3M MATERIAL SAFETY DATA SHEET 3M(TM) Scotch-Weld(TM) General Purpose 60CA Cylinder Spray Adhesive 01/19/2007
Material Safety Data Sheet
Copyright, 2007, 3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly
utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is
obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit
thereon.
SECTION 1: PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: 3M(TM) Scotch-Weld(TM) General Purpose 60CA Cylinder Spray Adhesive
MANUFACTURER: 3M
DIVISION: Industrial Adhesives and Tapes Division
ADDRESS: 3M Center
St. Paul, MN 55144-1000
EMERGENCY PHONE: 1-800-364-3577 or (651) 737-6501 (24 hours)
Issue Date: 01/19/2007
Supercedes Date: Initial Issue
Document Group: 22-4468-9
Product Use:
Intended Use: Adhesive
SECTION 2: INGREDIENTS
Ingredient C.A.S. No. % by Wt
METHYL ACETATE 79-20-9 50 - 60
NONHAZARDOUS INGREDIENTS Trade Secret 35 - 45
HEXANE 110-54-3 1- 4
CARBON DIOXIDE 124-38-9 1- 3
1,1-DIFLUOROETHANE 75-37-6 0.5 - 1
SECTION 3: HAZARDS IDENTIFICATION
3.1 EMERGENCY OVERVIEW
Odor, Color, Grade: Solvent Odor
General Physical Form: Gas
Immediate health, physical, and environmental hazards: Closed containers exposed to heat from fire may build pressure and
explode. Extremely flammable liquid and vapor. Vapors may travel long distances along the ground or floor to an ignition source and
flash back. May cause target organ effects. Contains a chemical or chemicals which can cause birth defects or other
reproductive harm.
3.2 POTENTIAL HEALTH EFFECTS
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3M MATERIAL SAFETY DATA SHEET 3M(TM) Scotch-Weld(TM) General Purpose 60CA Cylinder Spray Adhesive 01/19/2007
Eye Contact:
Moderate Eye Irritation: Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy vision.
Skin Contact:
Mild Skin Irritation: Signs/symptoms may include localized redness, swelling, and itching.
May be absorbed through skin and cause target organ effects.
Inhalation:
Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and
throat pain.
Intentional concentration and inhalation may be harmful or fatal.
May be absorbed following inhalation and cause target organ effects.
Ingestion:
Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea.
May be absorbed following ingestion and cause target organ effects.
Target Organ Effects:
Central Nervous System (CNS) Depression: Signs/symptoms may include headache, dizziness, drowsiness, incoordination, nausea,
slowed reaction time, slurred speech, giddiness, and unconsciousness.
Prolonged or repeated exposure may cause:
Peripheral Neuropathy: Signs/symptoms may include tingling or numbness of the extremities, incoordination, weakness of
the hands and feet, tremors and muscle atrophy.
Contains a chemical or chemicals which can cause birth defects or other reproductive harm.
SECTION 4: FIRST AID MEASURES
4.1 FIRST AID PROCEDURES
The following first aid recommendations are based on an assumption that appropriate personal and industrial hygiene practices are
followed.
Eye Contact: Flush eyes with large amounts of water. If signs/symptoms persist, get medical attention.
Skin Contact: Wash affected area with soap and water. If signs/symptoms develop, get medical attention.
Inhalation: Remove person to fresh air. If signs/symptoms develop, get medical attention.
If Swallowed: Do not induce vomiting unless instructed to do so by medical personnel. Give victim two glasses of water. Never
give anything by mouth to an unconscious person. Get medical attention.
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3M MATERIAL SAFETY DATA SHEET 3M(TM) Scotch-Weld(TM) General Purpose 60CA Cylinder Spray Adhesive 01/19/2007
SECTION 5: FIRE FIGHTING MEASURES
5.1 FLAMMABLE PROPERTIES
No Data Available
Autoignition temperature
8 篎
Flash Point
3.1 % volume
Flammable Limits - LEL
16 % volume
Flammable Limits - UEL
5.2 EXTINGUISHING MEDIA
Use fire extinguishers with class B extinguishing agents (e.g., dry chemical, carbon dioxide).
5.3 PROTECTION OF FIRE FIGHTERS
Special Fire Fighting Procedures: Wear full protective equipment (Bunker Gear) and a self-contained breathing apparatus
(SCBA).
Unusual Fire and Explosion Hazards: Closed containers exposed to heat from fire may build pressure and explode. Extremely
flammable liquid and vapor. Vapors may travel long distances along the ground or floor to an ignition source and flash back.
Note: See STABILITY AND REACTIVITY (SECTION 10) for hazardous combustion and thermal decomposition
information.
SECTION 6: ACCIDENTAL RELEASE MEASURES
Accidental Release Measures: Refer to other sections of this MSDS for information regarding physical and health hazards,
respiratory protection, ventilation, and personal protective equipment. Call 3M-HELPS line (1-800-364-3577) for more information
on handling and managing the spill. Evacuate unprotected and untrained personnel from hazard area. The spill should be cleaned up
by qualified personnel. Remove all ignition sources such as flames, smoking materials, and electrical spark sources. Use only non-
sparking tools. Ventilate the area with fresh air. Contain spill. Close cylinder. If the cylinder can't be closed, place in a well-
ventilated area, preferably an operating exhaust hood, or if necessary outdoors. Clean up residue. Collect the resulting residue
containing solution. Place in a closed container approved for transportation by appropriate authorities. Dispose of collected material
as soon as possible.
In the event of a release of this material, the user should determine if the release qualifies as reportable according to
local, state, and federal regulations.
SECTION 7: HANDLING AND STORAGE
7.1 HANDLING
Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. Keep away from heat,
sparks, open flame, pilot lights and other sources of ignition. No smoking while handling this material. Avoid breathing of vapors,
mists or spray. Avoid eye contact with vapors, mists, or spray. Keep out of the reach of children. Vapors may ignite explosively.
May cause flash fire. Prevent build-up of vapors - open all windows and doors. Maintain vapor concentrations below recommended
exposure limits. Use only with cross-ventilation. Without adequate ventilation, vapors may settle in low-lying areas. Keep away from
heat, sparks, and open flame. Do not smoke or ignite matches, lighters, etc. Use general dilution ventilation and/or local exhaust
ventilation to control airborne exposures to below Occupational Exposure Limits. If ventilation is not adequate, use respiratory
protection equipment.
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3M MATERIAL SAFETY DATA SHEET 3M(TM) Scotch-Weld(TM) General Purpose 60CA Cylinder Spray Adhesive 01/19/2007
7.2 STORAGE
Store away from acids. Keep container in well-ventilated area.
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
8.1 ENGINEERING CONTROLS
Use with appropriate local exhaust ventilation. Provide appropriate local exhaust ventilation on open containers. Do not use in a
confined area or areas with little or no air movement. Use general dilution ventilation and/or local exhaust ventilation to control
airborne exposures to below Occupational Exposure Limits and/or control mist, vapor, or spray. If ventilation is not adequate, use
respiratory protection equipment.
8.2 PERSONAL PROTECTIVE EQUIPMENT (PPE)
8.2.1 Eye/Face Protection
Avoid eye contact with vapors, mists, or spray.
The following eye protection(s) are recommended: Safety Glasses with side shields, Indirect Vented Goggles.
8.2.2 Skin Protection
Avoid skin contact.
Select and use gloves and/or protective clothing to prevent skin contact based on the results of an exposure assessment. Consult with
your glove and/or protective clothing manufacturer for selection of appropriate compatible materials.
Gloves made from the following material(s) are recommended: Butyl Rubber.
8.2.3 Respiratory Protection
Avoid breathing of vapors, mists or spray.
Select one of the following NIOSH approved respirators based on airborne concentration of contaminants and in accordance with
OSHA regulations: Half facepiece or fullface air-purifying respirator with organic vapor cartridges. Consult the current 3M
Respiratory Selection Guide for additional information or call 1-800-243-4630 for 3M technical assistance.
8.2.4 Prevention of Swallowing
Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. Not applicable.
8.3 EXPOSURE GUIDELINES
Ingredient Authority Type Limit Additional Information
1,1-DIFLUOROETHANE AIHA TWA 1000 ppm
1,1-DIFLUOROETHANE CMRG TWA 1000 ppm
CARBON DIOXIDE ACGIH TWA 5000 ppm
CARBON DIOXIDE ACGIH STEL 30000 ppm
CARBON DIOXIDE OSHA TWA 10000 ppm Table Z-1A
CARBON DIOXIDE OSHA STEL 30000 ppm Table Z-1A
HEXANE ACGIH TWA 50 ppm Skin Notation*
HEXANE OSHA TWA, Vacated 50 ppm Table Z-1A
HEXANE OSHA TWA 500 ppm Table Z-1A
METHYL ACETATE ACGIH TWA 200 ppm
METHYL ACETATE ACGIH STEL 250 ppm
METHYL ACETATE OSHA TWA 200 ppm Table Z-1A
METHYL ACETATE OSHA STEL 250 ppm Table Z-1A
* Substance(s) refer to the potential contribution to the overall exposure by the cutaneous route including mucous membrane and eye,
either by airborne or, more particularly, by direct contact with the substance. Vehicles can alter skin absorption.
VAC Vacated PEL:Vacated Permissible Exposure Limits [PEL] are enforced as the OSHA PEL in some states. Check with your local
regulatory agency.
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3M MATERIAL SAFETY DATA SHEET 3M(TM) Scotch-Weld(TM) General Purpose 60CA Cylinder Spray Adhesive 01/19/2007
SOURCE OF EXPOSURE LIMIT DATA:
ACGIH: American Conference of Governmental Industrial Hygienists
CMRG: Chemical Manufacturer Recommended Guideline
OSHA: Occupational Safety and Health Administration
AIHA: American Industrial Hygiene Association Workplace Environmental Exposure Level (WEEL)
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
Solvent Odor
Odor, Color, Grade:
Gas
General Physical Form:
No Data Available
Autoignition temperature
8 篎
Flash Point
3.1 % volume
Flammable Limits - LEL
16 % volume
Flammable Limits - UEL
140 篎
Boiling point
2.8 [Ref Std: AIR=1]
Vapor Density
163 mmHg [@ 20 篊]
Vapor Pressure
0.93 - 0.95 [Ref Std: WATER=1]
Specific Gravity
No Data Available
pH
No Data Available
Melting point
Nil
Solubility in Water
0
Hazardous Air Pollutants
3.67
Volatile Organic Compounds
35 g/l
Volatile Organic Compounds
79 g/l
VOC Less H2O & Exempt Solvents
SECTION 10: STABILITY AND REACTIVITY
Stability: Stable.
Materials and Conditions to Avoid: Sparks and/or flames
Hazardous Polymerization: Hazardous polymerization will not occur.
Hazardous Decomposition or By-Products
Substance Condition
Aldehydes During Combustion
Hydrocarbons During Combustion
Carbon monoxide During Combustion
Carbon dioxide During Combustion
Irritant Vapors or Gases During Combustion
SECTION 11: TOXICOLOGICAL INFORMATION
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3M MATERIAL SAFETY DATA SHEET 3M(TM) Scotch-Weld(TM) General Purpose 60CA Cylinder Spray Adhesive 01/19/2007
Please contact the address listed on the first page of the MSDS for Toxicological Information on this material and/or its
components.
SECTION 12: ECOLOGICAL INFORMATION
ECOTOXICOLOGICAL INFORMATION
Not determined.
CHEMICAL FATE INFORMATION
Not determined.
SECTION 13: DISPOSAL CONSIDERATIONS
Waste Disposal Method: Incinerate in a permitted hazardous waste incinerator. As a disposal alternative, dispose of waste product
in a permitted hazardous waste facility.
The facility should be equipped to handle gaseous waste.
EPA Hazardous Waste Number (RCRA): D001 (Ignitable)
Since regulations vary, consult applicable regulations or authorities before disposal.
SECTION 14:TRANSPORT INFORMATION
ID Number(s):
62-4952-8030-7, 62-4952-8150-3, 62-4952-8300-4
Please contact the emergency numbers listed on the first page of the MSDS for Transportation Information for this
material.
SECTION 15: REGULATORY INFORMATION
US FEDERAL REGULATIONS
Contact 3M for more information.
311/312 Hazard Categories:
Fire Hazard - Yes Pressure Hazard - Yes Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - Yes
Section 313 Toxic Chemicals subject to the reporting requirements of that section and 40 CFR part 372 (EPCRA):
Ingredient C.A.S. No % by Wt
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3M MATERIAL SAFETY DATA SHEET 3M(TM) Scotch-Weld(TM) General Purpose 60CA Cylinder Spray Adhesive 01/19/2007
HEXANE 110-54-3 1- 4
This material contains a chemical which requires export notification under TSCA Section 12[b]:
Ingredient (Category if applicable) C.A.S. No Regulation Status
HEXANE 110-54-3 Toxic Substances Control Act (TSCA) 4 Test Applicable
Rule Chemicals
METHYL ACETATE 79-20-9 Toxic Substances Control Act (TSCA) 4 Test Applicable
Rule Chemicals
STATE REGULATIONS
CHEMICAL INVENTORIES
The components of this product are in compliance with the chemical notification requirements of TSCA.
Contact 3M for more information.
INTERNATIONAL REGULATIONS
Contact 3M for more information.
This MSDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200.
SECTION 16: OTHER INFORMATION
NFPA Hazard Classification
Health: 2 Flammability: 3 Reactivity: 0 Special Hazards: None
National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are
presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the
inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to
be generated in significant quantities.
No revision information is available.
DISCLAIMER: The information in this Material Safety Data Sheet (MSDS) is believed to be correct as of the date issued. 3M
MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY
OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF
TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of
use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely
within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a
particular purpose and suitable for user's method of use or application.
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3M MATERIAL SAFETY DATA SHEET 3M(TM) Scotch-Weld(TM) General Purpose 60CA Cylinder Spray Adhesive 01/19/2007
3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may
have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy.
In addition, information obtained from a database may not be as current as the information in the MSDS available directly from 3M.
3M MSDSs are available at www.3M.com
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