MATERIAL SAFETY DATA SHEET
SECTION 1 ?CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: FPPF BRAKE 3
IDENTIFICATION NUMBER: A-1114-20 DATE PRINTED: 01/04/2006
PRODUCT USE/CLASS: BRAKE CLEANER
FPPF CHEMICAL COMPANY, INC. FPPF CHEMICAL COMPANY, INC.
117 WEST TUPPER STREET 117 WEST TUPPER STREET
BUFFALO, NEW YORK 14201-2193 BUFFALO, NEW YORK 14201-2193
PHONE: 716-856-9607 PHONE: 716-856-9607
FAX: 716-856-0750 FAX: 716-856-0750
24-HR PRODUCT EMERGENCY NUMBER: 1-800-424-9300
PREPARER: , PHONE: , PREPARE DATE: 11/11/04
SECTION 2 ?COMPOSITION/INFORMATION ON INGREDIENTS
ITEM CHEMICAL NAME CAS NUMBER WT/WT % LESS THAN
01 2-PROPANONE 67-64-1 50.0%
02 N-HEPTANE 142-82-5 45.0%
03 CARBON DIOXIDE 124-38-9 10.0%
04 METHYL ACETATE 79-20-9 5.0%
EXPOSURE LIMITS
ACGIH OSHA COMPANY
ITEM TLV-TWA TLV-STEL PEL-TWA PEL-CEILING TLV-TWA SKIN
01 750 PPM 1000 PPM 750 PPM N.E. N.E. NO
02 400 PPM 500 PPM 400 PPM 500 PPM N.E. YES
03 5000 PPM 30000 PPM 5000 PPM N.E. N.E. YES
04 200 PPM 250 PPM 200 PPM N.E. N.E. NO
(See Section 16 for abbreviation legend)
SECTION 3 ?HAZARDS IDENTIFICATION
*** EMERGENCY OVERVIEW ***: Vapors irritating to eyes and respiratory tract. Vapors may cause flash fire or
explosion.
EFFECTS OF OVEREXPOSURE ?EYE CONTACT: Liquid, aerosols and vapors of this product are irritating and can
cause pain, tearing, reddening and swelling accompanied by a stinging sensation and/or a feeling like that of fine dust in
the eyes.
EFFECTS OF OVEREXP OSURE ?SKIN CONTACT: Prolonged or repeated contact can result in defatting and drying of
the skin which may result in skin irritation and dermatitis (rash).
EFFECTS OF OVEREXPOSURE ?INHALATION: Headaches, dizziness, nausea, decreased blood pressure, changes in
heart rate and cyanosis may result from over-exposure to vapor or skin exposure. Prolonged inhalation may be harmful.
EFFECTS OF OVEREXPOSURE ?INGESTION: This material may be harmful or fatal if swallowed. Corrosive and may
cause severe and permanent damage to mouth, throat and stomach.
EFFECTS OF OVEREXPOSURE ?CHRONIC HAZARDS: Overexposure may cause nervous system damage.
Overexposure may cause lung damage. Overexposure may cause kidney damage.
PRMARY ROUTE (S) OF ENTRY: SKIN CONTACT, SKIN ABSORPTION, INHALATION, INGESTION, EYE CONTACT
SECTION 4 ?FIRST AID MEASURES
FIRST AID ?EYE CONTACT: Immediately flush eyes with plenty of water. Get medical attention if irritation persists.
FIRST AID ?SKIN CONTACT: Immediately flush skin with plenty of water. Remove clothing. Get medical attention
immediately. Wash clothing separately before reuse.
FIRST AID ?INHALATION: Remove to fresh air. It not breathing, give artificial respiration. If breathing is difficult, give
oxygen. Get immediate medical attention.
FIRST AID ?INGESTION: Get medical attention immediately. It swallowed, do NOT induce vomiting. Give victim a
glass of water or milk. Call a physician or poison control center immediately. Never give anything by mouth to an
unconscious person.
SECTION 5 ?FIRE FIGHTING MEASURES
FLASH POINT: -4 F LOWER EXPLOSIVE LIMIT: 1.2%
(PENSKY-MARTENS C.C.) UPPER EXPLOSIVE LIMIT: 16.0%
AUTOIGNITION TEMPERATURE: ND
EXTINGUISHING MEDIA: ALCOHOL FOAM C02 DRY CHEMICAL FOAM WATER FOG
UNUSUAL FIRE AND EXPLOSION HAZARDS: Vapors can travel to a source of ignition and flash back. "Empty"
containers retain product residue (liquid and/or vapor) and can be dangerous. DO NOT PRESSURIZE, CUT, WELD,
BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE SUCH CONTAINERS TO HEAT, FLAME, SPARKS, STATIC
ELECTRICITY, OR OTHER SOURCES OF IGNITION; THEY MAY EXPLODE AND CAUSE INJURY OR DEATH.
Empty drums should be completely drained, properly bunged and promptly returned to a drum reconditioner, or properly
disposed of.
SPECIAL FIREFIGHTING PROCEDURES: Containers can build up pressure if exposed to heat (fire). As in any fire,
wear self-contained breathing apparatus pressure-demand (MSHA/NIOSH approved or equivalent) and full protective
gear.
SECTION 6 ?ACCIDENTAL RELEASE MEASURES
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Absorb spill with inert material (e.g. dry sand
or earth), then place in a chemical waste container.
SECTION 7 ?HANDLING AND STORAGE
HANDLING: Wash thoroughly after handling.
STORAGE: Keep away from heat, sparks and flame. Keep from freezing.
SECTION 8 ?EXPOSURE CONTROLS/PERSONAL PROTECTION
ENGINEERING CONTROLS: Local exhaust ventilation may be necessary to control any air contaminants to within their
TLVs during the use of this product.
RESPIRATORY PROTECTION: A NIOSH/MSHA approved air purifying respirator with an organic vapor cartridge or
canister may be permissible under certain circumstances where airborne concentrations are expected to exceed exposure
limits. Protection provided by air purifying respirators is limited. Use a positive pressure air supplied respirator if there is
any potential for an uncontrolled release, exposure levels are not known, or any other circumstances where air purifying
respirators my not provide adequate protection.
SKIN PROTECTION: Where contact is likely, wear chemical resistant gloves,
a chemical suit, rubber boots, and chemical safety goggles plus a face shield.
EYE PROTECTION: Wear safety glasses with side shields (or goggles) and a face shield.
OTHER PROTECTIVE EQUIPMENT: STANDARD INDUSTRIAL CLOTHING STANDARDS SHOULD BE FOLLOWED:
HYGIENIC PRACTICES: Wash hands before eating. Remove contaminated clothing and wash before reuse. Use only
in a well ventilated area. Follow all MSDS/label precautions even after container is emptied because they may retain
product residues. Avoid prolonged or repeated contact with skin. Avoid breathing vapors from heated material. Avoid
contact with eyes, skin and clothing.
SECTION 9 ?PHYSICAL AND CHEMICAL PROPERTIES
BOILING RANGE: 132 - 209 F VAPOR DENSITY: Is heavier than air
ODOR: SOLVENT ODOR THRESHOLD: ND
APPEARANCE: COLORLESS EVAPORATION RATE: Is faster than Butyl Acetate
SOLUBILITY IN H20: NEGLIGIBLE SPECIFIC GRAVITY: 0.7817
FREEZE POINT: 32 Ph @ 0.0%: NA
VAPOR PRESSURE: 95-105 VISCOCITY: NA
PHYSICAL STATE: LIQUID
COEFFICIENT OF WATER/OIL DISTRIBUTION: COMPLETE
(See Section 16 for abbreviation legend)
SECTION 10 ?STABILITY AND REACTIVITY
CONDITIONS TO AVOID: ALL SOURCES OF IGNITION, WELDING ARCS, AND OPEN FLAMES.
INCOMPATIBILITY: STRONG ACIDS, ALKALIS, OXIDIZERS, AND AMINES.
HAZARDOUS DECOMPOSITION PRODUCTS: OXIDES OF CARBON, OXIDES OF NITROGEN, AND MAY PRODUCE
FORMS OF CHLORIDE, CHLORINE, AND PHOSGENE.
Product: A-1114-20 Preparation Date: 10/06/04
HAZARDOUS POLYMERIZATION: Will not occur under normal conditions.
STABILITY: This product is stable under normal storage conditions.
SECTION 11 ?TOXICOLOGICAL PROPERTIES
PRODUCT LD50: 5000 mg/kg PRODUCT LC50: 18937 ppm
COMPONENT TOXICOLOGICAL INFORMATION:
CHEMICAL NAME LD50 LC50
2-PROPANONE 5800 MG/KG/RAT 50100 MG/M3/8H/RAT
N-HEPTANE >7100 MG/KG/RAT 103000 MG/M3/4H/RA
CARBON DIOXIDE NE NE
METHYL ACETATE 6970 MG/KG/RAT >16000 PPM/4H/RAT
SECTION 12 ?ECOLOGICAL INFORMATION
ECOLOGICAL INFORMATON: No Information.
SECTION 13 ?DISPOSAL CONSIDERATIONS
DISPOSAL METHOD:
DISPOSE IN ACCORDANCE WITH ALL FEDERAL, STATE AND LOCAL REGULATIONS.
SECTION 14 ?TRANSPORATION INFORMATION
DOT PROPER SHIPPING NAME: AEROSOL ?CONSUMER COMMODITY
DOT TECHNICAL NAME: ORM-D
DOT HAZARD CLASS: 2.2 HAZARD SUBCLASS: NA
DOT UN/NA NUMBER: UN1950 PACKING GROUP: NA RESP. GUIDE PAGE: 126
SECTION 15 ?REGULATORY INFORMATION
U.S. FEDERAL REGULATIONS: AS FOLLOWS ?br>
OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200)
CERCLA ?SARA HAZARD CATEGORY: This product has been reviewed according to the EPA `Hazard Categories'
promulgated under Sections 311 and 312 of the Superfund Amendment and Reauthorization Act of 1986 (SARA Title III)
and is considered, under applicable definitions, to meet the following categories:
IMMEDIATE HEALTH HAZARD CHRONIC HEALTH HAZARD FIRE HAZARD
PRESSURIZED GAS HAZARD
SARA SECTION 313: This product contains the following substances subject to the reporting requirements of Section
313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372:
CHEMICAL NAME CAS NUMBER WT/WT % LESS THAN
No SARA Section 313 components exist in this product.
TOXIC SUBSTANCES CONTROL ACT: This product contains the following chemical substances subject to the reporting
requirements of TSCA 12 (B) if exported from the United State:
CHEMICAL NAME CAS NUMBER
N-HEPTANE 142-82-5
U.S. STATE REGULATIONS: AS FOLLOWS ?br>
NEW JERSEY RIGHT-TO-KNOW: The following materials are non-hazardous, but are among the top five components in
this product:
CHEMICAL NAME CAS NUMBER
No non-hazardous materials are among the top five ingredients.
PENNSYLVANIA RIGHT-TO-KNOW: The following non-hazardous ingredients are present in the product at greater than
3%:
CHEMICAL NAME CAS NUMBER
No non-hazardous ingredients are present at greater than 3%.
Product: A-1114-20 Preparation Date: 11/11/04
SECTION 15 ?REGULATORY INFORMATION
CALIFORNIA PROPOSITION 65: WARNING: The chemical(s) noted below and contained in this product are known to
the state of California to cause cancer, birth defects or other reproductive harm:
CHEMICAL NAME CAS NUMBER
No Proposition 65 chemicals exist in this product.
INTERNATIONAL REGULATIONS: AS FOLLOWS ?br>
CANADIAN WHMIS: This MSDS has been prepared in compliance with Controlled Product Regulations except for use of
the 16 headings.
CANADIAN WHMIS CLASS: No information available.
SECTION 16 ?OTHER INFORMATION
HMIS RATINGS ?HEALTH: 2 FLAMMABILITY: 4 REACTIVITY: 0
MSDS REVISION DATE: 04/01/08
VOLATILE ORGANIC COMPOUNDS (VOCS): 2.84 lbs/gal, 340 grams/ltr
LEGEND: N.A. ?Not Applicable, N.E. ?Not Established, N.D. ?Not Determined
The information contained on this MSDS has been checked and should be accurate. However, it is the responsibility of
the user to comply with all Federal, State and Local Laws and regulations.
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