MATERIAL SAFETY DATA SHEET
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1. Chemical Product and Company Identification
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51649 Series
Material name
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Inkjet printing
Use of the preparation
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04
Version #
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19-Mar-2008
Revision date
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Mixture
CAS #
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Hewlett-Packard Company
Manufacturer information
1000 NE Circle Boulevard
Corvallis, OR 97330-4239 US
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Hewlett-Packard health effects line
1-800-457-4209
(Toll-free within the US)
1-503-494-7199
(Direct)
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General information telephone number
1-800-474-6836
HP Customer Care Line
1-800-474-6836
(Toll-free)
1-208-323-2551
(Direct)
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Mar 18, 2008
Date prepared
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264182
MSDS number
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2. Hazards Identification
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Contact with skin and eyes may result in irritation.
Emergency overview
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Any potential hazards are presumed to be due to exposure to the components.
Acute health effects
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Skin contact
1,5-pentanediol
Contact with skin may result in irritation.
2-pyrrolidone
Contact with skin may result in irritation.
Alkyldiol ethoxylate
Contact with skin may result in severe irritation.
Ethyl alkyldiol
Contact with skin may result in mild irritation.
Metal nitrate # 1
Contact with skin may result in irritation.
Metal nitrate # 2
Contact with skin may result in irritation.
Substituted napthalenesulfonate salt #10
May cause sensitization by skin contact.
Substituted triphenylmethane salt #1
Contact with skin may result in irritation.
Material name 51649 SERIES MSDS US
Creation date Jul 07, 2003 Version number 4 1/ 8
MATERIAL SAFETY DATA SHEET
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Eye contact
1,5-pentanediol
Contact with eyes may result in irritation.
2-pyrrolidone
Contact with eyes may result in irritation.
Alkyldiol ethoxylate
Contact can cause moderate to severe irritation and possible injury to the eyes.
Ethyl alkyldiol
Contact with eyes may result in mild irritation.
Metal nitrate # 1
Contact with eyes may result in irritation.
Metal nitrate # 2
Contact with eyes may result in irritation.
Substituted napthalenesulfonate salt #10
Risk of serious damage to eyes.
Substituted triphenylmethane salt #1
Contact with eyes may result in irritation.
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Inhalation
2-pyrrolidone
Inhalation may result in respiratory irritation.
Metal nitrate # 1
Inhalation may result in respiratory irritation.
Metal nitrate # 2
Inhalation may result in respiratory irritation.
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Ingestion
2-pyrrolidone
Ingestion may result in nausea, vomiting and diarrhea.
Alkyldiol ethoxylate
Ingestion may cause irritation of mouth, throat, nausea, vomiting and diarrhea.
arylazopyrazolesulfonate salt # 1
Toxic if swallowed.
Diethylene glycol
Harmful if swallowed. May cause kidney and liver damage. May depress the central nervous
system.
Metal nitrate # 1
Contains nitrate salts, may cause methemoglobinemia.
Metal nitrate # 2
Contains nitrate salts, may cause methemoglobinemia.
Substituted phthalocyanine salt # 2
Harmful if swallowed.
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Potential health effects
Potential routes of overexposure to this product are skin and eye contact
Routes of exposure
Inhalation of vapor and ingestion are not expected to be significant routes of exposure for this
product under normal use conditions.
Complete toxicity data are not available for this specific formulation
Material name 51649 SERIES MSDS US
Creation date Jul 07, 2003 Version number 4 2/ 8
MATERIAL SAFETY DATA SHEET
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Cyan ink:
Chronic health effects
Substituted phthalocyanine salt: Prolonged ingestion exposure may cause serious damage to
health.
Yellow ink:
Arylazopyrazolesulfonate salt: Prolonged ingestion exposure may cause serious damage to
health.
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None of the components present in this formulation at concentrations equal to or greater than
Carcinogenicity
0.1% are listed by EU, MAK, IARC, NTP or OSHA.
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3. Composition / Information on Ingredients
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Component/Substance CAS Number % By Weight
Cyan ink
Water 7732-18-5 > 60
1,5-pentanediol 111-29-5 < 10
2-pyrrolidone 616-45-5 < 7.5
Ethyl alkyldiol Proprietary < 7.5
Metal nitrate # 2 Proprietary < 7.5
Substituted phthalocyanine salt # 2 Proprietary < 5
Alkyldiol ethoxylate Proprietary < 5
Substituted triphenylmethane salt #1 Proprietary < 2.5
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Magenta ink
Water 7732-18-5 > 60
1,5-pentanediol 111-29-5 < 10
2-pyrrolidone 616-45-5 < 7.5
Ethyl alkyldiol Proprietary < 7.5
Metal nitrate # 2 Proprietary < 7.5
Substituted napthalenesulfonate salt #10 Proprietary < 5
Alkyldiol ethoxylate Proprietary < 5
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Yellow ink
Water 7732-18-5 > 70
Ethyl alkyldiol Proprietary < 10
Metal nitrate # 1 Proprietary < 7.5
2-pyrrolidone 616-45-5 < 5
Diethylene glycol 111-46-6 < 5
arylazopyrazolesulfonate salt # 1 Proprietary < 5
Alkyldiol ethoxylate Proprietary < 5
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This ink supply contains an aqueous ink formulation.
Composition comments
This product has been evaluated using criteria specified in 29 CFR 1910.1200 (Hazard
Communication Standard).
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4. First Aid Measures
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First aid procedures
Do not rub eyes. Immediately flush with large amounts of clean, warm water (low pressure)
Eye contact
for at least 15 minutes or until particles are removed. If irritation persists get medical attention.
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Wash affected areas thoroughly with mild soap and water. Get medical attention if irritation
Skin contact
develops or persists.
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Remove to fresh air. If symptoms persist, get medical attention.
Inhalation
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If ingestion of a large amount does occur, seek medical attention.
Ingestion
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5. Fire Fighting Measures
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> 200 癋 (> 93.3 癈); Pensky-Martens Closed Cup
Flash point and method
Material name 51649 SERIES MSDS US
Creation date Jul 07, 2003 Version number 4 3/ 8
MATERIAL SAFETY DATA SHEET
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Refer to section 10.
Hazardous combustion
products
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None known.
Flammable properties
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Extinguishing media
Dry chemical, CO2, water spray or regular foam.
Suitable extinguishing
media
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None known.
Unsuitable extinguishing
media
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None known.
Unusual fire and explosion
hazard
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None established.
Special firefighting
procedures
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6. Accidental Release Measures
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Wear appropriate personal protective equipment.
Personal precautions
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Do not let product enter drains. Do not flush into surface water or sanitary sewer system.
Environmental precautions
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Dike the spilled material, where this is possible. Absorb with inert absorbent such as dry clay,
Methods for containment
sand or diatomaceous earth, commercial sorbents, or recover using pumps.
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Soak up with inert absorbent material.
Methods for cleaning up
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Soak up with inert absorbent material. Slowly vacuum or sweep the material into a bag or
Other information
other sealed container. Dispose of in compliance with federal, state, and local regulations. See
also section 13 Disposal considerations.
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7. Handling and Storage
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Avoid contact with skin, eyes and clothing.
Handling
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Keep out of the reach of children. Keep away from excessive heat or cold.
Storage
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8. Exposure Controls/Personal Protection
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Exposure limits have not been established for this product.
Exposure guidelines
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Personal protective equipment
Use personal protective equipment to minimize exposure to skin and eye.
General
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Not required under intended use.
Eye / face protection
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Protected gloves not required under intended use.
Skin protection
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For use other than intended use (such as in the event of a large spill), goggles and respirators
Respiratory protection
may be required.
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Handle in accordance with good industrial hygiene and safety practice.
General hygeine
considerations
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9. Physical & Chemical Properties
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Cyan, magenta, yellow
Color
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Not available
Odor threshold
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Liquid.
Physical state
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6.1 - 8.4
pH
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Not available
Melting point
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Not available
Freezing point
Material name 51649 SERIES MSDS US
Creation date Jul 07, 2003 Version number 4 4/ 8
MATERIAL SAFETY DATA SHEET
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Not determined
Boiling point
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> 200 癋 (> 93.3 癈); Pensky-Martens Closed Cup
Flash point
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Not determined
Evaporation rate
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Not available.
Flammability
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Not available
Flammability limits in air,
upper, % by volume
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Not determined
Flammability limits in air,
lower, % by volume
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Not determined
Vapor pressure
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> 1 (air = 1.0)
Vapor density
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1 - 1.2
Specific gravity
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Not available
Relative density
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Soluble in water
Solubility in water
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Not available
Partition coefficient
(n-octanol/water)
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Not available
Auto-ignition temperature
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Not available
Decomposition temperature
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<3%
VOC
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> 2 cp
Viscosity
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10. Chemical Stability & Reactivity Information
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Stable under recommended storage conditions.
Chemical stability
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Incompatible with strong bases and oxidizing agents.
Incompatible materials
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Upon decomposition, this product may yield gaseous nitrogen oxides, carbon monoxide,
Hazardous decomposition
carbon dioxide and/or low molecular weight hydrocarbons.
products
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Will not occur.
Possibility of hazardous
reactions
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11. Toxicological Information
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Oral toxicity
Magenta ink
Not classified for acute oral toxicity according to EU Directive 67/548/EEC and 1999/45/EC.
Yellow ink
LD50/oral/rat >2500 mg/kg (OECD 423)
Not classified for acute oral toxicity according to EU Directive 67/548/EEC and 1999/45/EC.
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Eye irritation
Magenta ink
Mild irritant in rabbit (OECD 405)
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Sensitization
Magenta ink
Non-sensitizer in guinea pig (OECD 406) (OECD 406)
Material name 51649 SERIES MSDS US
Creation date Jul 07, 2003 Version number 4 5/ 8
MATERIAL SAFETY DATA SHEET
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12. Ecological Information
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Aquatic toxicity
Cyan ink
LC50/96h/Fathead minnows =< 400 mg/L
Static acute toxicity (trout), survival (100 mg/L) = 67%
Static acute toxicity (trout), survival (10 mg/L) = 100%
Magenta ink
LC50/96h/Fathead minnows =< 400 mg/L
Static acute toxicity (trout), survival (100 mg/L) = 100%
Static acute toxicity (trout), survival (10 mg/L) = 100%
Yellow ink
LC50/96h/Fathead minnows =< 400 mg/L
Static acute toxicity (trout), survival (100 mg/L) = 23%
Static acute toxicity (trout), survival (10 mg/L) = 93%
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Not available
Persistence and degradability
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13. Disposal Considerations
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Dispose of in compliance with federal, state, and local regulations.
Disposal instructions
HP's Planet Partners (trademark) supplies recycling program enables simple, convenient
recycling of HP original inkjet and LaserJet supplies. For more information and to determine if
this service is available in your location, please visit http://www.hp.com/recycle.
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14. Transportation Information
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Department of Transportation (DOT) Requirements
Not regulated as hazardous goods.
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IATA
Not applicable
Proper shipping name
Not applicable
Hazard class
None
UN number
N/A
Packing group
None
Packaging exceptions
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15. Regulatory Information
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US TSCA 12(b): Does not contain listed chemicals.
US federal regulations
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CERCLA (Superfund) reportable quantity
None
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Superfund Amendments and Reauthorization Act of 1986 (SARA)
Immediate Hazard - No
Hazard categories
Delayed Hazard - No
Fire Hazard - No
Pressure Hazard - No
Reactivity Hazard - No
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No
Section 302 extremely
hazardous substance
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No
Section 311 hazardous
chemical
Material name 51649 SERIES MSDS US
Creation date Jul 07, 2003 Version number 4 6/ 8
MATERIAL SAFETY DATA SHEET
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All chemical substances in this HP product have been notified or are exempt from notification
International regulations
under chemical substances notification laws in the following countries: US (TSCA), EU
(EINECS/ELINCS), Switzerland, Canada (DSL/NDSL), Australia, Japan, Philippines, South Korea,
New Zealand, and China.
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State regulations
U.S. - Pennsylvania - RTK (Right to Know) List
Metal nitrate # 2 Proprietary Present
U.S. - New Jersey - Right to Know Hazardous Substance List
Metal nitrate # 2 Proprietary sn 1143
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16. Other Information
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Health: 1
HMIS?ratings
Flammability: 1
Physical hazard: 0
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Health: 1
NFPA ratings
Flammability: 1
Instability: 0
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Mar 18 2008 5:28PM
Issue date
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4
Revision
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Mar 13 2008 7:22PM
Replaces sheet dated
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This Safety Data Sheet document is provided without charge to customers of Hewlett-Packard
Disclaimer
Company. Data is the most current known to Hewlett-Packard Company at the time of
preparation of this document and is believed to be accurate. It should not be construed as
guaranteeing specific properties of the products as described or suitability for a particular
application. This document was prepared to the requirements of the jurisdiction specified in
Section 1 above and may not meet regulatory requirements in other countries.
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8. Exposure Controls/Personal Protection: Respiratory
MSDS sections updated
Material name 51649 SERIES MSDS US
Creation date Jul 07, 2003 Version number 4 7/ 8
MATERIAL SAFETY DATA SHEET
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Explanation of abbreviations
American Conference of Governmental Industrial Hygienists
ACGIH
Chemical Abstracts Service
CAS
Comprehensive Environmental Response Compensation and Liability Act
CERCLA
Code of Federal Regulations
CFR
Cleveland Open Cup
COC
Department of Transportation
DOT
Emergency Planning and Community Right-to-Know Act (aka SARA)
EPCRA
International Agency for Research on Cancer
IARC
National Institute for Occupational Safety and Health
NIOSH
National Toxicology Program
NTP
Occupational Safety and Health Administration
OSHA
Permissible Exposure Limit
PEL
Resource Conservation and Recovery Act
RCRA
Recommended
REC
Recommended Exposure Limit
REL
Superfund Amendments and Reauthorization Act of 1986
SARA
Short-Term Exposure Limit
STEL
Toxicity Characteristics Leaching Procedure
TCLP
Threshold Limit Value
TLV
Toxic Substances Control Act
TSCA
Volatile Organic Compounds
VOC
Material name 51649 SERIES MSDS US
Creation date Jul 07, 2003 Version number 4 8/ 8
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