SAFETY DATA SHEET
HEATLOK SOY
B-side
Section 1: PRODUCT & COMPANY INFORMATION
MANUFACTURER OF CHEMICAL COMPONENTS PRODUCT
Trade name: HEATLOK SOY B-side
DEMILEC (USA) LLC
Chemical name: Polyurethane Resin / B-side
2925 Galleria Dr.
Chemical family: Polyester Resin Blend
Arlington, TX 76011
Product Use: Component of a Polyurethane System
Phone: (817) 640-4900
Fax: (817) 633-2000
e-mail: info@demilecusa.com
Emergency telephone:
1-877-DEMILEC or
CHEMTREC: (800) 424-9300 or
CANUTEC: (613) 996-6666
Section 2: HAZARDS IDENTIFICATION
Liquid / Blue / Ester
Physical State / Color / Odor:
Emergency Overview / Warning:
This material is classified hazardous under OSHA Hazard Communication Standard (29
OSHA/HCS Status:
CFR 1910.1200).
Acute Health Hazard / Chronic Health Hazard / Fire Hazard: Toxic gases/fumes may be
Physical /Chemical Hazards:
released during burning or thermal decomposition.
Eye Contact, Skin Contact, Inhalation, Ingestion.
Routes of Entry:
Product liquids, aerosols or vapors are irritating. Vapors may cause a transient condition
Eye Contact:
known as glaucopsia, resulting in blurred vision and appearance of halos around bright objects.
May cause moderate irritation and dermatitis.
Skin Contact:
May cause irritation to throat, esophagus and stomach (nausea, abdominal pains, vomiting
Ingestion:
and diarrhea). May cause liver and kidney damage.
May cause headaches, dizziness, drowsiness and other central nervous system effects.
Inhalation:
The components of this product are not listed by NTP, IARC or regulated as a carcinogen
Carcinogenicity:
by OSHA.
Section 3: COMPOSITION / INFORMATION ON INGREDIENTS
% CAS #
Ingredients
40 ?70 N/A
Polyol blend
7 ?15 460-73-1
1,1,1,3,3-Pentafluoropropane
7 ?15 13674-84-5
Tris-iso-chloropropyl phosphate
1-5 156-60-5
Trans 1,2 dichloroethylene
1? N/A
Tertiary Amine Catalyst
1? N/A
Surfactant
Page 1 of 7
Heatlok Soy B-side
Section 4: FIRST AID MEASURES
Immediately flush eyes with running water for a minimum of 15 minutes. Hold eyelids open
Eye contact:
during flushing. Obtain medical attention immediately.
In case of contact, immediately remove contaminated clothing and shoes. Immediately flush
Skin contact:
skin with plenty of soap and cold water. Do not use hot water. Wash contaminated clothing and
shoes thoroughly before reuse. For severe exposures, immediately get under safety shower and
start rinsing. If the irritation develops, obtain medical attention.
Move exposed person to fresh air. Keep person warm and at rest. If not breathing, breathing
Inhalation:
irregularly, or if respiratory arrest occurs, provide artificial respiration or oxygen by trained
personnel. Obtain medical attention if adverse health effects persist.
If unconscious, place in recovery position and get medical attention immediately. Maintain an
open airway. Loosen tight clothing such s a collar, tie, belt or waistband.
In case of inhalation of decomposition products in a fire, symptoms may be delayed. The
exposed person may need to be kept under medical surveillance for 48hours.
Wash out mouth with water. Move exposed person to fresh air. Keep person warm and at rest.
Ingestion:
If material has been swallowed and the exposed person is conscious, give small quantities of
milk or water (250 ml) to drink to induce vomiting. Stop if the exposed person feels sick, as
vomiting may be dangerous.
DO NOT induce vomiting unless directed to do so by medical personnel. If vomiting occurs,
the head should be kept low so that vomit does not enter lungs. Get immediate medical attention
if adverse health effects persist or are severe.
Never give anything by mouth to an unconscious person. If unconscious, place in recovery
position and get medical attention immediately. Maintain an open airway. Loosen tight clothing
such as collar, tie, belt or waistband.
No action shall be taken involving any personal risk or without suitable training. If it is
Protection of first-aiders:
suspected that fumes are still present, the rescuer should wear an appropriate mask or self-
contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-
to-mouth resuscitation.
Following severe exposure the patient should be kept under medical review for at least 48
Notes to physician:
hours.
Section 5: FIRE FIGHTING MEASURES
> 200篎 (93篊)
Flash Point:
Not Established
Auto-Ignition Temperature:
Not Established
Upper Flammable Limit (%vol.):
Not Established
Lower Flammable Limit (%vol.):
Dry chemical, Carbon Dioxide (CO2), Foam, Water Spray for large fires.
Suitable Extinguishing Media:
Combustion products may include Carbon Monoxide, Carbon Dioxide, Nitrogen Oxides,
Hazardous Products of
halogenated compounds, traces of ammonia vapors, aldehydes and ketones, low molecular
Thermal Decomposition:
weight organic products.
Firefighter should be equipped with self-contained breathing apparatus (SCBA) with a full face-
Special Fire Fighting
piece operated in positive pressure mode to protect against potentially toxic and irritating fumes
Procedures:
generated by thermal decomposition or combustion during a fire. They should wear appropriate
protective equipment such as PVC boots, gloves, safety helmet and protective clothing.
Material supports combustion.
Page 2 of 7
Heatlok Soy B-side
Section 6: ACCIDENTAL RELEASE MEASURES
Spill and Leak Procedures:
Avoid breathing vapors or mist. Provide adequate ventilation. Use suitable protective
Personal Precautions:
equipment
Avoid spreading of spilled material, runoff and contact with soil, waterways, drains and sewers.
Environmental
Inform the relevant authorities if the product has caused environmental pollution.
Precautions:
Spread sawdust absorbent over the spill area and leave to react for at least 30 minutes in order
Methods for Cleaning-up:
to absorb as much of the remaining product as possible. Shovel into suitable metal containers
for waste disposal. Contaminated absorbent material may pose the same hazard as the spilt
product. Dispose via a licensed waste disposal contractor.
The spill area should then be washed down with soap and warm water to dilute and remove
remaining traces of material. Ventilate area to remove the remaining vapors.
Section 7: HANDLING & STORAGE
59 - 86篎 (15 - 30篊)
Storage Temperature
(minimum-maximum):
3months
Storage Life:
Avoid breathing vapors and contact with eyes or skin. Put on appropriate personal protective
Handling:
equipment (see Section 8). Eating, drinking and smoking should be prohibited in areas where
this material is handled, stored and processed. Workers should wash hands and face before
eating, drinking and smoking.
Store in tightly closed containers in a cool, dry and ventilated place away from incompatible
Storage:
materials, food and drink. Product is hygroscopic, keep it away from moisture. Store away from
ignition sources. Protect containers against physical damage. Smoking in area is prohibited.
If contamination with isocyanates is suspected, do not reseal containers. Employee education
Precautions:
and training in safe handling of this product are required under the OSHA Hazard
Communication Standard.
Original Container.
Packaging Containers:
Section 8: EXPOSURE CONTROL / PERSONAL PROTECTION
Exposure Limit Values:
Not evaluated
For Product:
For Ingredients:
Ingredients: WEEL(AIHA) (TWA) - 8hr OSHA PEL (TWA) - 8hr
Polyol blend N/A N/A
1,1,1,3,3-Pentafluoropropane 300 ppm / 1644 mg/m? Not Listed
Tris-iso-chloropropyl phosphate Not Listed Not Listed
Trans 1,2 dichloroethylene N/A 200 ppm / 790 mg/m?br>
Tertiary Amine Catalyst N/A N/A
Eye protection is required when directly handling liquid product. Use chemical goggles and
Eye Protection:
face shields or full-faced air-supplied respirator. Persons who work with this product should not
wear contact lenses.
Use long-sleeves protective clothing impervious to chemicals, boots and chemical-resistant gloves
Skin Protection:
such as Nitrile/butadiene rubber ("nitrile" or "NBR"), Butyl rubber, Polyvinyl chloride ("PVC"
Page 3 of 7
Heatlok Soy B-side
or "vinyl"), Polychloroprene (Neoprene*).
Protective gloves should be worn when handling freshly made polyurethane products to avoid
contact with trace residual materials that may be hazardous in contact with skin.
Wash hands, forearms and face thoroughly after handling chemical products, before eating,
drinking, smoking and using the lavatory and at the end of the working period.
An air-supplied respirator should be worn during applications and when the product is being
Respiratory Protection:
heated or in environments of high concentrations well above TLV.
Local exhaust should be used to maintain a fresh supply of air.
Environmental Exposure
Controls /Ventilation Open-air well ventilated foam spraying area:
Requirements:
Use air-purifying respirator and eye protection goggles, chemical resistant gloves and long-
sleeved protective clothing. Be sure to establish a safety zone to keep out nonessential
personnel. Protect people, cars, etc., against airborne overspray.
Spraying foam in enclosed areas:
Use full-face air-supplied respirator, chemical resistant gloves and long-sleeved protective
clothing. Make sure that others do not enter the area until residual vapors have been vented
away.
On-line foam processing:
Permanent ventilation equipment is necessary for on-line processing. Efficiency of this
equipment must be checked regularly, especially in foaming operations where fans, duct and
filters can become blocked with over-processed foam. Relevant operators must use air-
purifying respirator, chemical protective goggles and face shields, chemical-resistant gloves and
long sleeved coveralls.
Safety showers and eye wash stations should be easily accessible to the work area.
Additional Protective
Measures:
Section 9. PHYSICAL AND CHEMICAL PROPERTIES
Blue Liquid
Appearance:
Ester odor
Odor:
400 - 650
Viscosity @20癈, cps:
1.20 - 1.25 @ 68篎 (20篊)
Specific Gravity @20癈:
> 93篊 (200篎)
Flash Point:
Not Established
Auto-Ignition Temperature:
Not Established
Boiling Point:
Not Established
Freezing/Melting Point:
Not Established
Vapor Pressure:
4.6 for 1,1,1,3,3-Pentafluoropropane
Vapor Density (Air=1):
Moderate
Solubility in Water:
*N/A-Not Available
Section 10: STABILITY AND REACTIVITY
This product is considered stable under normal and anticipated storage and handling
Stability:
conditions.
Avoid exposure to moisture and high temperatures to protect product quality.
Conditions to avoid:
Strong oxidizing materials, strong acids and alkali or alkaline earth metals (aluminum, zinc,
Materials to avoid:
beryllium and copper). Avoid unintended contact with isocyanates.
Will not occur.
Hazardous Polymerization:
Combustion products may include Carbon Monoxide, Carbon Dioxide, Nitrogen Oxides,
Hazardous products of
halogenated compounds, traces of ammonia vapors, aldehydes and ketones, low molecular
decomposition:
weight organic products.
Page 4 of 7
Heatlok Soy B-side
Not Established
Decomposition Temperature:
Section 11: TOXICOLOGICAL INFORMATION
Toxicological testing has not been conducted for this product. Available toxicological data for individual ingredients are
summarized in table below.
Acute Oral Toxicity, Acute Inhalation Acute Dermal Repeated Dose Toxicity:
LD50 (Rat): Toxicity, LC50 (Rat) Toxicity, LD50 (Rat)
Ingredients (Rabbit):
Polyol blend N/A N/A N/A N/A
28 days, inhalation: NOAEL:
1,1,1,3,3-Pentafluoropropane
>200,000 ppm 50,000 ppm
N/A >2,000 mg/kg 90 days, inhalation: NOAEL
(4hrs)
2,000ppm
Tris-iso-chloropropyl >4.6 mg/l, aerosol >2,000 mg/kg 90 Days, oral: NOAEL: 36
< 2000 mg/kg mg/kg
phosphate (4 hrs) (24hrs)
Trans 1,2 dichloroethylene 1235 mg/kg 8000 ppm >5000 mg/kg N/A
Tertiary Amine Catalyst 1630 mg/kg 290 ppm (6hrs) 280 mg/kg 14 days, inhalation: 12ppm
*Tertiary Amine: can cause severe eye and skin irritation; prolonged contact may result in chemical burns and permanent damage of liver, stomach, lungs.
Potential Acute Health Effects:
Product liquids, aerosols or vapors are irritating. Vapors may cause a transient condition known as
Eye Contact:
glaucopsia, resulting in blurred vision and appearance of halos around bright objects.
May cause moderate irritation and dermatitis.
Skin Contact:
May cause irritation to throat, esophagus and stomach (nausea, abdominal pains, vomiting and
Ingestion:
diarrhea).
May cause headaches, dizziness, anesthesia, drowsiness and other central nervous system
Inhalation:
effects.
Potential chronic health effects:
Not known or reported.
Sensitization:
The components of this product are not listed by NTP, IARC or regulated as a carcinogen by
Carcinogenic Effects:
OSHA.
No known significant effects or critical hazards.
Mutagenic Effects:
No known significant effects or critical hazards.
Fertility Effects:
No known significant effects or critical hazards.
Developmental Effects:
Section 12: ECOLOGICAL INFORMATION
Ecological testing has not been conducted for this product. Available toxicological data for individual ingredients are
summarized in table below.
Aquatic Toxicity Data For Components Toxicity:
Polyol blend N/A
1,1,1,3,3-Pentafluoropropane LC50: >81.8mg/l (96hrs) (fish: rainbow trout);
EC50: >97.9mg/l (48hrs) (Daphnia magna)
Tris-iso-chloropropyl phosphate LC50: 51mg/l (96hrs) (fish: fathead minnow); 180mg/l (96hrs) (fish: bluegill sunfish);
LC50: 131mg/l (96hrs) (Daphnia magna)
Trans 1,2 dichloroethylene LC50: 135mg/l (96hrs) (fish: bluegill sunfish);
LC50: 170-290 mg/l (48hrs) (Daphnia magna)
Tertiary Amine Catalyst LC50(96hrs): 220mg/l (golden orfe)
EC50(48hrs): 76 mg/l (Daphnia magna)
Page 5 of 7
Heatlok Soy B-side
Section 11: DISPOSAL CONSIDERATION
The generation of waste should be avoided or minimized whenever possible. Waste must be
Waste Disposal Method:
disposed of in compliance with federal, state or local environmental control regulations.
Dispose of surplus and non-recyclable products via licensed waste disposal contractor.
Incineration is the preferred method. If incinerated, toxic and corrosive combustion gases must
be properly handled.
Empty containers retain product residue (liquid and / or vapor) and can be dangerous. Do not
Empty Container
pressurize, cut, weld, braze, solder, drill, grind or expose such containers to heat, flame, sparks,
Precautions:
static electricity, or other sources of ignition. All containers should be disposed of in an
environmentally safe manner and in accordance with governmental regulations.
The DEMILEC(USA), LLC. has no control over the management practices or manufacturing processes of parties
handling or using this material. The information presented here pertains only to the product as shipped in its original
condition as described in MSDS Section 2 (Ingredients).
Section 12: TRANSPORTATION INFORMATION
Polyurethane Resin, Heatlok Soy B-side
Technical Shipping Name:
Non-regulated
Land Transport / DOT Classification:
Non-regulated
Sea Transport / IMDG Classification:
Aviation regulated liquid, n.o.s (contains Hydrofluorocarbon)
Air Transport / ICAO/IATA Classification:
UN 3334 / Hazard Class or Division: 9 / Packaging Group III
Hazardous Label: Miscellaneous
Non-regulated
T.D.G. Classification:
Emergency telephone: 1-877-DEMILEC
CHEMTREC: (800) 424-9300 &
CANUTEC: (613) 996-6666
Section 15: REGULATORY INFORMATION
U.S. Federal Regulations
OSHA Hazcom Standard Rating: This material is classified hazardous under OSHA Hazard Communication
Standard (29 CFR 1910.1200)
HSC Classification: Irritant
US. Toxic Substances Control Act / TSCA: All ingredients are listed on the TSCA Inventory
US. EPA CERCLA Hazardous Substances Trans 1,2 dichloroethylene RQ=1000lbs
(40CFR 302):
SARA Section 311/312 Hazard Categories: Acute Health Hazard; Chronic Health Hazard; Fire Hazard
US. EPA EPCRA SARA Title III Section 302 None
Extremely Hazardous Substance (40 CFR 355,
Appendix A):
US. EPA EPCRA SARA Title III Section 313 None
Toxic Chemicals (40 CFR 372.65) - Supplier
Notification Required:
US. EPA RCRA Composite List of Hazardous If discarded in its purchased form, this product will not be a hazardous waste
Wastes and Appendix VIII Hazardous either by listing or by characteristic. However, under RCRA, it is
Page 6 of 7
Heatlok Soy B-side
Constituents (40CFR 261): responsibility of the product user to determine at the time of disposal,
whether a material containing the product or derived from the product
should be classified as a hazardous waste. (40 CFR 261.20-24)
Check individual state requirements.
State Regulations:
Canada
Class D-2B Material causing other toxic effects (toxic)
WHMIS
Section 16. OTHER INFORMATION
Health Hazard 2
HMIS Rating
0-Minimal; 1- Slight; 2- Moderate; 3-Serious; 4- Severe; Fire Hazard 1
*- Chronic Health Hazard Reactivity Hazard 0
Health Hazard: 2
NFPA Rating
Flammability Hazard: 1
0- Insignificant; 1-Slight; 2-Moderate; 3-High; 4-Extreme
Instability Hazard: 0
This product does not contain nor is it manufactured with ozone depleting substances.
Section 16: APPROVALS
Notice: The information herein is presented in good faith and believed to be accurate as of the effective date shown bellow.
However, no warranty expresses or implied is given.
Regulatory requirements are subject to change and may differ from one location to another; it is user's responsibility to
ensure that its activities comply with country, provincial and local laws.
This product may present hazards and should be used with caution. While certain hazards are described in this
publication, no guarantee is made that these are only hazards that exist.
Hazards, toxicity and behavior of the products may differ when used with other materials and are dependent upon
manufacturing circumstances or other processes. Such hazards, toxicity and behavior should be determined by the user
and made known to handlers, processors and end users.
Julija Sinanovic, Polyurethane Chemist
Prepared by:
Dave Lall, General Manager
Approved by:
February, 2010
Preparation date:
February, 2010
Current issue date:
Page 7 of 7
|