#142
MATERIAL SAFETY DATA SHEET
EPA Reg. No. 6836-86-1658 EPA Est. No. 1658-MO-1
NFPA RATING: Health = 3 Flammability = 0 Reactivity = 0
HMIS RATING: Health = / 3 Flammability = 1 Reactivity = 0
SECTION I -- IDENTITY AND MANUFACTURER'S INFORMATION (1117A)
Distributor's Name: HILLYARD INDUSTRIES Product Name: SHOWER ROOM CLEANER
Address: 302 North Fourth Street Date Prepared: January 12, 2007
St. Joseph, MO 64501 Prepared by: Regulatory Affairs Department
Emergency Telephone No.: (800) 424-9300 (Only in the event of chemical emergency involving a spill, leak, fire, exposure or
accident involving chemicals.) Other information calls: (816) 233-1321 (Ext. 8285)
http://www.hillyard.com
SECTION I ?INGREDIENTS/IDENTITY INFORMATION
Components
(Specific Chemical Identity: OTHER LIMITS
Common Name(s) CAS# OSHA PEL ACGIH TLV RECOMMENDED %
Phosphoric acid*(1) 7664-38-2 1 mg./m3 1 mg./m3 3 mg/m3 5 - 10
Oxalic acid (2) 144-62-7 1 mg./m3 1 mg./m3 2 mg/m3 1-3
Water 7732-18-5 none none N.A. ---
Primary alcohol ethoxylate 68439-46-3 not established not established not <2
established
Di-N-alkyl (C8/C10-50%: C10/C10-30%, 68424-95-3 not established not established N.A. 1.5
C8/C8-20%) dimethylammonium chloride
N-alkyl (C14-50%: C12-40%, C16-10%) 68424-85-1 not established not established N.A. 1.0
dimethyl benzylammonium chloride
*This product contains the following chemicals subject to the reporting requirements of SARA Title III, Sec. 313, and 40 CFR Part 372:
Phosphoric acid.
(1) Regulated by OSHA, and the following states: CT, FL, IL, LA, MA, NJ, NY, PA, and RI. (2) Regulated by OSHA and the following states:
CA., FL, IL, PA, TX.
VOC of concentrate = less than 0.01%
SECTION III ?PHYSICAL / CHEMICAL CHARACTERISTICS
Boiling Point: 208篎 Specific Gravity (H2O = 1): 25篊 = 1.05 & 39篊 = 1.05
Vapor Pressure (mm Hg.): not established Percent Volatile by Volume (%): 86.9%
Vapor Density (AIR = 1): not established Evaporation Rate (ethyl ether = 1): slower than 1
Solubility in Water: complete Appearance and Odor: blue/green liquid, mint odor
pH = 0.7-1.0
SECTION IV ?FIRE AND EXPLOSION HAZARD DATA
Flash point: None (T.C.C.) Flammable Limits: LEL = N.A. UEL = N.A.
Extinguishing Media: Water, CO2, dry chemical or foam.
Special Fire Fighting Procedures: Must wear NIOSH/MSHA approved self-contained breathing apparatus and
protective clothing. Cool fire-exposed containers with water spray.
Unusual Fire and Explosion Hazards: Products of combustion are toxic.
SECTION V ?PHYSICAL HAZARDS
Stability: Stable Conditions to Avoid: None known to manufacturer.
Incompatibility (Materials to Avoid): None known by manufacturer.
Hazardous Decomposition Products or Byproducts: Thermal decomposition may produce toxic fumes of hydrogen
chloride and oxides of carbon, nitrogen and phosphorous.
Hazardous Polymerization: Will not occur Conditions to Avoid: None known.
SECTION VI -- HEALTH HAZARD DATA
Routes of entry: Inhalation? by mist Skin? yes Ingestion? yes
HEALTH HAZARDS (1. Acute and 2. Chronic)
1. Harmful if swallowed. Eye and skin irritant. May cause permanent damage.
2. None known.
Chemical listed as Carcinogen or Potential Carcinogen:
National Toxicology Program = No I.A.R.C. Monographs = No OSHA = No
This product has no carcinogens listed by IARC, NTP, NIOSH, or ACGIH as of this date, greater than or equal to 0.1%.
page 2 of #142 Shower Room Cleaner
SECTION VI ?HEALTH HAZARD DATA continued
Signs and Symptoms of Overexposure: No information found on this formula. Based upon information available for similar products, it is
anticipated that this material will be corrosive to the skin and eyes upon direct or prolonged contact. Solvent vapors or mists or products
can cause irritation of mucous membranes. Ingestion can cause immediate burning pain in the mouth, throat, and abdomen; severe swelling
of the larynx; skeletal muscle paralysis affecting the ability to breathe; circulatory shock; and/or convulsions. May be fatal.
Medical Conditions Generally Aggravated by Exposure: No effects known to manufacturer.
Emergency and First Aid Procedures: Eyes: Flush eyes with large amounts of running water for at least 15 minutes. Hold eyelids apart
to ensure rinsing of the entire surface of the eye and lids with water. If physician not available, flush for additional 15 minutes. Get
immediate medical attention. Skin: Wash with large amounts of running water, and soap if available, for 15 minutes. Remove
contaminated clothing and shoes. Get immediate medical attention. Wash clothing and decontaminate shoes before reuse. Ingestion: If
swallowed, immediately give 3-4 glasses of milk (if unavailable, give water). DO NOT induce vomiting. If vomiting occurs, give fluids
again. Have physician determine if patient's condition allows for induction of vomiting or evacuation of the stomach. Do not give
anything by mouth to a convulsing or unconscious person. Get immediate medical attention. Inhalation: Remove from area to fresh air.
If not breathing, clear airway and start mouth-to-mouth artificial respiration or use a bag-mask respirator. Get immediate medical attention.
If victim is having trouble breathing, transport to medical care and, if available, give supplemental oxygen.
SECTION VII ?PRECAUTIONS FOR SAFE HANDLING AND USE
Steps To Be Taken In Case Material Is Released Or Spilled: Danger! Corrosive material. Floors may become slippery. Wear
appropriate protective equipment and MSHA/NIOSH approved respirator where mist or vapors of unknown concentrations may be
generated (self-contained breathing apparatus preferred). Dike and contain spill with inert material (sand, earth, etc.) and transfer the liquid
and solid separately to containers for recovery or disposal. Keep spill out of sewers and open bodies of water.
Waste Disposal Method: Disposal in compliance with all federal, state and local laws and regulations. Incineration is the preferred
method.
Precautions To Be Taken In Handling And Storing: Store at temperatures below 140篎. Keep containers closed until used. Do not
contaminate drinking water, food or feed by storage or disposal.
Other Precautions: Use only according to label directions. If unsure about safe use, contact your supervisor immediately.
SECTION VIII ?CONTROL MEASURES
Respiratory Protection (Specify Type): In processes where TLV may be exceeded, or mists and/or vapors may be generated, proper
ventilation must be provided in accordance with good ventilation practices. Where mist or vapors are generated by the process, a
NIOSH/OSHA jointly approved respirator is advised in the absence of proper environmental controls.
Ventilation: Local Exhaust = As necessary Mechanical (General) = As adequate Special = N.A. Other = N.A.
Protective Gloves: Rubber or neoprene, when needed, to prevent skin contact. Eye Protection: Wear chemical splash goggles where
there is a potential for eye contact. Use safety glasses with side shields under normal use conditions.
Other Protective Clothing or Equipment: Eye wash; safety shower; protective clothing (long sleeves, coveralls or other, as appropriate),
when needed to prevent skin contact.
Work / Hygienic Practices: Follow OSHA mandated procedures. Never eat or smoke while working with chemicals. Good housekeeping
practices apply. Wash thoroughly after handling.
SECTION IX ?TRANSPORTATION INFORMATION
Applicable regulations: DOT =Yes; IMCO = Yes; IATA = Yes
DOT SHIPPING DESCRIPTION ON BILL OF LADING:
(Gallon boxes) = Consumer Commodity ORM-D
(5 Gallon) = Disinfectants, corrosive liquid, n.o.s. (Phosphoric Acid, Oxalic acid), 8, UN1903, III
IMCO and IATA SHIPPING DESCRIPTION ON BILL OF LADING:
Gallon boxes and 5 Gallon = Disinfectants, corrosive liquid, n.o.s. (Phosphoric Acid, Oxalic acid), 8, UN1903, III
Package Marking = Disinfectants, corrosive liquid, n.o.s. (Phosphoric Acid, Oxalic acid), UN1903
Package Label = Corrosive Hazard Class = 8 Package Group = III
EPA Hazardous waste number/code: not listed
Hazardous waste characteristics: Ignitability = not applicable; Corrosivity = applicable; Reactivity = not applicable
DISCLAIMER OF WARRANTIES
NO REPRESENTATIONS OR WARRANTIES, EITHER EXPRESS OR IMPLIED, OF MERCHANTABILITY, FITNESS FOR A
PARTICULAR PURPOSE, OR OF ANY NATURE ARE MADE WITH RESPECT TO THE PRODUCT(S) OR INFORMATION
CONTAINED IN THIS MATERIAL SAFETY DATA SHEET. The information and recommendations contained in this Material Safety
Data Sheet are supplied pursuant to 29 CFR 1910.1200 of the Occupational Safety and Health Standards Hazard Communication Rule.
All information contained herein is presented in good faith and is believed to be appropriate and accurate. THE BUYER OR USER
ASSUMES ALL RISKS ASSOCIATED WITH THE USE, MISUSE OR DISPOSAL OF THIS PRODUCT. THE BUYER OR USER IS
RESPONSIBLE TO COMPLY WITH ALL FEDERAL, STATE OR LOCAL REGULATIONS CONCERNING THE USE, MISUSE OR
DISPOSAL OF THESE PRODUCTS.
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