MATERIAL SAFETY DATA SHEET
Last Reviewed 1/19/09
Less EMF Inc.
809 Madison Ave, Albany NY 12208 USA
tel: 1-518-432-1550 fax: 309-422-4355
SECTION I PRODUCT IDENTIFICATION
Product Class (Use): CONDUCTIVE COATING
Trade Name: 292 CuPro-Cote Copper Conductive Coating
SECTION II Composition
INGREDIENT NAME CAS# % INGREDIENT NAME CAS# %
Water - for information only 7732-18-5 40.01-50.00 Silver 7440-22-4 1.01-5.00
Copper 7440-50-8 25.01-30.00 Carbon black 1333-86-4 1.01-5.00
Titanium Dioxide 13463-67-7 5.01-10.00 Cyclic Amide 872-50-4 1.01-5.00
SECTION III HAZARDS IDENTIFICATION
HMIS Information: Health- 2* Flammability- 2 Reactivity- 0 Personal Protective Equipment- 0
HAZARD INDEX: 4=Severe 3=Serious 2=Moderate 1=Slight 0=Least *=Chronic Health Effects
Routes of Entry Inhalation, skin contact, eye contact, ingestion, absorption
Medical Conditions Aggravated Liver disease, Kidney disease, Eye disease, Skin disease including eczema and sensitization,
Lung disease
Immediate (Acute) Health Effects:
Inhalation Can cause moderate respiratory irritation, dizziness, weakness, fatigue, nausea, and
headaches. This product may cause metal fume fever with resulting flu-like symptoms. Nasal
perforation is possible from a single large or repeated smaller inhalation exposures. Harmful.
Can cause systemic damage, see target organs below.
Skin contact Can cause skin irritation, defatting and dermatitis. Not likely to cause permanent damage.
Eye contact Can cause moderate irritation, tearing and reddening, but not likely to permanently injure eye
tissue. Exposure may cause corneal injury.
Skin absorption Toxic if absorbed through the skin. Likely to cause significant systemic damage. The
absorption of silver compounds through breaks in the skin may result in local pigmentation at
the site of injury.
Ingestion Toxic if swallowed. May cause target organ failure and/or death. Can cause abdominal
discomfort, nausea, vomiting and diarrhea.
Target organ acute toxicity Respiratory system, Liver, Kidneys, Eyes, Skin, Bone marrow, Cardiovascular system, Lymphatic
system
Long-Term (Chronic) Health Effects:
Inhalation Upon prolonged and/or repeated exposure, can cause moderate respiratory irritation, dizziness,
weakness, fatigue, nausea and headache. Avoid prolonged or repeated exposure. If sensitized,
exposure below the TLV or PEL, or at low levels can result in respiratory irritation and
shortness of breath. These asthma-type symptoms may develop immediately or be delayed up to
several hours.
Skin contact Upon prolonged and/or repeated exposure, can cause moderate skin irritation, defatting, and
dermatitis. Not likely to cause permanent damage.
Eye contact Upon prolonged and/or repeated exposure, can cause moderate irritation, tearing and reddening,
but not likely to permanently injure eye tissue.
Skin absorption Upon prolonged and/or repeated exposure, toxic if absorbed through the skin. Like to cause
systemic damage. Excessive absorption of silver compounds may cause argyria, a permanent gray
discoloration of the skin, mucous membranes and/or eyes due to accumulation of reduced silver
in the organs.
Carcinogenicity IARC: Yes NTP: No OSHA: No
Target Organ Chronic Toxicity Respiratory system, Liver, Kidneys, Eyes, Skin, Lymphatic system
NOTICE: Reports have associated repeated and prolonged overexposure to solvents with brain and
nervous system damage. Intentional misuse by deliberately concentrating and inhaling the
contents may be harmful or fatal.
This product contains pigments which may become a dust nuisance when removed by abrasive
blasting, sanding, or grinding.
SECTION IV FIRST AID
Inhalation Remove to fresh air. If breathing is difficult, have a trained individual administer oxygen. If not breathing,
give artificial respiration and have trained individual administer oxygen. Get medical attention immediately.
Eyes Flush eyes with plenty of water for at least 20 minutes retracting the eyelids often. Remove contact lenses. Tilt
the head to prevent the chemical from transferring to the uncontaminated eye. Get immediate medical attention.
Skin contact Wash with soap and water. Remove contaminated clothing and launder. Get medical attention if irritation develops
or persists.
Ingestion Seek medical advice immediately. Provide ingredients from Section II of this MSDS to the medical care provider.
Contact local Poison Control Center (listed in telephone book), or dial local emergence (911) number for
additional information. Do not induce vomiting unless instructed to do so by a physician or other competent
medical personnel. Never give anything by mouth to an unconscious person.
SECTION V FIRE FIGHTING MEASURES
Flammability Summary Combustible at sufficiently elevated temperatures
Autoignition Temperature N/A
Fire Hazards Material may be ignited only if preheated to temperatures above flashpoint, for example in a
fire.
Extinguishing methods Use alcohol resistant foam, carbon dioxide, or dry chemical when fighting fires. Water or
foams may cause frothing of liquid is burning but still may be a useful extinguishing agent
if carefully applied to the surface of the fire. Do not direct a stream of water into the
burning liquid.
Hazardous combustion products Carbon dioxide, Carbon monoxide, Nitrogen contained gases
SECTION VI ACCIDENTAL RELEASE MEASURES
Health considerations for Exposure to the spilled material may be irritating or harmful. Follow personal protective equipment
spill response recommendations found in Section VIII of this MSDS. Additional precautions may be necessary based
on special circumstances created by the spill including: the material spilled, the quantity of the
spill, and the area in which the spill occurred. Also consider the expertise of the employees in
the area. Isolate area. Keep unnecessary personnel away. Personas not wearing protective equipment
should be excluded from the area until cleanup has been completed.
Spill mitigating procedures
General methods Prevent the spread of any spill to minimize harm to human health and the environment. Wear complete
and proper personal protective equipment following the recommendations of Section VIII at a
minimum. Dike with suitable absorbent material like granulated clay. Gather and store in a sealed
container pending a waste disposal evaluation.
Air release Ventilate the area by opening doors/windows and/or running fans and blowers.
Water release Retain all contaminated water for treatment
Land spills Avoid runoff into storm sewers and ditches that lead to waterways.
SECTION VII HANDLING AND STORAGE
Handling Harmful or irritating. Avoid overexposure to the material. Use only in a well ventilated area. As with all chemicals,
good industrial hygiene practices should be followed when handling this material. Do not get in eyes, on skin or
clothing. Use spark-proof tools and explosion proof equipment. Remove contaminated clothing and wash before reuse.
Ground and bond containers when transferring material.
Storage Store in a cool dry place. Isolate from incompatible materials. Keep container closed when not in use. Keep away from
food and drinking water. Keep away from heat, sparks and flame.
SECTION VIII ENGINEERING CONTROLS, PERSONAL PROTECTIVE EQUIPMENT, AND EXPOSURE LIMITS
Engineering Controls Local exhaust ventilation, process enclosures, or other engineering controls are necessary when handling or
using this product to avoid overexposure, and control airborne levels below recommended exposure limits.
Explosion proof exhaust ventilation should be used. Facilities storing or using this material should be
equipped with eye wash and safety shower. Vapor concentrations should be monitored and controlled in
accordance with 29 CFR 1910.1000
Protective equipment
Respiratory tract If exhaust ventilation is not available or sufficient to reduce exposure below acceptable levels, then
respiratory protection is required to avoid overexposure when handling this product.
Eyes Wear safety glasses with side shields when handling this product. Do not wear contact lenses. Wear chemical
splash goggles if splashing or high-pressure system is used.
Skin Wear protective gloves. Inspect gloves for chemical break-through and repeat at regular intervals. Clean
protective equipment regularly. Wash hands and other exposed areas with mild soap and water before eating,
drinking, and when leaving work.
Protective clothing Wear chemically resistant gloves and apron.
CHEMICAL NAME CAS # ACGHI TLV OSHA PEL IDLH
Water 7732-18-5 No TLV No PEL established Not determined
Copper 7440-50-8 fume: 0.2 mg/m?TWA; dusts and mists, 0.1 mg/m?TWA (fume); 1 dusts and mists as
as Cu: 1 mg/m?TWA mg/m?TWA (dusts & mists) Cu: 100 mg/m?IDLH
Titanium Dioxide 13463-67-7 10 mg/m?TWA 15 mg/m?TWA (total dust) 5000 mg/m?IDLH
Silver 7440-22-4 metal: 0.1 mg/m?TWA 0.01 mg/m?TWA as Ag: 10 mg/m?IDLH
Carbon Black 1333-86-4 3.5 mg/m?TWA 3.5 mg/m?TWA. 1750 mg/m?IDLH
Cyclic Amine 872-50-4 No TLV No PEL established Not determined
IX PHYSICAL DATA
Appearance Beige liquid Solubility in water partial
Color Beige Initial boiling point 100癈; 212癋
pH N/A Initial freezing point 0癈; 32癋
Octanol/Water coefficient Not determined
Vapor density Heavier than air. Vapors that evolve from this product will tend to settle and accumulate near floor.
Evaporation rate Slower than n-Butyl Acetate
Specific Gravity/Density 1.318 / 11.00 lbs/gal
V.O.C. 0.7 lbs/gal less water and exempt solvent; 84 g/l less water and exempt solvent
0.3 lbs/gal as packed
The VOC content is determined by using a percent solids basis, less water and exempt solvents.
SECTION X STABILITY AND REACTIVITY
Stability Information Stable under normal conditions
Conditions to avoid Temperatures above flash point in combination with sparks, open flames or other sources of
ignition. Contamination. Do not freeze.
Chemical incompatibility Chlorine, strong oxidizing agents, Ammonia, peroxides, acids, chlorinated compounds
Hazardous decomposition products Carbon dioxide, carbon monoxide, metal fumes, nitrogen containing gases
SECTION XI TOXICOLOGICAL INFORMATION
Chemical name LD50/LC50
Carbon black Oral LD50 Rat: >15400 mg/kg; dermal LD50 Rabbit: >3 gm/kg
2-pyrrolidinone, 1-methyl Oral LD50 Rat: 3914 mg/kg; Oral LD%) Mouse: 5130 mg/kg; dermal: LD50 Rabbit: 8mg/kg
SECTION XII ECOLOGICAL INFORMATION
Overview Care should be taken to minimize release of any industrial chemicals into the environment
SECTION XIII DISPOSAL CONSIDERATIONS
Waste disposal of spent product spent or discarded material is probably a hazardous waste
Disposal methods Information in this MSDS is provided only as a guide. Consult with competent authority to
determine proper waste disposal procedures. Clean up and dispose of waste and clean-up materials
in accordance with all federal, state and local environmental regulations
Potential EPS Waste Codes Not determined
Some components possibly subjected to USEPA land disposal restrictions: When disposing of unused products or waste, the preferred
options are to send to a licensed reclaimer or to permitted incinerators. There may be some other ingredients subject to LDR
categories. Silver 7440-22-4
SECTION XIV TRANSPORTATION INFORMATION
Agency: DOT Basic description and label: Not regulated per DOT
Hazardous substance
Copper final RQ - 5000 pounds (no reporting of releases of this hazardous substance is required is the diameter
of the pieces of the solid metal released is equal to or exceeds 0.004 inches).
Silver final RQ - 1000 pounds (no reporting of releases of this hazardous substance is required is the diameter
of the pieces of the solid metal released is equal to or exceeds 0.004 inches).
XV REGULATORY INFORMATION
Regulation
SARA 313 Reportable Copper, Silver, N-Methyl-2-pyrrolidinone
TSCA Inventory All components of this product are listed in, or exempt from the TSCA 8(b) Inventory
California Proposition 65 The following statement is made in order to comply with the California Safe Drinking Water and
Toxic Enforcement Act of 1986 Proposition 65: "WARNIONG This product contains chemical(s) known to
the State f California to cause cancer and birth defects or other reproductive harm."
THE INFORMATION CONTAINED HEREIN IS BASED ON INFORMATION RECEIVED FROM OUR RAW MATERIAL SUPPLIERS AND OTHER SOURCES AND IS BELIVED
TO BE RELIABLE. THIS INFORMATION IS NOT TO BE TAKEN AS A WARRANTY OR REPRESENTATION FOR WHICH LESS EMF INC. ASSUMES LEGAL
RESPONSIBILITY. INFORMATION ON THIS FORM IS TO BE USED TO COMPLY WITH OSHA AND HEALTH REGULATIONS ONLY AND MAY NOT BE USED OR
DISSEMINATED FOR OTHER PURPOSES.
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