Material Safety Data Sheet
Alcohol SDA 3C (093)
Version 1 Revision Date 11/11/2009 Print Date 11/11/2009
SECTION 1. PRODUCT AND COMPANY IDENTIFICATION
Product name : Alcohol SDA 3C (093)
MSDS Number : 000000011315
Product Use Description : Solvent
Company : Honeywell International Inc.
1953 South Harvey Street
Muskegon, MI 49442
For more information call :
(Monday-Friday, 9:00am-5:00pm)
In case of emergency call : Medical: 1-800-498-5701
: Transportation: 1-800-424-9300 or +1-703-527-3887
: (24 hours/day, 7 days/week)
SECTION 2. HAZARDS IDENTIFICATION
Emergency Overview
Form : liquid, clear
Color : colourless
Odor : slight alcoholic
Hazard Summary : Flammable. In use, may form flammable/explosive vapour-air
mixture. May be fatal if swallowed. May be fatal if inhaled. May
be harmful if absorbed through skin. Irritating to eyes,
respiratory system and skin. The product may be absorbed
through the skin. Repeated exposure may cause skin dryness
or cracking. This product may cause adverse reproductive
effects. Possible risk of harm to the unborn child. Avoid
exposure to pregnant women especially. Cannot be made
non-poisonous.
Potential Health Effects
Skin : Irritating to skin.
The product may be absorbed through the skin.
May cause systemic poisoning with symptoms paralleling those
of inhalation.
Prolonged or repeated skin contact with liquid may cause
defatting resulting in drying, redness and possible blistering.
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Material Safety Data Sheet
Alcohol SDA 3C (093)
Version 1 Revision Date 11/11/2009 Print Date 11/11/2009
Eyes : Irritating to eyes.
Causes itching, burning, redness and tearing.
May cause irreversible eye damage.
Ingestion : Ingestion may cause gastrointestinal irritation, nausea,
vomiting and diarrhoea.
May cause systemic poisoning with symptoms paralleling those
of inhalation.
Inhalation : Causes respiratory tract irritation.
Causes headache, drowsiness or other effects to the central
nervous system.
Vapours may cause drowsiness and dizziness.
Inhalation of high vapour concentrations can cause
CNS-depression and narcosis.
Chronic Exposure : Causes damage to the kidneys/liver/eyes/brain/respiratory
system/central nervous system through prolonged or repeated
exposure.
Prolonged or repeated skin contact with liquid may cause
defatting resulting in drying, redness and possible blistering.
This product may cause adverse reproductive effects.
Potential embryo-foetal toxicity and teratogenicity.
Possible risk of harm to the unborn child.
Confirmed animal carcinogen with unknown relevance to
humans.
Aggravated Medical : Liver disorders
Condition Eye disorders
Skin disorders
Neurological disorders
Kidney disorders
Do not use if pregnant.
Target Organs : Eyes
Skin
Liver
Kidney
Blood
Respiratory system
Central nervous system
Gastrointestinal tract
Carcinogenicity
ACGIH: Ethanol 64-17-5
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Material Safety Data Sheet
Alcohol SDA 3C (093)
Version 1 Revision Date 11/11/2009 Print Date 11/11/2009
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
Component CAS-No. Weight percent
Ethanol 64-17-5 95.00
Propan-2-ol 67-63-0 5.00
SECTION 4. FIRST AID MEASURES
Inhalation : Call a physician immediately. Remove to fresh air. If not
breathing, give artificial respiration. If breathing is difficult, give
oxygen. Use oxygen as required, provided a qualified operator is
present.
Skin contact : Wash off immediately with plenty of water for at least 15
minutes. Take off contaminated clothing and shoes immediately.
Wash contaminated clothing before re-use. Call a physician.
Eye contact : Rinse immediately with plenty of water, also under the eyelids,
for at least 15 minutes. Call a physician.
Ingestion : Call a physician immediately. Do NOT induce vomiting.
Immediate medical attention is required. Never give anything by
mouth to an unconscious person.
Notes to physician
Treatment : Treat symptomatically.
SECTION 5. FIRE-FIGHTING MEASURES
Flash point : 17 癈 (63 癋)
closed cup
Ignition temperature : 363 癈 (685 癋)
The physical data is that of the main component.
Lower explosion limit : 3.3 %(V)
The physical data is that of the main component.
Upper explosion limit : 19 %(V)
The physical data is that of the main component.
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Material Safety Data Sheet
Alcohol SDA 3C (093)
Version 1 Revision Date 11/11/2009 Print Date 11/11/2009
Suitable extinguishing : Alcohol-resistant foam
media Carbon dioxide (CO2)
Dry chemical
Cool closed containers exposed to fire with water spray.
Extinguishing media which : Do not use a solid water stream as it may scatter and spread
shall not be used for safety fire.
reasons
Specific hazards during fire : Flammable.
fighting Vapours may form explosive mixtures with air.
Vapours are heavier than air and may spread along floors.
Vapors may travel to areas away from work site before
igniting/flashing back to vapor source.
In case of fire hazardous decomposition products may be
produced such as:
Carbon monoxide
Carbon dioxide (CO2)
Formaldehyde
Special protective : Wear self-contained breathing apparatus and protective suit.
equipment for fire-fighters
SECTION 6. ACCIDENTAL RELEASE MEASURES
Personal precautions : Wear personal protective equipment.
Immediately evacuate personnel to safe areas.
Keep people away from and upwind of spill/leak.
Ensure adequate ventilation.
Remove all sources of ignition.
Do not swallow.
Do not breathe vapours or spray mist.
Avoid contact with skin, eyes and clothing.
Environmental precautions : Prevent further leakage or spillage if safe to do so.
Discharge into the environment must be avoided.
Do not flush into surface water or sanitary sewer system.
Prevent product from entering drains.
Do not allow run-off from fire fighting to enter drains or water
courses.
Methods for cleaning up : Ventilate the area.
No sparking tools should be used.
Use explosion-proof equipment.
Contain and collect spillage with non-combustible absorbent
materials, e.g. sand, earth, vermiculite, diatomaceous earth and
place in container for disposal according to local regulations
(see section 13).
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Material Safety Data Sheet
Alcohol SDA 3C (093)
Version 1 Revision Date 11/11/2009 Print Date 11/11/2009
SECTION 7. HANDLING AND STORAGE
Handling
Handling : Wear personal protective equipment.
Use only in well-ventilated areas.
Keep container tightly closed.
Do not smoke.
Do not swallow.
Do not breathe vapours or spray mist.
Avoid contact with skin, eyes and clothing.
Advice on protection against : Keep away from fire, sparks and heated surfaces.
fire and explosion Take precautionary measures against static discharges.
Ensure all equipment is electrically grounded before beginning
transfer operations.
Use explosion-proof equipment.
Keep product and empty container away from heat and sources
of ignition.
No sparking tools should be used.
No smoking.
Storage
Requirements for storage : Store in area designed for storage of flammable liquids. Protect
areas and containers from physical damage.
Keep containers tightly closed in a dry, cool and well-ventilated
place.
Containers which are opened must be carefully resealed and
kept upright to prevent leakage.
Keep away from heat and sources of ignition.
Keep away from direct sunlight.
Store away from incompatible substances.
Container hazardous when empty.
Do not pressurize, cut, weld, braze, solder, drill, grind or expose
containers to heat or sources of ignition.
SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Protective measures : Ensure that eyewash stations and safety showers are close to
the workstation location.
Engineering measures : Use with local exhaust ventilation.
Prevent vapor buildup by providing adequate ventilation during
and after use.
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Material Safety Data Sheet
Alcohol SDA 3C (093)
Version 1 Revision Date 11/11/2009 Print Date 11/11/2009
Eye protection : Do not wear contact lenses.
Wear as appropriate:
Safety glasses with side-shields
If splashes are likely to occur, wear:
Goggles or face shield, giving complete protection to eyes
Hand protection : Solvent-resistant gloves
Gloves must be inspected prior to use.
Replace when worn.
Skin and body protection : Wear as appropriate:
Solvent-resistant apron
Flame retardant antistatic protective clothing
If splashes are likely to occur, wear:
Protective suit
Respiratory protection : In case of insufficient ventilation wear suitable respiratory
equipment.
For rescue and maintenance work in storage tanks use
self-contained breathing apparatus.
Use NIOSH approved respiratory protection.
Hygiene measures : When using, do not eat, drink or smoke.
Wash hands before breaks and immediately after handling the
product.
Keep working clothes separately.
Remove and wash contaminated clothing before re-use.
Do not swallow.
Do not breathe vapours or spray mist.
Avoid contact with skin, eyes and clothing.
Exposure Guidelines
Ethanol 64-17-5 NIOSH REL 1,000 ppm 1,900 mg/m3
OSHA Z1 PEL 1,000 ppm 1,900 mg/m3
OSHA Z1A TWA 1,000 ppm 1,900 mg/m3
US CA OEL TWA PEL 1,000 ppm 1,900 mg/m3
ACGIH STEL 1,000 ppm
TX ESL ST ESL 18800 ug/m3
TX ESL AN ESL 1880 ug/m3
Isopropanol 67-63-0 NIOSH REL 400 ppm 980 mg/m3
NIOSH STEL 500 ppm 1,225 mg/m3
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Material Safety Data Sheet
Alcohol SDA 3C (093)
Version 1 Revision Date 11/11/2009 Print Date 11/11/2009
OSHA Z1 PEL 400 ppm 980 mg/m3
OSHA Z1A TWA 400 ppm 980 mg/m3
OSHA Z1A STEL 500 ppm 1,225 mg/m3
US CA OEL TWA PEL 400 ppm 980 mg/m3
US CA OEL STEL 500 ppm 1,225 mg/m3
ACGIH TWA 200 ppm
ACGIH STEL 400 ppm
TX ESL ST ESL 7850 ug/m3
Screening levels that have the odor designations
represent the levels of constituents in the air at
which the odor would be a nuisance.
TX ESL AN ESL 785 ug/m3
Screening levels that have the odor designations
represent the levels of constituents in the air at
which the odor would be a nuisance.
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
Form : liquid, clear
Color : colourless
Odor : slight alcoholic
pH : not applicable
Melting point/range : <-114 癈 (-173 癋)
The physical data is that of the main component.
Boiling point/boiling range : 78.32 癈 (172.98 癋)
The physical data is that of the main component.
Vapor pressure : 59.5 hPa
at 20 癈 (68 癋)
The physical data is that of the main component.
Relative vapour density : 1.6
(Air = 1.0), The physical data is that of the main component.
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Material Safety Data Sheet
Alcohol SDA 3C (093)
Version 1 Revision Date 11/11/2009 Print Date 11/11/2009
Density : 0.811 g/cm3
at 20 癈 (68 癋)
Water solubility : completely soluble
SECTION 10. STABILITY AND REACTIVITY
Conditions to avoid : Heat, flames and sparks.
Keep away from direct sunlight.
Materials to avoid : Strong oxidizing agents
Potassium superoxide
Bromine Pentafluoride
Acetyl bromide
Acetyl chloride
Platinum
Sodium
Hazardous decomposition : In case of fire hazardous decomposition products may be
products produced such as:
Carbon monoxide
Carbon dioxide (CO2)
Formaldehyde
Hazardous reactions : Hazardous polymerisation does not occur.
Stable under recommended storage conditions.
SECTION 11. TOXICOLOGICAL INFORMATION
Acute oral toxicity : LD50 rat
Dose: 7,060 mg/kg
Test substance: Ethanol
Acute oral toxicity : LD50 rat
Dose: 5,045 mg/kg
Test substance: Isopropanol
Acute dermal toxicity : LD50 rabbit
Dose: 12,800 mg/kg
Test substance: Isopropanol
Acute inhalation toxicity : LC50 rat
Dose: 20000 ppm
Exposure time: 10 h
Test substance: Ethanol
Acute inhalation toxicity : LC50 rat
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Material Safety Data Sheet
Alcohol SDA 3C (093)
Version 1 Revision Date 11/11/2009 Print Date 11/11/2009
Dose: 16000 ppm
Exposure time: 8 h
Test substance: Isopropanol
Skin irritation : rabbit
Exposure time: 24 h
irritating
Test substance:Ethanol
Skin irritation : rabbit
Mild skin irritation
Test substance:Isopropanol
Eye irritation : rabbit
irritating
Test substance: Ethanol
Eye irritation : rabbit
Severe eye irritation
Test substance: Isopropanol
Additional advice : Confirmed animal carcinogen with unknown relevance to
humans.
SECTION 12. ECOLOGICAL INFORMATION
Biodegradability : Biochemical Oxygen Demand (BOD) Biochemical oxygen
demand within 5 days
Biodegradation: 58 %
Test substance: Isopropanol
Toxicity to fish : LC0
Species: Leuciscus idus (Golden orfe)
Dose: 8,140 mg/l
Exposure time: 48 h
Test substance: Ethanol
Toxicity to fish : flow-through test LC50
Species: Oncorhynchus mykiss
Dose: 12,900 mg/l
Exposure time: 96 h
Test substance: Ethanol
Toxicity to fish : LC50
Species: Pimephales promelas (fathead minnow)
Dose: 14,200 mg/l
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Material Safety Data Sheet
Alcohol SDA 3C (093)
Version 1 Revision Date 11/11/2009 Print Date 11/11/2009
Exposure time: 96 h
Test substance: Ethanol
Toxicity to fish : LC50
Species: goldfish
Dose: > 5,000 mg/l
Exposure time: 24 h
Test substance: Isopropanol
Toxicity to fish : LC50
Species: Leuciscus idus (Golden orfe)
Dose: 8,970 mg/l
Exposure time: 48 h
Test substance: Isopropanol
Toxicity to fish : LC50
Species: Pimephales promelas (fathead minnow)
Dose: 10,400 mg/l
Exposure time: 96 h
Test substance: Isopropanol
Toxicity to daphnia and : EC50
other aquatic invertebrates. Species: Daphnia magna (Water flea)
Dose: 9,268 mg/l
Exposure time: 48 h
Test substance: Ethanol
Toxicity to daphnia and : EC50
other aquatic invertebrates. Species: Daphnia magna (Water flea)
Dose: 10,800 mg/l
Exposure time: 24 h
Test substance: Ethanol
Toxicity to daphnia and : EC50
other aquatic invertebrates. Species: Daphnia magna (Water flea)
Dose: > 100 mg/l
Exposure time: 48 h
Test substance: Isopropanol
Toxicity to algae : LC0
Species: Scenedesmus quadricauda
Dose: 5,000 mg/l
Test substance: Ethanol
Toxicity to algae : LC50
Species: Desmodesmus subspicatus (green algae)
Dose: > 2,000 mg/l
Exposure time: 72 h
Test substance: Isopropanol
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Material Safety Data Sheet
Alcohol SDA 3C (093)
Version 1 Revision Date 11/11/2009 Print Date 11/11/2009
Toxicity to bacteria : LC0
Species: Pseudomonas putida
Dose: 6,500 mg/l
Test substance: Ethanol
Toxicity to bacteria : EC50
Species: Photobacterium phosphoreum
Dose: 35,470 mg/l
Exposure time: 5 min
Test substance: Ethanol
Toxicity to bacteria : EC50
Species: Photobacterium phosphoreum
Dose: 34,634 mg/l
Exposure time: 30 min
Test substance: Ethanol
Toxicity to bacteria : EC50
Species: Photobacterium phosphoreum
Dose: 35,390 mg/l
Exposure time: 5 min
Test substance: Isopropanol
SECTION 13. DISPOSAL CONSIDERATIONS
Waste Information: Observe all Federal, State, and Local Environmental regulations.
SECTION 14. TRANSPORT INFORMATION
UN-Number : 1987
DOT
Proper shipping name : Alcohols, n.o.s.
(Ethanol, Isopropanol)
Class 3
Packing group II
Hazard Labels 3
UN Number : 1987
IATA
Description of the goods : Alcohols, n.o.s.
(Ethanol, Isopropanol)
Class :3
Packaging group : II
Hazard Labels :3
Packing instruction (cargo : 307
aircraft)
Packing instruction : 305
(passenger aircraft)
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Material Safety Data Sheet
Alcohol SDA 3C (093)
Version 1 Revision Date 11/11/2009 Print Date 11/11/2009
Packing instruction : Y305
(passenger aircraft)
Substance No. : UN 1987
IMDG
Description of the goods : Alcohols, n.o.s.
(ETHANOL, ISOPROPANOL)
Class :3
Packaging group : II
Hazard Labels :3
EmS Number : F-E
Marine pollutant : no
SECTION 15. REGULATORY INFORMATION
Inventories
1907/2006 (EU) : This mixture contains only ingredients which have been subject
to a pre-registration according to Regulation (EC) No. 1907/2006
(REACH).
US. Toxic Substances : On TSCA Inventory
Control Act
Australia. Industrial : On the inventory, or in compliance with the inventory
Chemical (Notification and
Assessment) Act
Canada. Canadian : All components of this product are on the Canadian DSL list.
Environmental Protection
Act (CEPA). Domestic
Substances List (DSL).
(Can. Gaz. Part II, Vol. 133)
Japan. Kashin-Hou Law List : On the inventory, or in compliance with the inventory
Korea. Toxic Chemical : On the inventory, or in compliance with the inventory
Control Law (TCCL) List
Philippines. The Toxic : On the inventory, or in compliance with the inventory
Substances and Hazardous
and Nuclear Waste Control
Act
China. Inventory of Existing : On the inventory, or in compliance with the inventory
Chemical Substances
New Zealand. Inventory of : On the inventory, or in compliance with the inventory
Chemicals (NZIoC), as
published by ERMA New
Zealand
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Material Safety Data Sheet
Alcohol SDA 3C (093)
Version 1 Revision Date 11/11/2009 Print Date 11/11/2009
National regulatory information
: Isopropanol 67-63-0
SARA 313 Components
: Fire Hazard
SARA 311/312 Hazards
Acute Health Hazard
: This product does not contain any chemicals known to the State
California Prop. 65
of California to cause cancer, birth, or any other reproductive
defects.
: Ethanol 64-17-5
Massachusetts RTK
: Isopropanol 67-63-0
: Ethanol 64-17-5
New Jersey RTK
: Isopropanol 67-63-0
: Ethanol 64-17-5
Pennsylvania RTK
: Isopropanol 67-63-0
: B2
WHMIS Classification
D2A
D2B
This product has been classified according to the hazard criteria
of the CPR and the MSDS contains all of the information required
by the CPR.
SECTION 16. OTHER INFORMATION
HMIS III NFPA
Health hazard : 2* 0
Flammability :3 3
Physical Hazard :0
Instability : 0
Further information
* - Chronic health hazard
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Material Safety Data Sheet
Alcohol SDA 3C (093)
Version 1 Revision Date 11/11/2009 Print Date 11/11/2009
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