MATERIAL SAFETY 3M
DATA SHEET 3M Center
St. Paul, Minnesota
55144-1000
1-800-364-3577 or (651) 737-6501 (24 hours)
Copyright, 2001, Minnesota Mining and Manufacturing Company.
All rights reserved. Copying and/or downloading of this
information for the purpose of properly utilizing 3M products
is allowed provided that:
1) the information is copied in full with no changes unless
prior agreement is obtained from 3M, and
2) neither the copy nor the original is resold or otherwise
distributed with the intention of earning a profit thereon.
DIVISION: ENGINEERED ADHESIVES
TRADE NAME:
3M BRAND SPRAY ADHESIVE 75
ID NUMBER/U.P.C.:
CS-0406-1744-4 - - - GS-2000-1130-1 - - -
GS-2000-1132-7 - - - GS-2000-1133-5 - - -
GS-2000-1134-3 - - - GS-2000-1135-0 - - -
GS-2000-1136-8 - - - GS-2000-1137-6 - - -
GS-2000-1138-4 - - - GS-2000-1139-2 - - -
GS-4443-0001-5 - - - GS-4443-0003-1 - - -
GS-4443-0005-6 - - - GS-4443-0006-4 - - -
GS-4443-0007-2 - - - GS-4443-0008-0 - - -
GS-4443-0009-8 - - - GS-4443-0010-6 - - -
GS-4443-0012-2 - - -
ISSUED: May 29, 2001
SUPERSEDES: October 16, 1998
DOCUMENT: 11-0539-4
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1. INGREDIENT C.A.S. NO. PERCENT
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ACRYLATE COPOLYMER...................... None 0
HYDROCARBON RESIN....................... None 0
PLASTICISER............................. None 0
TOTAL OF THE ABOVE...................... None 5.0 - 10.0
1,1,1-TRICHLOROETHANE................... 71-55-6 65.0 - 70.0
BUTANE.................................. 106-97-8 15.0 - 20.0
PROPANE................................. 74-98-6 5.0 - 10.0
This product contains the following toxic chemical or chemicals subject to
the reporting requirements of Section 313 of Title III of the Emergency
Planning and Community Right-To-Know Act of 1986 and 40 CFR Part 372:
1,1,1-TRICHLOROETHANE
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Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately
MSDS: 3M BRAND SPRAY ADHESIVE 75
May 29, 2001 PAGE 2
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2. PHYSICAL DATA
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BOILING POINT:................. COMPRESSED GAS
VAPOR PRESSURE:................ COMPRESSED GAS
VAPOR DENSITY:................. 4
EVAPORATION RATE:.............. 2.7
SOLUBILITY IN WATER:........... NIL
SPECIFIC GRAVITY:.............. N/A
PERCENT VOLATILE:.............. APPROX 90
pH:............................ N/A
VISCOSITY:..................... N/D
MELTING POINT:................. N/D
APPEARANCE AND ODOR:
Liquid in aerosol container, produces a clear film when sprayed.
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3. FIRE AND EXPLOSION HAZARD DATA
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FLASH POINT:................... -46 C PROPELLANT CLOSED CUP
FLAMMABLE LIMITS - LEL:........ N/D
FLAMMABLE LIMITS - UEL:........ N/D
AUTOIGNITION TEMPERATURE:...... N/D
EXTINGUISHING MEDIA:
Water spray, Carbon dioxide, Dry chemical, Foam
SPECIAL FIRE FIGHTING PROCEDURES:
Wear full protective clothing, including helmet, self-contained,
positive pressure or pressure demand breathing apparatus, bunker coat
and pants, bands around arms, waist and legs, face mask, and
protective covering for exposed areas of the head. Water may not
effectively extinguish fire; however, it should be used to keep fire-
exposed containers and surfaces cool and prevent explosive rupture.
UNUSUAL FIRE AND EXPLOSION HAZARDS:
Closed containers exposed to heat from fire may build pressure and
explode. Vapors may travel long distances along the ground or floor
to an ignition source and flash back.
NFPA HAZARD CODES: HEALTH: 2 FIRE: 4 REACTIVITY: 1
UNUSUAL REACTION HAZARD: none
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Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately
MSDS: 3M BRAND SPRAY ADHESIVE 75
May 29, 2001 PAGE 3
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4. REACTIVITY DATA
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STABILITY: Stable
INCOMPATIBILITY - MATERIALS/CONDITIONS TO AVOID:
Heat.
HAZARDOUS POLYMERIZATION: Hazardous polymerization will not occur.
HAZARDOUS DECOMPOSITION PRODUCTS:
Carbon Monoxide and Carbon Dioxide, Hydrogen Chloride, Phosgene,
Chlorine.
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5. ENVIRONMENTAL INFORMATION
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SPILL RESPONSE:
Observe precautions from other sections. Ventilate area. Extinguish
all ignition sources. Cover with absorbent material. Collect
spilled material. Place in an approved metal container.
RECOMMENDED DISPOSAL:
Incinerate in a permitted hazardous waste incinerator in the presence
of a combustible material. Facility must be capable of handling
aerosol cans. Combustion products will include HCl. Dispose of
empty cans in a sanitary landfill. Dispose of completely absorbed
waste product in a facility permitted to accept chemical wastes.
ENVIRONMENTAL DATA:
Not determined.
REGULATORY INFORMATION:
Volatile Organic Compounds: N/D.
VOC Less H2O & Exempt Solvents: N/D.
Since regulations vary, consult applicable regulations or authorities
before disposal. U.S. EPA Hazardous Waste Number = D001 (Ignitable)
EPCRA HAZARD CLASS:
FIRE HAZARD: Yes PRESSURE: Yes REACTIVITY: No ACUTE: Yes CHRONIC: Yes
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6. SUGGESTED FIRST AID
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EYE CONTACT:
Immediately flush eyes with large amounts of water. Get immediate
medical attention.
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Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately
MSDS: 3M BRAND SPRAY ADHESIVE 75
May 29, 2001 PAGE 4
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6. SUGGESTED FIRST AID (continued)
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SKIN CONTACT:
Flush skin with large amounts of water. If irritation persists, get
medical attention.
INHALATION:
Remove person to fresh air. If not breathing, give artificial
respiration. If breathing is difficult, get immediate medical
attention.
IF SWALLOWED:
Do not induce vomiting. Drink two glasses of water. Call a physician.
OTHER FIRST AID INFORMATION:
NOTE TO PHYSICIANS: Exposure may increase myocardial irritability. Do
not administer sympathomimetic drugs unless absolutely necessary.
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7. PRECAUTIONARY INFORMATION
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EYE PROTECTION:
Avoid eye contact with vapor, spray, or mist. Wear vented goggles.
Wear safety glasses with side shields.
SKIN PROTECTION:
Avoid prolonged or repeated skin contact. Wear appropriate gloves
when handling this material. A pair of gloves made from the
following material(s) are recommended: polyethylene/ethylene vinyl
alcohol, polyvinyl alcohol, polytetrafluoroethylene (Teflon),
fluoroelastomer (Viton).
RECOMMENDED VENTILATION:
Use in a well-ventilated area. Provide sufficient ventilation to
maintain emissions below recommended exposure limits. If exhaust
ventilation is not adequate, use appropriate respiratory protection.
RESPIRATORY PROTECTION:
Avoid breathing of vapors, mists or spray. Select one of the
following NIOSH approved respirators based on airborne concentration
of contaminants and in accordance with OSHA regulations: half-mask
organic vapor respirator.
PREVENTION OF ACCIDENTAL INGESTION:
Do not eat, drink or smoke when using this product. Wash exposed
areas thoroughly with soap and water. Do not ingest.
RECOMMENDED STORAGE:
Store at temperatures below 120 degrees F (49 degrees C). Keep out
of the reach of children.
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Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately
MSDS: 3M BRAND SPRAY ADHESIVE 75
May 29, 2001 PAGE 5
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7. PRECAUTIONARY INFORMATION (continued)
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FIRE AND EXPLOSION AVOIDANCE:
Aerosol container contains flammable gas under pressure. Do not
pierce or burn container, even after use. Do not spray near flame or
incandescent material. Avoid static discharge.
EXPOSURE LIMITS
INGREDIENT VALUE UNIT TYPE AUTH SKIN*
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ACRYLATE COPOLYMER................... NONE NONE NONE NONE
HYDROCARBON RESIN.................... NONE NONE NONE NONE
PLASTICISER.......................... NONE NONE NONE NONE
TOTAL OF THE ABOVE................... NONE NONE NONE NONE
1,1,1-TRICHLOROETHANE................ 350 PPM TWA ACGIH
1,1,1-TRICHLOROETHANE................ 450 PPM STEL ACGIH
1,1,1-TRICHLOROETHANE................ 350 PPM TWA OSHA
1,1,1-TRICHLOROETHANE................ 450 PPM STEL OSHA
BUTANE............................... 800 PPM TWA ACGIH
BUTANE............................... 800 PPM TWA OSHA
PROPANE.............................. 1000 PPM TWA OSHA
PROPANE.............................. 2500 PPM TWA ACGIH
* SKIN NOTATION: Listed substances indicated with 'Y' under SKIN refer to
the potential contribution to the overall exposure by the cutaneous route
including mucous membrane and eye, either by airborne or, more particularly,
by direct contact with the substance. Vehicles can alter skin absorption.
SOURCE OF EXPOSURE LIMIT DATA:
- ACGIH: American Conference of Governmental Industrial Hygienists
- OSHA: Occupational Safety and Health Administration
- NONE: None Established
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8. HEALTH HAZARD DATA
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EYE CONTACT:
Moderate Eye Irritation: signs/symptoms can include redness, swelling,
pain, tearing, and hazy vision.
SKIN CONTACT:
Mild Skin Irritation: signs/symptoms can include redness, swelling,
and itching.
INHALATION:
Intentional concentration and inhalation may be harmful or fatal.
Irritation (upper respiratory): signs/symptoms can include soreness
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Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately
MSDS: 3M BRAND SPRAY ADHESIVE 75
May 29, 2001 PAGE 6
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8. HEALTH HAZARD DATA (continued)
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of the nose and throat, coughing and sneezing.
Single overexposure, above recommended guidelines, may cause:
Cardiac Sensitization: sudden heart stoppage due to a reflex
effect on the nerves which control the heart. This effect
usually occurs only after inhalation of concentrated vapors such
as in intentional abusive sniffing of certain solvents and
propellants.
Central Nervous System Depression: signs/symptoms can include
headache, dizziness, drowsiness, incoordination, slowed reaction
time, slurred speech, giddiness and unconsciousness.
WHILE THE FOLLOWING EFFECTS ARE ASSOCIATED WITH ONE OR MORE OF THE
INDIVIDUAL INGREDIENTS IN THIS PRODUCT AND ARE REQUIRED TO BE
INCLUDED ON THE MSDS BY THE U.S. OSHA HAZARD COMMUNICATION STANDARD,
THEY ARE NOT EXPECTED EFFECTS DURING FORESEEABLE USE OF THIS PRODUCT.
Prolonged or repeated overexposure, above recommended guidelines, may
cause:
Kidney Effects: signs/symptoms can include reduced urine volume,
blood in urine and back pain.
Liver Effects: signs/symptoms can include yellow skin(jaundice)
and tenderness of upper abdomen.
IF SWALLOWED:
Ingestion is not a likely route of exposure to this product.
WHILE THE FOLLOWING EFFECTS ARE ASSOCIATED WITH ONE OR MORE OF THE
INDIVIDUAL INGREDIENTS IN THIS PRODUCT AND ARE REQUIRED TO BE
INCLUDED ON THE MSDS BY THE U.S. OSHA HAZARD COMMUNICATION STANDARD,
THEY ARE NOT EXPECTED EFFECTS DURING FORESEEABLE USE OF THIS PRODUCT.
Ingestion may cause:
Irritation of Gastrointestinal Tissues: signs/symptoms can
include pain, vomiting, abdominal tenderness, nausea, blood in
vomitus, and blood in feces.
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SECTION CHANGE DATES
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HEADING SECTION CHANGED SINCE October 16, 1998 ISSUE
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Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately
MSDS: 3M BRAND SPRAY ADHESIVE 75
May 29, 2001 PAGE 7
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The information in this Material Safety Data Sheet (MSDS) is believed to
be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR
IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF
MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF
PERFORMANCE OR USAGE OF TRADE. User is responsible for determining
whether the 3M product is fit for a particular purpose and suitable for
user's method of use or application. Given the variety of factors that
can affect the use and application of a 3M product, some of which are
uniquely within the user's knowledge and control, it is essential that
the user evaluate the 3M product to determine whether it is fit for a
particular purpose and suitable for user's method of use or application.
3M provides information in electronic form as a service to its customers.
Due to the remote possibility that electronic transfer may have resulted
in errors, omissions or alterations in this information, 3M makes no
representations as to its completeness or accuracy. In addition,
information obtained from a database may not be as current as the
information in the MSDS available directly from 3M.
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