Material Safety Data Sheet
Zep Inc. Section 1. Chemical Product and Company Identification
1310 Seaboard Industrial Blvd.
Product name
Atlanta, GA 30318 NON-ACID DEODORIZING TOILET
1-877-793-7776
BOWL CLEANER
Toilet Bowl & Urinal Cleaner
Product use
R003
Product code
Date of issue Supersedes
08/12/08
This product is a registered pesticide. EPA ID No. 1270-235
Emergency Telephone Numbers
For MSDS Information:
Compliance Services 1-877-793-7776
For Medical Emergency
INFOTRAC: (877) 541-2016 Toll Free - All Calls
Recorded
For Transportation Emergency
CHEMTREC: (800) 424-9300 - All Calls Recorded
In the District of Columbia (202) 483-7616
Prepared By
Compliance Services
1420 Seaboard Industrial Blvd.
Atlanta, GA 30318
Section 2. Hazards Identification
Emergency overview *Hazard Determination System (HDS): Health, Flammability, Reactivity
DANGER 2 0 0
CAUSES EYE AND SKIN BURNS.
MAY BE HARMFUL IF ABSORBED THROUGH SKIN OR IF SWALLOWED.
NOTE: MSDS data pertains to the product as delivered in the original shipping container(s). Risk of adverse effects are lessened by following all
prescribed safety precautions, including the use of proper personal protective equipment.
Dermal contact. Eye contact.
Acute Effects Routes of Entry
Causes eye burns. Eye exposure may cause severe and permanent eye injury (blindness).
Eyes
Skin contact may produce burns. May be harmul if absorbed through the skin. Skin inflammation
Skin
is characterized by itching, scaling, reddening or, occasionally, blistering.
Inhalation Avoid inhalation of vapor, spray or mist. Over-exposure by inhalation may cause respiratory
irritation.
Ingestion May be harmful if swallowed. May cause burns to mouth, throat, and stomach.
Repeated or prolonged contact with spray or mist may produce chronic eye irritation and severe
Chronic effects
skin irritation. Repeated or prolonged exposure to spray or mist may produce respiratory tract
irritation, leading to frequent attacks of bronchial infection.
Carcinogenicity
Additional Information: See Toxicological Information (Section 11)
Section 3. Composition/Information on Ingredients
Name of Hazardous Ingredients CAS number % by Weight
TETRASODIUM ETHYLENEDIAMINE TETRAACETATE; ethylenediamine tetraacetic 64-02-8 10 - 20
acid; tetrasodium salt
QUATERNARY AMMONIUM CHLORIDES; blend of alkyl dimethylbenzyl ammonium 68391-01-5; 68956- <5
chlorides, alkyl dimethyl ethylbenzyl ammonium chlorides, and ethanol 79-6; 64-17-5
Section 4. First Aid Measures
Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and
Eye Contact
remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention immediately.
Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Wash contaminated
Skin Contact
clothing thoroughly with water before removing or wear gloves. Continue to rinse for at least 10 minutes. Wash
clothing before reuse. Get medical attention if irritation develops.
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Inhalation
Get medical attention.
Page: 1/3
Product Name NON-ACID DEODORIZING TOILET
Material Safety Data Sheet
Product code R003
BOWL CLEANER
Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be
Ingestion
kept low so that vomit does not enter the lungs. Never give anything by mouth to an unconscious person. If
affected person is conscious, give plenty of water to drink. Get medical attention immediately.
National Fire Protection Association (U.S.A.)
Section 5. Fire Fighting Measures
0
None.
Flash Point 2 0
Flammable Limits Not applicable
Non-combustible.
Flammability
In a fire or if heated, a pressure increase will occur and the container may burst. May emit toxic
Fire hazard
fumes under fire conditions.
Use an extinguishing agent suitable for the surrounding fire. Fire-fighters should wear
Fire-Fighting
appropriate protective equipment. Do not release runoff from fire to sewers or waterways.
Procedures
Section 6. Accidental Release Measures
Put on appropriate personal protective equipment (see section 8). Move containers from spill area. Dilute with
Spill Clean up
water and mop up if water-soluble or absorb with an inert dry material and place in an appropriate waste disposal
container. Finish cleaning by spreading water on the contaminated surface and dispose of according to local and
regional authority requirements.
Section 7. Handling and Storage
Put on appropriate personal protective equipment (see section 8). Avoid contact with eyes, skin and clothing. Do not
Handling
ingest. Do not reuse container. Apply this product only as specified on the label. Wash thoroughly after handling.
Keep container tightly closed and sealed until ready for use. Keep container in a cool, well-ventilated area. Store
Storage
between the following temperatures: 40癋 - 120癋 (4.4癈 - 49癈). Keep away from food, drink and animal feeding
stuffs. Keep out of the reach of children.
Section 8. Exposure Controls/Personal Protection
Product name Exposure limits
No exposure limit value known.
Personal Protective Equipment (PPE)
Chemical splash goggles or face shield.
Eyes
Wear appropriate protective clothing to prevent skin contact.
Body
Recommended: Rubber gloves. Neoprene gloves. Wear apron or
coverall if there is a risk of exposure to splashes.
Respiratory Use with adequate ventilation. A respirator is not needed under normal and
intended conditions of product use.
Section 9. Physical and Chemical Properties
Liquid. [Viscous liquid.] Color Blue.
Physical State
9.5-10.5 Odor Floral.
pH
100癈 (212癋) Vapor Pressure Not determined.
Boiling Point
1.06 Vapor Density Not determined.
Specific Gravity
Easily soluble in the following materials: cold water Evaporation Rate <1 (Water = 1)
Solubility
and hot water.
VOC (Consumer) 5.93 (g/l). 0.05 lbs/gal (0.56%)
Section 10. Stability and Reactivity
The product is stable.
Stability and Reactivity
No incompatible product according to our database.
Incompatibility
Hazardous Polymerization Will not occur.
Hazardous Decomposition Products carbon oxides (CO, CO2), sulfur oxides (SO2, SO3 etc.)
Page: 2/3
Product Name NON-ACID DEODORIZING TOILET
Material Safety Data Sheet
Product code R003
BOWL CLEANER
Section 11. Toxicological Information
Acute Toxicity
Exposure
Product/ingredient name Result Species Dose
Tetrasodium Ethylenediamine Tetraacetate LD50 Oral Rat 4100 mg/kg -
Quaternary Ammonium Chlorides LD50 Dermal Rabbit >2000 mg/kg -
LD50 Oral Rat >500 mg/kg -
Section 12. Ecological Information
No known significant effects or critical hazards.
Environmental Effects
Aquatic Ecotoxicity
Product/ingredient name Test Result Species Exposure
Quaternary Ammonium Chlorides - Acute EC50 0.058 mg/L Daphnia 48 hours
- Acute LC50 0.52 mg/L Fish - Bluegill. 96 hours
Section 13. Disposal Considerations
Waste Information
Waste must be disposed of in accordance with federal, state and local environmental control regulations. Consult your local or
regional authorities for additional information.
Waste Stream Non-hazardous waste
Section 14. Transport Information
Regulatory information UN number Proper shipping name Classes PG* Label
-
DOT Classification Not regulated. Not a DOT controlled material -
(United States).
-
Not determined.
IMDG Class
NOTE: DOT classification applies to most package sizes. For specific container size classifications or for size exceptions, refer to
the Bill of Lading with your shipment.
PG* : Packing group
Section 15. Regulatory Information
U.S. Federal Regulations
SARA 313 toxic chemical notification and release reporting:
No products were found.
Clean Water Act (CWA) 307: No products were found.
Clean Water Act (CWA) 311: No products were found.
Clean Air Act (CAA) 112 regulated toxic substances: No products were found.
All Components of this product are listed or exempt from listing on TSCA Inventory.
State Regulations
No products were found.
California Prop 65
Section 16. Other Information
To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its subsidiaries assumes any
liability whatsoever for the accuracy or completeness of the information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution.
Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist.
*NOTE: Hazard Determination System (HDS) ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks
Although these ratings are not required on MSDSs under 29 CFR 1910.1200, the preparer may choose to provide them. HDS ratings are to be used with a fully implemented program to
relay the meanings of this scale.
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