MATERIAL SAFETY DATA SHEET
Page: 1
KYMAX (ALL BASES)
2/1/2008
PRODUCT NAME: KYMAX (ALL BASES)
PRODUCT CODE: KYM
~~~~ SECTION 1 ~~~~ MANUFACTURER IDENTIFICATION ~~~~
Manufacturer's Name : UNITED COATINGS MANUFACTURING CO
Address : 19011 EAST CATALDO AVE.
: SPOKANE VALLEY, WASHINGTON 99016-9423
: INITIAL(FIRST CALL)CHEMTREC(800)424-9300
INFORMATION PHONE : (509)926-7143
TOLL FREE : BACKUP(800)541-4383
DATE PRINTED : 2/1/2008
DATE REVISED : February 2008
~~~~ SECTION 2 ~~~~ HAZARDOUS INGREDIENTS/SARA III INFORMATION ~~~~
Reportable Components CAS Number MM HG @ Temp Weight %
FLUOROPOLYMER Mixture N/A N/A 40
No OEL's established for this chemical
~
ACGIH Limit for Hydrogen Fluoride (HF) has a TLV of 2ppm
~
Water 7732-18-5 UNK UNK 16
No OEL's Established
~
Titanium dioxide 13463-67-7 N/A N/A 15
Contains: Titanium dioxide, CAS#13463-67-7,
ACGIH TLV TWA: 10mg/m3, total dust, OSHA PEL TWA: 15mg/m3, total dust.
Aluminum hydroxide, CAS#21645-51-2, no exposure limits established.
Note: Titanium Dioxide has been classified in accordance with hazard
criteria of the Controlled Product Regulations and the MSDS contains all
the information required by the Controlled Products Regulations.
WHMIS: D2A-Very toxic material causing other toxic effects.
~
Acrylic polymer MIXTURE 17 68F/20C 9
Contains: Aqua Ammonia, CAS#1336-21-6, 0.2%Max,. OSHA PEL: 50ppm,
ACGIH TWA 25 ppm STEL 35ppm No other exposure limits have been established
~
* URETHANE POLYMER DISPERSION MIXTURE NO DATA N/A 9
*2-PYRROLIDINONE,1-METHYL, CAS#872-50-4, 6.8% MANUFACTURER RECOMMENDS
EXPOSURE GUIDELINE TLV OF 100PPM TWA. *TRIETHYLAMINE CAS #121-44-8 AT
1.2% BY WEIGHT - ACGIH/TLV 1 PPM, STEL 3PPM. OSHA PEL 10PPM STEL 15PPM.
~
2,2,4-Trimethyl-1,3-Pentanediol Monoisobutyrate25265-77-40.0168F 4
No occupational exposure limits have been established for this chemical
~
* Indicates toxic chemical(s) subject to the reporting requirements
of section 313 of Title III and of 40 CFR 372.
#Indicates carcinogenic chemical.
This MSDS may be used for other colors and container sizes
of this product.
~~~~ SECTION 3 ~~~~ HAZARDS IDENTIFICATION ~~~~
Potential Health Effects
Eyes:
May cause slight/moderate irritation to the eye
Skin:
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Contact causes moderate skin irritation. Causes drying of
the skin.
Ingestion:
May cause abdominal pain, nausea and vomiting.
Inhalation:
May cause irritation to respiratory tract.
~~~~ SECTION 4 ~~~~ FIRST AID MEASURES ~~~~
Eyes:
Immediately flush with copious amounts of water for at least
15 minutes. If redness, itching, or burning sensations persist
consult a physician or ophthalmologist immediately.
Skin:
Wash with plenty of soap and water. Remove contaminated
clothing and shoes, wash before reuse. Consult a physician
immediately.
Ingestion:
Not considered a potential route of exposure. If swallowed,
give 2 glasses of water to drink. Never give anything by mouth to an
unconscious person. Consult a physician immediately.
Inhalation:
Remove from source of exposure and into fresh air. If
symptoms persist consult a physician immediately. If not breathing,
give artificial respiration and call emergency medical services
immediately.
Note to Physician:
When heated to 600F and thermal decomposition occurs, the
Hexafluoropropylene-vinylidene fluoride in this product may release
Hydrogen Fluoride gas (HF). Hydrogen Fluoride is extremely corrosive
and can cause severe burns, which may not be immediately visible or
painful. Exposure to HF may be fatal if absorbed through the skin,
inhaled or swallowed. Patients that have been exposed to HF should
be monitored for hypocalcemia, delayed pulmonary edema and edema of
the upper respiratory tract.
~~~~ SECTION 5 ~~~~ FIRE FIGHTING MEASURES ~~~~
Flammable Properties
Flash Point: 248F/120C
Lower Flammable Limits: 0.62
Upper Flammable Limit: 4.24
Auto Ignition Temperature: N/A
Extinguishing Media:
Foam, CO2, dry chemical, water fog or spray, as appropriate
for surrounding fire.
Special Fire Fighting Procedures:
Do not enter any enclosed or confined fire space without
full protective equipment, including self-contained breathing
apparatus (pressure-demand MSHA/NIOSH approved or equivalent) to
protect against the hazardous effects of combustion products and
oxygen deficiency.
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KYMAX (ALL BASES)
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~~~~ SECTION 6 ~~~~ ACCIDENTAL RELEASE MEASURES ~~~~
Small Spill:
Contain spills immediately with inert materials (eg. sand,
earth). If material is spilled in a confined area ventilate the area
well. Keep spectators away. Floor may be slippery; use care to avoid
falling. Transfer liquids and solid diking material to separate
suitable containers for recovery or disposal. Caution: keep spills
and cleaning runoff out of municipal sewers and open bodies of water.
Large Spill:
Wear skin, eye & respiratory protection during clean-up.
Evacuate area of all non-essential personnel. Ventilate spill area.
Dike, and contain and/or absorb with inert material (sand, earth or
other suitable material) to prevent entry into storm drains, sewers
and other unauthorized treatment/drainage systems and natural
waterways. Scoop up and place in approved containers for proper
disposal. Cover with lid. If spill occurs near air inlets or inside,
turn off heating or air-conditioning equipment to prevent
contaminating building.
~~~~ SECTION 7 ~~~~ HANDLING AND STORAGE ~~~~
Handling & Storage:
Keep from freezing. Keep container cool and dry. Use and
store this product with adequate ventilation. Keep product containers
tightly closed when not in use. Avoid subjecting this product to
extreme temperature variations.
Other Precautions:
~~~~ SECTION 8 ~~~~ EXPOSURE CONTROLS/PERSONAL PROTECTION ~~~~
Engineering Controls:
General and local exhaust ventilation is recommended to
maintain vapor exposures below recommended limits. Where
concentrations are above recommended limits as determined by air
sampling or are unknown, appropriate respiratory protection should be
worn. Follow OSHA Respirator Regulations (29 CFR 1910.134) and use
NIOSH/MSHA approved respirators.
In outside mixing and application operations, situate workers upwind
of operation & provide airflow in a downwind direction so as to carry
fumes and residual spray away from workers. If there is a lack of air
movement monitor for maximum exposure limits as indicated in section
2 and if exceeded, use appropriate Respiratory Equipment.
Respiratory Protection:
Wear a NIOSH approved respirator appropriate for the vapor
or mist concentration at the point of use. Appropriate respirators
may be a full-face piece or a half mask air-purifying cartridge
respirator equipped for organic vapors/mists, a self-contained
breathing apparatus in the pressure demand mode, or a supplied-air
respirator. Refer to OSHA standard 29 CFR 1910.134 for additional
information.
Skin Protection:
The use of nitrile rubber gloves is advised to prevent skin
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KYMAX (ALL BASES)
2/1/2008
contact and possible irritation.
Eye Protection:
Isolate the area immediately; prevent unauthorized entry.
~~~~ SECTION 9 ~~~~ PHYSICAL AND CHEMICAL PROPERTIES ~~~~
Boiling Range: 193F/89.4C - 471F/243C
Melting Point: N/A
Specific Gravity(H2O=1): 1.2493
Vapor Density(Air=1): Lighter than air
Vapor Pressure: <17mm Hg @ 20C/68F
Evaporation Rate(N-Butyl Acetate=1) : Similar to water.
Coating V.O.C.: 1.6 lb/gl Coating V.O.C.: 192 g/l
Material V.O.C.: 0.65 lb/gl Material V.O.C.: 77 g/l
Solubility in Water: Soluble
Appearance: WHITE LIQUID.
Odor: MILD ODOR
pH: NEUTRAL
~~~~ SECTION 10 ~~~~ STABILITY & REACTIVITY DATA ~~~~
Stability:
Stable
Conditions To Avoid:
Extremely hot or cold temperatures
Incompatible Materials:
Avoid contact with strong oxidizing agents.
Strong bases
Hazardous Decomposition Products
Thermal decomposition may yield acrylic monomer, carbon
monoxide and carbon dioxide. Unidentified organic compounds in fumes
and smoke may be formed during combustion.
Thermal decomposition may yield hydrogen fluoride gas, which can
cause severe burns.
Hazardous Polymerization:
Not expected to occur
~~~~ SECTION 11 ~~~~ TOXICOLOGICAL INFORMATION ~~~~
*Data is for individual components of preparation.
Materials having a known chronic/acute effects on eyes:
Hexafluoropropelyene-vinylidene fluoride copolymer CAS#
9011-17-0
The uncured copolymer is slightly irritating to rabbit eyes.
Materials having a known dermal toxicity.
Hexafluoropropelyene-vinylidene fluoride copolymer CAS#
9011-17-0 The uncured copolymer is slightly irritating to rabbit
skin. Repeated skin contact with the cured copolymer produced
irritation in rabbits.
Titanium Dioxide CAS#13463-67-7 Dermal LD50 (rabbit) >10 g/kg
Materials having a known oral toxicity.
Hexafluoropropelyene-vinylidene fluoride copolymer CAS#
9011-17-0 Reversible liver effects were observed in rats given a diet
containing 25% of the uncured copolymer for 2-weeks.
TITANIUM DIOXIDE CAS#13463-67-7 Oral LD50 (rat) >25 g/kg
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Materials having a known Inhalation hazard:
Aluminum trihydroxide: Breathing airborne nuisance dust can
cause chronic breathing difficulty.
TITANIUM DIOXIDE CAS#13463-67-7 LC50 (rat)>6.82 mg/l(4 hr)
Identified Acute/ Short-term Effects:
Headache, nausea, abdominal pain and irritation of the nose,
throat and lungs. Skin and eye irritation.
Identified Carcinogens/Longterm Effects:
NO DATA
Identified Teratogens:
NO DATA
Identified Reproductive toxins :
NO DATA.
Identified Mutagens:
NO DATA.
~~~~ SECTION 12 ~~~~ ECOLOGICAL INFORMATION ~~~~
Ecotoxicological effects on plants and animals:
Titanium Dioxide CAS#13463-67-7 96 Hr LC50 (Fathead
minnows)>1,000 mg/l
Chemical Fate :
Product spills on porous surfaces can contaminate
groundwater.
This product is not expected to be biodegradable. Avoid spillage into
the environment.
~~~~ SECTION 13 ~~~~ DISPOSAL CONSIDERATIONS ~~~~
Instructions:
Dispose of unused product or contaminated product and
materials used in cleaning up spills or leaks in a manner approved
for this material. Consult appropriate federal, state and local
regulatory agencies to ascertain proper disposal procedures.
Incineration is acceptable and the preferred method of disposal,
however; nitrogen oxide emissions controls may be required to meet
specifications. Chemical and biological degradation is possible.
Empty containers will retain product residue and vapors and are
subject to proper waste disposal, as above.
~~~~ SECTION 14 ~~~~ TRANSPORT INFORMATION ~~~~
Shipping Information:
DOT INFORMATION - 49 CFR 172.101
DOT DESCRIPTION: NOT REGULATED
~~~~ SECTION 15 ~~~~ REGULATORY INFORMATION ~~~~
(Not meant to be all inclusive-selected regulations represented)
US Regulations:
Status Of Substances Lists:
The Concentrations Shown In Section II Are Maximum Ceiling Levels
(Weight %) to be used for calculations for regulations.
A reportable quantity is a quantity of a hazardous substance that
triggers reporting requirements under the Comprehensive Environmental
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KYMAX (ALL BASES)
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Response Compensation And Liability Act (CERCLA).
If a spill of a substance exceeds it's reportable quantity (RQ) in
CFR 302.3,Table 40 302.4 Appendix A & 302.4 Appendix B,
the release must be reported to The National Response Center
At (800) 424-8802, The State Emergency Response Commission
(SERC), And community emergency coordinators likely to be affected.
Components present that could require reporting under the statute are:
NONE KNOWN
Superfund Amendments And Reauthorization Act Of 1986 (SARA) Title III
Requires emergency planning based on the Threshold Quantities(TPQ'S)and
release reporting based on Reportable Quantities (RQ'S) In 40 CFR 355
Appendix A&B Extremely Hazardous Substances. The emergency planning and
release requirements of 40 CFR 355 apply to any facility at which there is
present any amount of any extremely hazardous substance(EHS)
equal to or in excess of it's Threshold Planning Quantity(TPQ).
Components present that could require reporting under the statute are:
NONE KNOWN
EPCRA 40 CFR 372(Section 313) Requires EPA and the States to
annually collect data on releases of certain toxic materials from
industrial facilities, and make the data available to the public in the
Toxics Release Inventory(TRI). This information must be included in all
MSDS'S that are copied and distributed or compiled for this material.
Reporting Threshold: Standard: A facility must report if it manufactures
(including imports) or processes 25,000 pounds or more or otherwise uses
10,000 pounds or more of a listed toxic chemical during the calendar year.
Components present that could require reporting under the statute are:
See Section II
The components of this product are listed or excluded from listing on the
US Toxic Substance Control Act (TSCA) chemical substance inventory.
Mixtures shall be assumed to present the same health hazards as do the
components which comprise one percent (by weight or volume) or
greater of the mixture, except that the mixture shall be assumed to present a
carcinogenic hazard if it has a component in concentrations of 0.1 percent or
greater. The remaining percentage of unspecified ingredients, if any, are not
contained in above DeMinimis concentrations and/or are believed to
be non-hazardous under the OSHA Hazard Communication Standard
(29 CFR 1910.1200), and may consist of pigments, fillers, defoamers,
wetting agents, resins, dryers,anti-bacterial agents, water and/or solvents
in varying concentrations.
International Regulations:
Canadian WHMIS:
This product is not listed in any division, class, or
subdivision.
This Product Contains the following in recordable amounts:
Titanium Dioxide CAS#13463-67-7
WHMIS Classification: D2A
WHMIS Health Effects Criteria Met by this Chemical:
Very toxic material causing other toxic effects
Canadian Environmental Protection Act (CEPA):
All of the components of this product are exempt or listed
on the DSL/NDSL. See Section II For Composition/Information on
Ingredients.
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KYMAX (ALL BASES)
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EINECS:
All of the components of this product are listed in the
EINECS inventory or are exempt from notification requirements.
State Regulations:
California:
California Proposition 65: The following Statement is made in order
to comply with The California Safe Drinking Water and Toxic
Enforcement Act of 1986
"WARNING:This product contains the chemical(s) appearing below known to the
State of California to:
A: Cause Cancer
California Proposition 65 code: D
2-Pyrrolidinone, 1-methyl CAS#872-50-4
*If tinted contains Carbon Black:CAS#1333-86-4 and may also contain trace
amounts of Crystalline Silica:CAS#14808-60-7
B: Cause Birth Defects or other Reproductive Harm :
NONE KNOWN
In addition to the above named chemical(s)(if any),this product may contain
trace amounts of chemicals, known to the State of California, to cause
Cancer or Birth Defects and other Reproductive Harm
Delaware:
Listed on the Delaware Air Quality Management List:
Aqua Ammonia CAS#1336-21-6 DRQ 1000#
Listed on the Delaware Air Quality Management list:
2-Pyrrolidinone, 1-Methyl CAS#872-50-4 RQ 100
RQ State: State requirement differs from Federal
Listed on the Delaware Air Quality Management list:
Triethylamine CAS#121-44-8
DRQ: 5000
RQ State: Federal Regulations Apply.
Florida:
TRIETHYLAMINE CAS#121-44-8 LISTED AS TOXIC
Idaho:
Dipropylene glycol monomethyl ether CAS#34590-94-8
Idaho Air Pollutant List:
Title 585--AAC: 30 Title 586--AAAC: --
Title 585--EL: 40 Title 586--EL: --
Title 585--OEL: 600 Title 586--OEF: --
Triethylamine CAS#121-44-8
Idaho Air Pollutant List:
Title 585--AAC: 0.2 Title 586--AAAC: --
Title 585--EL: 0.27 Title 586--EL: --
Title 585--OEL: 4. Title 586--OEF: --
Massachusetts:
Aqua Ammonia CAS#1336-21-6 Code: F8
Dipropylene glycol monomethyl ether CAS# 34590-94-8 Codes:2,4,F8
CALCIUM CARBONATE, CAS#1317-65-3
SUBSTANCE CODES:4
Titanium Dioxide CAS#13463-67-7 SUBSTANCE CODES:4
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N-METHYL PYRROLIDONE CAS#872-50-4 SUBSTANCE CODES:6
TRIETHYLAMINE CAS#121-44-8 SUBSTANCE CODES:2,4,5,6,F8
Michigan:
NONE KNOWN
Minnesota:
Dipropylene glycol monomethyl ether CAS# 34590-94-8
Codes: AO
Ratings: --
Status:
THE FOLLOWING ARE LISTED IN THE MINNESOTA HAZARDOUS SUBSTANCES LIST
CHEMICAL NAME CAS# CODES HAZARDS CARCINOGEN?
CALCIUM CARBONATE 1317-65-3 A -- NO
Titanium Dioxide CAS#13463-67-7
Listed In The Minnesota Hazardous Substances List:
Codes: A
Hazards: --
Carcinogen? NO
N-METHYL PYRROLIDONE CAS#872-50-4
LISTED IN THE MINNESOTA HAZARDOUS SUBSTANCES LIST:
CODES: I
RATINGS: --
Status: Title III. TRI.
TRIETHYLAMINE CAS#121-44-8
LISTED IN THE MINNESOTA HAZARDOUS SUBSTANCES LIST:
CODES: AO
Ratings: 9.82
Status: Air Pollutant. Title III. TRI.
New Jersey:
New Jersey Extraordinarily Hazardous Substance
Aqua Ammonia CAS#1336-21-6 RTK Substance number: 0084
NJ Threshold:19,000 Table I Part A Group II
N-METHYL PYRROLIDONE CAS#872-50-4
NEW JERSEY RTK HAZARDOUS SUBSTANCE:
DOT: --
Sub No.: 3716
TPQ: --
EHS:
TRIETHYLAMINE CAS#121-44-8
NEW JERSEY RTK HAZARDOUS SUBSTANCE:
DOT: 1296
Sub No.: 1907
TPQ: --
EHS:
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New York:
Aqua Ammonia CAS#1336-21-6 RQ Air 1000, RQ
Land/Water 100
TRIETHYLAMINE CAS#121-44-8 RQ--AIR: 5000, RQ--LAND: 1
Note: No note associated with this chemical.
Pennsylvania:
Ammonia Hydroxide CAS#1336-21-6 Code:E
Dipropylene glycol monomethyl ether CAS# 34590-94-8 Code:--
CALCIUM CARBONATE CAS#1317-65-3 CODE:E
Titanium Dioxide CAS#13463-67-7 CODE:--
N-METHYL PYRROLIDONE CAS#872-50-4 CODE:--
TRIETHYLAMINE CAS#121-44-8 CODE:E
Washington:
Dipropylene glycol methyl ether CAS#34590-94-8
Washington air contaminant: ppm mg/m3
TWA 100 600
STEL 150 900
CEILING --- ---
SKIN: Protective measures should be taken to prevent or reduce
skin absorption.
WASHINGTON AIR CONTAMINANT:
CALCIUM CARBONATE(RESPIRABLE) CAS#1317-65-3
WA ppm mg/Cubic Meter
TWA UNK 5
STEL UNK UNK
CEILING UNK UNK
SKIN:UNK
Titanium Dioxide(Total Dust) CAS#13463-67-7
Washington Air Contaminant: ppm mg/Cubic Meter
TWA UNK 10
STEL UNK UNK
CEILING UNK UNK
SKIN:UNK
TRIETHYLAMINE CAS#121-44-8
WASHINGTON AIR CONTAMINANT: ppm mg/Cubic Meter
TWA 10 40
STEL 15 60
CEILING UNK UNK
SKIN: UNK
MATERIAL SAFETY DATA SHEET
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Wisconsin:
WISCONSIN HAZARDOUS AIR CONTAMINANT LIST:
TRIETHYLAMINE CAS#121-44-8 TABLE A.
West Virginia
The follwing is on the West Virginia Toxic Air Pollutant
List:
Ammonium Hydroxide CAS#1336-21-6 (Pounds per Year):
The following is on the West Virginia Toxic Air Pollutant List:
Dipropylene glycol monomethyl ether CAS#345990-94-8
(Pounds per Year):
The follwing is on the West Virginia Toxic Air Pollutant List:
Calcium carbonate CAS#1317-65-3 (Pounds per Year):
The follwing is on the West Virginia Toxic Air Pollutant List:
Titanium Dioxide CAS#13463-67-7 (Pounds per Year):
The following is on the West Virginia Toxic Air Pollutant List:
2-Pyrrolidinone, 1-Methyl CAS#872-50-4 (Pounds per Year):
The following is on the West Virginia Toxic Air Pollutant List:
Triethylamine CAS#121-44-8 (Pounds per Year):
~~~~ SECTION 16 ~~~~ OTHER INFORMATION ~~~~
HMIS?III
Health :
Flammability :
Physical Hazard :
*Following Health rating Indicates Chronic/Carcinogenic Effects
HMIS?III Personal Protection :
This rating is for the product as it is packaged. This rating will need
to be adjusted by the user based on conditions of use.
The information contained herein relates only to the
specific material identified. United Coatings believes that such
information is accurate and reliable as of the date of this material
safety data sheet, but no representation, guarantee or warranty,
expressed or implied, is made as to the accuracy, reliability, or
completeness of the information. To assure proper use & disposal of
these materials & the safety & health of employees & customers,
United Coatings urges persons receiving this information to make
their own determination as to the information's suitability and
completeness for their particular application.
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