Material Safety Data Sheet
Jetbest Corporation
Website: www.jetbest.com
Address: No.236, Sec 4, Chun Hwa Road,
Hsinchu, 300, Taiwan
TEL: +886-3-530-5888
FAX:+886-3-540-1121
1. PODUCT IDENTIFICATION
Product Name: ECO SKY Inks
Product Type: Pigment
2. COMPOSITION/INFORMATION ON INGREDIENTS
Ingredients CAS-No. Percent
Resin (PVC and PVAc copolymer) Not Hazardous 1%-5%
Trade Secret
-
Pigment 1%-5%
1-Methyl-2-pyrrolidinone 872-50-4 1%-5%
2-Ethoxy Ethyl Ether 112-36-7 20%-30%
Tetraethylene Glycol Dimethyl Ether 143-24-8 5%-10%
Methyl Acetoacetate 105-45-3 20%-40%
Ethylene Glycol Monobutyl Ether 112-07-2 10%-30%
Acetate (in pigment dispersion)
Surfactant Not Hazardous 0.1-1.0%
Trade Secret
3. HAZARDS IDENTIFICATION
Emergency Overview
Ink component is a black liquid that causes eye, nose or throat irritation, and that
effects anesthesia, if inhales. Ink may flash, when under high temperature. Avoid
contact with eyes or clothing. In the case of skin contact, wash with soap and water.
Keep out of reach of children.
Potential Health Effects
Inhalation: May cause respiratory irritation.
Skin Contact: May cause severe skin irritation.
Eye Contact: May cause severe eye irritation.
Ingestion: Ingestion may be harmful or fatal.
4. FIRST AID MEASURES
First Aid
INHALATION
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing
is difficult, give oxygen. Call a physician.
SKIN CONTACT
In case of contact, immediately flush skin with plenty of water for at least 15 minutes,
while removing contaminated clothing and shoes. Call a physician. Wash
contaminated clothing before reuse.
EYE CONTACT
In case of contact, immediately flush eyes with plenty of water for at least 15 minutes.
Call a physician.
INGESTION
If swallowed, Seek medical advice; and attention if stomach continues to be upset.
5. FIRE FIGHTING MEASURES
Hazardous gases/vapors produced in fire are carbon monoxide, carbon dioxide, oxides
of nitrogen. Extinguishing Water spray, Media CO2, Dry Chemical or Alcohol foam.
Fire Fighting Instructions
Wear self-contained breathing apparatus (SCBA) and full protective equipment.
6. ACCIDENTAL RELEASE MEASURES
Personal protections: Remove the person of the leeward. Keep away the person
from periphery of the place of the leakage. Ventilate sufficiently during clean-up in
case of inside of a house.
Method for cleaning up: If a spill occurs, use sponges to wipe-up ink, then rinse
area with damp cloth. Place waste in closed container for disposal. Do not
disposal of waste to the sewer. Wash hands with soap and water.
7. HANDLING AND STORAGE
Handling: Use proper ventilation and no fire in work place. Put protection wear
that has electrical conductivity in case of work. Keep out of reach of children and do
not drink ink.
Storage:
Store in a cool, dry place.
Avoid freezing or extended storage in high temperatures.
Avoid exposure to moisture.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Engineering Controls
Use only with adequate ventilation.
Personal Protective Equipment
EYE/FACE PROTECTION
Wear safety glasses, or where splash potential exist wear chemical splash goggles.
RESPIRATORS
Where the potential exists for airborne exposure, wear NIOSH approved respiratory
protection.
PROTECTIVE CLOTHING
Where there is potential for skin contact, have available and wear as appropriate
impervious gloves, apron or smock.
9. PHYSICAL AND CHEMICAL PROPERTIES
1 Compatible plotter Roland SolJet Series, Mutoh ValueJet
Series, Mimaki JV3 Series
2 Color Cyan, Magenta, Yellow, Black, Light Cyan,
Light Magenta
3 Odor Fruity odor
approx. 185 癈
4 Boiling point/boiling range
of ink
approx. ?5 癈
5 Solidification temperature
of ink
approx. 70 癈
6 Flash point of ink
not below 220 癈
7 Ignition temperature of ink
8 Viscosity of ink (cp) 3.5~5.0
9 Surface Tension of ink 27~30
(dyne/cm)
0.980~0.990 (25 癈)
10 Density of ink
11 pH No data available
0.8
12 Water content (%)
13 Lightfastness 7~8
14 Weather fastness 2 year
15 Solid content (%) 10~20
The Physical and chemical data given in Section 9 are typical values for this product
and are not intended to be product specifications.
10. STABILITY AND REACTIVITY
Chemical Stability
Stability: Stable at normal temperatures
Conditions to avoid: High and freezing temperatures
Materials to avoid: Oxidizers and explosives
Decomposition
Thermal decomposition may produce carbon dioxide, carbon monoxide.
11. TOXICOLOGICAL INFORMATION
Routes of Overexposure: Eye, skin, inhalation, and oral ingestion
Acute Health Hazards: Overexposure of the eye surface to ink may be mildly
irritating. Overexposure of ink contact with the skin may cause irritation and in
some people, swelling and redness. Intentional inhalation to ink vapors may result
in respiratory tract irritation. Intentional or accidental oral ingestion may cause an
upset stomach.
Chronic Health Hazards: No information available
Carcinogenicity:
This product contains Ni-compound. But this Ni-compound is not listed on the IARC
carcinogenicity substances lists. Also, this Ni-compound shows the negative result on
AMES test.
N-Methyl pyrrolidone
Toxic influence and carcinogenic were not accepted as a result of inhalation (rat) 0
mg/L (0 ppm), 0.04 mg/L (10 ppm), 0.4 mg/L(99 ppm), 6.0 hr/day, 5 day/week, and
the exposure test for two years.
Toxicity Data:
N-Methyl pyrrolidone :
LD50/LC50: Draize test, rabbit, eye: 100 mg Moderate; Oral, mouse: LD50 = 5130
mg/kg; Oral, rat: LD50 = 3914 mg/kg; Skin, rabbit: LD50 = 8 gm/kg.
2-Ethoxy Ethyl Ether:
LD50/LC50: Draize test, rabbit, eye: 50 mg Moderate; Oral, rat: LD50 = 4970 mg/kg;
Skin, rabbit: LD50 = 6700 uL/kg.
Tetraethylene Glycol Dimethyl Ether:
LD50/LC50: Draize test, rabbit, eye: 500 mg Mild; Oral, rat: LD50 = 5140 mg/kg.
Methyl Acetoacetate
LD50/LC50: Draize test, rabbit, eye: 2 mg Severe; Draize test, rabbit, skin: 500
mg/24H Mild; Oral, rat: LD50 = 3228 mg/kg.
Ethylene Glycol Monobutyl Ether Acetate:
LD50/LC50: Draize test, rabbit, eye: 500 mg/24H Mild; Oral, mouse: LD50 = 3200
mg/kg; Oral, rat: LD50 = 2400 mg/kg; Skin, rabbit: LD50 = 1500 mg/kg.
Eye Irritating: Mildly or serious irritating (exposure time and amount)
Skin Irritating: Minimally irritating
Skin Sensitizing: None Known
The information shown in SECION 3, Hazards identification, is based on toxicity
profiles of similar materials or on the components present in this material.
12. ECOLOGICAL INFORMATION
Ecotoxicity:
N-Methyl pyrrolidone
Bluegill LC50: 832 mg/L (22 癈), bull trout LC50: 3048 mg/L (22 癈)
Methyl Acetoacetate
Fish: Gold orfe: LC50: 250 mg/L; 48h; .Daphnia: Daphnia: EC50: 600 mg/L;
24h; .Algae: EC50: 100 mg/L; 72h; .Log Pow: -0.26 Biodegradability: Zahn-Wellens
Test: 100.0%, 5days, Method:OECD 302 B
Other: Readily biodegradable.
Mobility: No data available
Persistence and Degradability: No data available
Bioaccumulative Potential: No data available
Other Adverse Effects: Disclosure of ink and abandonment have a possibility of
affecting environment. Then, cautions are required for handing. It is necessary to cope
with it so that especially a product or washing water may not flow to the ground, a
river, and a drain.
13. DISPOSAL CONSIDERATIONS
Waste Disposal
Treatment, storage, transportation, and disposal must be in accordance with applicable
Federal, State/Provincial, and Local regulations.
14. TRANSPORT INFORMATION
General: Not a regulated article under United States DOT, IATA, ADR, IMDG, or
RID
IATA
Proper shipping name: Not applicable
Hazard class: Not applicable
Packaging exceptions: None
Identification number: None
(UN)
Packing group: N/A
15. Regulatory Considerations
US Regulation:
TSCA Section 4(a) Final Test Rules Regulated: N-Methyl pyrrolidone
TSCA Section 8(a) Preliminary Assessment Information Rule (PAIR): Not
regulated.
TSCA Section 8(a) Inventory Update Rule: Ethylene glycol monobutyl ether
acetate, N-Methyl pyrrolidone
TSCA Section 8(d) Health and Safety Study Reporting: Not regulated.
TSCA Section 12(b) One-Time Export Notification Regulated: N-Methyl
pyrrolidone
California Proposition 65: N-Methyl pyrrolidone
EU Information
EU Information
Symbols and indication according to 1994/45/EC
Harmful: Xn
Working of Risk and Safety Phase:
R20/21: Harmful by inhalation and in contact with skin.
R36/38: Irritating to eyes and skin.
S24: avoid contact with skin
S41: In case of fire and/or explosion do not breathe fumes.
16. OTHER INFORMATION
The data in this Material Safety Data Sheet relates only to the specific material
designated herein and does not relate to use in combination with any other material or
in any process.
This information is based upon technical information believed to be reliable. It is
subject to revision as additional knowledge and experience is gained.
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