DY-MARK TAILPAINT AEROSOL ALL COLOURS LEAD FREE
Chemwatch Material Safety Data Sheet (REVIEW)
Issue Date: 15-Nov-2006 CHEMWATCH 6596-33
NC317TCP CD 2006/4 Page 1 of 21
Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME
DY-MARK TAILPAINT AEROSOL ALL COLOURS LEAD FREE
SYNONYMS
PROPER SHIPPING NAME
AEROSOLS
PRODUCT USE
The use of a quantity of material in an unventilated or confined space may result in
increased exposure and an irritating atmosphere developing. Before starting consider
control of exposure by mechanical ventilation. Application is by spray atomisation from a
hand held aerosol pack. Aerosol paint.
SUPPLIER
Company: Dy- Mark (Aust) Pty Ltd
Address:
89 Formation Street
Wacol
QLD, 4076
AUS
Telephone: +61 7 3271 2222
Fax: +61 7 3271 2751
Section 2 - HAZARDS IDENTIFICATION
STATEMENT OF HAZARDOUS NATURE
HAZARDOUS SUBSTANCE. DANGEROUS GOODS. According to the Criteria of NOHSC,
and the ADG Code.
POISONS SCHEDULE
None
RISK SAFETY
Extremely flammable. Do not breathe gas/fumes/vapour/spray.
Irritating to skin. Wear eye/face protection.
Risk of explosion if heated under confinement. Use only in well ventilated areas.
Very toxic to aquatic organisms, may cause long- Keep container in a well ventilated place.
term adverse effects in the aquatic environment.
Vapours may cause drowsiness and dizziness. To clean the floor and all objects contaminated
by this material, use water and detergent.
Keep container tightly closed.
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DY-MARK TAILPAINT AEROSOL ALL COLOURS LEAD FREE
Chemwatch Material Safety Data Sheet (REVIEW)
Issue Date: 15-Nov-2006 CHEMWATCH 6596-33
NC317TCP CD 2006/4 Page 2 of 21
Section 2 - HAZARDS IDENTIFICATION
This material and its container must be disposed
of in a safe way.
Take off immediately all contaminated clothing.
In case of contact with eyes, rinse with plenty
of water and contact Doctor or Poisons
Information Centre.
If swallowed, IMMEDIATELY contact Doctor or
Poisons Information Centre. (show this container
or label).
Use appropriate container to avoid environment
contamination.
Avoid release to the environment. Refer to
special instructions/Safety data sheets.
This material and its container must be disposed
of as hazardous waste.
Section 3 - COMPOSITION / INFORMATION ON INGREDIENTS
NAME CAS RN %
heptane 142-82-5 30-60
aliphatic hydrocarbon resin <10
isobutylene homopolymer 9003-27-4 <10
pigment, nonhazardous <10
toluene 108-88-3 <5
silica amorphous 7631-86-9 <1
tallow alkyldimethylammonium chloride/ bentonite 68953-58-2 <1
dimethyl ether 115-10-6 10-30
hydrocarbon propellant 68476-85-7. 10-30
Section 4 - FIRST AID MEASURES
SWALLOWED
Not considered a normal route of entry.
If spontaneous vomiting appears imminent or occurs, hold patient's head down, lower than
their hips to help avoid possible aspiration of vomitus.
Avoid giving milk or oils.
Avoid giving alcohol.
EYE
If aerosols come in contact with the eyes:
- Immediately hold the eyelids apart and flush the eye continuously for at least 15
minutes with fresh running water.
- Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and
moving the eyelids by occasionally lifting the upper and lower lids.
- Transport to hospital or doctor without delay.
- Removal of contact lenses after an eye injury should only be undertaken by skilled
personnel.
SKIN
If solids or aerosol mists are deposited upon the skin:
- Flush skin and hair with running water (and soap if available).
- Remove any adhering solids with industrial skin cleansing cream.
- DO NOT use solvents.
- Seek medical attention in the event of irritation.
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DY-MARK TAILPAINT AEROSOL ALL COLOURS LEAD FREE
Chemwatch Material Safety Data Sheet (REVIEW)
Issue Date: 15-Nov-2006 CHEMWATCH 6596-33
NC317TCP CD 2006/4 Page 3 of 21
Section 4 - FIRST AID MEASURES
INHALED
If aerosols, fumes or combustion products are inhaled:
- Remove to fresh air.
- Lay patient down. Keep warm and rested.
- Prostheses such as false teeth, which may block airway, should be removed, where
possible, prior to initiating first aid procedures.
- If breathing is shallow or has stopped, ensure clear airway and apply resuscitation,
preferably with a demand valve resuscitator, bag-valve mask device, or pocket mask as
trained. Perform CPR if necessary.
- Transport to hospital, or doctor.
NOTES TO PHYSICIAN
Treat symptomatically.
for lower alkyl ethers:
--------------------------------------------------------------
BASIC TREATMENT
--------------------------------------------------------------
- Establish a patent airway with suction where necessary.
- Watch for signs of respiratory insufficiency and assist ventilation as necessary.
- Administer oxygen by non-rebreather mask at 10 to 15 l/min.
- A low-stimulus environment must be maintained.
- Monitor and treat, where necessary, for shock.
- Anticipate and treat, where necessary, for seizures.
- DO NOT use emetics. Where ingestion is suspected rinse mouth and give up to 200 ml
water (5 ml/kg recommended) for dilution where patient is able to swallow, has a strong
gag reflex and does not drool.
--------------------------------------------------------------
ADVANCED TREATMENT
--------------------------------------------------------------
- Consider orotracheal or nasotracheal intubation for airway control in unconscious
patient or where respiratory arrest has occurred.
- Positive-pressure ventilation using a bag-valve mask might be of use.
- Monitor and treat, where necessary, for arrhythmias.
- Start an IV D5W TKO. If signs of hypovolaemia are present use lactated Ringers
solution. Fluid overload might create complications.
- Drug therapy should be considered for pulmonary oedema.
- Hypotension without signs of hypovolaemia may require vasopressors.
- Treat seizures with diazepam.
- Proparacaine hydrochloride should be used to assist eye irrigation.
--------------------------------------------------------------
EMERGENCY DEPARTMENT
--------------------------------------------------------------
- Laboratory analysis of complete blood count, serum electrolytes, BUN, creatinine,
glucose, urinalysis, baseline for serum aminotransferases (ALT and AST), calcium,
phosphorus and magnesium, may assist in establishing a treatment regime. Other useful
analyses include anion and osmolar gaps, arterial blood gases (ABGs), chest radiographs
and electrocardiograph.
- Ethers may produce anion gap acidosis. Hyperventilation and bicarbonate therapy might
be indicated.
- Haemodialysis might be considered in patients with impaired renal function.
- Consult a toxicologist as necessary.
BRONSTEIN, A.C. and CURRANCE, P.L.
EMERGENCY CARE FOR HAZARDOUS MATERIALS EXPOSURE: 2nd Ed. 1994.
For acute or short term repeated exposures to petroleum distillates or related
hydrocarbons:
- Primary threat to life, from pure petroleum distillate ingestion and/or inhalation, is
respiratory failure.
- Patients should be quickly evaluated for signs of respiratory distress (e.g. cyanosis,
tachypnoea, intercostal retraction, obtundation) and given oxygen. Patients with
inadequate tidal volumes or poor arterial blood gases (pO2 50 mm Hg) should be intubated.
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DY-MARK TAILPAINT AEROSOL ALL COLOURS LEAD FREE
Chemwatch Material Safety Data Sheet (REVIEW)
Issue Date: 15-Nov-2006 CHEMWATCH 6596-33
NC317TCP CD 2006/4 Page 4 of 21
Section 4 - FIRST AID MEASURES
- Arrhythmias complicate some hydrocarbon ingestion and/or inhalation and
electrocardiographic evidence of myocardial injury has been reported; intravenous lines
and cardiac monitors should be established in obviously symptomatic patients. The lungs
excrete inhaled solvents, so that hyperventilation improves clearance.
- A chest x-ray should be taken immediately after stabilisation of breathing and
circulation to document aspiration and detect the presence of pneumothorax.
- Epinephrine (adrenalin) is not recommended for treatment of bronchospasm because of
potential myocardial sensitisation to catecholamines. Inhaled cardioselective
bronchodilators (e.g. Alupent, Salbutamol) are the preferred agents, with aminophylline a
second choice.
- Lavage is indicated in patients who require decontamination; ensure use of cuffed
endotracheal tube in adult patients. [Ellenhorn and Barceloux: Medical Toxicology].
Section 5 - FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA
SMALL FIRE:
- Water spray, dry chemical or CO2
LARGE FIRE:
- Water spray or fog.
FIRE FIGHTING
FOR FIRES INVOLVING MANY GAS CYLINDERS:
- To stop the flow of gas, specifically trained personnel may inert the atmosphere to
reduce oxygen levels thus allowing the capping of leaking container(s).
- Reduce the rate of flow and inject an inert gas, if possible, before completely
stopping the flow to prevent flashback.
- DO NOT extinguish the fire until the supply is shut off otherwise an explosive re
-ignition may occur.
- If the fire is extinguished and the flow of gas continues, used increased ventilation
to prevent build-up, of explosive atmosphere.
- Use non-sparking tools to close container valves.
- Be CAUTIOUS of a Boiling Liquid Evaporating Vapour Explosion, BLEVE, if fire is
impinging on surrounding containers.
- Direct 2500 litre/min (500 gpm) water stream onto containers above liquid level with
the assistance remote monitors.
- Alert Fire Brigade and tell them location and nature of hazard.
- May be violently or explosively reactive.
- Wear breathing apparatus plus protective gloves.
- Prevent, by any means available, spillage from entering drains or water course.
- If safe, switch off electrical equipment until vapour fire hazard removed.
- Use water delivered as a fine spray to control fire and cool adjacent area.
- DO NOT approach containers suspected to be hot.
- Cool fire exposed containers with water spray from a protected location.
- If safe to do so, remove containers from path of fire.
- Equipment should be thoroughly decontaminated after use.
FIRE/EXPLOSION HAZARD
- Liquid and vapour are highly flammable.
- Severe fire hazard when exposed to heat or flame.
- Vapour forms an explosive mixture with air.
- Severe explosion hazard, in the form of vapour, when exposed to flame or spark.
- Vapour may travel a considerable distance to source of ignition.
- Heating may cause expansion or decomposition with violent container rupture.
- Aerosol cans may explode on exposure to naked flames.
- Rupturing containers may rocket and scatter burning materials.
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DY-MARK TAILPAINT AEROSOL ALL COLOURS LEAD FREE
Chemwatch Material Safety Data Sheet (REVIEW)
Issue Date: 15-Nov-2006 CHEMWATCH 6596-33
NC317TCP CD 2006/4 Page 5 of 21
Section 5 - FIRE FIGHTING MEASURES
- Hazards may not be restricted to pressure effects.
- May emit acrid, poisonous or corrosive fumes.
- On combustion, may emit toxic fumes of carbon monoxide (CO).
Combustion products include: carbon monoxide (CO), carbon dioxide (CO2), other
pyrolysis products typical of burning organic material.
Contains low boiling substance: Closed containers may rupture due to pressure
buildup under fire conditions.
May emit clouds of acrid smoke.
FIRE INCOMPATIBILITY
Avoid contamination with oxidising agents i.e. nitrates, oxidising acids, chlorine
bleaches, pool chlorine etc. as ignition may result.
HAZCHEM: 2Y
Personal Protective Equipment
Breathing apparatus.
Gas tight chemical resistant suit.
Limit exposure duration to 1 BA set30 mins.
Section 6 - ACCIDENTAL RELEASE MEASURES
EMERGENCY PROCEDURES
MINOR SPILLS
- Clean up all spills immediately.
- Avoid breathing vapours and contact with skin and eyes.
- Wear protective clothing, impervious gloves and safety glasses.
- Shut off all possible sources of ignition and increase ventilation.
- Wipe up.
- If safe, damaged cans should be placed in a container outdoors, away from all ignition
sources, until pressure has dissipated.
- Undamaged cans should be gathered and stowed safely.
MAJOR SPILLS
- Remove leaking cylinders to a safe place.
- Fit vent pipes. Release pressure under safe, controlled conditions
- Burn issuing gas at vent pipes.
DO NOT exert excessive pressure on valve; DO NOT attempt to operate damaged valve.
- Clear area of personnel and move upwind.
- Alert Fire Brigade and tell them location and nature of hazard.
- May be violently or explosively reactive.
- Wear breathing apparatus plus protective gloves.
- Prevent, by any means available, spillage from entering drains or water courses
- No smoking, naked lights or ignition sources.
- Increase ventilation.
- Stop leak if safe to do so.
- Water spray or fog may be used to disperse / absorb vapour.
- Absorb or cover spill with sand, earth, inert materials or vermiculite.
- If safe, damaged cans should be placed in a container outdoors, away from ignition
sources, until pressure has dissipated.
- Undamaged cans should be gathered and stowed safely.
- Collect residues and seal in labelled drums for disposal.
PROTECTIVE ACTIONS FOR SPILL
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DY-MARK TAILPAINT AEROSOL ALL COLOURS LEAD FREE
Chemwatch Material Safety Data Sheet (REVIEW)
Issue Date: 15-Nov-2006 CHEMWATCH 6596-33
NC317TCP CD 2006/4 Page 6 of 21
Section 6 - ACCIDENTAL RELEASE MEASURES
PROTECTIVE ACTION ZONE
half
evacuation
downwind
direction
distance
down wind distance
wind isolation
distance
direction
half
evacuation downwind
INITIAL direction distance
ISOLATION
ZONE
From IERG (Canada/Australia)
Isolation Distance -
Downwind Protection Distance 8 metres
IERG Number 49
FOOTNOTES
1 PROTECTIVE ACTION ZONE is defined as the area in which people are at risk of harmful exposure. This zone
assumes that random changes in wind direction confines the vapour plume to an area within 30 degrees on
either side of the predominant wind direction, resulting in a crosswind protective action distance equal
to the downwind protective action distance.
2 PROTECTIVE ACTIONS should be initiated to the extent possible, beginning with those closest to the spill
and working away from the site in the downwind direction. Within the protective action zone a level of
vapour concentration may exist resulting in nearly all unprotected persons becoming incapacitated and
unable to take protective action and/or incurring serious or irreversible health effects.
3 INITIAL ISOLATION ZONE is determined as an area, including upwind of the incident, within which a high
probability of localised wind reversal may expose nearly all persons without appropriate protection to
life-threatening concentrations of the material.
4 SMALL SPILLS involve a leaking package of 200 litres (55 US gallons) or less, such as a drum (jerrican or
box with inner containers). Larger packages leaking less than 200 litres and compressed gas leaking from
a small cylinder are also considered "small spills".
LARGE SPILLS involve many small leaking packages or a leaking package of greater than 200 litres, such as
a cargo tank, portable tank or a "one-tonne" compressed gas cylinder.
5 Guide 126 is taken from the US DOT emergency response guide book.
6 IERG information is derived from CANUTEC - Transport Canada.
EMERGENCY RESPONSE PLANNING GUIDELINES (ERPG)
The maximum airborne concentration below which it is believed that nearly all individuals could be exposed
for up to one hour WITHOUT experiencing or developing
life-threatening health effects is:
heptane 750 ppm
dimethyl ether 60000 ppm
hydrocarbon propellant 2000 ppm
irreversible or other serious effects or symptoms which could impair an individual's ability to take
protective action is:
heptane 440 ppm
dimethyl ether 50000 ppm
hydrocarbon propellant 2000 ppm
other than mild, transient adverse effects without perceiving a clearly defined odour is:
heptane 440 ppm
dimethyl ether 3000 ppm
hydrocarbon propellant 2000 ppm
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DY-MARK TAILPAINT AEROSOL ALL COLOURS LEAD FREE
Chemwatch Material Safety Data Sheet (REVIEW)
Issue Date: 15-Nov-2006 CHEMWATCH 6596-33
NC317TCP CD 2006/4 Page 7 of 21
Section 6 - ACCIDENTAL RELEASE MEASURES
The threshold concentration below which most people will experience no appreciable risk of health effects:
heptane 440 ppm
dimethyl ether 1000 ppm
hydrocarbon propellant 1000 ppm
American Industrial Hygiene Association (AIHA)
Ingredients considered according to the following cutoffs
Very Toxic (T+) >= 0.1% Toxic (T) >= 3.0%
R50 >= 0.25% Corrosive (C) >= 5.0%
R51 >= 2.5%
else >= 10%
where percentage is percentage of ingredient found in the mixture
SAFE STORAGE WITH OTHER CLASSIFIED CHEMICALS
___________________________________________
+ X X X X +
___________________________________________
+: May be stored together
O: May be stored together with specific preventions
X: Must not be stored together
Personal Protective Equipment advice is contained in Section 8 of the MSDS.
Section 7 - HANDLING AND STORAGE
PROCEDURE FOR HANDLING
- Containers, even those that have been emptied, may contain explosive vapours.
- Do NOT cut, drill, grind, weld or perform similar operations on or near containers.
- Electrostatic discharge may be generated during pumping - this may result in fire.
- Ensure electrical continuity by bonding and grounding (earthing) all equipment.
- Restrict line velocity during pumping in order to avoid generation of electrostatic
discharge (<=1 m/sec until fill pipe submerged to twice its diameter, then <= 7 m/sec).
- Avoid splash filling.
- Do NOT use compressed air for filling discharging or handling operations.
Atmospheres must be tested and O.K. before work resumes after leakage.
Avoid generation of static electricity. Earth all lines and equipment.
Obtain a work permit before attempting any repairs. Do not attempt repair work on lines,
vessels under pressure.
DO NOT transfer gas from one cylinder to another.
- Avoid all personal contact, including inhalation.
- Wear protective clothing when risk of exposure occurs.
- Use in a well-ventilated area.
- Prevent concentration in hollows and sumps.
- DO NOT enter confined spaces until atmosphere has been checked.
- Avoid smoking, naked lights or ignition sources.
- Avoid contact with incompatible materials.
- When handling, DO NOT eat, drink or smoke.
- DO NOT incinerate or puncture aerosol cans.
- DO NOT spray directly on humans, exposed food or food utensils.
- Avoid physical damage to containers.
- Always wash hands with soap and water after handling.
- Work clothes should be laundered separately.
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DY-MARK TAILPAINT AEROSOL ALL COLOURS LEAD FREE
Chemwatch Material Safety Data Sheet (REVIEW)
Issue Date: 15-Nov-2006 CHEMWATCH 6596-33
NC317TCP CD 2006/4 Page 8 of 21
Section 7 - HANDLING AND STORAGE
- Use good occupational work practice.
- Observe manufacturer's storing and handling recommendations.
- Atmosphere should be regularly checked against established exposure standards to ensure
safe working conditions are maintained.
SUITABLE CONTAINER
- Aerosol dispenser.
- Check that containers are clearly labelled.
STORAGE INCOMPATIBILITY
Ethers may react violently with strong oxidising agents and acids.
The tendency of many ethers to form explosive peroxides is well documented. Ethers
lacking non-methyl hydrogen atoms adjacent to the ether link are thought to be relatively
safe. When solvents have been freed from peroxides (by percolation through a column of
activated alumina for example), the absorbed peroxides must promptly be desorbed by
treatment with the polar solvents methanol or water, which should be discarded safely.
Avoid reaction with oxidising agents.
STORAGE REQUIREMENTS
Keep dry to avoid corrosion of cans. Corrosion may result in container perforation and
internal pressure may eject contents of can.
- Store in original containers in approved flammable liquid storage area.
- DO NOT store in pits, depressions, basements or areas where vapours may be trapped.
- No smoking, naked lights, heat or ignition sources.
- Keep containers securely sealed. Contents under pressure.
- Store away from incompatible materials.
- Store in a cool, dry, well ventilated area.
- Avoid storage at temperatures higher than 40 deg C.
- Store in an upright position.
- Protect containers against physical damage.
- Check regularly for spills and leaks.
- Observe manufacturer's storing and handling recommendations.
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
EXPOSURE CONTROLS
Source Material TWA TWA STEL STEL Peak Peak TWA
ppm mg/m鲁 ppm mg/m鲁 ppm mg/m鲁 F/CC
_________________ __________________ ______ ______ ______ ______ ______ ______ ______
Australia Exposure heptane (Heptane 400 1, 640 500 2, 050
Standards (n- Heptane))
Australia Exposure toluene (Toluene) 50 191 150 574
Standards
Australia Exposure silica amorphous 2
Standards (Fumed silica
(respirable dust))
Australia Exposure tallow 10
Standards alkyldimethylammon
ium chloride/
bentonite
(Inspirable dust
(Not specified))
Australia Exposure dimethyl ether 400 760 500 950
Standards (Dimethyl ether)
Australia Exposure hydrocarbon 1, 000 1, 800
Standards propellant (LPG
(liquified
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DY-MARK TAILPAINT AEROSOL ALL COLOURS LEAD FREE
Chemwatch Material Safety Data Sheet (REVIEW)
Issue Date: 15-Nov-2006 CHEMWATCH 6596-33
NC317TCP CD 2006/4 Page 9 of 21
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
Source Material TWA TWA STEL STEL Peak Peak TWA
ppm mg/m鲁 ppm mg/m鲁 ppm mg/m鲁 F/CC
_________________ __________________ ______ ______ ______ ______ ______ ______ ______
petroleum gas))
The following materials had no OELs on our records
鈥? isobutylene homopolymer: CAS:9003-27-4 CAS:9003-29-6
EMERGENCY EXPOSURE LIMITS
Material Revised IDLH Value (mg/m3) Revised IDLH Value (ppm)
heptane 750
toluene 500
silica amorphous 3, 000
hydrocarbon propellant 2, 000 [LEL]
NOTES
Values marked LEL indicate that the IDLH was based on 10% of the lower explosive limit
for safety considerations even though the relevant toxicological data indicated that
irreversible health effects or impairment of escape existed only at higher
concentrations.
MATERIAL DATA
Sensory irritants are chemicals that produce temporary and undesirable side-effects on
the eyes, nose or throat. Historically occupational exposure standards for these
irritants have been based on observation of workers' responses to various airborne
concentrations. Present day expectations require that nearly every individual should be
protected against even minor sensory irritation and exposure standards are established
using uncertainty factors or safety factors of 5 to 10 or more. On occasion animal no
-observable-effect-levels (NOEL) are used to determine these limits where human results
are unavailable. An additional approach, typically used by the TLV committee (USA) in
determining respiratory standards for this group of chemicals, has been to assign ceiling
values (TLV C) to rapidly acting irritants and to assign short-term exposure limits (TLV
STELs) when the weight of evidence from irritation, bioaccumulation and other endpoints
combine to warrant such a limit. In contrast the MAK Commission (Germany) uses a five
-category system based on intensive odour, local irritation, and elimination half-life.
However this system is being replaced to be consistent with the European Union (EU)
Scientific Committee for Occupational Exposure Limits (SCOEL); this is more closely
allied to that of the USA.
OSHA (USA) concluded that exposure to sensory irritants can:
- cause inflammation
- cause increased susceptibility to other irritants and infectious agents
- lead to permanent injury or dysfunction
- permit greater absorption of hazardous substances and
- acclimate the worker to the irritant warning properties of these substances thus
increasing the risk of overexposure.
INGREDIENT DATA
HEPTANE:
The TLV-TWA is protective against narcotic and irritant effects which are
greater than those of pentane or n-hexane but less than those of octane.
The TLV-TWA applies to all isomers.
Inhalation by humans of 1000 ppm for 6 minutes produced slight dizziness.
Higher concentrations for shorter periods produce marked vertigo,
incoordination and hilarity. Signs of central nervous system depression
occur in the absence of mucous membrane irritation. Brief exposures to
high levels (5000 ppm for 4 minutes) produce nausea, loss of appetite and
a "gasoline-like" taste in the mouth that persists for many hours after
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DY-MARK TAILPAINT AEROSOL ALL COLOURS LEAD FREE
Chemwatch Material Safety Data Sheet (REVIEW)
Issue Date: 15-Nov-2006 CHEMWATCH 6596-33
NC317TCP CD 2006/4 Page 10 of 21
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
exposure ceases.
ISOBUTYLENE HOMOPOLYMER:
No exposure limits set by NOHSC or ACGIH.
TOLUENE:
Exposure limits with "skin" notation indicate that vapour and liquid may be absorbed
through intact skin. Absorption by skin may readily exceed vapour inhalation exposure.
Symptoms for skin absorption are the same as for inhalation. Contact with eyes and mucous
membranes may also contribute to overall exposure and may also invalidate the exposure
standard.
Odour Threshold Value: 0.16-6.7 (detection), 1.9-69 (recognition)
NOTE: Detector tubes measuring in excess of 5 ppm, are available.
High concentrations of toluene in the air produce depression of the
central nervous system (CNS) in humans. Intentional toluene exposure
(glue-sniffing) at maternally-intoxicating concentration has also produced
birth defects. Foetotoxicity appears at levels associated with CNS
narcosis and probably occurs only in those with chronic toluene-induced
kidney failure. Exposure at or below the recommended TLV-TWA is thought
to prevent transient headache and irritation, to provide a measure of
safety for possible disturbances to human reproduction, the prevention of
reductions in cognitive responses reported amongst humans inhaling
greater than 40 ppm, and the significant risks of hepatotoxic, behavioural
and nervous system effects (including impaired reaction time and
incoordination). Although toluene/ethanol interactions are well
recognised, the degree of protection afforded by the TLV-TWA among
drinkers is not known.
SILICA AMORPHOUS:
Not available
DIMETHYL ETHER:
The no-effect-level for dimethyl ether is somewhere between 2000 ppm
(rabbits) and 50,000 ppm (humans) with possible cardiac sensitisation
occurring around 200,000 ppm (dogs). The AIHA has adopted a safety factor
of 100 in respect to the 50,000 ppm level in its recommendation for a
workplace environmental exposure level (WEEL) which is thought to protect
against both narcotic and sensitising effects. This level is consistent
with the TLV-TWA of 400 ppm for diethyl ether and should be easily
achievable using current technologies. The use of the traditionally
allowable excursion of 1.25 to the level of 6.25 ppm is felt to be more
than adequate as an upper safe limit of exposure.
Human data:
50,000 ppm (12 mins): Feelings of mild intoxication.
75,000 ppm (12 mins): As above plus slight lack of attenuation.
82,000 ppm (12 mins): Some incoordination, slight blurring of vision
(30 mins): As above plus analgesia of the face and rushing of
blood to the face.
100,000 ppm (10-20 mins): Narcotic symptoms
(64 mins) : Sickness (assumed to be nausea)
144,000 ppm (36 mins): Unconsciousness
HYDROCARBON PROPELLANT:
Not available
PERSONAL PROTECTION
EYE
No special equipment for minor exposure i.e. when handling small quantities.
OTHERWISE: For potentially moderate or heavy exposures:
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DY-MARK TAILPAINT AEROSOL ALL COLOURS LEAD FREE
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Issue Date: 15-Nov-2006 CHEMWATCH 6596-33
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Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
- Safety glasses with side shields.
- NOTE: Contact lenses pose a special hazard; soft lenses may absorb irritants and ALL
lenses concentrate them.
HANDS/FEET
Neoprene rubber gloves.
No special equipment needed when handling small quantities.
OTHERWISE:
For potentially moderate exposures:
Wear general protective gloves, eg. light weight rubber gloves.
For potentially heavy exposures:
Wear chemical protective gloves, eg. PVC. and safety footwear.
OTHER
The clothing worn by process operators insulated from earth may develop static charges
far higher (up to 100 times) than the minimum ignition energies for various flammable gas
-air mixtures. This holds true for a wide range of clothing materials including cotton.
Avoid dangerous levels of charge by ensuring a low resistivity of the surface material
worn outermost.
BRETHERICK: Handbook of Reactive Chemical Hazards.
No special equipment needed when handling small quantities.
OTHERWISE:
- Overalls.
- Skin cleansing cream.
- Eyewash unit.
- Do not spray on hot surfaces.
RESPIRATOR
Selection of the Class and Type of respirator will depend upon the level of breathing
zone contaminant and the chemical nature of the contaminant. Protection Factors (defined
as the ratio of contaminant outside and inside the mask) may also be important.
Breathing Zone Level Maximum Protection Half- face Respirator Full- Face Respirator
ppm (volume) Factor
1000 10 AX- AUS -
1000 50 - AX- AUS
5000 50 Airline * -
5000 100 - AX- 2
10000 100 - AX- 3
100+ Airline**
* - Continuous Flow ** - Continuous-flow or positive pressure demand.
The local concentration of material, quantity and conditions of use determine the type of
personal protective equipment required.
For further information consult site specific
CHEMWATCH data (if available), or your
Occupational Health and Safety Advisor.
ENGINEERING CONTROLS
CARE: Use of a quantity of this material in confined space or poorly ventilated area,
where rapid build up of concentrated atmosphere may occur, could require increased
ventilation and/or protective gear.
General exhaust is adequate under normal conditions. If risk of overexposure exists, wear
SAA approved respirator. Correct fit is essential to obtain adequate protection.
Provide adequate ventilation in warehouse or closed storage areas.
Air contaminants generated in the workplace possess varying "escape" velocities which, in
turn, determine the "capture velocities" of fresh circulating air required to effectively
remove the contaminant.
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DY-MARK TAILPAINT AEROSOL ALL COLOURS LEAD FREE
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Issue Date: 15-Nov-2006 CHEMWATCH 6596-33
NC317TCP CD 2006/4 Page 12 of 21
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
Type of Contaminant: Speed:
aerosols, (released at low velocity into zone 0.5- 1 m/s
of active generation)
direct spray, spray painting in shallow 1- 2.5 m/s (200- 500 f/min.)
booths, gas discharge (active generation into
zone of rapid air motion)
Within each range the appropriate value depends on:
Lower end of the range Upper end of the range
1: Room air currents minimal or favourable to 1: Disturbing room air currents
capture
2: Contaminants of low toxicity or of nuisance 2: Contaminants of high toxicity
value only.
3: Intermittent, low production. 3: High production, heavy use
4: Large hood or large air mass in motion 4: Small hood- local control only
Simple theory shows that air velocity falls rapidly with distance away from the opening
of a simple extraction pipe. Velocity generally decreases with the square of distance
from the extraction point (in simple cases). Therefore the air speed at the extraction
point should be adjusted, accordingly, after reference to distance from the contaminating
source. The air velocity at the extraction fan, for example, should be a minimum of 1-2
m/s (200-400 f/min.) for extraction of solvents generated in a tank 2 meters distant from
the extraction point. Other mechanical considerations, producing performance deficits
within the extraction apparatus, make it essential that theoretical air velocities are
multiplied by factors of 10 or more when extraction systems are installed or used.
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
APPEARANCE
Supplied as an aerosol pack. Contents under PRESSURE. Contains highly flammable
hydrocarbon propellant. Coloured flammable liquid; does not mix with water.
PHYSICAL PROPERTIES
Gas.
Does not mix with water.
Molecular Weight: Not Applicable Boiling Range (掳 Not Av ailable
C):
Melting Range (掳 Not Available
C): Specific Gravity (water= 1): Not Available
Solubility in water (g/L): Immiscible pH (as supplied): Not Applicable
pH (1% solution): Not Applicable Vapour Pressure (kPa): Not Available
Volatile Component (%vol): Not Available Evaporation Rate: Not Available
Relative Vapour Density (air=1): Not Available Flash Point (掳 Not Available
C):
Lower Explosive Limit (%): Not Available Upper Explosive Limit (%): Not Available
Autoignition Temp (掳 Not Available
C): Decomposition Temp ( 掳 Not Available
C):
State: COMPRESSED GAS Viscosity: Not Available
Section 10 - CHEMICAL STABILITY AND REACTIVITY INFORMATION
CONDITIONS CONTRIBUTING TO INSTABILITY
- Elevated temperatures.
- Presence of open flame.
- Product is considered stable.
- Hazardous polymerisation will not occur.
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Section 11 - TOXICOLOGICAL INFORMATION
POTENTIAL HEALTH EFFECTS
ACUTE HEALTH EFFECTS
SWALLOWED
Not normally a hazard due to physical form of product.
Considered an unlikely route of entry in commercial/industrial environments.
Swallowing of the liquid may cause aspiration into the lungs with the risk of chemical
pneumonitis; serious consequences may result. (ICSC13733).
Central nervous system (CNS) depression may include general discomfort, symptoms of
giddiness, headache, dizziness, nausea, anaesthetic effects, slowed reaction time,
slurred speech and may progress to unconsciousness. Serious poisonings may result in
respiratory depression and may be fatal.
EYE
The liquid produces a high level of eye discomfort and is capable of causing pain and
severe conjunctivitis. Corneal injury may develop, with possible permanent impairment of
vision, if not promptly and adequately treated.
There is evidence that material may produce eye irritation in some persons and produce
eye damage 24 hours or more after instillation. Severe inflammation may be expected with
pain. There may be damage to the cornea. Unless treatment is prompt and adequate there
may be permanent loss of vision. Conjunctivitis can occur following repeated exposure.
Eye contact with alkyl ethers (vapour or liquid) may produce irritation,
redness and tears.
SKIN
Skin contact with the material may damage the health of the individual; systemic effects
may result following absorption.
The material may accentuate any pre-existing dermatitis condition.
Spray mist may produce discomfort.
Entry into the blood-stream, through, for example, cuts, abrasions or lesions, may
produce systemic injury with harmful effects. Examine the skin prior to the use of the
material and ensure that any external damage is suitably protected.
The material may cause moderate inflammation of the skin either following direct contact
or after a delay of some time. Repeated exposure can cause contact dermatitis which is
characterised by redness, swelling and blistering.
Alkyl ethers may defat and dehydrate the skin producing dermatoses. Absorption may
produce headache, dizziness, and central nervous system depression.
INHALED
There is some evidence to suggest that the material can cause respiratory irritation in
some persons. The body's response to such irritation can cause further lung damage.
Inhalation hazard is increased at higher temperatures.
Inhalation of toxic gases may cause:
- Central Nervous System effects including depression, headache, confusion, dizziness,
stupor, coma and seizures;
- respiratory: acute lung swellings, shortness of breath, wheezing, rapid breathing,
other symptoms and respiratory arrest;
- heart: collapse, irregular heartbeats and cardiac arrest;
- gastrointestinal: irritation, ulcers, nausea and vomiting (may be bloody), and
abdominal pain.
Inhalation of high concentrations of gas/vapour causes lung irritation with coughing and
nausea, central nervous depression with headache and dizziness, slowing of reflexes,
fatigue and inco-ordination.
Central nervous system (CNS) depression may include general discomfort, symptoms of
giddiness, headache, dizziness, nausea, anaesthetic effects, slowed reaction time,
slurred speech and may progress to unconsciousness. Serious poisonings may result in
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Section 11 - TOXICOLOGICAL INFORMATION
respiratory depression and may be fatal.
Material is highly volatile and may quickly form a concentrated atmosphere in confined or
unventilated areas. Vapour is heavier than air and may displace and replace air in
breathing zone, acting as a simple asphyxiant. This may happen with little warning of
overexposure.
If exposure to highly concentrated solvent atmosphere is prolonged this may lead to
narcosis, unconsciousness, even coma and possible death.
WARNING:Intentional misuse by concentrating/inhaling contents may be lethal.
Inhalation of vapours may cause drowsiness and dizziness. This may be accompanied by
sleepiness, reduced alertness, loss of reflexes, lack of co-ordination, and vertigo.
CHRONIC HEALTH EFFECTS
Principal route of occupational exposure to the gas is by inhalation.
Substance accumulation, in the human body, may occur and may cause some concern following
repeated or long-term occupational exposure.
There is some evidence that inhaling this product is more likely to cause a sensitisation
reaction in some persons compared to the general population.
Chronic solvent inhalation exposures may result in nervous system impairment and liver
and blood changes. [PATTYS].
TOXICITY AND IRRITATION
Not available. Refer to individual constituents.
unless otherwise specified data extracted from RTECS - Register of Toxic Effects of
Chemical Substances
HEPTANE:
TOXICITY IRRITATION
Inhalation (human) TCLo: 1000 ppm/6m Nil Reported
ISOBUTYLENE HOMOPOLYMER:
No significant acute toxicological data identified in literature search.
TOLUENE:
TOXICITY IRRITATION
Oral (human) LDLo: 50 mg/kg Skin (rabbit): 20 mg/24h- Moderate
Oral (rat) LD50: 636 mg/kg Skin (rabbit): 500 mg - Moderate
Inhalation (human) TCLo: 100 ppm Eye (rabbit): 0.87 mg - Mild
Inhalation (man) TCLo: 200 ppm Eye (rabbit): 2 mg/24h - SEVERE
Inhalation (rat) LC50: >26700 ppm/1h Eye (rabbit): 100 mg/30sec - Mild
Dermal (rabbit) LD50: 12124 mg/kg
The material may cause skin irritation after prolonged or repeated exposure and may
produce on contact skin redness, swelling, the production of vesicles, scaling and
thickening of the skin.
SILICA AMORPHOUS:
TOXICITY IRRITATION
Oral (rat) LD50: 3160 mg/kg Skin (rabbit): non- irritating *
Dermal (rabbit) LD50: >5000 mg/kg * Eye (rabbit): non- irritating *
Inhalation (rat) LC50: >0.139 mg/l/14h * * [Grace]
The substance is classified by IARC as Group 3:
NOT classifiable as to its carcinogenicity to humans.
Evidence of carcinogenicity may be inadequate or limited in animal testing.
Reports indicate high/prolonged exposures to amorphous silicas induced lung
fibrosis in experimental animals; in some experiments these effects were
reversible. [PATTYS]
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Section 11 - TOXICOLOGICAL INFORMATION
TALLOW ALKYLDIMETHYLAMMONIUM CHLORIDE/ BENTONITE:
No data of toxicological significance identified in literature search.
DIMETHYL ETHER:
TOXICITY IRRITATION
Inhalation (rat) LC50: 308000 mg/m鲁 Nil Reported
HYDROCARBON PROPELLANT:
Not available. Refer to individual constituents.
MATERIAL CARCINOGEN REPROTOXIN SENSITISER SKIN
________________________ ____________________ ________________ ________________ _____________
toluene IARC: ILOEl
silica amorphous IARC:
CARCINOGEN
IARC: International Agency for Research on Cancer (IARC) Carcinogens: toluene Category:
REPROTOXIN
ILOEl: ILO Chemicals in the electronics industry that have toxic effects on
reproduction: toluene
CARCINOGEN
IARC: International Agency for Research on Cancer (IARC) Carcinogens: silica amorphous
Category:
Section 12 - ECOLOGICAL INFORMATION
Marine Pollutant:Not Determined
The lower molecular weight hydrocarbons are expected to form a "slick" on the surface of
waters after release in calm sea conditions. This is expected to evaporate and enter the
atmosphere where it will be degraded through reaction with hydroxy radicals.
Some of the material will become associated with benthic sediments, and it is likely to
be spread over a fairly wide area of sea floor. Marine sediments may be either aerobic or
anaerobic. The material, in probability, is biodegradable, under aerobic conditions
(isomerised olefins and alkenes show variable results). Evidence also suggests that the
hydrocarbons may be degradable under anaerobic conditions although such degradation in
benthic sediments may be a relatively slow process.
Under aerobic conditions the material will degrade to water and carbon dioxide, while
under anaerobic processes it will produce water, methane and carbon dioxide.
Based on test results, as well as theoretical considerations, the potential for
bioaccumulation may be high. Toxic effects are often observed in species such as blue
mussel, daphnia, freshwater green algae, marine copepods and amphipods.
Drinking Water Standards:
hydrocarbon total: 10 ug/l (UK max.).
DO NOT discharge into sewer or waterways.
Do NOT allow product to come in contact with surface waters or to intertidal areas below
the mean high water mark. Do not contaminate water when cleaning equipment or disposing
of equipment wash-waters.
Wastes resulting from use of the product must be disposed of on site or at approved waste
sites.
Refer to data for ingredients, which follows:
HEPTANE:
Fish LC50 (96hr.) (mg/l): 4924
log Kow (Sangster 1997): 4.66
BOD5: 1.92
COD: 0.06
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Section 12 - ECOLOGICAL INFORMATION
The lower molecular weight hydrocarbons are expected to form a "slick" on the surface of
waters after release in calm sea conditions. This is expected to evaporate and enter the
atmosphere where it will be degraded through reaction with hydroxy radicals.
Some of the material will become associated with benthic sediments, and it is likely to
be spread over a fairly wide area of sea floor. Marine sediments may be either aerobic or
anaerobic. The material, in probability, is biodegradable, under aerobic conditions
(isomerised olefins and alkenes show variable results). Evidence also suggests that the
hydrocarbons may be degradable under anaerobic conditions although such degradation in
benthic sediments may be a relatively slow process.
Under aerobic conditions the material will degrade to water and carbon dioxide, while
under anaerobic processes it will produce water, methane and carbon dioxide.
Based on test results, as well as theoretical considerations, the potential for
bioaccumulation may be high. Toxic effects are often observed in species such as blue
mussel, daphnia, freshwater green algae, marine copepods and amphipods.
Drinking Water Standards:
hydrocarbon total: 10 ug/l (UK max.).
Do NOT allow product to come in contact with surface waters or to intertidal areas below
the mean high water mark. Do not contaminate water when cleaning equipment or disposing
of equipment wash-waters.
Wastes resulting from use of the product must be disposed of on site or at approved waste
sites.
DO NOT discharge into sewer or waterways.
log Kow: 4.66
Koc: 2400-8100
Half-life (hr) air: 52.8
Half-life (hr) H2O surface water: 2.9-312
Henry's atm m鲁 /mol: 2.06
BOD 5 if unstated: 1.92
COD: 0.06
BCF: 340-2000
Log BCF: 2.53-3.31
TOLUENE:
Hazardous Air Pollutant: Yes
Fish LC50 (96hr.) (mg/l): 7.3- 22.8
BCF<100: 13.2 (EELS
log Kow (Sangster 1997): 2.73
log Pow (Verschueren 1983): 2.69
BOD5: 5%
COD: 21%
ThOD: 3.13
Half- life Soil - High (hours): 528
Half- life Soil - Low (hours): 96
Half- life Air - High (hours): 104
Half- life Air - Low (hours): 10
Half- life Surface water - High (hours): 528
Half- life Surface water - Low (hours): 96
Half- life Ground water - High (hours): 672
Half- life Ground water - Low (hours): 168
Aqueous biodegradation - Aerobic - High (hours): 528
Aqueous biodegradation - Aerobic - Low (hours): 96
Aqueous biodegradation - Anaerobic - High (hours): 5040
Aqueous biodegradation - Anaerobic - Low (hours): 1344
Aqueous biodegradation - Removal secondary treatment - High (hours): 75%
Photolysis maximum light absorption - High (nano- m): 268
Photolysis maximum light absorption - Low (nano- m): 253.5
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Section 12 - ECOLOGICAL INFORMATION
Photooxidation half- life water - High (hours): 1284
Photooxidation half- life water - Low (hours): 321
Photooxidation half- life air - High (hours): 104
Photooxidation half- life air - Low (hours): 10
The lower molecular weight hydrocarbons are expected to form a "slick" on the surface of
waters after release in calm sea conditions. This is expected to evaporate and enter the
atmosphere where it will be degraded through reaction with hydroxy radicals.
Some of the material will become associated with benthic sediments, and it is likely to
be spread over a fairly wide area of sea floor. Marine sediments may be either aerobic or
anaerobic. The material, in probability, is biodegradable, under aerobic conditions
(isomerised olefins and alkenes show variable results). Evidence also suggests that the
hydrocarbons may be degradable under anaerobic conditions although such degradation in
benthic sediments may be a relatively slow process.
Under aerobic conditions the material will degrade to water and carbon dioxide, while
under anaerobic processes it will produce water, methane and carbon dioxide.
Based on test results, as well as theoretical considerations, the potential for
bioaccumulation may be high. Toxic effects are often observed in species such as blue
mussel, daphnia, freshwater green algae, marine copepods and amphipods.
DO NOT discharge into sewer or waterways.
log Kow: 2.1-3
log Koc: 1.12-2.85
Koc: 37-250
log Kom: 1.39-2.89
Half-life (hr) air: 2.4-104
Half-life (hr) H2O surface water: 5.55-528
Half-life (hr) H2O ground: 168-2628
Half-life (hr) soil: <48-240
Henry's Pa m鲁 /mol: 518-694
Henry's atm m鲁 /mol: 5.94E-03
BOD 5 if unstated: 0.86-2.12,5%
COD: 0.7-2.52,21-27%
ThOD: 3.13
BCF: 1.67-380
Log BCF: 0.22-3.28
SILICA AMORPHOUS:
Aquatic toxicity (Daphnia magna) 24h EC50: >1000 mg/l
Fish toxicity (Brachydanio rerio) 96h LC50: >10,000 mg/l [Grace]
DIMETHYL ETHER:
Water solubility (mg/l): 35300
log Kow (Sangster 1997): 0.1
log Kow: 0.1-0.12
Koc: 14
Half-life (hr) air: 528
Half-life (hr) H2O surface water: 2.6-30
Henry's atm m鲁 /mol: 9.78E-04
BCF: 1.7
Bioaccumulation: not sig
processes Abiotic: RxnOH*
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Section 13 - DISPOSAL CONSIDERATIONS
- Consult State Land Waste Management Authority for disposal.
- Discharge contents of damaged aerosol cans at an approved site.
- Allow small quantities to evaporate.
- DO NOT incinerate or puncture aerosol cans.
- Bury residues and emptied aerosol cans at an approved site.
Section 14 - TRANSPORTATION INFORMATION
Labels Required: FLAMMABLE GAS
HAZCHEM: 2Y
UNDG:
Dangerous Goods 2.1 Subrisk: None
Class:
UN Number: 1950 Packing Group: None
Shipping Name:AEROSOLS
Air Transport IATA:
ICAO/IATA Class: 2.1 ICAO/IATA Subrisk: None
UN/ID Number: 1950 Packing Group: None
ERG Code: 10L
Shipping Name: Aerosols, flammable
Maritime Transport IMDG:
IMDG Class: 2 IMDG Subrisk: SP63
UN Number: 1950 Packing Group: None
EMS Number: F- D, S- U Marine Pollutant: Not Determined
Shipping Name: AEROSOLS
Section 15 - REGULATORY INFORMATION
POISONS SCHEDULE: None
REGULATIONS
heptane (CAS: 142-82-5) is found on the following regulatory lists;
Australia Exposure Standards
Australia High Volume Industrial Chemical List (HVICL)
Australia Inventory of Chemical Substances (AICS)
Australia Poisons Schedule
IMO MARPOL 73/78 (Annex II) - List of Other Liquid Substances
International Council of Chemical Associations (ICCA) - High Production Volume List
OECD Representative List of High Production Volume (HPV) Chemicals
isobutylene homopolymer (CAS: 9003-27-4) is found on the following regulatory lists;
Australia Inventory of Chemical Substances (AICS)
OECD Representative List of High Production Volume (HPV) Chemicals
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Section 15 - REGULATORY INFORMATION
isobutylene homopolymer (CAS: 9003-29-6) is found on the following regulatory lists;
Australia Inventory of Chemical Substances (AICS)
IMO MARPOL 73/78 (Annex II) - List of Other Liquid Substances
OECD Representative List of High Production Volume (HPV) Chemicals
toluene (CAS: 108-88-3) is found on the following regulatory lists;
Australia - Australia New Zealand Food Standards Code - Processing Aids - Permitted
extraction solvents
Australia - Australian Capital Territory Environment Protection Regulation Ecosyste
maintenance - Organic chemicals - Non-pesticide anthropogenic organics
Australia - Australian Capital Territory Environment Protection Regulation
Pollutants entering waterways - Domestic water quality
Australia - Australian Capital Territory Environment Protection Regulation
Pollutants entering waterways - Ecosystem maintenance
Australia Exposure Standards
Australia High Volume Industrial Chemical List (HVICL)
Australia Illicit Drug Reagents/Essential Chemicals - Category III
Australia Inventory of Chemical Substances (AICS)
Australia National Pollutant Inventory
Australia Poisons Schedule
IMO MARPOL 73/78 (Annex II) - List of Noxious Liquid Substances Carried in Bulk
International Agency for Research on Cancer (IARC) Carcinogens
OECD Representative List of High Production Volume (HPV) Chemicals
United Nations List of Precursors and Chemicals Frequently used in the Illicit
Manufacture of Narcotic Drugs and Psychotropic Substances Under International Control -
Table II (English)
WHO Guidelines for Drinking-water Quality - Guideline values for chemicals that are
of health significance in drinking-water
silica amorphous (CAS: 7631-86-9) is found on the following regulatory lists;
Australia - Australia New Zealand Food Standards Code - Food Additives - Schedule 1
Permitted uses of food additives by food type
Australia Exposure Standards
Australia High Volume Industrial Chemical List (HVICL)
Australia Inventory of Chemical Substances (AICS)
CODEX General Standard for Food Additives (GSFA) - Additives Permitted for Use in
Food in General, Unless Otherwise Specified, in Accordance with GMP
International Agency for Research on Cancer (IARC) Carcinogens
International Council of Chemical Associations (ICCA) - High Production Volume List
OECD Representative List of High Production Volume (HPV) Chemicals
silica amorphous (CAS: 112945-52-5) is found on the following regulatory lists;
Australia High Volume Industrial Chemical List (HVICL)
Australia Inventory of Chemical Substances (AICS)
International Council of Chemical Associations (ICCA) - High Production Volume List
OECD Representative List of High Production Volume (HPV) Chemicals
tallow alkyldimethylammonium chloride/ bentonite (CAS: 68953-58-2) is found on the
following regulatory lists;
Australia - Australian Capital Territory Environment Protection Regulation Domestic
water quality standards - Inorganic chemicals
Australia - Australian Capital Territory Environment Protection Regulation
Pollutants entering waterways - Agricultural uses (Irrig)
Australia - Australian Capital Territory Environment Protection Regulation
Pollutants entering waterways - Agricultural uses (Stock)
Australia - Australian Capital Territory Environment Protection Regulation
Pollutants entering waterways - Domestic water quality
Australia Exposure Standards
Australia Inventory of Chemical Substances (AICS)
International Council of Chemical Associations (ICCA) - High Production Volume List
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Section 15 - REGULATORY INFORMATION
OECD Representative List of High Production Volume (HPV) Chemicals
WHO Guidelines for Drinking-water Quality - Chemicals for which guideline values have
not been established
tallow alkyldimethylammonium chloride/ bentonite (CAS: 1340-69-8) is found on the
following regulatory lists;
Australia - Australian Capital Territory Environment Protection Regulation Domestic
water quality standards - Inorganic chemicals
Australia - Australian Capital Territory Environment Protection Regulation
Pollutants entering waterways - Agricultural uses (Irrig)
Australia - Australian Capital Territory Environment Protection Regulation
Pollutants entering waterways - Agricultural uses (Stock)
Australia - Australian Capital Territory Environment Protection Regulation
Pollutants entering waterways - Domestic water quality
Australia Exposure Standards
Australia Inventory of Chemical Substances (AICS)
WHO Guidelines for Drinking-water Quality - Chemicals for which guideline values have
not been established
dimethyl ether (CAS: 115-10-6) is found on the following regulatory lists;
Australia Exposure Standards
Australia Inventory of Chemical Substances (AICS)
International Council of Chemical Associations (ICCA) - High Production Volume List
OECD Representative List of High Production Volume (HPV) Chemicals
hydrocarbon propellant (CAS: 68476-85-7) is found on the following regulatory lists;
Australia Exposure Standards
Australia High Volume Industrial Chemical List (HVICL)
Australia Inventory of Chemical Substances (AICS)
OECD Representative List of High Production Volume (HPV) Chemicals
hydrocarbon propellant (CAS: 68476-86-8) is found on the following regulatory lists;
Australia Inventory of Chemical Substances (AICS)
OECD Representative List of High Production Volume (HPV) Chemicals
Section 16 - OTHER INFORMATION
INGREDIENTS WITH MULTIPLE CAS NUMBERS
Ingredient Name CAS
isobutylene 9003- 27- 4, 9003- 29- 6
homopolymer
silica amorphous 7631- 86- 9, 112945- 52- 5
tallow 68953- 58- 2, 1340- 69- 8
alkyldimethylammoniu
m chloride/
bentonite
hydrocarbon 68476- 85- 7, 68476- 86- 8
propellant
REPRODUCTIVE HEALTH GUIDELINES
Established occupational exposure limits frequently do not take into consideration
reproductive end points that are clearly below the thresholds for other toxic effects.
Occupational reproductive guidelines (ORGs) have been suggested as an additional
standard. These have been established after a literature search for reproductive no
-observed-adverse effect-level (NOAEL) and the lowest-observed-adverse-effect-level
(LOAEL). In addition the US EPA's procedures for risk assessment for hazard
identification and dose-response assessment as applied by NIOSH were used in the creation
of such limits. Uncertainty factors (UFs) have also been incorporated.
Ingredient ORG UF Endpoint CR Adeq TLV
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Section 16 - OTHER INFORMATION
toluene 9.6 mg/m3 10 D NA -
These exposure guidelines have been derived from a screening level of risk assessment and
should not be construed as unequivocally safe limits. ORGS represent an 8-hour time
-weighted average unless specified otherwise.
CR = Cancer Risk/10000; UF = Uncertainty factor:
TLV believed to be adequate to protect reproductive health:
LOD: Limit of detection
Toxic endpoints have also been identified as:
D = Developmental; R = Reproductive; TC = Transplacental carcinogen
Jankovic J., Drake F.: A Screening Method for Occupational Reproductive
American Industrial Hygiene Association Journal 57: 641-649 (1996).
This document is copyright. Apart from any fair dealing for the purposes of private study, research, review or
criticism, as permitted under the Copyright Act, no part may be reproduced by any process without written permission
from CHEMWATCH. TEL (+61 3) 9572 4700.
Issue Date: 15-Nov-2006
Print Date: 15-Nov-2006
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