Material Safety Data Sheet
Section 1: Product & Company Identification
Product Name: MARYKATE?Cleaning Detail?Non-skid Deck Cleaner
Product Number (s): MK2132
general purpose boat cleaner
Product Use:
Manufacturer / Supplier Contact Information:
In United States: In Canada: In Mexico:
CRC Industries, Inc. CRC Canada Co. CRC Industries Mexico
885 Louis Drive 2-1246 Lorimar Drive Av. Benito Ju醨ez 4055 G
Warminster, PA 18974 Mississauga, Ontario L5S 1R2 Colonia Orqu韉ea
www.crcindustries.com www.crc-canada.ca San Lu韘 Potos? SLP CP 78394
1-215-674-4300 (General) 1-905-670-2291 www.crc-mexico.com
(800) 521-3168 (Technical) 52-444-824-1666
(800) 272-4620 (Customer Service)
24-Hr Emergency ?CHEMTREC: (800) 424-9300 or (703) 527-3887
Section 2: Hazards Identification
Emergency Overview
WARNING: May Cause Eye and Skin Irritation
As defined by OSHA's Hazard Communication Standard, this product is hazardous.
Appearance & Odor: Viscous, opaque green liquid, clove fragrance.
Potential Health Effects:
ACUTE EFFECTS:
EYE: May cause mild eye irritation including stinging and redness.
SKIN: May cause mild skin irritation including burning and redness.
INHALATION: Not expected to cause significant health effects. May cause minor, temporary throat irritation with
extended exposure.
INGESTION: May cause severe gastric distress.
CHRONIC EFFECTS: None known
TARGET ORGANS: Unknown
Medical Conditions Aggravated by Exposure: None known
See Section 11 for toxicology and carcinogenicity information on product ingredients.
Page 1 of 7
Product Name: MARYKATE?Cleaning Detail?Non-skid Deck Cleaner
Product Number (s): MK2132
Section 3: Composition/Information on Ingredients
COMPONENT CAS NUMBER % by Wt.
Water 7732-18-5 50 ?60
Oxalic acid 144-62-7 1-5
Section 4: First Aid Measures
Eye Contact: Immediately flush with plenty of water for 15 minutes. Call a physician if irritation persists.
Skin Contact: Remove contaminated clothing and wash affected area with soap and water. Call a physician if
irritation persists. Wash contaminated clothing prior to re-use.
Inhalation: Remove person to fresh air. Keep person calm. If not breathing, give artificial respiration. If
breathing is difficult give oxygen. Call a physician.
Ingestion: Induce vomiting by administering syrup of IPEAC, salt water, or if these are not available use finger
in throat method. Give one or two glasses of water and repeat vomiting until vomit is clear. Contact
a poison control center or physician for further instructions.
Note to Physicians: Treat symptomatically.
Section 5: Fire-Fighting Measures
As defined by OSHA, this product is not flammable.
Flammable Properties:
Flash Point: None (TCC) Upper Explosive Limit: ND
Autoignition Temperature: ND Lower Explosive Limit: ND
Fire and Explosion Data:
Suitable Extinguishing Media: As appropriate for surrounding fire.
Products of Combustion: Irritating gases or fumes may be released when product is heated.
Explosion Hazards: Containers, when exposed to heat from fire, may build pressure and rupture.
Protection of Fire-Fighters: Firefighters should wear self-contained, NIOSH-approved breathing apparatus for
protection against suffocation and possible toxic decomposition products. Proper eye and
skin protection should be provided. Use water spray to keep fire-exposed containers cool
and to knock down vapors which may result from product decomposition.
Section 6: Accidental Release Measures
Personal Precautions: Use personal protection recommended in Section 8.
Environmental Precautions: Take precautions to prevent entry into waterways, sewers, basements or confined areas.
Do not flush into sewers or storm drains.
Methods for Containment & Clean-up: Dike area to contain spill. Ventilate the area with fresh air. If in confined space or
limited air circulation area, clean-up workers should wear appropriate respiratory
protection. Recover or absorb spilled material using an absorbent designed for
chemical spills. Place used absorbents into proper waste containers.
Page 2 of 7
Product Name: MARYKATE?Cleaning Detail?Non-skid Deck Cleaner
Product Number (s): MK2132
Section 7: Handling and Storage
Handling Procedures: Avoid contact with skin and eyes. Use good personal hygiene practices. Wash hands before
eating or drinking. Wash thoroughly after work using soap and water. For product use
instructions, please see the product label.
Storage Procedures: Store in a cool dry area out of direct sunlight. Containers should be tightly closed while in
storage. Store in a well ventilated area. Keep from freezing and overheating (store between 50
and 100?F). Keep out of reach of children.
Aerosol Storage Level: NA
Section 8: Exposure Controls/Personal Protection
Exposure Guidelines:
OSHA ACGIH OTHER
COMPONENT TWA STEL TWA STEL TWA SOURCE UNIT
Water NE NE NE NE NE
mg/m3
Oxalic acid 1 NE 1 2 NE
N.E. ?Not Established (c) ?ceiling (s) ?skin (v) ?vacated
Controls and Protection:
Engineering Controls: Area should have ventilation to provide fresh air. Local exhaust ventilation is generally
preferred because it can control the emissions of the contaminant at the source, preventing
dispersion into the general work area. Use mechanical means if necessary to maintain vapor
levels below the exposure guidelines. If working in a confined space, follow applicable OSHA
regulations.
Respiratory Protection: None required for normal work where adequate ventilation is provided. If engineering controls
are not feasible or if exposure exceeds the applicable exposure limits, use a NIOSH-approved
cartridge respirator with an acid gas cartridge. Air monitoring is needed to determine actual
employee exposure levels. Use a self-contained breathing apparatus in confined spaces and
for emergencies.
Eye/face Protection: For normal conditions, wear safety glasses. Where there is reasonable probability of liquid
contact, wear splash-proof goggles.
Skin Protection: Use protective gloves such as butyl rubber or latex. Also, use full protective clothing if there is
prolonged or repeated contact of liquid with skin.
Section 9: Physical and Chemical Properties
Physical State: viscous liquid
Color: green
Odor: clove fragrance
Odor Threshold: ND
Specific Gravity: 1.13
Initial Boiling Point: 212? F
Freezing Point: ND
Vapor Pressure: ND
Vapor Density: ND (air = 1)
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Product Name: MARYKATE?Cleaning Detail?Non-skid Deck Cleaner
Product Number (s): MK2132
Evaporation Rate: Slow
Solubility: 71% in water
Coefficient of water/oil distribution: ND
pH: 8.0 ?9.0
Volatile Organic Compounds: wt %: 0 g/L: 0 lbs./gal: 0
Section 10: Stability and Reactivity
Stability: Stable
Conditions to Avoid: Freezing and overheating
Incompatible Materials: Strong oxidizers
Hazardous Decomposition Products: Oxides of carbon
Possibility of Hazardous Reactions: No
Section 11: Toxicological Information
Long-term toxicological studies have not been conducted for this product. The following information is available for
components of this product.
Acute Toxicity:
Component Oral LD50 (rat) Dermal LD50 (rabbit) Inhalation LC50 (rat)
Water > 90 mL/kg No data No data
Oxalic acid No data No data No data
Chronic Toxicity:
OSHA IARC NTP
Component Carcinogen Carcinogen Carcinogen Irritant Sensitizer
Water No No No No No
Oxalic acid No No No E (severe) / Unknown
S (severe)
E ?Eye S ?Skin R - Respiratory
Reproductive Toxicity: No information available
Teratogenicity: No information available
Mutagenicity: No information available
Synergistic Effects: No information available
Section 12: Ecological Information
Ecological studies have not been conducted for this product. The following information is available for components of this
product.
Ecotoxicity: No information available
Persistence / Degradability: Biodegradable.
Bioaccumulation / Accumulation: No information available
Mobility in Environment: No information available
Section 13: Disposal Considerations
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Product Name: MARYKATE?Cleaning Detail?Non-skid Deck Cleaner
Product Number (s): MK2132
This product is not a RCRA hazardous waste. (See 40 CFR Part 261.20 ?261.33)
Waste Classification:
Empty containers may be recycled.
All disposal activities must comply with federal, state, provincial and local regulations. Local regulations may be more
stringent than state, provincial or national requirements.
Section 14: Transport Information
Not Regulated
US DOT (ground):
Not Regulated
ICAO/IATA (air):
Not Regulated
IMO/IMDG (water):
None
Special Provisions:
Section 15: Regulatory Information
U.S. Federal Regulations:
Toxic Substances Control Act (TSCA):
All ingredients are either listed on the TSCA inventory or are exempt.
Comprehensive Environmental Response, Compensation and Liability Act (CERCLA):
Reportable Quantities (RQ's) exist for the following ingredients: None
Spills or releases resulting in the loss of any ingredient at or above its RQ require immediate notification to the
National Response Center (800-424-8802) and to your Local Emergency Planning Committee.
Superfund Amendments Reauthorization Act (SARA) Title III:
Section 302 Extremely Hazardous Substances (EHS): None
Section 311/312 Hazard Categories: Fire Hazard No
Reactive Hazard No
Release of Pressure No
Acute Health Hazard Yes
Chronic Health Hazard No
Section 313 Toxic Chemicals: This product contains the following substances subject to the reporting requirements
of Section 313 of Title III of the Superfund Amendments and Reauthorization Act of
1986 and 40 CFR Part 372:
None
Clean Air Act:
Section 112 Hazardous Air Pollutants (HAPs): None
U.S. State Regulations:
California Safe Drinking Water and Toxic Enforcement Act (Prop 65):
This product may contain the following chemicals known to the state of
California to cause cancer, birth defects or other reproductive harm: None
Consumer Products VOC Regulations: In states with Consumer Products VOC regulations, this product is compliant as
a General Purpose Cleaner.
State Right to Know:
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Product Name: MARYKATE?Cleaning Detail?Non-skid Deck Cleaner
Product Number (s): MK2132
New Jersey: 144-62-7
Pennsylvania: 144-62-7
Massachusetts: 144-62-7
Rhode Island : 144-62-7
Canadian Regulations:
Controlled Products Regulations:
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the
MSDS contains all the information required by the Controlled Products Regulations.
WHMIS Hazard Class: D2B
Canadian DSL Inventory: All ingredients are either listed on the DSL Inventory or are exempt.
European Union Regulations:
RoHS Compliance: This product is compliant with Directive 2002/95/EC of the European Parliament and of the
Council of 27 January 2003. This product does not contain any of the restricted substances as
listed in Article 4(1) of the RoHS Directive.
None
Additional Regulatory Information:
Section 16: Other Information
NFPA
HMIS?(II)
Health: 1
Flammability: 0
0
Reactivity: 0
1 0
PPE: B
Ratings range from 0 (no hazard) to 4 (severe hazard)
Prepared By: Michelle Rudnick
CRC #: 76213
Revision Date: 08/03/2009
Changes since last revision: MSDS reformatted to meet the requirements of the Canadian Controlled Products
Regulations.
The information contained in this document applies to this specific material as supplied. It may not be valid for this
material if it is used in combination with any other materials. This information is accurate to the best of CRC Industries'
knowledge or obtained from sources believed by CRC to be accurate. Before using any product, read all warnings and
directions on the label. For further clarification of any information contained on this MSDS consult your supervisor, a
health & safety professional, or CRC Industries.
Page 6 of 7
Product Name: MARYKATE?Cleaning Detail?Non-skid Deck Cleaner
Product Number (s): MK2132
IMDG: International Maritime Dangerous Goods
IMO: International Maritime Organization
lbs./gal: pounds per gallon
LC: Lethal Concentration
LD: Lethal Dose
NA: Not Applicable
ND: Not Determined
NIOSH: National Institute of Occupational Safety & Health
NFPA: National Fire Protection Association
NTP: National Toxicology Program
ACGIH: American Conference of Governmental Industrial Hygienists OSHA: Occupational Safety and Health Administration
CAS: Chemical Abstract Service PMCC: Pensky-Martens Closed Cup
CFR: Code of Federal Regulations PPE: Personal Protection Equipment
DOT: Department of Transportation ppm: Parts per Million
DSL: Domestic Substance List RoHS: Restriction of Hazardous Substances
g/L: grams per Liter STEL: Short Term Exposure Limit
HMIS: Hazardous Materials Identification System TCC: Tag Closed Cup
IARC: International Agency for Research on Cancer TWA: Time Weighted Average
IATA: International Air Transport Association WHMIS: Workplace Hazardous Materials Information System
ICAO: International Civil Aviation Organization
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