Material Safety Data Sheet
Zep Inc. Section 1. Chemical Product and Company Identification
1310 Seaboard Industrial Blvd.
Product name
Atlanta, GA 30318 ZEP CONCENTRATED WEED
1-877-793-7776
KILLER AND SOIL STERILANT
Herbicide.
Product use
R056
Product code
Date of issue Supersedes
08/13/08
This product is a registered pesticide. EPA ID No. 1270-113
Emergency Telephone Numbers
For MSDS Information:
Compliance Services 1-877-793-7776
For Medical Emergency
INFOTRAC: (877) 541-2016 Toll Free - All Calls
Recorded
For Transportation Emergency
CHEMTREC: (800) 424-9300 - All Calls Recorded
In the District of Columbia (202) 483-7616
Prepared By
Compliance Services
1420 Seaboard Industrial Blvd.
Atlanta, GA 30318
Section 2. Hazards Identification
Emergency overview *Hazard Determination System (HDS): Health, Flammability, Reactivity
WARNING 1 1 0
CAUSES EYE IRRITATION. HARMFUL IF ABSORBED THROUGH
SKIN. HARMFUL IF SWALLOWED.
NOTE: MSDS data pertains to the product as delivered in the original shipping container(s). Risk of adverse effects are lessened by following all
prescribed safety precautions, including the use of proper personal protective equipment.
Dermal contact. Eye contact. Inhalation.
Acute Effects Routes of Entry
Causes eye irritation. Liquid in eye may cause irritation with possible damage if not rinsed
Eyes
immediately. Inflammation of the eye is characterized by redness, watering and itching.
Direct contact may cause irritation and redness. May cause allergic reactions in certain
Skin
individuals. Skin inflammation is characterized by itching, scaling, or reddening.
Inhalation Avoid inhalation of vapor, spray or mist. Over-exposure by inhalation may cause respiratory
irritation.
Ingestion Harmful if swallowed. Can cause gastrointestinal disturbances.
Prolonged or repeated contact may dry skin and cause irritation.
Chronic effects
Additional Information: See Toxicological Information (Section 11)
Section 3. Composition/Information on Ingredients
ALKYL (C16-C18) METHYL ESTERS 67784-80-9 >90
N-METHYL-PYRROLIDONE ; 1-methyl-2-pyrrolidone; m-pyrol 872-50-4 1-5
BROMACIL; (5-bromo-3-sec-butyl-6-methyluracil) 314-40-9 1.52
Section 4. First Aid Measures
Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and
Eye Contact
remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention immediately.
Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Wash clothing before
Skin Contact
reuse. Get medical attention if irritation develops.
Move exposed person to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give
Inhalation
oxygen. Get medical attention.
Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be
Ingestion
kept low so that vomit does not enter the lungs. Never give anything by mouth to an unconscious person. If
affected person is conscious, give plenty of water to drink. Get medical attention immediately.
Page: 1/3
Product Name Z E P C O N C E N T R A T E D W E E D
Material Safety Data Sheet
Product code R056
KILLER AND SOIL STERILANT
National Fire Protection Association (U.S.A.)
Section 5. Fire Fighting Measures
1
Closed cup: >93.33癈 (>200癋)
Flash Point 1 0
Flammable Limits Not available.
Non-flammable. Combustible when exposed to heat
Flammability
or flame.
Rags, steel wool or other wastes soaked with product may spontaneously catch fire if
Fire hazard
improperly discarded. In a fire or if heated, a pressure increase will occur and the container
may burst.
Use an extinguishing agent suitable for the surrounding fire. Cool closed containers exposed to
Fire-Fighting
fire with water. Do not release runoff from fire to sewers or waterways.
Procedures
Section 6. Accidental Release Measures
Put on appropriate personal protective equipment (see section 8). Stop leak if without risk. Move containers
Spill Clean up
from spill area. Dilute with water and mop up if water-soluble or absorb with an inert dry material and place in
an appropriate waste disposal container.
Section 7. Handling and Storage
Put on appropriate personal protective equipment (see section 8). Avoid contact with eyes, skin and clothing. Avoid
Handling
breathing vapor or mist. Do not ingest. Do not reuse container. Wash thoroughly after handling. Apply this product
only as specified on the label.
Keep away from sources of ignition. Store in original container protected from direct sunlight in a dry, cool and well-
Storage
ventilated area, away from incompatible materials (see section 10) and food and drink. Keep container tightly closed
and sealed until ready for use. Rags, steel wool or other wastes soaked with product may spontaneously catch fire if
improperly discarded. Do not contaminate water by cleaning of equipment or disposal of wastes. Keep out of the reach
of children.
Section 8. Exposure Controls/Personal Protection
Product name Exposure limits
N-METHYL-PYRROLIDONE ; 1-methyl-2-pyrrolidone; m-pyro ACGIH TLV (United States).
TWA: 100 ppm 8 hour(s).
BROMACIL; (5-bromo-3-sec-butyl-6-methyluracil) ACGIH TLV (United States).
TWA: 10 mg/m?8 hour(s).
Personal Protective Equipment (PPE)
Chemical splash goggles or face shield.
Eyes
Wear appropriate protective clothing to prevent skin contact.
Body
Recommended: Nitrile gloves. Neoprene gloves. Rubber gloves.
Viton gloves. Synthetic apron.
Respiratory Wear appropriate respirator when ventilation is inadequate.
Section 9. Physical and Chemical Properties
Liquid. [Thin liquid] Color Brown.
Physical State
Not applicable Odor Solvent-like.
pH
>315.5癈 (>599.9癋) Vapor Pressure Not determined.
Boiling Point
0.881 Vapor Density Not determined.
Specific Gravity
Emulsifies in water. Evaporation Rate Not determined.
Solubility
VOC (Consumer) 17.59 (g/l). 0.15 lbs/gal (2.00%)
Section 10. Stability and Reactivity
The product is stable.
Stability and Reactivity
Keep away from heat, sparks and flame. Slightly reactive or incompatible with the following
Incompatibility
materials: oxidizing materials and acids. May be reactive with acidic clay.
Hazardous Polymerization Will not occur.
Hazardous Decomposition Products carbon oxides (CO, CO2)
Page: 2/3
Product Name Z E P C O N C E N T R A T E D W E E D
Material Safety Data Sheet
Product code R056
KILLER AND SOIL STERILANT
Section 11. Toxicological Information
Acute Toxicity
Exposure
Product/ingredient name Result Species Dose
Alkyl Methyl Esters LD50 Oral Rat >15000 mg/kg -
n-Methyl-Pyrrolidone LD50 Oral Mouse 5270 mg/kg -
LD50 Oral Rat 3600 mg/kg -
Section 12. Ecological Information
Keep out of waterways.
Environmental Effects
Aquatic Ecotoxicity
Not available.
Section 13. Disposal Considerations
Waste Information
Waste must be disposed of in accordance with federal, state and local environmental control regulations. Consult your local or
regional authorities for additional information.
Waste Stream Non-hazardous waste
Section 14. Transport Information
Regulatory information UN number Proper shipping name Classes PG* Label
DOT Classification None. Not a DOT controlled material
(United States).
Not determined.
IMDG Class
NOTE: DOT classification applies to most package sizes. For specific container size classifications or for size exceptions, refer to
the Bill of Lading with your shipment.
PG* : Packing group
Section 15. Regulatory Information
U.S. Federal Regulations
SARA 313 toxic chemical notification and release reporting:
Product name
n-Methyl-Pyrrolidone
Bromacil
Clean Water Act (CWA) 307: No products were found.
Clean Water Act (CWA) 311: No products were found.
Clean Air Act (CAA) 112 regulated toxic substances: No products were found.
All Components of this product are listed or exempt from listing on TSCA Inventory.
State Regulations
WARNING: This product contains a chemical or chemicals known to the state
California Prop 65
of California to cause cancer, birth defects or other reproductive harm.: n-
Methyl-Pyrrolidone
Section 16. Other Information
To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its subsidiaries assumes any
liability whatsoever for the accuracy or completeness of the information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution.
Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist.
*NOTE: Hazard Determination System (HDS) ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks
Although these ratings are not required on MSDSs under 29 CFR 1910.1200, the preparer may choose to provide them. HDS ratings are to be used with a fully implemented program to
relay the meanings of this scale.
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