No Clean Flux Remover G3
MATERIAL SAFETY DATA SHEET
Finished Product
Date-Issued: 08/29/2003
MSDS Ref. No: 1634-12S
Date-Revised: 08/29/2003
Revision No: New MSDS
No Clean Flux Remover G3
1. PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: No Clean Flux Remover G3
PRODUCT DESCRIPTION: No Clean Flux Remover G3
PRODUCT CODE: 1634-12S
MANUFACTURER 24 HR. EMERGENCY TELEPHONE
NUMBERS
Techspray, L.P. CHEMTREC (U.S.): (800) 424-9300
1001 N.W. 1st Street CANUTEC: (613) 996-6666
P.O. Box 949 Emergency Phone: 1-800-858-4043
Amarillo, TX 79107
Contact: Chemtrec
Product Stewardship: 1-800-858-4043
2. COMPOSITION / INFORMATION ON INGREDIENTS
Chemical Name Wt.% CAS# EINECS#
156-60- 205-860-
1,2-transdichloroethylene (Trans) 30 - 90
5 2
460-73-
1,1,1,3,3-Pentafluoropropane (HFC-245fa) 10 - 50 4191706
1
200-659-
Methanol 1-5 67-56-1
6
202-598-
Ethyl Hydroxy Propionate <1 97-64-3
0
811-97-
1,1,1,2-Tetrafluoroethane (HFC-134a) 10 - 20 223770
2
124-38-
Carbon dioxide 1 - 10
9
EEC LABEL SYMBOL AND CLASSIFICATION
file:///C|/Documents%20and%20Settings/brown/Desktop/MSDS/English/6959ovmi.htm (1 of 8)9/22/2003 6:19:59 AM
No Clean Flux Remover G3
EEC Harmful - "Xn"
3. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
PHYSICAL APPEARANCE: Transparent, colorless liquid.
IMMEDIATE CONCERNS: Warning! High concentrations of vapor can reduce oxygen available for
breathing. Harmful if inhaled. May decompose on contact with flames or extremely hot metal surfaces to
produce toxic and corrosive products.
POTENTIAL HEALTH EFFECTS
EYES: Substance causes substantial eye irritation.
SKIN: Prolonged or repeated contact can result in defatting and drying of the skin which may result in skin
irritation and dermatitis (rash).
INGESTION: Substance may be harmful if swallowed.
INHALATION: High concentrations in immediate area can displace oxygen and can cause dizziness,
unconsciousness, and possibly death with longer exposure. Keep people away from such vapors without self-
contained breathing apparatus.
SIGNS AND SYMPTOMS OF OVEREXPOSURE
EYES: Liquid splashed in the eye may cause redness, irritation and conjunctivitis.
SKIN: Prolonged exposure causes redness, pain, drying and cracking of the skin.
INGESTION: For large amounts; abdominal pain, nausea and vomiting.
INHALATION: High concentrations may lead to central nervous system effects (drowsiness, dizziness, nausea,
headaches, paralysis and loss of consciousness).
ACUTE TOXICITY: Overexposure may cause dizziness and loss of concentration. At higher levels, CNS
depression and cardiac arrhythmia may result.
REPRODUCTIVE TOXICITY
TERATOGENIC EFFECTS: Contains Methanol which has been established as a teratogen by inhalation. See
Sec.11 for details.
4. FIRST AID MEASURES
EYES: Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue
flushing for at least 15 minutes. Have eyes examined and tested by medical personnel.
SKIN: Immediately flush skin with plenty of water. Remove clothing. Get medical attention immediately. Wash
clothing separately before reuse.
file:///C|/Documents%20and%20Settings/brown/Desktop/MSDS/English/6959ovmi.htm (2 of 8)9/22/2003 6:19:59 AM
No Clean Flux Remover G3
INGESTION: If swallowed, gently wipe or rinse the inside of the mouth with water. DO NOT induce vomiting.
Sips of water may be given if person is fully conscious. Never give anything by mouth to an unconscious or
convulsing person. Immediately contact a poison control center, emergency room or physician as further treatment
may be necessary.
INHALATION: Remove to fresh air. If not breathing, give artificial respiration or give oxygen by trained
personnel. Seek immediate medical attention.
5. FIRE FIGHTING MEASURES
FLASHPOINT AND METHOD: Not Flammable
EXTINGUISHING MEDIA: Use alcohol foam, carbon dioxide, or water spray when fighting fires involving this
material.
FIRE FIGHTING PROCEDURES: Use water spray to keep fire-exposed containers cool and to knock down
vapors which may result from product decomposition.
FIRE FIGHTING EQUIPMENT: As in any fire, wear self-contained breathing apparatus pressure-demand,
(MSHA/NIOSH approved or equivalent) and full protective gear.
HAZARDOUS DECOMPOSITION PRODUCTS: Toxic oxides of carbon and corrosive vapors of hydrogen
chloride.
6. ACCIDENTAL RELEASE MEASURES
SMALL SPILL: Contain spill with dike to prevent entry into sewers.
LARGE SPILL: If this material is released into a work area, evacuate the area immediately.
GENERAL PROCEDURES: Dike area to contain spill. Take precautions as necessary to prevent contamination
of ground and surface waters. Recover spilled material on adsorbent, such as sawdust or vermiculite, and sweep into
closed containers for disposal. After all visible traces, including vapors, have been removed thoroughly wet vacuum
the area. Do not flush to sewer. If area of spill is porous, remove as much contaminated earth, gravel, etc. as
necessary and place in closed containers for disposal.
SPECIAL PROTECTIVE EQUIPMENT: Only personnel equipped with proper respiratory and skin/eye
protection should be permitted in area. See Section 8 for details.
7. HANDLING AND STORAGE
HANDLING: Use with sufficient ventilation to keep employee exposure below recommended limits. Provide
adequate ventilation for storage, handling and use, especially for enclosed or low spaces. Avoid contact of liquid
with eyes and prolonged skin exposure. Do not allow product to contact open flame or electrical heating elements
because dangerous decomposition products may form.
STORAGE: Store away from heat.
file:///C|/Documents%20and%20Settings/brown/Desktop/MSDS/English/6959ovmi.htm (3 of 8)9/22/2003 6:19:59 AM
No Clean Flux Remover G3
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
EXPOSURE GUIDELINES:
OSHA HAZARDOUS COMPONENTS (29 CFR 1910.1200)
EXPOSURE LIMITS
OSHA PEL ACGIH TLV Supplier OEL
3 3 3
ppm mg/m ppm mg/m ppm mg/m
TWA NE[1]
1,2-transdichloroethylene (Trans) 200 NE
STEL NE 200
1,1,1,3,3-Pentafluoropropane (HFC-245fa) TWA NONE NONE 300
STEL NONE NONE
TWA S 200[2] 260
Methanol S 200 262 NL NL
STEL 250 310 250 328 NL NL
TWA [3]
Ethyl Hydroxy Propionate
[4]
STEL
[5]
1,1,1,2-Tetrafluoroethane (HFC-134a) TWA NONE NONE NONE 1000
OSHA TABLE COMMENTS:
1. NOT ESTABLISHED
2. S = Skin
3. NA=NOT APPLICABLE
4. NOT APPLICABLE
5. Limit established by supplier
ENGINEERING CONTROLS: Use process enclosures, local exhaust ventilation, or other engineering controls to
control airborne levels below recommended exposure limits.
PERSONAL PROTECTIVE EQUIPMENT
EYES AND FACE: For normal conditions, wear safety glasses. Where there is reasonable probability of liquid
contact, wear splash-proof goggles.
SKIN: The glove(s) listed below may provide protection against permeation. Gloves of other chemically
resistant materials may not provide adequate protection.
Buna
Butyl
Natural Latex
Neoprene
Solvex
Viton
RESPIRATORY: A respiratory protection program that meets OSHA 1910.134 and ANSI Z88.2 requirements
must be followed whenever workplace conditions warrant a respirator's use.
OTHER USE PRECAUTIONS: Emergency shower and eyewash facility should be in close proximity.
file:///C|/Documents%20and%20Settings/brown/Desktop/MSDS/English/6959ovmi.htm (4 of 8)9/22/2003 6:19:59 AM
No Clean Flux Remover G3
9. PHYSICAL AND CHEMICAL PROPERTIES
ODOR: Faint ethereal odor
APPEARANCE: Clear, Colorless liquid
PERCENT VOLATILE: 100 at 20癈 (68癋)
VAPOR PRESSURE: 17.75 psi at 20癈 (68癋)
EVAPORATION RATE: >1 (TCE=1)
SPECIFIC GRAVITY: 1.236 @ 20癈/20癈
(VOC): 855.2 g/L (non-exempt VOC)
10. STABILITY AND REACTIVITY
STABLE: YES
HAZARDOUS POLYMERIZATION: NO
CONDITIONS TO AVOID: Stable. However, may decompose if heated.
STABILITY: Stable.
POLYMERIZATION: Will not occur.
HAZARDOUS DECOMPOSITION PRODUCTS: May form hydrochloric and hydrofluoric acids - possibly
carbonyl halides, when exposed to high temperatures.
INCOMPATIBLE MATERIALS: Oxidizing agents, alkalies and bases.
11. TOXICOLOGICAL INFORMATION
ACUTE
EYES: Moderately to severely irritating
DERMAL LD : Mildly to moderately irritating.
50
ORAL LD : Slight to very low toxicity.
50
INHALATION LC : Slight to very low toxicity.
50
SKIN EFFECTS: Based on human exposure reports, prolonged and repeated skin contact with Methanol has
produced toxic effects including vision effects and death.
12. ECOLOGICAL INFORMATION
ENVIRONMENTAL DATA: There is limited information available on the environmental fate and effects of this
material. The primary environmental concern for release is the impact on aquatic and terrestrial species. Due care
file:///C|/Documents%20and%20Settings/brown/Desktop/MSDS/English/6959ovmi.htm (5 of 8)9/22/2003 6:19:59 AM
No Clean Flux Remover G3
should be taken to avoid the accidental release of this material into the environment.
ECOTOXICOLOGICAL INFORMATION: Invertebrate toxicity: LC50 (30 min) Photobacterium phosphoreum
= 1540 ppm Microtoxicity test.
13. DISPOSAL CONSIDERATIONS
FOR LARGE SPILLS: Contaminated sawdust, vermiculite, or porous surfaces must be disposed of in a permitted
hazardous waste management facility. Recovered liquids may be reprocessed or incinerated or must be treated in a
permitted hazardous waste management facility.
GENERAL COMMENTS: Dispose of in a manner consistent with federal, state, and local regulations.
14. TRANSPORT INFORMATION
DOT (DEPARTMENT OF TRANSPORTATION)
PROPER SHIPPING NAME: CONSUMER COMMODITY ORM-D
PRIMARY HAZARD CLASS/DIVISION: No classification
UN/NA NUMBER: N/A
PACKING GROUP: N/A
AIR (ICAO/IATA)
PROPER SHIPPING NAME: CONSUMER COMMODITY ID8000
PRIMARY HAZARD CLASS/DIVISION: 9
UN/NA NUMBER: ID8000
PACKING GROUP: N/A
IATA NOTE: Domestic shipments only. When shipping International contact TechSpray shipping department.
VESSEL (IMO/IMDG)
PROPER SHIPPING NAME: AEROSOLS IN LIMITED QUANTITIES OF CLASS 2
PRIMARY HAZARD CLASS/DIVISION: 2.2
UN/NA NUMBER: UN1950
PACKING GROUP: N/A
IMDG NOTE: Page 2102
15. REGULATORY INFORMATION
UNITED STATES
SARA TITLE III (SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT)
311/312 HAZARD CATEGORIES: IMMEDIATE / DELAYED
FIRE: NO PRESSURE GENERATING: YES REACTIVITY: NO ACUTE: YES
CHRONIC: YES
313 REPORTABLE INGREDIENTS: Methanol (3.55%)
TITLE III NOTES: Not listed as an Extremely Hazardous Substance.
302/304 EMERGENCY PLANNING
file:///C|/Documents%20and%20Settings/brown/Desktop/MSDS/English/6959ovmi.htm (6 of 8)9/22/2003 6:19:59 AM
No Clean Flux Remover G3
EMERGENCY PLAN: Methanol (#67-56-1)
CERCLA (COMPREHENSIVE RESPONSE, COMPENSATION, AND LIABILITY ACT)
CERCLA REGULATORY: Releases to air, land, or water which exceed the RQ must be reported to the
National Response Center [(800)424-8802] and to your Local Emergency Planning Committee.
CERCLA RQ: Trans-1,2-dichloroethylene is listed in Table 302.4 of 40 CFR Part 302 as a hazardous
substance. Reportable Quantity = 1,000 lbs. Methanol has an RQ of 5000 lbs.
EPA
EPA RQ INGREDIENT: trans-1,2-dichloroethylene (# 156-60-5)
TSCA (TOXIC SUBSTANCE CONTROL ACT)
TSCA REGULATORY: This product is listed on the TSCA Inventory.
OSHA HAZARD COMM. RULE: Contents of this MSDS comply with the OSHA Hazard Communication
Standard 29 CFR 1910.1200.
OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION (OSHA)
29 CFR 1910.119---PROCESS SAFETY MANAGEMENT OF HIGHLY HAZARDOUS
CHEMICALS: None of the chemicals in this product are considered highly hazardous by OSHA.
CANADA
WHMIS (WORKER HAZARDOUS MATERIALS INFORMATION SYSTEM): This MSDS has been
prepared according to the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains
all of the information required by the CPR.
WHMIS CLASS: Class D2B - Toxic Materials
EUROPEAN COMMUNITY
EEC LABEL SYMBOL AND CLASSIFICATION
EEC Harmful - "Xn"
CALIFORNIA PROPOSITION 65: This product does not contain any chemicals known to the State of California
to cause cancer.
16. OTHER INFORMATION
APPROVED BY: Pierce A. Pillon TITLE: Chemist
REVISION SUMMARY New MSDS
file:///C|/Documents%20and%20Settings/brown/Desktop/MSDS/English/6959ovmi.htm (7 of 8)9/22/2003 6:19:59 AM
No Clean Flux Remover G3
NFPA CODES
HMIS RATING
2
HEALTH:
3
3
FLAMMABILITY:
0
PHYSICAL HAZARD: 2 0
PERSONAL PROTECTION:
MANUFACTURER SUPPLEMENTAL NOTES: The use of this product for cleaning is subject to U.S. Patent
no. 5,902,412 and use is restricted by Tech Spray, L.P.
DATA SOURCES: Code of Federal Regulations (CFR)
The Sigma-Aldrich Library of Regulatory and Safety Data
OSHA Hazard Communication Standard (29CFR1910.1200)
Various Federal, State and Local Regulations
MANUFACTURER DISCLAIMER: To the best of our knowledge, the information contained herein is accurate.
However, neither Tech Spray, L.P., or any of its subsidiaries assumes any liability whatsoever for the accuracy or
completeness of the information contained herein. Final determination of suitability of any material is the sole
responsibility of the user. All materials may present unknown hazards and should be used with caution. Although
certain hazards are described herein, we cannot guarantee that these are the only hazards which exist.
file:///C|/Documents%20and%20Settings/brown/Desktop/MSDS/English/6959ovmi.htm (8 of 8)9/22/2003 6:19:59 AM
|