for user's method of use or application.
3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may
have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy.
In addition, information obtained from a database may not be as current as the information in the MSDS available directly from 3M.
3M MSDSs are available at www.3M.com
_________________________________________________________________________________________________
Page 8 of 8
|