MATERIAL SAFETY DATA SHEET Page: 1
Klean-Strip Brush Cleaner
Flammability Instability
HEALTH 3 3 Printed: 12/12/2005
3
FLAMMABILITY Revision: 10/21/2005
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PHYSICAL HAZ. Health
PPE G Special
1. Product and Company Identification
GBC12
Product Code:
Klean-Strip Brush Cleaner
Product Name:
805.13
Reference #:
Manufacturer Information
W. M. Barr
Company Name:
2105 Channel Avenue
Memphis, TN 38113
(901)775-0100
Phone Number:
3E 24 Hour Emergency Contact (800)451-8346
Emergency Contact:
W.M. Barr Customer Service (800)398-3892
Information:
www.wmbarr.com
Web site address:
W.M. Barr and Company, Inc. (901)775-0100
Preparer Name:
2. Composition/Information on Ingredients
Hazardous Components (Chemical Name) CAS # Percentage OSHA TWA ACGIH TWA Other Limits
1. N-Methyl-2-Pyrrolidone 872-50-4 1.0 -10.0 % No data. No data. No data.
2. Dichloromethane 75-09-2 1.0 -3.0 % 25 ppm 50 ppm No data.
3. Methanol 67-56-1 5.0 -35.0 % 200 ppm 200 ppm No data.
4. Toluene 108-88-3 1.0 -10.0 % 200 ppm 50 ppm No data.
5. Tall oil acids 61790-12-3 1.0 -5.0 % No data. No data. No data.
6. Potassium hydroxide 1310-58-3 1.0 -5.0 % 100 ppm 5 ppm No data.
7. Ethanol, 2-Amino- 141-43-5 1.0 -5.0 % 3 ppm 3 ppm No data.
8. Raffinates (petroleum), sorption process 64741-85-1 20.0 -80.0 % No data. No data. No data.
9. Acetone 67-64-1 15.0 -30.0 % 1000 ppm 500 ppm No data.
Hazardous Components (Chemical Name) RTECS # OSHA STEL OSHA CEIL ACGIH STEL ACGIH CEIL
1. N-Methyl-2-Pyrrolidone UY5790000 No data. No data. No data. No data.
2. Dichloromethane PA8050000 125 ppm (15 min) No data. No data. No data.
3. Methanol PC1400000 No data. No data. 250 ppm No data.
4. Toluene XS5250000 500 ppm/(10min) 300 ppm No data. No data.
5. Tall oil acids NA No data. No data. No data. No data.
6. Potassium hydroxide TT2100000 No data. No data. No data. 2 mg/m3
7. Ethanol, 2-Amino- KJ5775000 No data. No data. 6 ppm No data.
8. Raffinates (petroleum), sorption process NA No data. No data. No data. No data.
9. Acetone AL3150000 No data. No data. 750 ppm No data.
3. Hazards Identification
Emergency Overview
Danger! Extremely flammable. Keep away from heat, sparks, flame and all other sources of ignition. Vapors
may cause flash fire or ignite explosively. Vapors may travel long distances to other areas and rooms away from
work site. Do not smoke. Extinguish all flames and pilot lights, and turn off stoves, heaters, electric motors and
all other sources of ignition anywhere in the structure, dwelling or building during use and until all vapors are
gone from the work site and all areas away from the work site. Keep away from electrical outlets and switches.
Beware of static electricity that may be generated by synthetic clothing and other sources.
This material is classified as hazardous under OSHA regulations.
OSHA Regulatory Status:
Licensed to W.M. Barr and Company ANSI Z400.1 Format
MATERIAL SAFETY DATA SHEET Page: 2
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Klean-Strip Brush Cleaner Revision: 10/21/2005
Health Hazards (Acute and Chronic)
Inhalation Acute Exposure Effects:
Vapor harmful. May cause dizziness, headache, irritation of the respiratory tract, injuries to mucous membranes,
watering of eyes, weakness, drowsiness, nausea, loss of coordination, numbness in fingers and arms and legs,
depression of central nervous system, loss of appetite, blurred vision, fatigue, stupor, vomiting, stomach and
intestinal pain, heartburn, confusion, brain damage, lower blood pressure, liver and kidney injury, hallucinations,
irregular heartbeat, cold clammy extremities, diarrhea, blood disorders,spotted vision, dilation of pupils, visual
disturbances, giddiness and intoxication, sleepiness, cough and dypsnea, nose tumors, hot flashes, arm leg and
chest pain, rapid heartbeat, increase in carboxyhemoglobin levels which can cause stress to the cardiovascular
system, convulsions, unconsciousness, coma, and death.
Elevated carboxyhemoglobin levels can be additive to the increase caused by smoking and other carbon monoxide
sources.
Intentional misuse of this product by deliberately concentrating and inhaling can be harmful or fatal. May
produce symptoms similar to those listed under ingestion.
Skin Contact Acute Exposure Effects:
This product may be absorbed through the skin. HArmful if absorbed through skin. May cause irritation, drying
and cracking of skin, defatting of skin, dermatitis, itching, burning, redness, inflammation, swelling, tissue
damage, keratitis, discomfort or pain, erythema, numbness in fingers and arms. May be absorbed readily to
produce symptoms similar to those listed for ingestion. Prolonged or widespread contact may result in
absorption of potentially harmful amounts of this material. May cause additional symptoms listed under
inhalation.
Eye Contact Acute Exposure Effects:
This material is an eye irritant. May cause irritation and injury, redness, tearing, blurred vision, burns,
conjunctivitis of eyes, corneal ulcerations of the eye. If not promptly removed, it will injure eye tissue, which
may result in permanent damage.
Ingestion Acute Exposure Effects:
May be fatal or cause blindness if swallowed. May cause dizziness, headache, drowsiness, nausea, weakness,
stupor, irritation to mouth throat and stomach, depression of the central nervous system, vomiting, muscle
twitches, gastrointestinal irritation, diarrhea, loss of appetite, narcosis, red blood cell hemolysis, mental
confusion, slurred speech, changes in white blood cells, fatigue, blindness, liver damage, kidney damage, heart
damage, unconsciousness, convulsions, coma, and death.
May produce additional symptoms listed under inhalation. Liquid aspirated into lungs can cause chemical
pneumonitis or pulmonary edema, which can be fatal.
Chronic Exposure Effects:
Reports have associated repeated and prolonged overexposure to solvents with neurological and other
physiological damage. Prolonged skin contact may result in absorption of a harmful amount of this material.
Prolonged or repeated contact may cause dermatitis. May cause weakness, skin irritation, nausea, numbness in
hands and feet, permanent central nervous system changes, some loss of memory, gastric disturbances, giddiness,
insomnia, brain damage, bone marrow damage, liver damage, kidney damage, hallucinations, blood disorders,
irregular heartbeat, jaundice, anemia, inflammation, redness, eye irritation, pancreatic damage, visual impairment
or blindness.
Prolonged or repeated contact may cause drying and cracking of skin. Repeated overexposure may cause red
blood cell hemolysis.
Licensed to W.M. Barr and Company ANSI Z400.1 Format
MATERIAL SAFETY DATA SHEET Page: 3
Printed: 12/12/2005
Klean-Strip Brush Cleaner Revision: 10/21/2005
Signs and Symptoms Of Exposure
Inhalation, ingestion, and dermal.
Medical Conditions Generally Aggravated By Exposure
Diseases of the skin, eyes, liver, kidneys, lungs, cardiovascular system, respiratory system, asthma, blood,
inflammatory or fibrotic pulmonary disease, alcoholism, and rhythm disorders of the heart.
OSHA Hazard Classes:
HEALTH HAZARDS : N/E
PHYSICAL HAZARDS : N/E
TARGET ORGANS & EFFECTS: N/E
4. First Aid Measures
Emergency and First Aid Procedures
Inhalation:
If user experiences breathing difficulty, move to air free of vapors. Administer oxygen or artificial respiration
until medical assistance can be rendered.
Skin Contact:
Irritation may result. Immediately wash with soap and water. Seek medical attention if irritation from contact
persists.
Eye Contact:
Immediately flush with water, remove any contact lenses, continue flushing with water for at least 15 minutes,
then get medical attention.
Ingestion:
Call you local poison control center, hospital emergency room, or physician immediately for instructions.
Note to Physician
Poison. This product contains methanol.
Methanol is metabolized to formaldehyde and formic acid. These metabolites may cause metabolic acidosis,
visual disturbances and blindness. Since metabolism is required for these toxic symptoms, their onset may be
delayed from 6 to 30 hours following ingestion. Ethanol competes for the same metabolic pathway and has been
used as an antidote. Methanol is effectively removed by hemodialysis.
Call your local poison control center for further information.
5. Fire Fighting Measures
OSHA Class IB
Flammability Classification:
4.00 F Method Used: TCC
Flash Pt:
LEL: 1.00 UEL: No data.
Explosive Limits:
No data.
Autoignition Pt:
Special Fire Fighting Procedures
Self-contained respiratory protection should be provided for fire fighters fighting fires in buildings or confined
areas. Storage containers exposed to fire should be kept cool with water spay to prevent pressure build-up. Stay
away from heads of containers that have been exposed to intense heat or flame.
Unusual Fire and Explosion Hazards
No data available.
Extinguishing Media
Use carbon dioxide, dry powder, or foam.
Licensed to W.M. Barr and Company ANSI Z400.1 Format
MATERIAL SAFETY DATA SHEET Page: 4
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Klean-Strip Brush Cleaner Revision: 10/21/2005
Unsuitable Extinguishing Media
No data available.
6. Accidental Release Measures
Steps To Be Taken In Case Material Is Released Or Spilled
Cleanup:
Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind, out of low areas, and ventilate
closed spaces before entering. Shut off ignition sources; keep flares, smoking or flames out of hazard area.
Small Spills:
Take up liquid with sand, earth or other noncombustible absorbent material and place in a plastic container where
applicable.
Large Spills:
Dike far ahead of spill for later disposal.
7. Handling and Storage
Precautions To Be Taken in Handling
Read carefully all cautions and directions on product label before use. Since empty container retains residue,
follow all label warnings even after container is empty. Dispose of empty container according to all regulations.
Do not reuse this container.
Precautions To Be Taken in Storing
Keep container tightly closed when not in use. Store in a cool, dry place. Do not store near flames or at elevated
temperatures.
8. Exposure Controls/Personal Protection
Respiratory Equipment (Specify Type)
For OSHA controlled work place and other regular users --Use only with adequate ventilation under engineered
air control systems designed to prevent exceeding appropriate TLV. For occasional use, where engineered air
control is not feasible, use properly maintained and properly fitted NIOSH approved respirator for organic solvent
vapors. A dust mask does not provided protection against vapors.
Eye Protection
Safety glasses, chemical goggles or face shields are recommended to safeguard against potential eye contact,
irritation, or injury. Contact lenses should not be worn while working with chemicals.
Protective Gloves
Wear impermeable gloves. Gloves contaminated with product should be discarded. Promptly remove clothing
that becomes soiled with product.
Other Protective Clothing
Various application methods can dictate the use of additional protective safety equipment, such as impermeable
aprons, etc., to minimize exposure. A source of clean water should be available in the work area for flushing
eyes and skin. Do not eat, drink, or smoke in the work area. Wash hands thoroughly after use. Before reuse,
thoroughly clean any clothing or protective equipment that has been contaminated by prior use. Discard any
clothing or other protective equipment that cannot be decontaminated, such as gloves or shoes.
Ventilation
Use only with adequate ventilation to prevent buildup of vapors. Do not use in areas where vapors can
accumulate and concentrate such as basements, bathrooms, or small enclosed areas. Whenever possible, use
outdoors in an open area. If using indoors, open all windows and doors and maintain a cross ventilation of
moving fresh air across the work area. If strong odor is noticed or you experience slight dizziness, headache,
nausea or eye-watering -- Stop -- ventilation is inadequate. Leave area immediately. If the work area is not well
ventilated, then do not use this product. A dust mask does not provide protection against vapors.
Licensed to W.M. Barr and Company ANSI Z400.1 Format
MATERIAL SAFETY DATA SHEET Page: 5
Printed: 12/12/2005
Klean-Strip Brush Cleaner Revision: 10/21/2005
9. Physical and Chemical Properties
[ ] Gas [ X ] Liquid [ ] Solid
Physical States:
No data.
Melting Point:
> 133.00 F
Boiling Point:
No data.
Autoignition Pt:
4.00 F Method: TCC
Flash Pt:
LEL: 1.00 UEL: No data.
Explosive Limits:
0.000000
Specfic Gravity:
6.52 LB/GA
Bulk Density:
No data.
Vapor Presure:
No data.
Vapor Density:
No data.
Evaporation Rate:
No data.
Solubility in Water:
100.0 % by weight.
Percent Volatile:
780.0000 G/L
VOC / Volume:
No data.
Corrosion Rate:
No data.
pH:
Appearance and Odor
No data available.
10. Stability and Reactivity
Unstable [ ] Stable [ X ]
Stability:
Conditions To Avoid - Instability
No data available.
Incompatibility - Materials To Avoid
Incompatible with strong oxidizing agents, strong caustics, acids, alkali, amines, reducing agents, aldehydes,
ammonia, nitrogen peroxides and reactive metals.
Hazardous Decomposition Or Byproducts
Decomposition may produce carbon monoxide, carbon dioxide, acrid smoke, formaldehyde, oxides of nitrogen
and irritating fumes, chlorine gas, small quantities of phosgene, and hydrogen chloride.
Will occur [ ] Will not occur [ X ]
Hazardous Polymerization:
Conditions To Avoid - Hazardous Polymerization
No data available.
11. Toxicological Information
Toxicological Information
No data available.
Carcinogenicity/Other Information
No data available.
NTP? No IARC Monographs? No OSHA Regulated? No
Carcinogenicity:
12. Ecological Information
Ecological Information
No data available.
13. Disposal Considerations
Waste Disposal Method
Dispose in accordance with local, state, and federal regulations.
Licensed to W.M. Barr and Company ANSI Z400.1 Format
MATERIAL SAFETY DATA SHEET Page: 6
Printed: 12/12/2005
Klean-Strip Brush Cleaner Revision: 10/21/2005
14. Transport Information
LAND TRANSPORT (US DOT)
DOT Proper Shipping Name
No data available.
15. Regulatory Information
US EPA SARA Title III
Hazardous Components (Chemical Name) CAS # Sec.302 (EHS) Sec.304 RQ Sec.313 (TRI) Sec.110
1. N-Methyl-2-Pyrrolidone 872-50-4 No No Yes No
2. Dichloromethane 75-09-2 No Yes 1000 LB Yes Yes
3. Methanol 67-56-1 No Yes 5000 LB Yes No
4. Toluene 108-88-3 No Yes 1000 LB Yes Yes
5. Tall oil acids 61790-12-3 No No No No
6. Potassium hydroxide 1310-58-3 No Yes 1000 LB No No
7. Ethanol, 2-Amino- 141-43-5 No No No No
8. Raffinates (petroleum), sorption process 64741-85-1 No No No No
9. Acetone 67-64-1 No Yes 5000 LB No Yes
US EPA CAA, CWA, TSCA
Hazardous Components (Chemical Name) CAS # EPA CAA EPA CWA NPDES EPA TSCA CA PROP 65
1. N-Methyl-2-Pyrrolidone 872-50-4 No No No Yes
2. Dichloromethane 75-09-2 HAP Yes 8A CAIR Yes
3. Methanol 67-56-1 HAP No No No
4. Toluene 108-88-3 HAP Yes 8A CAIR Yes
5. Tall oil acids 61790-12-3 No No No No
6. Potassium hydroxide 1310-58-3 No No No No
7. Ethanol, 2-Amino- 141-43-5 No Yes No No
8. Raffinates (petroleum), sorption process 64741-85-1 No No No No
9. Acetone 67-64-1 No No No No
SARA (Superfund Amendments and
Reauthorization Act of 1986) Lists:
Sec.302: EPA SARA Title III Section 302 Extremely Hazardous Chemical with TPQ. * indicates 10000
LB TPQ if not volatile.
Sec.304: EPA SARA Title III Section 304: CERCLA Reportable + Sec.302 with Reportable Quantity. **
indicates statutory RQ.
Sec.313: EPA SARA Title III Section 313 Toxic Release Inventory. Note: -Cat indicates a member of a
chemical category.
Sec.110: EPA SARA 110 Superfund Site Priority Contaminant List
TSCA (Toxic Substances Control
Act) Lists:
5A(2): Chemical Subject to Significant New Rules (SNURS)
6A: Commercial Chemical Control Rules
8A: Toxic Substances Subject To Information Rules on Production
8A CAIR: Comprehensive Assessment Information Rules - (CAIR)
8A PAIR: Preliminary Assessment Information Rules - (PAIR)
8C: Records of Allegations of Significant Adverse Reactions
8D: Health and Safety Data Reporting Rules
8D TERM: Health and Safety Data Reporting Rule Terminations
Other Important Lists:
CWA NPDES: EPA Clean Water Act NPDES Permit Chemical
CAA HAP: EPA Clean Air Act Hazardous Air Pollutant
CAA ODC: EPA Clean Air Act Ozone Depleting Chemical (1=CFC, 2=HCFC)
Licensed to W.M. Barr and Company ANSI Z400.1 Format
MATERIAL SAFETY DATA SHEET Page: 7
Printed: 12/12/2005
Klean-Strip Brush Cleaner Revision: 10/21/2005
CA PROP 65: California Proposition 65
EPA Hazard Categories:
This material meets the EPA 'Hazard Categories' defined for SARA Title III Sections 311/312 as indicated:
[ ] Yes [X] No Acute (immediate) Health Hazard
[ ] Yes [X] No Chronic (delayed) Health Hazard
[ ] Yes [X] No Fire Hazard
[ ] Yes [X] No Reactive Hazard
[ ] Yes [X] No Sudden Release of Pressure Hazard
16. Other Information
Company Policy or Disclaimer
The information contained herein is presented in good faith and believed to be accurate as of the effective date
shown above. This information is furnished without warranty of any kind. Employers should use this information
only as a supplement to other information gathered by them and must make independent determination of
suitability and completeness of information from all sources to assure proper use of these materials and the safety
and health of employees. Any use of this data and information must be determined by the user to be in
accordance with applicable federal, state and local laws and regulations.
Licensed to W.M. Barr and Company ANSI Z400.1 Format
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