THIONYL CHLORIDE http://www.jtbaker.com/msds/englishhtml/t2938.htm
MSDS Number: T2938 * * * * * Effective Date: 08/10/04 * * * * * Supercedes: 11/02/01
THIONYL CHLORIDE
1. Product Identification
Synonyms: Sulfinyl chloride; Sulfurous oxychloride; Thionyl dichloride; Sulfur chloride oxide
CAS No.: 7719-09-7
Molecular Weight: 118.98
Chemical Formula: SOCl2
Product Codes:
J.T. Baker: 8660
Mallinckrodt: 8522, 8523
2. Composition/Information on Ingredients
Ingredient CAS No Percent Hazardous
--------------------------------------- ------------ ------------ ---------
Thionyl Chloride 7719-09-7 90 - 100% Yes
3. Hazards Identification
Emergency Overview
--------------------------
DANGER! CORROSIVE. CAUSES BURNS TO ANY AREA OF CONTACT. MAY BE FATAL IF
INHALED. HARMFUL IF SWALLOWED. VAPORS CAUSE SEVERE IRRITATION TO SKIN, EYES
AND RESPIRATORY TRACT. WATER REACTIVE.
J.T. Baker SAF-T-DATA(tm) Ratings (Provided here for your convenience)
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Health Rating: 3 - Severe (Poison)
Flammability Rating: 0 - None
Reactivity Rating: 3 - Severe (Water Reactive)
Contact Rating: 4 - Extreme (Corrosive)
Lab Protective Equip: GOGGLES & SHIELD; LAB COAT & APRON; VENT HOOD; PROPER GLOVES
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Storage Color Code: White (Corrosive)
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Potential Health Effects
----------------------------------
Inhalation:
Corrosive. Extremely destructive to tissues of the mucous membranes and upper respiratory tract. Symptoms
may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea and
vomiting. Inhalation may be fatal as a result of spasm inflammation and edema of the larynx and bronchi,
chemical pneumonitis and pulmonary edema.
Ingestion:
Corrosive. May cause burning pain in throat, abdominal pain, nausea, and vomiting.
Skin Contact:
Corrosive. Liquid contact may cause blistering burns, irritation, and pain. Vapors may be severely irritating to
the skin.
Eye Contact:
Corrosive! Vapors are irritating and may cause damage to the eyes. Contact may cause severe burns and
permanent eye damage.
Chronic Exposure:
Prolonged or repeated exposure may cause conjunctivitis, dermatitis, rhinitis, and pneumonitis.
Aggravation of Pre-existing Conditions:
Persons with pre-existing skin disorders or impaired respiratory function may be more susceptible to the effects
of the substance.
4. First Aid Measures
Inhalation:
Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical
attention immediately.
Ingestion:
If swallowed, DO NOT INDUCE VOMITING. Give large quantities of water. Never give anything by mouth to
an unconscious person. Get medical attention immediately.
Skin Contact:
Wipe off excess material from skin then immediately flush skin with plenty of water for at least 15 minutes while
removing contaminated clothing and shoes. Get medical attention immediately. Wash clothing before reuse.
Thoroughly clean shoes before reuse.
Eye Contact:
Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally.
Get medical attention immediately.
5. Fire Fighting Measures
Fire:
Not considered to be a fire hazard. May react violently with water or moist air.
Can liberate flammable hydrogen gas when in contact with metal and moisture.
Explosion:
Sealed containers may rupture when heated.
Fire Extinguishing Media:
Carbon dioxide or dry chemical. Do not use water or foam.
Special Information:
In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with
full facepiece operated in the pressure demand or other positive pressure mode. Water spray may be used to keep
fire exposed containers cool. Keep water from getting inside containers. Structural firefighter's protective
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clothing is ineffective for fires involving this material. Stay away from sealed containers.
6. Accidental Release Measures
Do not contact with water. Ventilate area of leak or spill. Wear appropriate personal protective equipment as
specified in Section 8. Isolate hazard area. Keep unnecessary and unprotected personnel from entering. Contain
and recover liquid when possible. Neutralize with alkaline material (soda ash, lime), then absorb with an inert
material (e. g., vermiculite, dry sand, earth), and place in a chemical waste container. Do not use combustible
materials, such as saw dust. Do not flush to sewer!
7. Handling and Storage
Keep in a tightly closed container, stored in a cool, dry, ventilated area. Protect against physical damage. Isolate
from incompatible substances. Use air-drying vent tube or inert gas for partial withdrawals from containers or
drums. Keep away from water. Containers of this material may be hazardous when empty since they retain
product residues (vapors, liquid); observe all warnings and precautions listed for the product.
8. Exposure Controls/Personal Protection
Airborne Exposure Limits:
-ACGIH Threshold Limit Value (TLV):
1 ppm Ceiling
Ventilation System:
A system of local and/or general exhaust is recommended to keep employee exposures below the Airborne
Exposure Limits. Local exhaust ventilation is generally preferred because it can control the emissions of the
contaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH
document, Industrial Ventilation, A Manual of Recommended Practices, most recent edition, for details.
Personal Respirators (NIOSH Approved):
If the exposure limit is exceeded and engineering controls are not feasible, wear a supplied air, full-facepiece
respirator, airlined hood, or full-facepiece self-contained breathing apparatus. Breathing air quality must meet the
requirements of the OSHA respiratory protection standard (29CFR1910.134).
Skin Protection:
Rubber or neoprene gloves and additional protection including impervious boots, apron, or coveralls, as needed
in areas of unusual exposure.
Eye Protection:
Use chemical safety goggles and/or a full face shield where splashing is possible. Maintain eye wash fountain
and quick-drench facilities in work area.
9. Physical and Chemical Properties
Appearance:
Clear, pale yellow to red liquid.
Odor:
Characteristic, pungent odor.
Solubility:
Decomposes in water.
Specific Gravity:
1.64 @ 20C/4C
pH:
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No information found.
% Volatiles by volume @ 21C (70F):
100
Boiling Point:
76C (169F) @ 760 mmHg; Decomposes @ 140C (284F)
Melting Point:
-105C (-157F)
Vapor Density (Air=1):
4.1
Vapor Pressure (mm Hg):
100 @ 21C (70F)
Evaporation Rate (BuAc=1):
No information found.
10. Stability and Reactivity
Stability:
Stable at room temperature in sealed containers. Fumes on exposure to moist air. Hydrolyzes in presence of
moisture to sulfur dioxide and hydrogen chloride gas.
Hazardous Decomposition Products:
Decomposes when heated above 140C (284F) forming chlorine, sulfur dioxide, and sulfur monochloride and
giving a suffocating odor.
Hazardous Polymerization:
Will not occur.
Incompatibilities:
Water, ammonia, chloryl perchlorate, dimethyl sulfoxide, linseed oil, quinoline, sodium, 2,4-hexadiyn-1-6-diol,
o-nitrobenzoyl acetic acid, and o-nitrophenylacetic acid.
Conditions to Avoid:
Heat, moisture, incompatibles.
11. Toxicological Information
Inhalation rat LC50: 500 ppm/1-hour.
--------\Cancer Lists\------------------------------------------------------
---NTP Carcinogen---
Ingredient Known Anticipated IARC Category
------------------------------------ ----- ----------- -------------
Thionyl Chloride (7719-09-7) No No None
12. Ecological Information
Environmental Fate:
When released to moist soil or water, this material is expected to hydrolyze.
Environmental Toxicity:
No information found.
13. Disposal Considerations
Whatever cannot be saved for recovery or recycling should be handled as hazardous waste and sent to a RCRA
approved waste facility. Processing, use or contamination of this product may change the waste management
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options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container
and unused contents in accordance with federal, state and local requirements.
14. Transport Information
Domestic (Land, D.O.T.)
-----------------------
Proper Shipping Name: THIONYL CHLORIDE
Hazard Class: 8
UN/NA: UN1836
Packing Group: I
Information reported for product/size: 500G
International (Water, I.M.O.)
-----------------------------
Proper Shipping Name: THIONYL CHLORIDE
Hazard Class: 8
UN/NA: UN1836
Packing Group: I
Information reported for product/size: 500G
15. Regulatory Information
--------\Chemical Inventory Status - Part 1\---------------------------------
Ingredient TSCA EC Japan Australia
----------------------------------------------- ---- --- ----- ---------
Thionyl Chloride (7719-09-7) Yes Yes Yes Yes
--------\Chemical Inventory Status - Part 2\---------------------------------
--Canada--
Ingredient Korea DSL NDSL Phil.
----------------------------------------------- ----- --- ---- -----
Thionyl Chloride (7719-09-7) Yes Yes No Yes
--------\Federal, State & International Regulations - Part 1\----------------
-SARA 302- ------SARA 313------
Ingredient RQ TPQ List Chemical Catg.
----------------------------------------- --- ----- ---- --------------
Thionyl Chloride (7719-09-7) No No No No
--------\Federal, State & International Regulations - Part 2\----------------
-RCRA- -TSCA-
Ingredient CERCLA 261.33 8(d)
----------------------------------------- ------ ------ ------
Thionyl Chloride (7719-09-7) No No No
Chemical Weapons Convention: Yes TSCA 12(b): No CDTA: No
SARA 311/312: Acute: Yes Chronic: Yes Fire: No Pressure: No
Reactivity: Yes (Pure / Liquid)
Australian Hazchem Code: 4WE
Poison Schedule: None allocated.
WHMIS:
This MSDS has been prepared according to the hazard criteria of the Controlled Products Regulations (CPR)
and the MSDS contains all of the information required by the CPR.
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16. Other Information
NFPA Ratings: Health: 4 Flammability: 0 Reactivity: 2 Other: Water reactive
Label Hazard Warning:
DANGER! CORROSIVE. CAUSES BURNS TO ANY AREA OF CONTACT. MAY BE FATAL IF
INHALED. HARMFUL IF SWALLOWED. VAPORS CAUSE SEVERE IRRITATION TO SKIN, EYES
AND RESPIRATORY TRACT. WATER REACTIVE.
Label Precautions:
Do not get in eyes, on skin, or on clothing.
Wash thoroughly after handling.
Do not breathe vapor or mist.
Keep container closed.
Use only with adequate ventilation.
Do not contact with water.
Label First Aid:
If swallowed, DO NOT INDUCE VOMITING. Give large quantities of water. Never give anything by mouth to
an unconscious person. If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is
difficult, give oxygen. In case of contact, wipe off excess material from skin then immediately flush eyes or skin
with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing
before reuse. In all cases get medical attention immediately.
Product Use:
Laboratory Reagent.
Revision Information:
No Changes.
Disclaimer:
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Mallinckrodt Baker, Inc. provides the information contained herein in good faith but makes no
representation as to its comprehensiveness or accuracy. This document is intended only as a guide to the
appropriate precautionary handling of the material by a properly trained person using this product.
Individuals receiving the information must exercise their independent judgment in determining its
appropriateness for a particular purpose. MALLINCKRODT BAKER, INC. MAKES NO
REPRESENTATIONS OR WARRANTIES, EITHER EXPRESS OR IMPLIED, INCLUDING
WITHOUT LIMITATION ANY WARRANTIES OF MERCHANTABILITY, FITNESS FOR A
PARTICULAR PURPOSE WITH RESPECT TO THE INFORMATION SET FORTH HEREIN OR
THE PRODUCT TO WHICH THE INFORMATION REFERS. ACCORDINGLY, MALLINCKRODT
BAKER, INC. WILL NOT BE RESPONSIBLE FOR DAMAGES RESULTING FROM USE OF OR
RELIANCE UPON THIS INFORMATION.
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Prepared by: Environmental Health & Safety
Phone Number: (314) 654-1600 (U.S.A.)
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