P,.ge: 2
DATE PRb:PAREP: 03.27,2002
MSDS N,,: 601000
TOMADOL (R) 91-6
INHALATION:
Not ~xpected be a relevant routc of expQ"ure. However,high v~por or aerosol mist COQcen-
to
trationDmay be irritating to tlw nose,throat and upper re:ipirar:orytract.
SIGNS AND SYMPTOMS OF OVEREXPOSURE
EYES;
Irritation
SKIN:
Irritation
MEDICAL CONDITIONS AGGRAVATED:
Pre~"'
4. FffiST AID MEASURES
EYES:
Imruediately flusheye:)
with large amounts6f water for at leUl3t minutEl~
15 while holding e~lid.~
open. Get prompt m~licalll.tt~ntion.
SKIN:
lmmeuiatcly flush with largc amounts of wiltcr for at least 15 minute:3; use soap if available
Remove contaminated clothing, including shoes, after flushing ha.$begun.
Get prompt uledical attention.
Do not reuse clothing or shoes until thoroughly clt!aned.
INGESTION:
Do not give liquids if victim j..; uncoI1SCiou~ YC1"y
or druwsy. Otherwise, give no more than 2
glasse:3of water and induct'! vomiting by giving 30 cC (2 Tablespoons) ~yrup of IPECAC'" If
IPECAC is not available, give 2 ~Ia.c;sesof W/1.tcrarld induce vomiting by touching fingcr to back
of vit'tim's thruat. Keep victim'拢! head below hip~ while volluting. Get Modica! Attention.
INHALATION:
Using propt!f respiratory prott!ccion, iIIlrnediately remove the affected victim from expo:oure. Ad-
ministcr artificial rt!spiration if breathing is :otoppcd. Keep at rt!~t. Call for prompt medical
attention.
NOTES TO PHYSICIAN:
If victim is a chilrl, give no more than 1 gl~s of wt\ter and 15 cc (1 Tablespoon) syrup af IPECAC"
If ~ymptau1$such (i.i;!()$:2 .rl;ag
of retiex, convulsions or uncunr;ciousne:JDoccur before eme:!is,gastric
lavage ~hollld be r:()n~ider~ following intubation with a. cutt"ed~nciotracheall:ube.
Plitt": :I
DATE PREPARI,;D: 03.;17.2002
MSD3 No~ 6910flO
TOMADOL (R) 91-6
ADDITIONAL INFORMATION:
Ttil拢'e! of free ethyleneoxide EO may bo preaentin thi~ product and thcy COllldaccumulate ill
thc headspace ~tor!l.ge tran~pori vessels.
of and
The trace aznOllnts of EO in this product are not expected to re~ult in either a(:ute or lung
term hazard whcn the material is h8Jldled according to sections X and XI. You should b~ aw!!.re
though, that EO i:! a cancer and reproductive hazard. RepeatE':dexpO:3\1re EO may be harmful.
to
FffiE FIGHTING MEASURES
5,
Fla$hpoint and Method: 289掳F Pcnskey-Marten CC
Flanmlable Linlit~: Not Applicable to Not Applicable
EXTINGUISHING MEDIA:
Use alcohol type foam, unive~al foam, dry chemical, carbon dioxide or w~tcr spray to extinguish
fire.
lIAZARDOUS COMBUSTION PRODUCTS:
Carbon Monoxidc, Carbon Dioxidc
FffiE FIGHTING PROCEDURES:
Usewater spray to cool fire E!xpo~ed
surface5and to protect per:;onnel.
lo;olate,.fue!n supply frow
fire.
FIRE EXPLOSION:
Low Hazard, liquid can burn upon heating to temperaturesat Or aboveth~ ftashpoint.
"Empty" cont3iner:!rl~tilinproduct residue(liquid arId/or vapor) and can be dangerous. NOT
DO
PRESSURIZE,CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE SUCH CON-
TAINERS TO HEAT, FLAtvIE, SPARKS,STATIC ELECTRICITY, OR OTHER SOURCESOF
IGNITION; THEY MAY EXPLODE AND CAUSE INJURY OR DEATH. Empty drUIn8~hould
be completely drained, properly bungod and promptly re. turncd to a drum reconditioner, Or
properly di~p()sed
of.
SENSITIVE TO STATIC DISCHARGE:
Unlmown, U~t!
propt!I grounding proct!dure
6. ACCIDENTAL RELEASE MEASURES
Sl'vIALL SPILL:
For :lm$lUspills, take lip materii\.l with an absorbent SllChas t:lay or ~aIld and di;:;p()Se properly.
of
Flush area with water ro relli()V~ trat:e residue.
P"gc; 01
DA'I'Ji: PREf'AR拢D: 03.27.~002
MSDS Nu: 691060
TOMADOL (R) 91-6
LARGE SPILL:
WeA.rTe:lpirator and protective clotlling ~ appropriatc. Shu~ off source of leak if it is safe to do
tIC. Dike and contain spilled material. Remove with vacuum tnlcks or p"mp to iJtoragej9alvage
containers. Soak up re~idu~ with an absorhent illich as clay, sand or other :Juita.ble ulaterial.
Flush arAa with water tu rcmove trace Tt'~idu~.
COIldUIr: expcrt on dispo:Jal of recovercd m~terial and ensure conformity to local disposal
an
regulations.
ENVIRONMENTAL PRECAUTIONS:
WATER SPILL:
Rnmove from :iW"faceby 3kimming or with 51rit3.bleadsorbent5. If allowed by local authoritif)拢
and environmental agencies, sinking and/or ~\litable disper:llints may be 11Sed non-confined
in
water~.
Consult an exp~rt on disposal of rccovered material and endurc: conformity to local disposal
r~gultttion.,.
LAND SPILL:
Eliminate :JOIJ.rces ignition. Prevent ~ditio[lltl
of disch'd.rgeof materiii.l, if poo6ible to do so
without hll?:3rd. For small :Jpills wlplemcnt CleSJl11p
procedl1res; for large ~pill~ implement cleanup
pro("edllres and, if in public area, kE!eppublic away and advi:Je al/T.horities. Also, if till" product:
i:! ~'lbject to CERCLA reporting (see Section15) notify tb~ National RA$ponseCenter.
'"
HANDLING AND STORAGE
GENERAL PROCEDURES:
Ke~p container cIQ~cd. Handle and open cOntainer~ with care. Store in a (:001,well vcntil~te(l
place away from incompatible material5.
Do NOT handle or store ncar an op~n ftazne, heat Or other :lourccs of ignition. Protect material
ironl direct ilunlight.
It il3not known if this material is a :;tatic accUIUlLlator. Thcrefore, u.o;a
proper grounding proce-
dllres.
Do NOT pre5~urize,cut, heat, or weld containers. Empty product containers may conrain product
residue. Do NOT reutle empty container:; without commercial cleaning or reconditionin.e;.
Storage Temperature: 55掳F IIlinimum to 100掳F maximunl
Loading Temperature: 5.5掳F Ininimum to 120掳F m;l.Ximum
Loal.!ing/Uruoading Viscosity: , 10 to 30 cps
SPECIAL SENSITIVITY:
It j.<:
recoromcnded to ~tore Lhis material under a nitrogen blanket to minimizc the potf!ntial [or
ethoA-yl~r.1!oxid~\r.ion- OvfJrheatin~ of an ethoxylate ~[()red under air ~hou)d be avoidcd. When
an ethoxylate is vigoluU"-ly mixed in the presence of air or oxygen at temperatuI~S > :325degrees
F) it can tltldcrgo t!xvthermic oxidative degr!!.dation.
ELEc'rROSTA'frC ACCUMULATION HAZ.'\RD
Unlalown, U:Ieproper !.!:rollndiIll!;
procedurA
5
po-g.:
DATE PR,.:.f>ARED: 03.21.2no:2
TOMADOL 060 91-6
MSJ)S No: 6'" (R)
--
EXPOSURE CONTROLS/PERSONAL PROTECTION
8
ENGINEERING CONTROLS:
Ventilation ~hOllldb~ provilled to control work~r expO$ure:i prevent:health risk.
Md
PERSONAL PROTECTION
RESPffiATORY:
Utle a NIOSH-Approved re:>pirator as required to prevent uvereXpOdUrf'..In accord with 29 CFR
1910.),34)U~0 cither atmo:lphcre-~upplying or air-purifying reapirator for organic vapor:l. For EO:
H occllpational expO-.;uremayor dof!S ex<:eed1 ppm, respiratory protACtion il3 raquired. Use a
NIOSH-Approved, ~tmotlphore..:!upplying. nlll -facepicce respirator in pressure-df:wanu mode for
> 50 ppm. NIOSH hii.i approved a full f拢l.ccpiece canister rF!Spirator with an ~nd of ~ervice life
indicator for < 50 ppUl.
WORK HYGIENIC PRACTICES:
Avoid contact with eyes, ~kin and <:lothing.
WhAre contact may occur, wear long sleeve~Jcllenlical r~i~tant glove.$,chenucaJ goggl~, and a
facc swt!ld.
Where concentr8.1:ioru. air may exceed the liwits given in this Section and C'.ugineering,work
in
practice or other means of exposure reduction are not adeq\la.te, NIOSH/MSHA approved respi-
rators may be ncce:l:1aryto prevcnt ovetexpo~uce by inhalation.
PHYSICAL AND
9. CHEM:ICAL PROPERTIES
Physical State: Liquid
Odor: Mild odoc
Appearance: Slightly vL5COU;i liqllid
Vapor Pressure: <0.10 mmHg at 100掳F
Vapor Deu3ity: 15 (Air = 1)
Boiling PoUlt: >450掳F
Freezing Point: -23 to 59掳P
Melting Point: -23 to 59掳F
Evapora.tion Rate: Not Applicable
Specific Gravity: .984 gjrru at 17掳F
Viscosity: 23 CST at 100掳F
(VOC): 9.46 Perccnt Method 2.1
COMMENTS:
= 43 deg F.
Fre~ing Point: POllf pain.
W'lter Solubility; Complt!tcly ~luble, m~y form ~ gel.
STABILITY AND REACTIVITY
10
STABLE: Ye~
P~ba: 6
DATE PREPARED: 03.27.2002
MSD5 Nol 691000
TOMADOL (R) 91-6
HAZARDOUSPOLYMERIZATION: No
STABILITY:
Not applicable
POLYMERIZATION:
Not I!.pplicable
CONDITIONS TO AVOID:
Oxidation of alcohol ethoA-ylatcs may occur under certain conditions. Avl)id oVt!rheating (~xn-
perat.ues> 325 F) especially when vigoroU$ly ~d with air. See :lpecial precautions.
HAZARDOUSDECOMPOSITION:
CarbonInonO:>cide Ilnidentificd organic compound:imay be formed during combustion
and
TOXICOLOGICAL INFORMATION
11
ACU'fE
Skin: Acllte Dermal LD50: >5 g;kg (rabbit)
Inge:ltion:AcutG!
oral LD50: 1.4 g/kg (rat)
SENSITIZATION:
Thi:I material was not ;I.sen~itizcrin a gunea. sensitization t~t,
pig
12. ECOLOGICAL INFORMATION
CHEMICAL FATE INFORMATION:
Thill ma.teril:l.l expectE:dto biodegrade at a.moderate rata and b~ "readily biodegradable" based
i!:
on the following d!l.ta:
DOD gig COD gig % Biodegraded
2.0(30 day) 2.2 91%
1.6 (15 day)
0.36(5 day)
GENERAL COMMENTS:
No data il1availablc,ple~e conttI.Ct techaical:iervicedepartment to discuss environmen{;al
the the
fate arId t:aJcicity thitl product..
of
DISPOSAL CONSIDERATIONS
13
DISPOSAL METHOD:
DispC)~e ill ilccordance with federi\l, ~tate I'LndlocEll regulations
of
Ps.,."; 7
DAT~ PREPARED: 03.:27.2002
TOMADOL (R) 91-6
M~nS No: 69101\,)
" -~ ~
RCRA/USPA WASTE INFORMATION:
H thi.~ prod\tct becc.)mes wa3te, it would not b~ a h~a.rQou:l waste by RCRA criteria (40CFR
tL
261). However thl! Wa3tt! ~hould be propcrly characterized tu evaluate whether its composition
ha.'\been modified through pro<;essiunprior to dispo$al.
TRANSPORT INFORMATION
14.
DOT (DEPARTMENT OF TRANSPORTATION)
Proper Shippin~ Name: Not reg1tlated
Hot Hazard: No
Combu..;tible Class: No
INTERNATIONAL (I.M.O.)
Proper Shipplllg Name: Not r6gluated
AIR. (l.C.A.G.)
Proper Shipping Name:Not reg1utlted
INFORMATION
15 REGULATORY
UNITED STATES
SARA TITLE III (SUPERFUND AMENDMENTS AND REAUTHOR1ZATION ACT)
Fire: No Pre:l:!ure Generating; No Reactivity: No Acutc: y~ Chronic: No
311/312 Hazard Ca~egories;Under the provision~ of Title ill, Section$ 311/312 of the Superfund
Amendments a.nd Reauthorization Act (SAILA.-)thilJ product is classified intO the hazard:!
listed above.
313 Rep()rtabl~ Ingredients: This product doe~ not contain any ingredicnts reportable Ilnder
Section 313.
CERCLA (COMPREl-IENSIVE RESPONSE, CO1l.rPENSATION, AND LIABILITY ACT)
CER,CLA R.egulatory: If this product is accidentally :lpillcd, it is not :jubj(!ct to any special repurt-
ing tinder the requircment6 of the Comprehensive Envirorunentl:\! Rcspo~e, Compensation,
aud Liability Act (CERCLA). WA recoxnmcnd YOll contact local al1thuriti~ to detEJrroiueif
there may be uthcr loc~\l reporting requirement~-
EPA
EPA RQ lIlgr~dient; Not applicable
TSCA (TOXIC SUBSTANCE CONTROL ACT)
TSCA ST.atU:3:
Componentsof &hlsproullct ar~ }isted on the TSCA Inventory.
P.g,,: &
DATe PREPARED: O~.2",2002
MSDS N,,: 691060
--
TOMADOL (R) 91-6
RCR."- S'l'ATUS:
If this product bccom~~ a Wabtc, it would not be a haza.rdol!S w~te by RCRA lTiteria (4.QCFR
261). However the wt\"f;c should be properly charactorized to evalltate whether its composition
has been modified through procession prior to di!lposal.
STATE REGULATIONS
PROPOSITION65 STKfEMENT: ,
This product con~ the following levcls of compoW1dsfound by the ~tate of California to cau~e
canct!I, birtll defects aJ1dothcr reproductive haml:
CAS NO. 75-21-8 <1 pPII1
Ethylene oxide
REGULATIONS
State Regulations: The foUowing chemical:i nc~ specifically lil3tcd by individual state:!j other prod-
tlct specific health aIld l1a.fetydata in other 5eCtion~ of the MSDS may also be applicable
for state requirement:!. For cletail3 on your reglJlatory requirementS YO\I should COntAc.'t rhe
appropriate II.gAncyin your state.
Ethylene Oxide CAS No 75-21-8 <1 ppm
Mass~chllSetts
California Safe driIlking water and toxics enforcement ilct
of 1996 (PROP 65)
GENERAL COMMENTS:
PROTECTION OF STRATOSPHERIC OZONE (PURSUANT TO SECTION 611 OF THE
CLEAN AIR ACT AMMENDMENTS OF 1990):
Per 40 CFR Part 82, this product doC!Snot contain nor WM it directly mttnufactured with any
Cl~ I or CIa-", II oz.one dt:pleting .$llbstanCE1$.
OTHER INFORMATION
16,
Approval datc: 05.08.2002
REVISION SUMMARY
Rev1SWII 5
#:
Thi:! MSDS !cpJat:e;;the Mrtrch 27) 2002 MSDS. Any ch禄nges ill inform~r.ion are 'L~foJlows:
NFPA CODES
Fir~: 1 Health: :2 R.e~ctivity: 0
I-IMIS CODES
Reactivity: 0
Fir~: 1 Hoalth: 2
!'~I;~' (I
DATE PllliPAREl>: 03.27.~OO2
MSDS No: ~g] nAn
TOMADOL (R) 91-6
MANUFACTURER DISCLAllvIER:
This information relat~ to thc specific materia.! debignated and may not be valid for $1.tchmaterial
u..;~din cornbi1lation with any other materials ur in any proc~:j. Such infoTnl~tion is to the
b~t of OIJr kn()wledg~ and hclief, accurate and reliable Ii:1 of the date compiled. However, no
repre:ientatiun, warranty ut guarantee it! made as to its accuracy, relitt.bility or completeness.
It i:j thc u~et.c;
re:jponsibili,y to satisfy himself A.~to tht1 .iuitabillty aIld completeness of such
infl>rmation for hi" OWIlparticular U:je. We do not ~CApt liability for any loas or dama.ge that
may occur from the u~ of this information not do we offer warranty against patent infringement.
|