Material Safety Data Sheet
MSDS Update: 11/16/2009
Version: 1.0
Date Printed:
SECTION 1 - Chemical Product & Company Identification
Product Name Crystal Screen Cryo HT TM
Product Number HR2-133
Company Hampton Research
Street Address 34 Journey
City, State, Zip, Country Aliso Viejo, CA 92656, U.S.A.
Technical Phone 949 425 1321
Fax 949 425 1611
Emergency Phone 949 425 1321
For CHEMTREC Assistance, call: 800 424 9300
For International CHEMTREC Assistance, call: 703 527 3887
SECTION 2 - Composition / Information on Ingredient
Substance Name CAS # EC No SARA RTECS LD50
(+/-)-2-Methyl-2,4-pentanediol 107-41-5 203-489-0 No SA0810000 3,700 mg/kg - Rat - Oral
1,4-Dioxane 123-91-1 204-661-8 Yes JG8225000 4,200 mg/kg - Rat - Oral
1,6-Hexanediol 629-11-8 211-074-0 No MO2100000 3,730 mg/kg - Rat - Oral
2-Propanol 67-63-0 200-661-7 Yes NT8050000 5,045 mg/kg - Rat - Oral
Ammonium acetate 631-61-8 211-162-9 Yes AF3675000 736 mg/kg - Mouse - Intraperitoneal
Ammonium formate 540-69-2 208-753-9 Yes BQ6650000 2,250 mg/kg - Mouse - Oral
Ammonium phosphate monobasic 7722-76-1 231-764-5 No N/A 5,750 mg/kg - Rat - Oral
Ammonium sulfate 7783-20-2 231-984-1 No BS4500000 2,840 mg/kg - Rat - Oral
BICINE 150-25-4 205-755-1 No MB9700000 1,540 mg/kg - Mouse - Intraperitoneal
Cadmium chloride hydrate 654054-66-7 N/A Yes N/A N/A
Cadmium sulfate hydrate 7790-84-3 233-331-6 Yes EV2850000 N/A
Calcium acetate hydrate 114460-21-8 200-540-9 No AF7525000 75 mg/kg - Mouse - Intraperitoneal
Calcium chloride dihydrate 10035-04-8 233-140-8 No EV9810000 N/A
Cesium chloride 7647-17-8 231-600-2 No FK9625000 2,600 mg/kg - Rat - Oral
Cobalt(II) chloride hexahydrate 7791-13-1 231-589-4 Yes GG0200000 766 mg/kg - Rat - Oral
Ethanol 64-17-5 200-578-6 No KQ6300000 7,060 mg/kg - Rat - Oral
Ethylene glycol 107-21-1 203-473-3 Yes KW2975000 4,700 mg/kg - Rat - Oral
Ethylene imine polymer 9002-98-6 205-793-9 No N/A N/A
Glycerol 56-81-5 200-289-5 No MA8050000 12,600 mg/kg - Rat - Oral
HEPES 7365-45-9 230-907-9 No TL6809000 > 316 mg/kg - Quail - Oral
HEPES sodium 75277-39-3 278-169-7 No N/A N/A
TM
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(CONTINUED) - SECTION 2 - Composition / Information on Ingredient
Substance Name CAS # EC No SARA RTECS LD50
Hexadecyltrimethylammonium
57-09-0 200-311-3 No BQ7875000 410 mg/kg - Rat - Oral
bromide
Imidazole 288-32-4 206-019-2 No NI3325000 220 mg/kg - Rat - Oral
Iron(III) chloride hexahydrate 10025-77-1 231-729-4 No NO5425000 260 mg/kg - Mouse - Intraperitoneal
Jeffamine ? M-600 ? 77110-54-4 N/A No N/A N/A
Lithium sulfate monohydrate 10102-25-7 233-820-4 No N/A N/A
Magnesium acetate tetrahydrate 16674-78-5 205-554-9 No AI5600000 111 mg/kg - Mouse - Intravenous
Magnesium chloride hexahydrate 7791-18-6 232-094-6 No OM2975000 8,100 mg/kg - Rat - Oral
Magnesium formate dihydrate 557-39-1 N/A No N/A N/A
Magnesium sulfate heptahydrate 10034-99-8 231-298-2 No OM4508000 N/A
MES monohydrate 145224-94-8 224-632-3 No N/A N/A
Nickel(II) chloride hexahydrate 7791-20-0 231-743-0 Yes QR6480000 186 mg/kg - Rat - Oral
Polyethylene glycol 400 25322-68-3 500-038-2 No TQ3675000 N/A
Polyethylene glycol 1,000 25322-68-3 500-038-2 No TQ4025000 32,000 mg/kg - Rat - Oral
Polyethylene glycol 1,500 25322-68-3 500-038-2 No TQ4030000 44,200 mg/kg - Rat - Oral
Polyethylene glycol 4,000 25322-68-3 500-038-2 No TQ4050000 50,000 mg/kg - Rat - Oral
Polyethylene glycol 6,000 25322-68-3 500-038-2 No N/A N/A
Polyethylene glycol 8,000 25322-68-3 500-038-2 No TQ4105000 > 50,000 mg/kg - Rat - Oral
Polyethylene glycol 10,000 25322-68-3 500-038-2 No TQ4110000 50,000 mg/kg - Rat - Oral
Polyethylene glycol 20,000 25322-68-3 500-038-2 No TQ4110000 50,000 mg/kg - Rat - Oral
Polyethylene glycol monomethyl
9004-74-4 N/A No PE8271000 39,800 mg/kg - Rat - Oral
ether 550
Polyethylene glycol monomethyl
9004-74-4 N/A No PE8271000 39,800 mg/kg - Rat - Oral
ether 2,000
Polyethylene glycol monomethyl
9004-74-4 N/A No PE8271000 39,800 mg/kg - Rat - Oral
ether 5,000
Potassium phosphate monobasic 7778-77-0 231-913-4 No TC6615500 4,640 mg/kg - Rabbit - Dermal
Potassium sodium tartrate
6381-59-5 206-156-8 No N/A N/A
tetrahydrate
Sodium acetate trihydrate 6131-90-4 204-823-8 No AJ4580000 N/A
Sodium cacodylate trihydrate 6131-99-3 204-708-2 Yes CH7890000 2,000 mg/kg - Rat - Oral
Sodium chloride 7647-14-5 231-598-3 No VZ4725000 3,000 mg/kg - Rat - Oral
Sodium citrate tribasic dihydrate 6132-04-3 200-675-3 No N/A N/A
Sodium formate 141-53-7 205-488-0 No LR0350000 11,200 mg/kg - Mouse - Oral
Sodium phosphate monobasic
10049-21-5 231-449-2 No N/A N/A
monohydrate
tert-Butanol 75-65-0 200-869-7 Yes EO1925000 2,743 mg/kg - Rat - Oral
Tris 77-86-1 201-064-4 No TY2900000 5,900 mg/kg - Rat - Oral
TRIS hydrochloride 1185-53-1 214-684-5 No N/A N/A
Zinc acetate dihydrate 5970-45-6 209-170-2 No ZG8750000 794 mg/kg - Rat - Oral
Zinc sulfate heptahydrate 7446-20-0 231-793-3 No ZH5300000 2,150 mg/kg - Rat - Oral
N/A = NOT AVAILABLE
TM
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SECTION 3 - Hazards Identification
HMIS RATING HAZARD RATINGS
HEALTH HAZARD: 0 0 - LEAST
FLAMMABILITY: 0 1 - SLIGHT
REACTIVITY: 0 2 - MODERATE
3 - HIGH
NFPA RATING 4 - EXTREME
HEALTH HAZARD: 0
FLAMMABILITY: 0
REACTIVITY: 0
* For additional information on toxicity, please refer to SECTION 11.
SECTION 4 - First Aid Measures
ORAL EXPOSURE
?If swallowed, wash out mouth with water provided person is conscious.
?DO NOT INDUCE VOMITING.
?Call a physician.
INHALATION EXPOSURE
?If inhaled, remove to fresh air.
?If breathing is difficult, GIVE OXYGEN.
?Call a physician.
DERMAL EXPOSURE
?In case of contact, immediately wash skin with soap and copious amounts of water for at least 15 minutes.
?Take off contaminated clothing and shoes immediately.
?Call a physician.
EYE EXPOSURE
?In case of contact with eyes, flush with copious amounts of water for at least 15 minutes.
?Assure adequate flushing by separating the eyelids with fingers.
?Call a physician.
SECTION 5 - Fire Fighting Measures
FLASH POINT AUTOIGNITION TEMPERATURE FLAMMABILITY
N/A N/A N/A
EXTINGUISHING MEDIA
?Suitable: Water spray, Carbon dioxide, dry chemical powder, or appropriate foam.
TM
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(CONTINUED) - SECTION 5 - Fire Fighting Measures
FIREFIGHTING
?Protective Equipment: Wear self-contained breathing apparatus and protective clothing to prevent contact
with skin and eyes.
?Specific Hazard(s): Emits toxic fumes under fire conditions.
SECTION 6 - Accidental Release Measures
PROCEDURE(S) OF PERSONAL PRECAUTIONS
?Exercise appropriate precautions to minimize direct contact with skin or eyes and prevent inhalation of dust.
METHODS FOR CLEANING UP
?Wash spill site with soap solution. Flush spill area with copious amounts of water.
?Place in appropriate container.
?Ventilate area and wash spill site after material pickup is complete.
SECTION 7 - Handling & Storage
HANDLING
?User Exposure - Ensure adequate inhalation.
- Avoid inhalation.
- Avoid contact with eyes, skin, and clothing.
- Avoid prolonged or repeated exposure.
STORAGE
?Suitable: Keep container tightly closed.
SECTION 8 - Exposure Controls / PPE
ENGINEERING CONTROLS
?Mechanical exhaust required.
?Safety shower and eye bath
PERSONAL PROTECTIVE EQUIPMENT
?Respiratory: Use respirators and components tested and approved under appropriate government standards
such as (NIOSH) or CEN (EU). Respiratory protection is not required. Where protection from
nuisance levels of dust are desired, use type N95 (US) or type (P1) (EN 143) dust masks.
?Hand: Compatible chemical-resistant gloves.
?Eye: Chemical safety goggles.
GENERAL HYGIENE MEASURES
?Wash thoroughly before and after handling.
TM
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SECTION 9 - Physical / Chemical Properties
APPEARANCE PHYSICAL STATE: Liquid
PROPERTY VALUE AT TEMPERATURE OR PRESSURE
Molecular Weight N/A
pH N/A
BP / BP Range N/A
MP / MP Range N/A
Freezing Point N/A
Vapor Pressure N/A
Vapor Density N/A
Saturated Vapor Concentration N/A
SG / Density N/A
Bulk Density N/A
Odor Threshold N/A
Volatile % N/A
VOC Content N/A
Water Content N/A
Solvent Content N/A
Evaporation Rate N/A
Viscosity N/A
Surface Tension N/A
Partition Coefficient N/A
Decomposition Temperature N/A
Flash Point N/A
Explosion Limits N/A
Flammability N/A
Autoignition Temperature N/A
Refractive Index N/A
Optical Rotation N/A
Miscellaneous Data N/A
Solubility N/A
N/A = NOT AVAILABLE
SECTION 10 - Stability & Reactivity
STABILITY
?Stable: Stable under recommended storage conditions.
HAZARDOUS DECOMPOSITION PRODUCTS
?No data available.
HAZARDOUS EXOTHERMIC REACTIONS
?Will not occur.
TM
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(CONTINUED) - SECTION 10 - Stability & Reactivity
HAZARDOUS POLYMERIZATION
?Will not occur.
SECTION 11 - Toxicological Information
ACUTE TOXICITY
?No data available.
IRRITATION AND CORROSION
?No data available.
SENSITISATION
?No data available.
CHRONIC EXPOSURE
?No data available.
ROUTE OF EXPOSURE
?Skin Contact: May cause skin irritation
?Skin Absorption: May be harmful if absorbed through the skin.
?Eye Contact: May cause eye irritation.
?Inhalation: Material may be irritating to mucous membranes and upper respiratory tract.
May be harmful if inhaled.
?Ingestion: May be harmful if swallowed.
SIGNS & SYMPTOMS OF EXPOSURE
?To the best of our knowledge, the chemical, physical, and toxicological properties have NOT been thoroughly
investigated.
SECTION 12 - Ecological Information
?No data available.
SECTION 13 - Disposal Considerations
APPROPRIATE METHOD OF DISPOSAL OF SUBSTANCE OR PREPARATION
?Contact a licensed professional waste disposal service to dispose of this material.
?Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an
afterburner and a scrubber.
?Observe all federal, state, and local environmental regulations.
TM
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SECTION 14 - Transportation Information
DOT (US)
?UN- Number: 3316 ?Class: N/A
?Proper Shipping Name: Chemical kits or First aid kits (containing hazardous materials)
?Non-Hazardous for Transport: This substance is considered to be non-hazardous for transport.
IATA
?UN- Number: 3316 ?Class: N/A
?Proper Shipping Name: Chemical kits or First aid kits (containing hazardous materials)
?Non-Hazardous for Transport: Non-hazardous for air transport.
SECTION 15 - Regulatory Information
OSHA HAZARDS
?N/A
TSCA STATUS
?N/A
EU ADDITIONAL INFORMATION
Substance Name CAS # R-Phrase S-Phrase
HAZARD Code
(+/-)-2-Methyl-2,4-pentanediol 107-41-5 Xi 36/38 26-36
1,4-Dioxane 123-91-1 F, Xn 11-19-36/37-40-66 9-16-36/37-46
1,6-Hexanediol 629-11-8 23-24/25-36/37
2-Propanol 67-63-0 F, Xi 11-36-67 7-16-24/25-26
Ammonium acetate 631-61-8
Ammonium formate 540-69-2 Xi 36/37/38 26-36
Ammonium phosphate monobasic 7722-76-1
Ammonium sulfate 7783-20-2
BICINE 150-25-4
45-46-60-61-25-26-
Cadmium chloride hydrate 654054-66-7 T+, N 53-45-60-61
48/23/25-50/53
45-46-60-61-25-26-
Cadmium sulfate hydrate 7790-84-3 T+, N 53-45-60-61
48/23/25-50/53
Calcium acetate hydrate 114460-21-8 Xi 36/37/38 26-36
Calcium chloride dihydrate 10035-04-8 Xi 36 26
Cesium chloride 7647-17-8
Cobalt(II) chloride hexahydrate 7791-13-1 T, N 49-22-42/43-50/53 53-22-45-60-61
Ethanol 64-17-5 F 11 7-16
Ethylene glycol 107-21-1 Xn 22
Ethylene imine polymer 9002-98-6
Glycerol 56-81-5
HEPES 7365-45-9
HEPES sodium 75277-39-3 22-24/25
TM
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(CONTINUED) - SECTION 15 - Regulatory Information
EU ADDITIONAL INFORMATION (CONTINUED)
Substance Name CAS # R-Phrase S-Phrase
HAZARD Code
Hexadecyltrimethylammonium
57-09-0 Xn, N 22-37/38-41-50 26-39-61
bromide
Imidazole 288-32-4 C 22-34 26-36/37/39-45
Iron(III) chloride hexahydrate 10025-77-1 Xn 22-38-41 26-39
? M-600 ?br>
Jeffamine 77110-54-4 Xn 21/22-36/38 26-36/37
Lithium sulfate monohydrate 10102-25-7 Xn 22
Magnesium acetate tetrahydrate 16674-78-5 22-24/25
Magnesium chloride hexahydrate 7791-18-6
Magnesium formate dihydrate 557-39-1
Magnesium sulfate heptahydrate 10034-99-8
MES monohydrate 145224-94-8 Xi 36/37/38 26-36
Nickel(II) chloride hexahydrate 7791-20-0 T, N 45-25-36/38-43-50/53 53-36/37-45-60-61
Polyethylene glycol 400 25322-68-3
Polyethylene glycol 1,000 25322-68-3
Polyethylene glycol 1,500 25322-68-3
Polyethylene glycol 4,000 25322-68-3
Polyethylene glycol 6,000 25322-68-3
Polyethylene glycol 8,000 25322-68-3
Polyethylene glycol 10,000 25322-68-3
Polyethylene glycol 20,000 25322-68-3
Polyethylene glycol monomethyl
9004-74-4
ether 550
Polyethylene glycol monomethyl
9004-74-4
ether 2,000
Polyethylene glycol monomethyl
9004-74-4
ether 5,000
Potassium phosphate monobasic 7778-77-0
Potassium sodium tartrate
6381-59-5 22-24/25
tetrahydrate
Sodium acetate trihydrate 6131-90-4
Sodium cacodylate trihydrate 6131-99-3 T, N 23/25-50/53 20/21-28-45-60-61
Sodium chloride 7647-14-5
Sodium citrate tribasic dihydrate 6132-04-3
Sodium formate 141-53-7
Sodium phosphate monobasic
10049-21-5
monohydrate
tert-Butanol 75-65-0 F, Xn 11-20 9-16
Tris 77-86-1 Xi 36 26
TRIS hydrochloride 1185-53-1 Xi 36/37/38 26-36
Zinc acetate dihydrate 5970-45-6 Xn, N 22-36-50/53 26-60-61
Zinc sulfate heptahydrate 7446-20-0 Xn, N 22-41-50/53 22-26-39-46-60-61
N/A = NOT AVAILABLE
TM
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(CONTINUED) - SECTION 15 - Regulatory Information
UNITED STATES REGULATORY INFORMATION
?SARA LISTED: No
?SARA LISTED: For additional information on toxicity, please refer to SECTION 2.
?TSCA INVENTORY ITEM: N/A
CANADA REGULATORY INFORMATION
?WHMIS Classification: This product has been classified in accordance with the hazard criteria of the CPR,
and the MSDS contains all the information required by the CPR.
SECTION 16 - Other Information
DISCLAIMER
?For R&D use only. Not for drug, household, or other use.
WARRANTY
?The above information is believed to be correct but does no purport to be all inclusive and shall be used only
as a guide. The information in this document is based on the present state of our knowledge and is applicable
to the product with regard to appropriate safety precautions. It does not represent any guarantee of the proper-
ties of this product. Hampton Research Corp., shall not be held liable for any damage resulting from handling
or from contact with the above product. See reverse side of invoice or packing slip for additional terms and
conditions of sale.
?License granted to make unlimited paper copies for internal use only.
?1991-2009 Hampton Research Corp.
TM
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