3M Canada Company
1840 Oxford Street East, Post Office Box 5757
London, Ontario N6A 4T1
Medical Emergency Telephone: (519) 451-2500, Ext. 2222
Transportation Emergency Telephone (CANUTEC): (613) 996-6666
=======================================================================
Material Safety Data Sheet
=======================================================================
Document id : 19-5320-7 Issue date : 2006/06/27
Version : 4.00 Supersedes date : 2004/09/10
Copyright, 1997, 3M Canada Company. All rights reserved. Copying
and/or downloading of this information for the purpose of properly
utilizing 3M products is allowed provided that: (1) the information
is copied in full with no changes unless prior written agreement is
obtained from 3M, and (2) neither the copy nor the original is resold
or otherwise distributed with the intention of earning a profit
thereon.
Prepared by: Corporate Regulatory Services, 3M Canada Company
Telephone: (800) 364-3577, Fax: (800) 603-7758, Web Site: www.3M.ca
-----------------------------------------------------------------------
1 Product Identification
-----------------------------------------------------------------------
Tradename:
3M (TM) RUBBER & VINYL SPRAY ADHESIVE 80 (CANADA)
Product ID:
CS-0406-7142-5
Intended Use of Product:
Adhesive;
Division:
3M CANADA COMPANY
-----------------------------------------------------------------------
2 Composition/Information on Ingredients
-----------------------------------------------------------------------
Ingredient Name CAS Number Percentage
------------------------------------- ------------------ -------------
METHYL ACETATE 79-20-9 15 - 31
DIMETHYL ETHER 115-10-6 10 - 28
NON-VOLATILE COMPONENTS Trade Secret 10 - 20
CYCLOHEXANE 110-82-7 10 - 14
1,2-TRANS-DICHLOROETHYLENE 156-60-5 5-9
TOLUENE 108-88-3 3-6
P-TERT-BUTYLPHENOL-FORMALDEHYDE RESIN 25085-50-1 1-5
ETHYL NONAFLUOROISOBUTYL ETHER 163702-06-5 1-2
ETHYL NONAFLUOROBUTYL ETHER 163702-05-4 0.5 - 1.5
NOTE:
NONVOLATILE COMPONENT is a non-hazardous Trade Secret material
3M (TM) RUBBER & VINYL SPRAY ADHESIVE 80 (CANADA) Page 2 of 10
-----------------------------------------------------------------------
according to WHMIS criteria.
Each percentage is expressed as the ratio of the weight of the
ingredient to the weight of the controlled product.
-----------------------------------------------------------------------
3 Hazards Identification
-----------------------------------------------------------------------
Critical Hazards:
Aerosol container contains flammable gas under pressure.
Moderate Eye Irritation: Signs/symptoms may include redness,
swelling, pain, tearing, and blurred or hazy vision.
Allergic Skin Reaction (non-photo induced): Signs/symptoms may
include redness, swelling, blistering, and itching.
May be absorbed through skin and cause target organ effects.
May be absorbed following inhalation and cause target organ effects.
May be absorbed following ingestion and cause target organ effects.
TOLUENE (108-88-3): can cause birth defects or other reproductive
harm.
See Sections 7 and 11 for further information.
-----------------------------------------------------------------------
4 First Aid Measures
-----------------------------------------------------------------------
Instructions for Eye Contact:
Flush eyes with large amounts of water. If signs/symptoms persist,
get medical attention.
Instructions for Skin Contact:
Remove contaminated clothing and shoes. Immediately flush skin with
large amounts of water. Get medical attention. Wash contaminated
clothing and clean shoes before reuse.
Instructions for Inhalation:
Remove person to fresh air. Get immediate medical attention.
Instructions for Ingestion:
Do not induce vomiting unless instructed to do so by medical
personnel. Give victim two glasses of water. Never give anything
by mouth to an unconscious person. Get medical attention.
-----------------------------------------------------------------------
5 Fire Fighting Measures
-----------------------------------------------------------------------
Flash point: -13 C (Methyl Acetate)
Lower Explosive Limit (%): 3.1 % by volume (Methyl
Acetate)
Upper Explosive Limit (%): 16 % (Methyl Acetate)
Autoignition temperature: 501 C (Methyl Acetate)
Suitable Extinguishing Media:
Use fire extinguishers with class B extinguishing agents (e.g., dry
chemical, carbon dioxide).
Exposure Hazards during Fire:
Closed containers exposed to heat from fire may build pressure and
3M (TM) RUBBER & VINYL SPRAY ADHESIVE 80 (CANADA) Page 3 of 10
-----------------------------------------------------------------------
explode. Vapours may travel long distances along the ground or
floor to an ignition source and flash back.
Combustion Products from Fire:
Formaldehyde - During Combustion;
Carbon monoxide - During Combustion;
Carbon dioxide - During Combustion;
Fire Fighting Procedures:
Water may not effectively extinguish fire; however, it should be
used to keep fire-exposed containers and surfaces cool and prevent
explosive rupture. Wear full protective equipment (Bunker Gear) and
a self-contained breathing apparatus (SCBA).
-----------------------------------------------------------------------
6 Accidental Release Measures
-----------------------------------------------------------------------
Personal Precautions:
Refer to other sections of this MSDS for information regarding
physical and health hazards, respiratory protection, ventilation,
and personal protective equipment. Call 3M-HELPS line
(1-800-364-3577) for more information on handling and managing the
spill.
Spill Response:
Evacuate unprotected and untrained personnel from hazard area. The
spill should be cleaned up by qualified personnel. Remove all
ignition sources such as flames, smoking materials, and electrical
spark sources. Use only non-sparking tools. Ventilate the area
with fresh air. For large spill, or spills in confined spaces,
provide mechanical ventilation to disperse or exhaust vapors, in
accordance with good industrial hygiene practice. Warning! A motor
could be an ignition source and could cause flammable gases or
vapors in the spill area to burn or explode. Contain spill. For
larger spills, cover drains and build dikes to prevent entry into
sewer systems or bodies of water. Cover spill area with a
fire-extinguishing foam. An aqueous film forming foam (AFFF) is
recommended. Working from around the edges of the spill inward,
cover with bentonite, vermiculite, or commercially available
inorganic absorbent material. Mix in sufficient absorbent until it
appears dry. Remember, adding an absorbent material does not remove
a toxic, corrosivity or flammability hazard. Collect as much of the
spilled material as possible using non-sparking tools. Clean up
residue with an appropriate solvent selected by a qualified and
authorized person. Ventilate the area with fresh air. Read and
follow safety precautions on the solvent label and MSDS. Collect
the resulting residue containing solution. Place in a metal
container approved for use in transportation by appropriate
authorities. The container must be lined with polyethylene plastic
or contain a plastic drum liner made of polyethylene. Seal the
container. Dispose of collected material as soon as possible.
3M (TM) RUBBER & VINYL SPRAY ADHESIVE 80 (CANADA) Page 4 of 10
-----------------------------------------------------------------------
-----------------------------------------------------------------------
7 Handling and Storage
-----------------------------------------------------------------------
Storage Requirements:
No data available.
Incompatible Materials:
Store away from heat; Sparks and/or Flames; Store out of direct
sunlight. Store away from acids; Store away from oxidizing agents.
Ventilation:
No data available.
Fire Prevention:
Ground containers securely when transferring contents. Wear low
static or properly grounded shoes. Do not spray near flames or
sources of ignition. No smoking while handling this material.
Explosion Prevention:
Aerosol container contains flammable gas under pressure.
Keep away from heat, sparks, open flame, pilot lights and other
sources of ignition.
Static Prevention:
Avoid static discharge.
Use Instructions:
Do not eat, drink or smoke when using this product. Wash exposed
areas thoroughly with soap and water. Keep container tightly
closed. Avoid breathing of vapours, mists or spray. Avoid eye
contact with vapours, mists, or spray. Avoid contact with oxidizing
agents.
-----------------------------------------------------------------------
8 Exposure Controls/Personal Protection
-----------------------------------------------------------------------
Personal Protection
-------------------
Eye Protection:
Avoid eye contact with vapours, mists, or spray. The following
should be worn alone or in combination, as appropriate, to prevent
eye contact: Indirect vented goggles;
Hand Protection:
Select and use gloves and/or protective clothing to prevent skin
contact based on the results of an exposure assessment. Consult
with your glove and/or protective clothing manufacturer for
selection of appropriate compatible materials.
Skin Protection:
Avoid skin contact.
Respiratory Protection:
Avoid breathing of vapours, mists or spray. Select one of the
following approved respirators based on airborne concentration of
contaminants and in accordance with regulations: Half facepiece or
fullface pressure demand self-contained breathing apparatus.
Ingestion (Prevention):
3M (TM) RUBBER & VINYL SPRAY ADHESIVE 80 (CANADA) Page 5 of 10
-----------------------------------------------------------------------
Do not eat, drink or smoke when using this product. Wash exposed
areas thoroughly with soap and water. Keep out of the reach of
children.
Recommended Ventilation:
Use with appropriate local exhaust ventilation. Provide appropriate
local exhaust ventilation at transfer points. If exhaust
ventilation is not available, use appropriate respiratory
protection. Do not use in a confined area or areas with little or
no air movement.
Ingredient Exposure Data
------------------------
METHYL ACETATE (79-20-9)
LD50 (rat, oral) > 5 g/kg
LD50 (dermal, rabbit) > 5 g/kg
LC50 (rat, inhalation/4 hours) No data available.
Exposure Limits
ACGIH: TWA 200 ppm
ACGIH: TWA 606 mg/m3
ACGIH: STEL 250 ppm
ACGIH: STEL 760 mg/m3
DIMETHYL ETHER (115-10-6)
LD50 (rat, oral) No data available.
LC50 (rat, inhalation/4 hours) 164000 ppm
Exposure Limits
CMRG: TWA 1000 ppm
AIHA: TWA 1000 ppm
NON-VOLATILE COMPONENTS (Trade Secret)
Specific Ingredient Data
No data available.
LD50 (rat, oral) No data available.
LC50 (rat, inhalation/4 hours) No data available.
Exposure Limits
No data available.
CYCLOHEXANE (110-82-7)
LD50 (rat, oral) 12,705 mg/kg
LC50 (rat, inhalation/4 hours) 13.9 mg/l
Exposure Limits
ACGIH: TWA 100 ppm
1,2-TRANS-DICHLOROETHYLENE (156-60-5)
Specific Ingredient Data
No data available.
LD50 (rat, oral) 1235 mg/kg
LC50 (rat, inhalation/4 hours) No data available.
Exposure Limits
ACGIH: TWA 200 ppm
TOLUENE (108-88-3)
Specific Ingredient Data
LC50 (female rat, inhalation/4 hours vapour): 19.0 mg/l
3M (TM) RUBBER & VINYL SPRAY ADHESIVE 80 (CANADA) Page 6 of 10
-----------------------------------------------------------------------
LD50 (rat, oral) 636 mg/kg
LD50 (dermal, rabbit) 14100 uL/kg
LC50 (rat, inhalation/4 hours) No data available.
Exposure Limits
ACGIH: TWA 50 ppm (skin contact contributes to exposure) (Table
A4)
ACGIH: TWA 188 mg/m3 (skin contact contributes to exposure)
(Table A4)
ACGIH: TWA 75 ppm (skin contact contributes to exposure)
P-TERT-BUTYLPHENOL-FORMALDEHYDE RESIN (25085-50-1)
Specific Ingredient Data
No data available.
LD50 (rat, oral) No data available.
LC50 (rat, inhalation/4 hours) No data available.
Exposure Limits
No data available.
ETHYL NONAFLUOROISOBUTYL ETHER (163702-06-5)
Specific Ingredient Data
No data available.
LD50 (rat, oral) No data available.
LC50 (rat, inhalation/4 hours) No data available.
Exposure Limits
3M: TWA 200 ppm (specific form) 3M: TWA (Total for all isomers)
ETHYL NONAFLUOROBUTYL ETHER (163702-05-4)
Specific Ingredient Data
No data available.
LD50 (rat, oral) No data available.
LC50 (rat, inhalation/4 hours) No data available.
Exposure Limits
3M: TWA 200 ppm (specific form) 3M: TWA (Total for all isomers)
-----------------------------------------------------------------------
9 Physical and Chemical Properties
-----------------------------------------------------------------------
Physical form,Color,Odour: Liquid; Aerosol; Clear; sweet
odour;
Odour Threshold: No data available.
pH: Not Available
Boiling point/boiling range: Not Available
Melting point/melting range: Not applicable
Vapour pressure: Not Available
Water Solubility: Negligible
Specific gravity: 0.827
Vapour density: Not Available
Volatile organic compounds: 54.2 %
Evaporation rate: No data available.
Viscosity: No data available.
3M (TM) RUBBER & VINYL SPRAY ADHESIVE 80 (CANADA) Page 7 of 10
-----------------------------------------------------------------------
Percent Volatile: Not Available
-----------------------------------------------------------------------
10 Stability and Reactivity
-----------------------------------------------------------------------
Conditions to Avoid:
Store away from heat; Sparks and/or Flames; Store out of direct
sunlight.
Materials to Avoid:
Store away from acids; Strong oxidizing agents;
Hazardous Decomposition:
Formaldehyde - During Combustion;
Carbon monoxide - During Combustion;
Carbon dioxide - During Combustion;
Stability and Reactivity:
Stable. Hazardous polymerization will not occur.
-----------------------------------------------------------------------
11 Toxicological Information
-----------------------------------------------------------------------
Effects from Eye Contact:
Moderate Eye Irritation: Signs/symptoms may include redness,
swelling, pain, tearing, and blurred or hazy vision.
Effects from Skin Contact:
Mild Skin Irritation: Signs/symptoms can include localized redness,
swelling, and itching.
Allergic Skin Reaction (non-photo induced): Signs/symptoms may
include redness, swelling, blistering, and itching.
May be absorbed through skin and cause target organ effects.
Effects from Inhalation:
Respiratory Tract Irritation: Signs/symptoms may include cough,
sneezing, nasal discharge, headache, hoarseness, and nose and
throat pain.
Cardiac Sensitization: Signs/symptoms may include irregular
heartbeat (arrhythmia), faintness, chest pain, and may be fatal.
Intentional concentration and inhalation may be harmful or fatal.
May be absorbed following inhalation and cause target organ
effects.
Effects from Ingestion:
Gastrointestinal Irritation: Signs/symptoms may include abdominal
pain, stomach upset, nausea, vomiting and diarrhea.
May be absorbed following ingestion and cause target organ effects.
Sensitization Information:
Allergic Skin Reaction (non-photo induced): Signs/symptoms may
include redness, swelling, blistering, and itching.
Carcinogenicity:
No data available.
Mutagenicity:
No data available.
Reproductive Effects:
3M (TM) RUBBER & VINYL SPRAY ADHESIVE 80 (CANADA) Page 8 of 10
-----------------------------------------------------------------------
TOLUENE (108-88-3): can cause birth defects or other reproductive
harm.
Component Based Information:
No data available.
Product Based Information:
No data available.
Other Effects & Information:
Central Nervous System (CNS) Depression: Signs/symptoms may include
headache, dizziness, drowsiness, incoordination, nausea, slowed
reaction time, slurred speech, giddiness, and unconsciousness.
May cause blindness.
Prolonged or repeated exposure may cause:
Central Neuropathy: Signs/symptoms may include irritability, memory
impairment, personality changes, sleep disorders, and decreased
ability to concentrate.
Liver Effects: Signs/symptoms may include loss of appetite, weight
loss, fatigue, weakness, abdominal tenderness and jaundice.
Kidney/Bladder Effects: Signs/symptoms may include changes in
urine production, abdominal or lower back pain, increased protein
in urine, increased blood urea nitrogen (BUN), blood in urine, and
painful urination.
-----------------------------------------------------------------------
12 Ecological Information
-----------------------------------------------------------------------
Environmental Data:
Ecotoxicity Data:
Not determined.
Ecofate Data:
Not determined.
-----------------------------------------------------------------------
13 Disposal Considerations
-----------------------------------------------------------------------
Product as Sold:
Incinerate in a permitted hazardous waste incinerator. As a
disposal alternative, dispose of waste product in a permitted
hazardous waste facility.
Product Packaging:
No data available.
Special Instructions:
Since regulations vary, consult applicable regulations or
authorities before disposal.
3M (TM) RUBBER & VINYL SPRAY ADHESIVE 80 (CANADA) Page 9 of 10
-----------------------------------------------------------------------
-----------------------------------------------------------------------
14 Transportation Information
-----------------------------------------------------------------------
Transportation of Dangerous Goods
---------------------------------
TDG Classification: Consumer Commodity
Special Information:
Contact 3M for more information.
International Dangerous Goods Classification
--------------------------------------------
-----------------------------------------------------------------------
15 Regulatory Information
-----------------------------------------------------------------------
WHMIS Classification: Exempt (Consumer Product)
NOTE:
This product has been classified in accordance with the hazard
criteria of the Controlled Products Regulations (CPR) and the MSDS
contains all the information required by the CPR.
-----------------------------------------------------------------------
16 Other Information
-----------------------------------------------------------------------
Reason for Reissue:
The following Sections and topics have been updated or revised:
Section 2 - Composition/Information on Ingredients;
Section 3 - Hazards Identification - Critical Hazards;
Section 4 - First Aid Measures;
Section 6 - Accidental Release Measures;
Section 7 - Handling and Storage;
Section 8 - Exposure Controls/Personal Protection;
Section 11 - Toxicological Information;
Section 13 - Disposal Considerations;
Section 14 - Transportation Information
The information in this Material Safety Data Sheet (MSDS) is believed
to be correct as of the date issued. 3M MAKES NO WARRANTIES,
EXPRESSED OR IMPLIED, STATUTORY OR OTHERWISE, INCLUDING, BUT NOT
LIMITED TO, ANY IMPLIED WARRANTY OR CONDITION OF MERCHANTABILITY OR
FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF
TRADE. User is responsible for determining whether the 3M product is
fit for a particular purpose and suitable for user's method of use or
application. Given the variety of factors that can affect the use
and application of a 3M product, some of which are uniquely within
the user's knowledge and control, it is essential that the user
evaluate the 3M product to determine whether it is fit for a
3M (TM) RUBBER & VINYL SPRAY ADHESIVE 80 (CANADA) Page 10 of 10
-----------------------------------------------------------------------
particular purpose and suitable for user's method of use or
application.
---End---
|