Safety Data Sheet (91/155/EEC)
ITW Dykem
Revision date: 11.10.2006 No.: 2,00
ACTION MARKER FELT TIP (BLACK & RED)
00392-0012
__________________________________________________________________________________________
1. Identification of the substance/preparation and company
1.1 Commercial product name
ACTION MARKER FELT TIP (BLACK & RED)
Art.-No.:
33002, 33003
44002, 44003
Colours: red, black
Use of the substance/preparation
Industrial paint marker
1.2 Information manufacturer/supplier
ITW Dykem
805 E. Old 56 Highway
Olathe, KS 66061
Telephone: 001 913 397 9889 Telefax: 001 913 397 8761
24 Hour Emergency Contact Number: 001 352 323 3500
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2. Composition/information on ingredients
Chemical characterization : ( preparation )
Preparation in organic solvents
Hazardous components
(Full text of each relevant R phrase can be found in heading 16)
EC No. CAS No. Components Value Symbols R-phrases
--------------------------------------------------------------------------------------------
203-539-1 107-98-2 1-methoxy-2-propanol < 50 % R10
212-828-1 872-50-4 N-methyl-2-pyrrolidone < 10 % Xi R36/38
204-626-7 123-42-2 4-hydroxy-4-methylpentan-2-one < 60 % Xi R36
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3. Hazards identification
Explication of special hazards for human health and environment
Flammable.
Irritating to eyes.
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4. First aid measures
General information
Remove contaminated soaked clothing immediately.
If you feel unwell, seek medical advice.
After inhalation
Move to fresh air in case of accidental inhalation of vapours.
Consult a physician.
If patient is not breathing, apply artificial respiration.
After contact with skin
Rinse with plenty of water.
Consult a doctor if skin irritation persists.
Page 1 of 7
GB_e
Safety Data Sheet (91/155/EEC)
ITW Dykem
Revision date: 11.10.2006 No.: 2,00
ACTION MARKER FELT TIP (BLACK & RED)
00392-0012
__________________________________________________________________________________________
After contact with eyes
Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes.
Seek medical treatment by eye specialist.
After ingestion
Do not induce vomiting.
Summon a doctor immediately..
Never give anything by mouth to an unconscious person.
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5. Fire-fighting measures
Suitable extinguishing media
Alcohol-resistant foam, dry chemical, carbon dioxide (CO2), water-spray
Extinguishing media that must not be used for safety reasons
Full water jet
Special exposure hazards arising from the substance or preparation itself, combustion products,
resulting gases
Fire may produce:
Carbon monoxide (CO), carbon dioxide (CO2) and nitrogen oxides (NOx)
Irritant/corrosive, flammable as well as toxic distillation gases (carbonization gases).
Special protective equipment for firefighters
Wear self-contained breathing apparatus and protective suit.
Additional information
Vapours are heavier than air and spread along ground.
The vapour/air mixture is explosive, even in empty, uncleaned receptacles.
Cool containers at risk with water spray jet.
Collect contaminated firefighting water separately, must not be discharged into the drains.
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6. Accidental release measures
Personal precautions
In case of vapour formation use respirator.
Use only explosion-proof equipment.
Ensure adequate ventilation.
Remove persons to safety.
Use personal protective clothing.
Environmental precautions
Do not discharge into the drains/surface waters/groundwater.
Methods for cleaning up/taking up
Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder).
Shovel into suitable container for disposal.
Additional information
Clean contaminated surface thoroughly.
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GB_e
Safety Data Sheet (91/155/EEC)
ITW Dykem
Revision date: 11.10.2006 No.: 2,00
ACTION MARKER FELT TIP (BLACK & RED)
00392-0012
__________________________________________________________________________________________
7. Handling and storage
7.1 Handling
Advice on safe handling
Keep container tightly closed.
Vapours are heavier than air and spread along ground.
Avoid contact with the skin and the eyes.
Use only in thoroughly ventilated areas.
Advice on protection against fire and explosion
Keep away from heat and sources of ignition.
Do not smoke.
Take precautionary measures against static discharges.
7.2 Storage
Requirements for storage rooms and vessels
Keep container tightly closed in a dry, cool and well-ventilated place.
Pay attention to anti-explosion rules.
Advice on storage compatibility
Incompatible with:
strong acids and strong bases
strong oxidizing agents, reducing agents
Further information on storage conditions
Keep away from food, drink and animal feeding stuffs.
Storageclass (VCI): 3 A
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8. Exposure controls/personal protection
8.1 Exposure limit values
Exposure limits (EH40)
Components Exposure limit
CAS No. ml/m? mg/m? F/ml Category Origin
--------------------------------------------------------------------------------------------
1-Methoxypropanol-2 (propylene glycol monomethyl ether)
107-98-2 100 - TWA (8 h) OES
150 - STEL (15 min) OES
1-Methyl-2-pyrrolidone
872-50-4 25 103 TWA (8 h) OES
75 309 STEL (15 min) OES
4-Hydroxy-4-methyl-pentan-2-one
123-42-2 50 241 TWA (8 h) OES
75 362 STEL (15 min) OES
8.2 Exposure controls
Occupational exposure controls
Ensure adequate ventilation, especially in confined areas.
Protective and hygiene measures
Wash hands before breaks and immediately after handling the product.
When using, do not eat, drink or smoke.
Treat subsequently with skin cream.
Take off immediately all contaminated clothing.
Page 3 of 7
GB_e
Safety Data Sheet (91/155/EEC)
ITW Dykem
Revision date: 11.10.2006 No.: 2,00
ACTION MARKER FELT TIP (BLACK & RED)
00392-0012
__________________________________________________________________________________________
Avoid contact with skin, eyes and clothing.
Respiratory protection
In case of insufficient ventilation wear suitable respiratory equipment (gas filter type A).
Hand protection
Protective gloves resistant to chemicals made off butyl, Minimum coat thickness 0,7 mm, Permeation resistance
(wear duration) approx. 480 minutes, i.e. protective glove made by www.kcl.de
This recommendation refers exclusively to the chemical compatibility and the lab test conforming to EN 374
carried out under lab conditions.
Requirements can vary as a function of the use. Therefore it is necessary to adhere additionally to the
recommendations given by the manufacturer of protective gloves.
Eye protection
Tightly fitting goggles
Eye wash bottle with pure water
Body protection
Chemical resistant apron
Long sleeved clothing.
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9. Physical and chemical properties
9.1 Appearance
Form: viscous liquid Colour: various Odour: alcoholic
9.2 Important health, safety and environmental information
Test method
Changes in the physical state
Boiling point: 120 - 170 °C
Flash point: 31,7 °C
Ignition temperature: n.d. °C
Lower Explosion limit: 1,0 vol. %
Upper Explosion limit: 7,0 vol. %
Vapour pressure: n.d. hPa
(at 20 °C)
Density: > 1 g/ml
(at 20 °C)
Water solubility: partially miscible g/l
(at 20 °C)
Vapour density: >1
Solvent content
> 80 %
Further information
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GB_e
Safety Data Sheet (91/155/EEC)
ITW Dykem
Revision date: 11.10.2006 No.: 2,00
ACTION MARKER FELT TIP (BLACK & RED)
00392-0012
__________________________________________________________________________________________
10. Stability and reactivity
Conditions to avoid
Vapours may form explosive mixture with air.
Materials to avoid
strong acids and strong bases
strong oxidizing agents, reducing agents
Hazardous decomposition products
Carbon monoxide and carbon dioxide
Irritant/corrosive, flammable as well as toxic distillation gases (carbonization gases).
Additional information
No decomposition if stored and applied as directed.
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11. Toxicological information
Empirical data on effects on humans
Irritating to eyes.
Additional information
Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhoea.
Effects of breathing high concentrations of vapour may include
headache, dizziness, weakness, unconsciousness
Repeated or prolonged skin contact may cause skin irritation and/or dermatitis and sensitization of susceptible
persons.
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12. Ecological information
Additional information
Do not flush into surface water or sanitary sewer system.
Slightly water hazardous.
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13. Advice on disposal
Dispose
Where possible recycling is preferred to disposal.
Can be incinerated, when in compliance with local regulations.
Waste disposal number of Waste from residues / unused product : 080111
WASTES FROM THE MANUFACTURE, FORMULATION, SUPPLY AND USE (MFSU) OF COATINGS
(PAINTS, VARNISHES AND VITREOUS ENAMELS), ADHESIVES, SEALANTS AND PRINTING INKS;
wastes from MFSU and removal of paint and varnish; waste paint and varnish containing organic solvents or
other dangerous substances
Classified as hazardous waste.
Contaminated packaging
Empty containers should be taken for local recycling, recovery or waste disposal.
Contaminated packaging should be emptied as far as possible and after appropriate cleansing may be taken for
reuse.
Packaging that cannot be cleaned should be disposed of like the product.
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GB_e
Safety Data Sheet (91/155/EEC)
ITW Dykem
Revision date: 11.10.2006 No.: 2,00
ACTION MARKER FELT TIP (BLACK & RED)
00392-0012
__________________________________________________________________________________________
14. Transport information
14.1 Land transport (ADR/RID)
ADR/RID: 3
Hazard-no.: 30
UN number: 1263
Hazard label: 3
ADR packaging group: III
Description of the goods:
PAINT
Remarks
"LQ 7: combination packaging: 5 l / 45 l; trays: 5 l / 20 l (20 kg total gross mass)"
14.2 Inland waterways transport
14.3 Marine transport
IMDG-Code: 3
UN number: 1263
EMS: F-E; S-E
Packaging group: III
Marine pollutant: No
Description of the goods
PAINT
Hazard label: 3
Remarks
Limited quantities (section 3.4): combination packaging: 5 l / 30 kg (total gross mass); trays: 5 l / 20 kg (total gross
mass)
14.4 Air transport
ICAO/IATA-DGR: 3
UN/ID number: 1263
Hazard label: 3
IATA-packing instructions - passenger: 309
IATA-max. quantity - passenger: 60 L
IATA-packing instructions - Cargo: 310
IATA-max. quantity - Cargo: 220 L
ICAO-packaging group: III
Description of the goods
PAINT
14.5 Further Information
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GB_e
Safety Data Sheet (91/155/EEC)
ITW Dykem
Revision date: 11.10.2006 No.: 2,00
ACTION MARKER FELT TIP (BLACK & RED)
00392-0012
__________________________________________________________________________________________
15. Regulatory information
15.1 Labelling
Labelling according to EC-guidelines
As an article the product does not need to be labelled in accordance with EC-directives or respective national
laws.
15.2 National regulations
Water contaminating class: 1 - slightly water contaminating
1999/13/EC (VOC): > 80 %
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16. Other information
List of relevant R phrases
10 Flammable.
36 Irritating to eyes.
36/38 Irritating to eyes and skin.
Other data
Data of items 4 to 8, as well as 10 to 12, do partly not refer to the use and the regular employing of the product (in
this sense consult information on use and on product), but to liberation of major amounts in case of accidents and
irregularities.
The information describes exclusively the safety requirements for the product (s) and is based on the present level
of our knowledge.
The delivery specifications are contained in the corresponding product sheet.
This data does not constitute a guarantee for the characteristics of the product(s) as defined by the legal warranty
regulations.
"(n.a. = not applicable; n.d. = not determined)"
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