SIGMA-ALDRICH
Material Safety Data Sheet
Date Printed: 09/AUG/2005
Date Updated: 14/MAR/2004
Version 1.1
According to 91/155/EEC
Classified as Hazardous according to the criteria of EU Annex 1 and
NOHSC.
1 - Product and Company Information
Product Name HEXAFLUOROPROPENE, 99+%
Product Number 295388
Company Sigma-Aldrich Pty. Ltd.
12 Anella Avenue
Castle Hill NSW 2154
Technical Phone # +61 2 9841 0555 (1800 800 097)
Fax +61 2 9841 0500 (1800 800 096)
Emergency Phone # +44 8701906777 (1800 448 465)
2 - Composition/Information on Ingredients
Product Name CAS # EC no Annex I
Index Number
HEXAFLUOROPROPENE 116-15-4 204-127-4 602-061-00-4
Formula C3F6
Molecular Weight 150.02 AMU
Synonyms Hexafluoropropene * Perfluoropropene *
Perfluoropropylene * Propylene, hexafluoro-
3 - Hazards Identification
SPECIAL INDICATION OF HAZARDS TO HUMANS AND THE ENVIRONMENT
Harmful by inhalation. Irritating to respiratory system.
4 - First Aid Measures
AFTER INHALATION
If inhaled, remove to fresh air. If not breathing give
artificial respiration. If breathing is difficult, give oxygen.
AFTER SKIN CONTACT
In case of contact, immediately wash skin with soap and copious
amounts of water.
AFTER EYE CONTACT
In case of contact, immediately flush eyes with copious amounts
of water for at least 15 minutes.
5 - Fire Fighting Measures
EXTINGUISHING MEDIA
Suitable: Use water spray or fog nozzle to keep cylinder cool.
Move cylinder away from fire if there is no risk.
SPECIAL RISKS
Specific Hazard(s): Emits toxic fumes under fire conditions.
Explosion Hazards: Container explosion may occur under fire
conditions.
SPECIAL PROTECTIVE EQUIPMENT FOR FIREFIGHTERS
Wear self-contained breathing apparatus and protective clothing
to prevent contact with skin and eyes.
6 - Accidental Release Measures
PERSONAL PRECAUTION PROCEDURES TO BE FOLLOWED IN CASE OF LEAK OR SPILL
Evacuate area and keep personnel upwind. Shut off leak if there
is no risk.
PROCEDURE(S) OF PERSONAL PRECAUTION(S)
Wear self-contained breathing apparatus, rubber boots, and heavy
rubber gloves.
7 - Handling and Storage
HANDLING
Directions for Safe Handling: Do not breathe gas. Do not get in
eyes, on skin, on clothing. Avoid prolonged or repeated exposure.
STORAGE
Conditions of Storage: Keep tightly closed. Store away from
heat. Store in a cool dry place. Cylinder temperature should not
exceed 125藲F (52藲C).
SPECIAL REQUIREMENTS: Contents under pressure.
8 - Exposure Controls / Personal Protection
ENGINEERING CONTROLS
Safety shower and eye bath.
GENERAL HYGIENE MEASURES
Wash thoroughly after handling.
PERSONAL PROTECTIVE EQUIPMENT
Eye Protection: Chemical safety goggles.
9 - Physical and Chemical Properties
Appearance Color: Colorless
Property Value At Temperature or Pressure
pH N/A
BP/BP Range -28 藲C 760 mmHg
MP/MP Range -153 藲C
Flash Point N/A
Flammability N/A
Autoignition Temp N/A
Oxidizing Properties N/A
Explosive Properties N/A
Explosion Limits N/A
Vapor Pressure N/A
SG/Density N/A
Partition Coefficient N/A
Viscosity N/A
Vapor Density 5.18 g/l
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Saturated Vapor Conc. N/A
Evaporation Rate N/A
Bulk Density N/A
Decomposition Temp. N/A
Solvent Content N/A
Water Content N/A
Surface Tension N/A
Conductivity N/A
Miscellaneous Data N/A
Solubility N/A
10 - Stability and Reactivity
STABILITY
Materials to Avoid: Strong oxidizing agents, Alkali metals, Finely
powdered metals.
HAZARDOUS DECOMPOSITION PRODUCTS
Hazardous Decomposition Products: Carbon monoxide, Carbon dioxide,
Hydrogen fluoride, Carbonyl fluoride.
11 - Toxicological Information
RTECS NUMBER: UD0350000
ACUTE TOXICITY
LC50 LC50
Inhalation Inhalation
Rat Rat
11,200 mg/m3 11,200 mg/m3
4H 4H
Remarks: Behavioral:Muscle contraction or spasticity.
Behavioral:Muscle contraction or spasticity.
LC50 LC50
Inhalation Inhalation
Mouse Mouse
750 ppm 750 ppm
4H 4H
ROUTE OF EXPOSURE
Skin Contact: Can cause severe frostbite.
Inhalation: Harmful if inhaled. Can cause rapid suffocation.
12 - Ecological Information
No data available.
13 - Disposal Considerations
SUBSTANCE DISPOSAL
Observe all federal, state, and local environmental regulations.
CONTAMINATED CONTAINER DISPOSAL
Caution: no-return cylinder. Do not reuse. Empty cylinder will
contain hazardous residue. Follow proper disposal techniques.
14 - Transport Information
RID/ADR
UN#: 1858
Class: 2
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Proper Shipping Name: Hexafluoropropylene (Refrigerant
gas R1216)
IMDG
UN#: 1858
Class: 2.2
Proper Shipping Name: HEXAFLUOROPROPYLENE
Marine Pollutant: No
Severe Marine Pollutant: No
IATA
UN#: 1858
Class: 2.2
Proper Shipping Name: HEXAFLUOROPROPYLENE
Inhalation Packing Group I: No
15 - Regulatory Information
CLASSIFICATION AND LABELING ACCORDING TO EU DIRECTIVES
ANNEX I INDEX NUMBER: 602-061-00-4
INDICATION OF DANGER: Xn
Harmful.
R-PHRASES: 20 37
Harmful by inhalation. Irritating to respiratory system.
S-PHRASES: 41
In case of fire and/or explosion do not breathe fumes.
SWITZERLAND
SWISS POISON CLASS: 5
16 - Other Information
WARRANTY
The above information is believed to be correct but does not
purport to be all inclusive and shall be used only as a guide. The
information in this document is based on the present state of our
knowledge and is applicable to the product with regard to
appropriate safety precautions. It does not represent any
guarantee of the properties of the product. Sigma-Aldrich Inc.,
shall not be held liable for any damage resulting from handling or
from contact with the above product. See reverse side of invoice
or packing slip for additional terms and conditions of sale.
Copyright 2005 Sigma-Aldrich Co. License granted to make unlimited
paper copies for internal use only.
DISCLAIMER
For R&D use only. Not for drug, household or other uses.
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