MATERIAL SAFETY DATA SHEET
FURADAN?LFR INSECTICIDE / NEMATICIDE
MSDS Ref. No.: 1563-66-2-26
Date Approved: 10/26/2005
Revision No.: 9
This document has been prepared to meet the requirements of the U.S. OSHA Hazard Communication
Standard, 29 CFR 1910.1200; the EC directive, 2001/58/EC and other regulatory requirements. The
information contained herein is for the concentrate as packaged, unless otherwise noted.
1. PRODUCT AND COMPANY IDENTIFICATION
FURADAN?LFR INSECTICIDE / NEMATICIDE
PRODUCT NAME:
2837
PRODUCT CODE:
Carbofuran
ACTIVE INGREDIENT(S):
Carbamate Pesticide
CHEMICAL FAMILY:
(carbofuran)
MOLECULAR FORMULA:
FMC 10242; 2,3-dihydro-2,2-dimethyl-7-benzofuranyl
SYNONYMS:
methylcarbamate; IUPAC: 2,3-dihydro-2,2-dimethylbenzofuran-7-yl
methylcarbamate
MANUFACTURER EMERGENCY TELEPHONE NUMBERS
FMC CORPORATION (800) 331-3148 (FMC - U.S.A. & Canada)
Agricultural Products Group (716) 735-3765 (FMC - Reverse charges)
1735 Market Street
Philadelphia, PA 19103
(215) 299 6000 (General Information) For leak, fire, spill, or accident emergencies, call:
(800) 424-9300 (CHEMTREC - U.S.A. & Canada)
(703) 527-3887 (CHEMTREC - All Other Countries)
2. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW:
? Creamy off-white liquid suspension with a mildly phenolic odor.
? Slightly combustible. May support combustion at elevated temperatures.
? Degrades at temperatures above 130癈 (266癋).
? Thermal decomposition and burning may form toxic by-products.
? For large exposures or fire, wear personal protective equipment.
? Highly toxic to fish and aquatic organisms. Keep out of drains and water courses.
? Highly toxic if swallowed, and could be highly toxic if absorbed through the mucous membranes of the
eyes.
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? It is expected to be highly toxic by inhalation.
POTENTIAL HEALTH EFFECTS: Effects from overexposure result from either
swallowing, inhaling or coming into contact with the eyes or skin. Conditions of increased temperature and
humidity may aid skin absorption of this product and, therefore, increase toxicity. Symptoms of
overexposure include headache, light-headedness, weakness, abdominal cramps, nausea, excessive
salivation, perspiration, blurred vision, tearing, pin-point pupils, blue skin color, convulsions, tremor and
coma.
MEDICAL CONDITIONS AGGRAVATED: None presently known.
3. COMPOSITION / INFORMATION ON INGREDIENTS
Chemical Name CAS# Wt.% EC No. EC Class
Carbofuran 1563-66-2 40.64 216-353-0 R26/28-50/53; S1/2-36/37-
45-60-61
Propylene Glycol 57-55-6 6 200-338-0 Not classified
Surfactant Blend 3 None Not classified
Silica, quartz 14808-60-7 <0.5 238-878-4 Not classified
4. FIRST AID MEASURES
EYES: Immediately flush with water for at least 15 minutes, lifting the upper and lower eyelids
intermittently. See a medical doctor immediately.
SKIN: Wash with plenty of soap and water. Get medical attention if irritation occurs and persists.
INGESTION: Drink 2 glasses of water and induce vomiting by touching the back of the throat with a
finger. Never induce vomiting or give anything by mouth to an unconscious person. See a medical doctor.
INHALATION: Remove to fresh air. If breathing difficulty or discomfort occurs and persists, see a
medical doctor. If breathing has stopped, give artificial respiration and see a medical doctor immediately.
NOTES TO MEDICAL DOCTOR: This product is highly toxic if swallowed, and has low
dermal toxicity. It is expected to be highly toxic by inhalation. It is minimally irritating to the skin and
practically non-irritating to the eyes, however, absorption through the mucous membranes of the eyes could
be highly toxic. Carbofuran is a reversible cholinesterase inhibitor. Atropine sulfate is antidotal. Support
respiration as needed with removal of secretions, maintenance of a patent airway and, if necessary, artificial
ventilation. If cyanosis is absent: Adults - start treatment by giving 2 mg atropine intravenously or
intramuscularly, if necessary, and repeat with 0.4 - 2.0 mg atropine at 15 minute intervals until
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atropinization occurs (tachycardia, flushed skin, dry mouth, mydriasis); Children under 12 - initial dose =
0.05 mg/kg body weight and repeat dose = 0.02 - 0.05 mg/kg body weight. Use of oximes such as 2-PAM
is controversial. Observe patient to insure that these symptoms do not recur as atropinization wears off. If in
eyes, instill one drop of homatropine. Treatment is otherwise controlled removal of exposure followed by
symptomatic and supportive care.
5. FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA: Foam, CO2 or dry chemical. Soft stream water fog only if
necessary. Contain all runoff.
FIRE / EXPLOSION HAZARDS: Slightly combustible. Carbofuran will burn if ignited and
degrades at temperatures above 130癈 (266癋).
FIRE FIGHTING PROCEDURES: Isolate fire area. Evacuate downwind. Wear full
protective clothing and self-contained breathing apparatus. Do not breathe smoke, gases or vapors
generated.
6. ACCIDENTAL RELEASE MEASURES
RELEASE NOTES: Isolate and post spill area. Wear protective clothing and personal protective
equipment as prescribed in Section 8, "Exposure Controls/Personal Protection". Keep unprotected persons
and animals out of the area.
Keep material out of lakes, streams, ponds and sewer drains. Dike to confine spill and absorb with a non-
combustible absorbent such as clay, sand or soil. Vacuum, shovel or pump waste into a drum and label
contents for disposal.
To clean and neutralize spill area, tools and equipment, wash with a bleach or caustic/soda ash solution.
Follow this by washing with a strong soap and water solution. Absorb, as above any excess liquid and add
to the drums of waste already collected. Repeat if necessary. Dispose of drummed wastes according to the
method outlined in Section 13, "Disposal Considerations".
7. HANDLING AND STORAGE
HANDLING AND STORAGE: Store in a cool, dry, well-ventilated place. Do not use or
store near heat, open flame or hot surfaces. Store in original containers only. Keep out of reach of children
and animals. Do not contaminate other pesticides, fertilizers, water, food or feed by storage or disposal.
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8. EXPOSURE CONTROLS / PERSONAL PROTECTION
EXPOSURE LIMITS
Chemical Name ACGIH OSHA Supplier
0.1 mg/m3 (TWA) 0.1 mg/m3 (PEL)
Carbofuran
10.0 mg/m3 (WEEL)
Propylene Glycol
0.05 mg/m3 (TWA) 0.1 mg/m3 (PEL)
Silica, quartz
(respirable fraction) (respirable dust)
ENGINEERING CONTROLS: Use local exhaust at all process locations where vapor or
mist may be emitted. Ventilate all transport vehicles prior to unloading.
PERSONAL PROTECTIVE EQUIPMENT
EYES AND FACE: For splash, mist or spray exposure, wear chemical protective goggles
or a face shield.
RESPIRATORY: For splash, mist or spray exposures wear, as a minimum, a properly
fitted half-face or full-face air-purifying respirator which is approved for pesticides (U.S.
NIOSH/MSHA, EU CEN or comparable certification organization). Respirator use and selection
must be based on airborne concentrations.
PROTECTIVE CLOTHING: Depending upon concentrations encountered, wear
coveralls or long-sleeved uniform and head covering. For larger exposures as in the case of spills,
wear full body cover barrier suit, such as a PVC suit. Leather items - such as shoes, belts and
watchbands - that become contaminated should be removed and destroyed. Launder all work
clothing before reuse (separately from household laundry).
GLOVES: Wear chemical protective gloves made of materials such as rubber, neoprene or
nitrile. Thoroughly wash the outside of gloves with soap and water prior to removal. Inspect
regularly for leaks.
WORK HYGIENIC PRACTICES: Clean water should be available for washing in case of
eye or skin contamination. Wash skin prior to eating, drinking, chewing gum, or using tobacco. Shower at
the end of the workday.
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9. PHYSICAL AND CHEMICAL PROPERTIES
Mildly phenolic
ODOR:
Creamy off-white liquid suspension
APPEARANCE:
9.78 lbs/gal (1175 g/L)
DENSITY / WEIGHT PER VOLUME:
> 100 癈 (> 212 癋)
FLASH POINT:
221.26 (carbofuran)
MOLECULAR WEIGHT:
6.34
pH:
1.17
SPECIFIC GRAVITY:
10. STABILITY AND REACTIVITY
Excessive heat and fire.
CONDITIONS TO AVOID:
Stable
STABILITY:
Will not occur
POLYMERIZATION:
Carbon monoxide, carbon dioxide, nitrogen oxides,
HAZARDOUS DECOMPOSITION PRODUCTS:
and methyl isocyanate.
11. TOXICOLOGICAL INFORMATION
EYE EFFECTS: Practically non-irritating
SKIN EFFECTS: Minimally irritating
DERMAL LD50: 6,783 mg/kg (rabbit)
ORAL LD50: 7.34 mg/kg (rat)
INHALATION LC50: Carbofuran: 0.10 mg/l (1 h) (rat)
ACUTE EFFECTS FROM OVEREXPOSURE: This product is highly toxic if
swallowed, and has low dermal toxicity. It is expected to be highly toxic by inhalation. It is minimally
irritating to the skin and practically non-irritating to the eyes, however, absorption through the mucous
membranes of the eyes could be highly toxic. With dermal exposure to this product, conditions of increased
temperature and humidity facilitate skin absorption and, therefore, promote increased toxicity. Carbofuran
is a reversible cholinesterase inhibiting pesticide, which elicits symptoms in humans typical of
cholinesterase inhibition including headaches, light-headedness, weakness, abdominal cramps, nausea,
excessive salivation, perspiration and blurred vision. More severe signs of cholinesterase inhibition include
tearing, pin-point pupils, excessive respiratory secretions, cyanosis, convulsions, generalized tremor and
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coma. Excessive exposure may result in death. In humans, ingestion of large amounts of propylene glycol
has resulted in symptoms of reversible central nervous system depression including stupor, rapid breathing
and heartbeat, profuse sweating and seizures.
CHRONIC EFFECTS FROM OVEREXPOSURE: No data available for the
formulation. In studies with laboratory animals, carbofuran did not cause reproductive toxicity,
teratogenicity, or carcinogenicity. Chronic exposure of laboratory animals to carbofuran has caused
decreased cholinesterase activity (erythrocyte, plasma, and/or brain). An overall absence of genotoxicity
has been demonstrated in mutagenicity testing with carbofuran. Repeated overexposure to propylene glycol
can produce central nervous system depression, hemolysis and minimal kidney damage. Repeated
overexposure to crystalline silica for extended periods has caused acute silicosis. IARC has classified
crystalline silica, inhaled in the form of quartz or cristobalite from occupational sources, as carcinogenic to
humans (Group 1). NTP has clasified respirable crystalline silica (quartz, cristobalite and tridymite) as
"reasonably anticipated to be carcinogenic". The American Conference of Governmental Industrial
Hygienists (ACGIH) has concluded that silica quartz is a suspected human carcinogen (A2 - limited
evidence of carcinogenicity in humans and sufficient evidence of carcinogenicity in experimental animals
with relevance to humans).
CARCINOGENICITY:
Chemical Name IARC NTP OSHA Other
Silica, quartz Listed Listed Not listed (ACGIH) Listed
12. ECOLOGICAL INFORMATION
Unless otherwise indicated, the data presented below are for the active ingredient.
ENVIRONMENTAL DATA: Carbofuran has a moderate rate of degradation in soil (half-life
= 50 days). It undergoes rapid hydrolysis under alkaline (high pH) conditions, but is stable at acidic (low)
pH. Carbofuran has a Log Pow of 1.4 and a bioconcentration factor of 9 (low potential for environmental
accumulation). It may be mobile in soil, especially soils with a high sand content and, therefore, has a
potential to contaminate groundwater. In heavier textured soils, the mobility of carbofuran is expected to be
moderate.
ECOTOXICOLOGICAL INFORMATION: With LC50 values between 5.3 to 36 礸/L
to fish and aquatic arthropods in the laboratory, this product is considered highly toxic. Care should be
taken to avoid contamination of the aquatic environment. It is also considered highly toxic to waterfowl and
upland game birds, and has an oral LD50 of 2.67 to 10.75 mg/kg. Carbofuran is easily metabolized and,
because it is a rapidly reversible cholinesterase inhibitor, recovery from symptoms of sublethal exposure
occurs quickly.
13. DISPOSAL CONSIDERATIONS
DISPOSAL METHOD: Open dumping or burning of this material or its packaging is prohibited.
If spilled material cannot be disposed of by use according to label instructions, an acceptable method of
disposal is to incinerate in accordance with local, state and national environmental laws, rules, standards
and regulations. However, because acceptable methods of disposal may vary by location and regulatory
requirements may change, the appropriate agencies should be contacted prior to disposal.
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EMPTY CONTAINER: Non-returnable containers that held this material should be cleaned,
prior to disposal, by triple rinsing. Containers which held this material may be cleaned by being triple-
rinsed, and recycled, with the rinsate being incinerated. Do not cut or weld metal containers. Vapors that
form may create an explosion hazard.
14. TRANSPORT INFORMATION
U.S. DEPARTMENT OF TRANSPORTATION (DOT)
Non-Bulk
PACKAGING TYPE:
Carbamate pesticide, liquid, toxic
PROPER SHIPPING NAME:
Carbofuran
TECHNICAL NAME(S):
6.1
PRIMARY HAZARD CLASS / DIVISION:
UN 2992
UN/NA NUMBER:
II
PACKING GROUP:
6.1
LABEL(S):
6.1
PLACARD(S):
RQ Carbamate pesticide, liquid, toxic
MARKING(S):
(carbofuran), UN 2992
Carbofuran
REPORTABLE QUANTITY (RQ):
Carbofuran is in an "RQ" quantity when this
ADDITIONAL INFORMATION:
material meets or exceeds 24.6 pounds (2.5
gallons) per package.
Bulk
PACKAGING TYPE:
Carbamate pesticide, liquid, toxic
PROPER SHIPPING NAME:
Carbofuran
TECHNICAL NAME(S):
6.1
PRIMARY HAZARD CLASS / DIVISION:
UN 2992
UN/NA NUMBER:
II
PACKING GROUP:
Carbofuran
MARINE POLLUTANT:
6.1
LABEL(S):
6.1
PLACARD(S):
2992
MARKING(S):
Carbofuran
REPORTABLE QUANTITY (RQ):
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INTERNATIONAL MARITIME DANGEROUS GOODS (IMDG)
Non-Bulk
PACKAGING TYPE:
Carbamate pesticide, liquid, toxic
PROPER SHIPPING NAME:
Carbofuran
TECHNICAL NAME(S):
6.1
PRIMARY HAZARD CLASS / DIVISION:
UN 2992
UN/NA NUMBER:
II
PACKING GROUP:
Carbofuran
MARINE POLLUTANT:
6.1
LABEL(S):
6.1
PLACARD(S):
RQ Carbamate pesticide, liquid, toxic
MARKING(S):
(carbofuran), UN 2992 + Marine Pollutant
Carbofuran
REPORTABLE QUANTITY (RQ):
Carbofuran is in an "RQ" quantity when
ADDITIONAL INFORMATION:
this material meets or exceeds 24.6 pounds
(2.5 gallons) per package.
ADR - EUROPEAN AGREEMENT CONCERNING THE
INTERNATIONAL CARRIAGE OF DANGEROUS GOODS BY ROAD
Non-Bulk
PACKAGING TYPE:
Carbamate pesticide, liquid, toxic
PROPER SHIPPING NAME:
Carbofuran
TECHNICAL NAME(S):
6.1
PRIMARY HAZARD CLASS / DIVISION:
T6
CLASSIFICATION CODE:
UN2992
UN/NA NUMBER:
II
PACKING GROUP:
60
HAZARD IDENTIFICATION NUMBER:
Carbofuran
MARINE POLLUTANT:
6.1
LABEL(S):
6.1
PLACARD(S):
UN 2992 + Marine Pollutant
MARKING(S):
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INTERNATIONAL CIVIL AVIATION ORGANIZATION (ICAO) /
INTERNATIONAL AIR TRANSPORT ASSOCIATION (IATA)
Non-Bulk
PACKAGING TYPE:
Carbamate pesticide, liquid, toxic
PROPER SHIPPING NAME:
Carbofuran
TECHNICAL NAME(S):
6.1
PRIMARY HAZARD CLASS / DIVISION:
UN2992
UN/NA NUMBER:
II
PACKING GROUP:
6.1
LABEL(S):
Y609 / 1 L
LIMITED QUANTITY:
609 / 5 L
LIMITED QUANTITY: PASSENGER / CARGO:
611 / 60 L
LIMITED QUANTITY: CARGO:
Carbofuran is in an "RQ" quantity when
ADDITIONAL INFORMATION:
this material meets or exceeds 24.6 pounds
(2.5 gallons) per package.
Marks: RQ Carbamate pesticide, liquid,
toxic (carbofuran), UN2992
RQ: carbofuran
OTHER INFORMATION:
It has been determined that a lethal concentration of this material, by mist or particle, will not be reasonably
encountered by humans while this material is in transportation.
HARMONIZED SYSTEM
Import to the U.S.A.: 3808.10.2500
Export from the U.S.A.: 3808.10.0000
15. REGULATORY INFORMATION
UNITED STATES
SARA TITLE III (SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT)
SECTION 302 EXTREMELY HAZARDOUS SUBSTANCES (40 CFR 355, APPENDIX A):
Listed
REPORTABLE QUANTITY:
Chemical Name RQ
Carbofuran 10 lb
SECTION 311 HAZARD CATEGORIES (40 CFR 370):
Immediate, Delayed
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SECTION 312 THRESHOLD PLANNING QUANTITY (40 CFR 370):
The Threshold Planning Quantity (TPQ) for this product, if treated as a mixture, is 10,000 lbs;
however, this product contains the following ingredients with a TPQ of less than 10,000 lbs.:
None
SECTION 313 REPORTABLE INGREDIENTS (40 CFR 372):
This product contains the following ingredients subject to Section 313 reporting requirements:
Carbofuran
CERCLA (COMPREHENSIVE ENVIRONMENTAL RESPONSE COMPENSATION AND
LIABILITY ACT)
CERCLA DESIGNATION & REPORTABLE QUANTITIES (RQ) (40 CFR 302.4):
Listed
Chemical Name RQ
Carbofuran 10 lb
RESOURCE CONSERVATION AND RECOVERY ACT (RCRA)
RCRA IDENTIFICATION OF HAZARDOUS WASTE (40 CFR 261):
Waste Number: P127, Carbofuran
FEDERAL INSECTICIDE FUNGICIDE RODENTICIDE ACT
U.S. EPA Signal Word: DANGER-POISON
INTERNATIONAL LISTINGS
Australian Hazard Code: 3XE
HAZARD, RISK AND SAFETY PHRASE DESCRIPTIONS:
Carbofuran, (Index #006-026-00-9):
EC Symbols: T+ (Very Toxic)
N (Dangerous for the environment)
EC Risk Phrases: R26/28 (Very toxic by inhalation and if swallowed)
R50/53 (Very toxic to aquatic organisms, may cause long-term adverse
effects in the aquatic environment.)
EC Safety Phrases: S1/2 (Keep locked up and out of reach of children.)
S36/37 (Wear suitable protective clothing and gloves.)
S45 (In case of accident or if you feel unwell, seek medical advice
immediately - show the label where possible.)
S60 (This material and its container must be disposed of as
hazardous waste)
S61 (Avoid release to the environment. Refer to special
instructions/safety data sheets.)
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16. OTHER INFORMATION
REVISION SUMMARY:
This MSDS replaces Revision #8, dated October 27, 2004.
Changes in information are as follows:
Section 1 (Product and Company Identification) - Previous Tradename: Furadan 4F
Section 3 (Composition / Information on Ingredients)
Section 9 (Physical and Chemical Properties)
Section 16 (Other Information)
Furadan and FMC Logo - FMC Trademarks
?2005 FMC Corporation. All Rights Reserved.
FMC Corporation believes that the information and recommendations contained herein (including data and
statements) are accurate as of the date hereof. NO WARRANTY OF FITNESS FOR ANY PARTICULAR
PURPOSE, WARRANTY OF MERCHANTABILITY, OR ANY OTHER WARRANTY, EXPRESSED
OR IMPLIED, IS MADE CONCERNING THE INFORMATION PROVIDED HEREIN. The information
provided herein relates only to the specific product designated and may not be applicable where such
product is used in combination with any other materials or in any process. Use of this product is regulated
by the U.S. Environmental Protection Agency (EPA). It is a violation of Federal law to use this product in a
manner inconsistent with its labeling. Further, since the conditions and methods of use are beyond the
control of FMC Corporation, FMC Corporation expressly disclaims any and all liability as to any results
obtained or arising from any use of the product or reliance on such information.
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