Olean Tile MSDS (Prepared 09/25/07) Page 1 of 5
MATERIAL SAFETY DATA SHEET
OLEAN TILE
Keystone Shapes, Unglazed & Blends Series
DAL-TILE CORPORATION
Contains
Pre-Consumer
Dal-Tile Group
Recycled Material
P.O. Box 170130
Dallas, Texas 75217
EMERGENCY ASSISTANCE: Environmental, Health and Safety Department
Richard Ray - (214) 309-4295
1-800-933-TILE; (214) 398-1411 (24-hour number)
Tile products manufactured by Dal-Tile are environmental preferable building materials when compared to other
floor/wall coverings. As defined by guidelines issued by the Environmental Protection Agency, the American Society
for Testing & Materials, and the Federal Trade Commission, Olean Tile is one of the most environmentally friendly
building materials you can buy today. Should you desire additional information, please direct your inquiry to the
address above.
1. PRODUCT IDENTIFICATION
Common Name: Mosaic Tile
Synonyms: Ceramic Tile and wares
Chemical Name: None
Chemical Family: Natural inorganic products
Chemical Formula: Not applicable to tiles.
CAS Reg. No.: Not applicable to the tiles. Listed for individual components in Section 2.
This document has been prepared in accordance with the Occupational Safety and Health Administration (OSHA)
Hazard Communication standard, 29 Code of Federal Regulations (CFR) 1910.1200, and American National Standard
for Hazardous Industrial Chemicals, ANSI Z400.1-1993, Material Safety Data Sheets - Preparation.
2. COMPOSITION/INFORMATION ON INGREDIENTS
Tile products are mixtures of predominately Clays and other naturally-occurring mineral, that have been mixed with
water and fired in a high temperature kiln.
Tiles are manufactured in various shapes, sizes, and colors.
These products do not contain asbestos.
Under normal condition these products do not release hazardous materials after installation and are not considered
hazardous waste should disposal be necessary..
Estimated
CAS % OSHA NIOSH ACGIH
*
Units
Composition Number By Wt. PEL IDLH TLV
__________________________________________________________________________________________
Crystalline silica as quartz 14808-60-7 14-18
mg/m3
- respirable fraction 10 25 0.1
%SiO2+2
mg/m3
- total dust 30 N.E. N.E.
%SiO2+2
2. COMPOSITION/INFORMATION ON INGREDIENTS (Cont.)
Estimated
Olean Tile MSDS (Prepared 09/25/07) Page 2 of 5
CAS % OSHA NIOSH ACGIH ACGIH
*
Composition Number By Wt. PEL IDLH TLV STEL Units
____________________________________________________________________________________________
Clays 1332-58-7 30-40
mg/m3
- respirable fraction 5 N.E 2 N.E
- total dust** mg/m3
15 N.E 10 N.E
Nepheline syenite 37244-96-5 45
**
mg/m3
- respirable fraction 5 N.E. N.E. N.E
**
mg/m3
- total dust 15 N.E. N.E. N.E
____________________________________________________________________________________________
*
2001 Edition, respirable fraction to be determined as per Appendix D of ACGIH TLV.
**
Covered as particles not otherwise regulated per OSHA and particles not otherwise classified per ACGIH.
N.D. - Not determined
N.E. - Not established
3. HAZARDS IDENTIFICATION
3.1 Summary
Tile products are mixtures of predominantly clays and other natural occurring minerals that have been mixed with water
and fired in a high temperature kiln. The tiles are odorless, stable, non-flammable, and pose no immediate hazard to
health. Respiratory, hand and eye protection may be needed to prevent excess exposure to airborne particulates if dust
is produced by cutting tiles or if dust is produced by any other operations, including removal.
3.2 Potential Health Effects
Primary Routes of Exposure
None for intact tile. Inhalation and potential eye exposure to eyes, hands, or other body parts if contact is made with
broken, and/or during procedures involving the cutting of tiles, and/or for operations involving the removal of installed
tiles.
Acute Effects
No acute effects from exposure to intact tile are known. Working with broken or cut tile produces a potential for cuts
to the hands and exposed body parts. Acute effects such as eye irritation may occur if associated with high dust
operations such as dry cutting tile or during the removal of tile surfaces. In very rare cases, symptoms of acute silicosis,
a form of silicosis (a nodular pulmonary fibrosis) associated with exposure to respirable crystalline silica, may develop
following acute exposure to extremely dusty environments generated from tile dust. Signs such as labored breathing
and early fatigue may indicate silicosis; however, these symptoms can arise from many other causes.
Chronic Effects
No chronic effects are known for exposure to intact tile. Long-term, continual exposure to respirable crystalline silica
at or above allowable occupational exposure limits may lead to the development of silicosis (a nodular pulmonary
fibrosis), and are associated with pulmonary tuberculosis, bronchitis, emphysema, and other airway diseases. This type
of exposure may also be related to the development of autoimmune disorders, chronic renal disease, and other adverse
health effects. Recent epidemiologic studies demonstrate that workers exposed to elevated silica concentrations have a
significant risk of developing chronic silicosis. Signs such as labored breathing and early fatigue may indicate
silicosis; however, these symptoms can arise from many other causes.
3.2 Potential Health Effects (Continued)
Potential Adverse Interactions
Olean Tile MSDS (Prepared 09/25/07) Page 3 of 5
Silicosis may be complicated by severe mycobacterial or fungal infections and result in tuberculosis (TB).
Epidemiologic studies have established that silicosis is a risk factor for developing TB. Any existing respiratory or
pulmonary diseases may be complicated by exposure to respirable crystalline silica. Smoking may increase the risk of
adverse effects if done in conjunction with occupational exposure to silica at or above allowable limits.
Carcinogen Status
Respirable crystalline silica is classified by the International Agency for Research on Cancer (IRAC) as a Group I
Carcinogen (carcinogenic to humans). The National Toxicology Program (9th Report) lists respirable crystalline silica
as Known to be a Human Carcinogen. USDOL/OSHA and NIOSH have recommended that crystalline silica be
considered a potential occupational carcinogen.
Overview of Animal Testing Data
Short term experimental studies of rats have found that intratracheal instillation of quartz particles leads to the
formation of discrete silicotic nodules in rats, mice and hamsters.
Oral (silica) Lethality
LD50 Rat oral >22,500 mg/kg
LD50 Mouse oral >15,000 mg/kg
LC50 Carp >10,000 mg/l (per 72 hr)
4. FIRST AID MEASURES
Eyes: Immediately flush eyes with large amounts of water for at least 15 minutes if dust gets in eyes.
Get medical attention if irritation persists.
Skin: Wash thoroughly after working with tiles.
Inhalation: Remove to fresh air if exposed to large amounts of tile dust.
Administer artificial respiration if breathing has stopped. Keep victim at rest. Call for prompt
medical attention.
Ingestion: Not applicable for intact tiles.
Have emergency eyewash station available in area where tiles are cut.
5. FIRE-FIGHTING MEASURES AND INFORMATION
Flash Point (Method Used): Not applicable.
Autoignition Temperature: Not applicable.
Flammable Limits (% by Volume in Air): LEL - not applicable.
UEL - not applicable.
Fire Extinguishing Media: None required. Non-flammable.
Special Fire Fighting Procedures: None required.
Fire and Explosion Hazards: None.
6. ACCIDENTAL RELEASE MEASURES
If material is released or spilled, avoid creating excessive dust. Clean up dust by vacuum or damp sweeping.
7. HANDLING AND STORAGE
Olean Tile MSDS (Prepared 09/25/07) Page 4 of 5
When cutting, grinding or removing, use equipment with integral dust collection and/or use local exhaust ventilation.
Use wet cutting methods to reduce generation of dust. Use respiratory protection in the absence of effective
engineering controls.
Shelf life is unlimited.
Do not store near acids. If tiles contact some acids, damage/discoloration to the surface may occur.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Ventilation: Use adequate ventilation to keep exposure to dust below recommended exposure levels. Avoid inhalation
of dust. The highest probability of silica exposure occurs during dry cutting or removal of installed tile. Wet cutting
methods are recommended.
Respiratory Protection: Use of a properly fitted NIOSH/MSHA approved particulate respirator is recommended when
cutting tiles or during the removal of tile surfaces.
Eye Protection: Use dust-proof goggles or safety glasses with side shields. Contact lenses may absorb irritants. Do not
wear contact lenses in work areas.
Skin Protection: Cotton or leather work gloves should be worn when cutting this product to minimize skin exposure to
dust and/or cuts. Wash hands prior to eating, drinking, or smoking, and at the end of the work shift, after cutting
operations are conducted.
NOTE: Personal protection information in Section 8 is based on general information for normal uses and conditions.
Where special or unusual uses or conditions exist, it is suggested that the assistance of an industrial hygienist
or other qualified professional be sought.
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance: Brittle solid; color may vary.
Odor: Odorless.
Not available (>2200 oF).
Melting Point:
Boiling Point: Not applicable.
Vapor Pressure: Not applicable.
Vapor Density (Air = 1): Not applicable.
Solubility in Water: Insoluble.
Specific Gravity (H2O = 1): 1.2 to 1.5
Percent Volatile by Volume: Not applicable.
Evaporation Rate (Ethyl Ether = 1): Not applicable.
Viscosity: Not applicable.
10. STABILITY AND REACTIVITY
Stability: Stable in current form.
Conditions to Avoid: Avoid contact with acids (e.g., acetic, hydrofluoric, etc.)
Incompatibility (Materials to Avoid): Avoid contact with acids (e.g., acetic, hydrofluoric, etc.)
Hazardous Polymerization: Will not occur.
Hazardous Decomposition Products: None.
11. DISPOSAL CONSIDERATIONS
Waste should be disposed of in a landfill certified to accept such materials in accordance with federal, state, and local
regulations.
12. TRANSPORTATION INFORMATION
Olean Tile MSDS (Prepared 09/25/07) Page 5 of 5
D.O.T. Shipping Name: Not applicable
Hazard Class: Non-regulated (for disposal purposes material is non-hazardous Class III regulated
material)
ID Number: Not applicable
Marking: Not applicable
Label: None
Placard: None
Hazardous Substance/RQ: Not Applicable
Shipping Description: Porcelain Ceramic Tiles
Packaging References: None
13. REGULATORY INFORMATION
This product and/or its components have been previously introduced into U.S. commerce and is listed in the Toxic
Substances Control Act (TSCA) Inventory of Chemicals in Commerce. Hence, it is subject to all applicable provisions
and restrictions under TSCA 40 CFR Section 721 and 723.250.
This tile contains <1 percent by weight each of the following elements, which are SARA 313 Recordable:
Antimony, Arsenic, Barium, Beryllium, Cadmium, Cobalt, Chromium, Copper, Manganese, Mercury, Nickel, Lead,
Silver, Thallium, Tin, Titanium, Vanadium, and Zinc.
This product or its components meets the following hazard definition(s) as defined by the Occupational Safety and
Health Hazard Communication Standard (29 CFR Section 1910.1200):
Combustible Liquid Flammable Aerosol Oxidizer
Compressed Gas Explosive Pyrophoric
Flammable Gas _X Health Hazard (Sections 3 and 11) Unstable
Flammable Liquid Organic Peroxide Water Reactive
Flammable Solid
_Based on information presently available, this product does not meet any of the hazard definitions of 29 CFR Section
1910.1200.
Title 22 Division 2, California Code of Regulation Chapter 3 (Proposition 65): This product contains a chemical or
chemicals known to the State of California to cause cancer and/or birth defects or other reproductive harm.
Note: The information in this data sheet provides information related to the potential hazards associated with dusts
which may be produced during cutting or otherwise changing the shape of the tile during installation and/or removal.
14. ADDITIONAL INFORMATION
Hazardous Material Identification System
HMIS: Health: 0 Fire: 0 Reactivity: 0
National Fire Protection Association
NFPA: Health: 0 Fire: 0 Reactivity: 0
|