HILL MANUFACTURING -- NO 5023 SAFETY SOLVENT AERO

MATERIAL SAFETY DATA SHEET

NSN: 685000N020168

Manufacturer's CAGE: 66086

Part No. Indicator: A

Part Number/Trade Name: NO 5023 SAFETY SOLVENT AERO

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                     General Information

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Company's Name: HILL MANUFACTURING CO INC

Company's Street: 1500 JONESBORO RD

Company's City: ATLANTA

Company's State: GA

Company's Country: US

Company's Zip Code: 30315

Company's Emerg Ph #: 404-522-8364

Company's Info Ph #: 404-522-8364

Record No. For Safety Entry: 001

Tot Safety Entries This Stk#: 001

Status: SMJ

Date MSDS Prepared: 29JAN90

Safety Data Review Date: 26JUL95

MSDS Preparer's Name: RICK GLISSON

Preparer's Company: SAME

MSDS Serial Number: BLLJH

Hazard Characteristic Code: T4

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                Ingredients/Identity Information

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Proprietary: NO

Ingredient: METHYL CHLOROFORM (1,1,1-TRICHLOROEHANE) (SARA III)

Ingredient Sequence Number: 01

Percent: 95

NIOSH (RTECS) Number: KJ2975000

CAS Number: 71-55-6

OSHA PEL: 350 PPM/450 STEL

ACGIH TLV: 350 PPM/450STEL;9192

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Proprietary: NO

Ingredient: CARBON DIOXIDE

Ingredient Sequence Number: 02

Percent: 4-5

NIOSH (RTECS) Number: FF6400000

CAS Number: 124-38-9

OSHA PEL: 5000 PPM

ACGIH TLV: 5000PPM/30000STEL;93

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Proprietary: NO

Ingredient: SUPP DATA: ABSORBENT MATERIAL & SHOVELED INTO CONTAINERS.

Ingredient Sequence Number: 03

NIOSH (RTECS) Number: 9999999ZZ

OSHA PEL: NOT APPLICABLE

ACGIH TLV: NOT APPLICABLE

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Proprietary: NO

Ingredient: RESP PROT: ADMINISTRATIVE CONTROLS SHOULD BE IMPLEMENTED TO

REDUCE EXPOSURE.

Ingredient Sequence Number: 04

NIOSH (RTECS) Number: 9999999ZZ

OSHA PEL: NOT APPLICABLE

ACGIH TLV: NOT APPLICABLE

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              Physical/Chemical Characteristics

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Appearance And Odor: CLEAR COLORLESS THIN LIQUID WITH CHLORINATED SOLVENT

ODOR.

Boiling Point: 165F,74C

Vapor Pressure (MM Hg/70 F): 100 @ 68F

Vapor Density (Air=1): 4.5

Specific Gravity: 1.293-1.303

Evaporation Rate And Ref: SLOWER THAN ETHER

Solubility In Water: NIL

Percent Volatiles By Volume: 100

pH: N/A

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              Fire and Explosion Hazard Data

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Flash Point: NOT APPLICABLE

Lower Explosive Limit: 6%

Extinguishing Media: WATER FOG.

Special Fire Fighting Proc: WATER MAY BE USED TO KEEP FIRE-EXPOSED CONTRS

COOL UNTIL FIRE IS OUT. WEAR NIOSH/MSHA APPROVED PRESSURE DEMAND SCBA &

FULL PROTECTIVE EQUIPMENT (FP N).

Unusual Fire And Expl Hazrds: TEMPERATURES OVER 120F. MAY CAUSE CAN TO

BURST. THERMAL DECOMPOSITION PRODUCTS MAY INCLUDE HCL & PHOSGENE (FP N).

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                   Reactivity Data

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Stability: YES

Cond To Avoid (Stability): TEMPERATURES OVER 120F. MAY CAUSE CAN TO BURST.

Materials To Avoid: WATER, REACTIVE METALS SUCH AS ALUMINUM & MAGNESIUM,

OPEN FLAME, WELDING ARCS, RESISTANCE HEATERS, ETC., (SUPP DATA)

Hazardous Decomp Products: CO2 & CO, HYDROGEN CHLORIDE, PHOSGENE, VARIOUS

HYDROCARBONS, ETC.

Hazardous Poly Occur: NO

Conditions To Avoid (Poly): NOT RELEVANT

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                  Health Hazard Data

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LD50-LC50 Mixture: NONE SPECIFIED BY MANUFACTURER.

Route Of Entry - Inhalation: YES

Route Of Entry - Skin: NO

Route Of Entry - Ingestion: NO

Health Haz Acute And Chronic: EYES: CAN CAUSE SEVERE IRRIT, REDNESS,

TEARING, BLURRED VISION. SKIN: PRLNG/RPTD CONT CAN CAUSE MODERATE IRRIT,

DEFAT, DERMAT. INHAL: EXCESSIVE INHAL OF VAPS CAN CAUSE NASAL & RESPIRATORY

IRRIT, DIZZ, WEAK, FATG, NAUS, HDACH, POSS UNCON & EVEN ASPHY. INGEST: CAN

CAUSE GI IRRIT, NAUS, VOMIT & DIARR. (EFTS OF OVEREXP)

Carcinogenicity - NTP: NO

Carcinogenicity - IARC: NO

Carcinogenicity - OSHA: NO

Explanation Carcinogenicity: NOT RELEVANT

Signs/Symptoms Of Overexp: CHLOROCARBON MATLS HAVE PRDCED SENSITIZATION OF

THE MYOCARDIUM TO EPINEPHRINE IN LAB ANIMALS & MAY HAVE A SIMILAR EFFECT IN

HUMANS. ADRENOMIMETICS (E.G. EPINEPHRINE) MAY BE CONTRAINDICATED EXCEPT

FOR

LIFE-SUSTAINING USES IN HUMANS ACUTELY OR CHRONICALLY EXPOSED TO

CHLOROCARBONS (FP N).

Med Cond Aggravated By Exp: NONE SPECIFIED BY MANUFACTURER.

Emergency/First Aid Proc: SKIN: THORO WASH EXPOSED AREA W/SOAP & WATER.

REMOVE CONTAM CLTHG. LAUNDER CONTAM CLTHG BEFORE RE-USE. EYES: FLUSH

W/LARGE AMTS OF WATER, LIFTING UPPER/LOWER LIDS OCCAS, FOR A MINIMUM OF 15

MIN. GET MEDICAL ATTN. INGEST: DO NOT INDUCE VOMIT. CALL MD OR TRANSPORT TO

AN EMER FACILITY. INHAL: REMOVE TO FRESH AIR. IF BRTHG IS DFCLT, ADMIN O2.

IF BRTHG HAS STOPPED, GIVE ARTF RESP. KEEP (SUPP DATA)

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            Precautions for Safe Handling and Use

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Steps If Matl Released/Spill: SMALL SPILL: ABSORB LIQUID ON PAPER,

VERMICULITE, FLOOR ABSORBENT OR OTHER ABSORBENT MATL. LARGE SPILL: PERSONS

NOT WEARING PROT EQUIP SHLD BE EXCLUDED FROM AREA OF SPILL UNTIL CLEAN-UP

HAS BEEN COMPLETED. STOP SPILL AT SOURCE, DIKE AREA (SUPP DATA)

Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER.

Waste Disposal Method: WRAP CAN IN SEVERAL LAYERS OF NEWSPAPER & DISPOSE

OF IN TRASH I/A/W STATE, FEDERAL, AND LOCAL REGULATIONS. DO NOT INCINERATE

OR THROW IN FIRE.

Precautions-Handling/Storing: STORE IN COOL DRY PLACE. NEVER STORE IN

UNLABELED OR IMPROPERLY LABELED CONTAINER.

Other Precautions: KEEP OUT OF REACH OF CHILDREN. FOR COMMERCIAL/

INDUSTRIAL USE ONLY. NO SMKNG IN AREA OF USE. DO NOT USE IN THE GEN VICIN

OF ARC WELDING, OPEN FLAMES OR HOT SURFACES. HEAT &/OR UV RADIA MAY CAUSE

THE FORMATION OF HCL &/OR PHOSGENE (FP N).

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                  Control Measures

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Respiratory Protection: IF TLV OF THE PROD OR ANY COMPONENT IS EXCEEDED, A

NIOSH/MSHA JOINTLY APPRVD AIR SUPPLIED RESPIRATOR IS ADVISED IN ABSENCE OF

PROPER ENVIRON CTL. OSHA REGS ALSO PERMIT OTHER NIOSH/MSHA RESP UNDER

SPECIFIED CNDTNS. ENGINEERING OR (ING 4)

Ventilation: PROVIDE SUFFICIENT MECH (GENERAL) VENT &/OR LOCAL EXHAUST TO

MAINTAIN EXPOSURE BELOW TLV(S).

Protective Gloves: NEOPRENE GLOVES.

Eye Protection: CHEMICAL WORKERS GOGGLES (FP N).

Other Protective Equipment: TO PREVENT REPEATED/PROLONGED SKIN CONTACT,

WEAR IMPERVIOUS CLOTHING & BOOTS.

Work Hygienic Practices: LAUNDER CONTAMINATED CLOTHING BEFORE RE-USE.

Suppl. Safety & Health Data: MATLS TO AVOID: WHICH CAN RSLT IN THERMAL

DECOMP RELEASING HYDROGEN CHLORIDE & SMALL AMTS OF PHOSGENE & CHLORINE.

FIRST AID PROC: PERSON WARM/QUIET & GET MED ATTN. SPILL PROC: OF SPILL TO

PVNT SPREADING, PUMP LIQUID TO SALVAGE TANK. REMAINING LIQUID MAY BE TAKEN

UP ON SAND, CLAY, EARTH, FLOOR ABSORB OR OTHER (ING 3)

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                 Transportation Data

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Trans Data Review Date: 91361

DOT PSN Code: OQD

DOT Proper Shipping Name: 1,1,1- TRICHLOROETHANE *

DOT Class: 6.1

DOT ID Number: UN2831

DOT Pack Group: III

DOT Label: KEEP AWAY FROM FOOD

IMO PSN Code: OVK

IMO Proper Shipping Name: 1,1,1- TRICHLOROETHANE *

IMO Regulations Page Number: 6272-1

IMO UN Number: 2831

IMO UN Class: 6.1

IMO Subsidiary Risk Label: -

IATA PSN Code: YLY

IATA UN ID Number: 2831

IATA Proper Shipping Name: 1,1,1- TRICHLOROETHANE *

IATA UN Class: 6.1

IATA Label: TOXIC

AFI PSN Code: YLY

AFI Prop. Shipping Name: 1,1,1- TRICHLOROETHANE *

AFI Class: 6.1

AFI ID Number: UN2831

AFI Pack Group: III

AFI Special Prov: N36

AFI Basic Pac Ref: 10-10

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                   Disposal Data

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                    Label Data

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Label Required: YES

Technical Review Date: 01NOV91

Label Date: 01NOV91

Label Status: G

Common Name: NO 5023 SAFETY SOLVENT AERO

Chronic Hazard: YES

Signal Word: WARNING!

Acute Health Hazard-Slight: X

Contact Hazard-Moderate: X

Fire Hazard-None: X

Reactivity Hazard-None: X

Special Hazard Precautions: ACUTE: CAN CAUSE SEVERE EYE IRRITATION,

REDNESS, TEARING, BLURRED VISION. PROLONGED/REPEATED CONTACT CAN CAUSE

SKIN

IRRITATION, DEFATTING, DERMATITIS. VAPORS CAN CAUSE NASAL & RESPIRATORY

IRRITATION, DIZZINESS, WEAKNESS, FATIGUE, NAUSEA, HEADACHE, POSSIBLE

UNCONSCIOUSNESS, ASPHYXIATION. IF SWALLOWED, CAN CAUSE GI IRRITATION,

NAUSEA, VOMITING, DIARRHEA. MAY CONTRIBUTE TO THE OCCURRANCE OF IRREGULAR

HEARTBEATS.CHRONIC: PROLONGED/REPEATED SKIN CONTACT MAY CAUSE DEFATTING,

IRRITATION AND DERMATITIS.

Protect Eye: Y

Protect Skin: Y

Protect Respiratory: Y

Label Name: HILL MANUFACTURING CO INC

Label Street: 1500 JONESBORO RD

Label City: ATLANTA

Label State: GA

Label Zip Code: 30315

Label Country: US

Label Emergency Number: 404-522-8364