Material Safety Data Sheet
Section 1. Product and Company Identification
Product Name ZUD?HEAVY DUTY CLEANSER Not available
MSDS#
(POWDER) - CANADIAN
Validation Date 10/27/2004
This MSDS applies to the nationally sold version of ZUD?Heavy
Product Description
Duty Cleanser that is distributed in Canada. 10/27/2004
Print Date
Reckitt Benckiser (Canada) Inc.
Manufacturer
2 Wickman Road
In case of Telephone: 800-888-0192
Toronto, Ontario M8Z 5M5 CANADA
Emergency: (Canada)
Not available.
Product Identifier
Transportation Chemtrec: 1-800-424-9300
Emergencies: (U.S. & Canada)
Item Number 62200-00214-00
Outside the U.S & Canada
(North America), call:
703-527-3887
F/F 890573
Formula Number
62200-00214 (400 gm.).
UPC Number
Section 2. Composition and Information on Ingredients
Name % by Weight
CAS # Exposure Limits : TLV/PEL
TWA: 0.1 (mg/m3) from ACGIH (TLV) Respirable.
1) SILICA, CRYSTALLINE 14808-60-7 70-80
TWA: 0.3 (mg/m3) from OSHA (PEL) Respirable.
TWA: 1 STEL: 2 (mg/m3) from ACGIH (TLV)
2) OXALIC ACID 144-62-7 5-10
TWA: 1 (mg/m3) from OSHA (PEL)
TWA: 15 (mg/m3) from ACGIH (TLV) Total.
3) PUMICE 1332-09-8 10-20
TWA: 10 (mg/m3) from OSHA (PEL) Total.
Section 3. Hazards Identification
WARNING: Irritating to eyes. Harmful if swallowed. Contains oxalic acid. Do not mix with chlorine type
Emergency Overview
bleach or other household chemicals.
KEEP OUT OF REACH OF CHILDREN.
Section 4. First Aid Measures
In case of eye contact, immediately rinse eyes with water, remove any contact lenses and continue to rinse
Eye Contact
eyes with plenty of water for at least 15 minutes. If irritation occurs or persists, get medical attention.
In case of skin contact, wash skin thoroughly with soap and water. If irritation persists, consult a physician.
Skin Contact
Remove to fresh air. If irritation persists or there is any trouble breathing, get immediate medical attention.
Inhalation
If swallowed, rinse mouth and give a glass of water. DO NOT induce vomiting. Contact a poison control
Ingestion
centre or physician immediately. NEVER give an unconscious person anything to ingest.
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ZUD?HEAVY DUTY CLEANSER (POWDER)
- CANADIAN
Section 5. Fire and Explosion Data
Not flammable. See Section 14 for any Shipping Classifications.
Flammability
Not applicable.
Flash Point
Not applicable.
Explosive Limits in Air
Not available.
Products of Combustion
None known.
Fire and Explosion Hazards
Not a fire hazard. Use extinguishing media suitable for surrounding materials.
Fire Fighting Media
and Instructions
Wear self-contained breathing apparatus and protective clothing appropriate for fighting a chemical fire.
Special Fire Fighting
Instructions
Section 6. Accidental Release Measures
Small powder spills: Collect powder raising as little dust as possible. Discard small amounts of material with
Accidental Spill
trash collection. Discard empty container in trash.
Large powder spills: Collect powder raising as little dust as possible and wear appropriate dust respirator
during clean-up operations. The disposal of the product must be made in accordance with provincial and
federal regulations.
Section 7. Handling and Storage
WARNING: Irritating to eyes. Harmful if swallowed. Contains oxalic acid. Do not mix with chlorine type
Handling and Storage
bleach or other household chemicals.
Store in original container in an upright position in a cool, dry place in areas inaccessible to children and
pets. KEEP OUT OF REACH OF CHILDREN.
Section 8. Exposure Controls/Personal Protection
None normally required. If user operations generate excessive dust, use ventilation to keep exposure to
Ventilation Requirements
airborne contaminants below the exposure limit.
Avoid contact with eyes. Emergency responders should wear full eye and face protection.
Eye Protection
Avoid skin contact. Emergency responders should wear impermeable gloves.
Skin Protection
Avoid breathing dust. Emergency responders should wear suitable respiratory protection where exposure to
Respiratory Protection
airborne dust is possible.
None required.
Other Protection
Washing with soap and water after use is recommended as good hygienic practice to prevent possible skin
Work/Hygienic Practices
irritation and/or eye irritation from hand contact.
Section 9. Physical and Chemical Properties
Free flowing powder.
Description None.
Odor
pH 1.5-2.5 (3% aqueous slurry). White. Off-white.
Color
Not applicable.
Boiling/Condensation Point
0.800 - 0.962 g/cc.
Specific Gravity
Not determined.
Vapor Pressure
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ZUD?HEAVY DUTY CLEANSER (POWDER)
- CANADIAN
Not determined.
Vapor Density
Not available.
Viscosity
<10% at 70癋.
Solubility
Physical Chemical Comments Not available.
Section 10. Stability and Reactivity Data
The product is stable.
Chemical Stability
None known.
Conditions of Instability
Do not use or mix with chlorine type bleaches or other household cleaning agents as harmful fumes may
Incompatibility with Various
result. May be harmful to painted or lacquered surfaces. Requires very gentle rubbing for use on fiberglass,
Substances
countertops, and plastic surfaces.
Oxalic acid may generate formic acid and carbon monoxide under fire conditions.
Hazardous Decomposition
Products
Will not occur.
Hazardous Polymerization
Section 11. Toxicological Information
Exposure effects
Eye Contact Irritating to eyes.
Not a primary skin irritant. May cause skin irritation upon prolonged or repeated contact.
Skin Contact
Inhalation toxicity not determined. May cause irritation to mucous membranes.
Inhalation
Harmful if swallowed.
Ingestion
Respirable crystalline silica has been designated by NTP and OSHA as a suspect carcinogen and by IARC
Carcinogenicity
as a Group 1 carcinogen. However, the use of this product in accordance with label instructions is not
expected to result in adverse health effects.
Section 12. Ecological Information
Not available.
Ecotoxicity
Section 13. Disposal Considerations
Small powder spills: Collect powder raising as little dust as possible. Discard small amounts of material with
Waste Disposal
trash collection. Discard empty container in trash.
Large powder spills: Collect powder raising as little dust as possible and wear appropriate dust respirator
during clean-up operations. The disposal of the product must be made in accordance with provincial and
federal regulations.
Section 14. Transport Information
Not regulated by DOT (United States).
DOT Classification
Not applicable.
Proper Shipping Name
Not applicable.
DOT Identification Number
Not applicable.
Packing Group
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ZUD?HEAVY DUTY CLEANSER (POWDER)
- CANADIAN
Not applicable.
Maritime Transportation
Not applicable.
Hazardous Substances
Reportable Quantity
Not applicable.
Special Provisions for
Transport
Not regulated by TDG.
TDG Classification
Not applicable.
ADR Classification
Not regulated by IMDG.
IMDG Classification
Not regulated by IATA.
IATA Classification
Section 15. Regulatory Information
SARA Title III, Section 313 Toxic Chemical Notification & Release Reporting:
Federal and State
Regulations
None
California Proposition 65: This product contains the following ingredients which require a warning under the Safe
Drinking Water & Toxic Enforcement Act:
1) SILICA, CRYSTALLINE Not available. 70-80 Not
available.
CLASS D-2A: Material causing other toxic effects (VERY TOXIC).
Other Classifications WHMIS (Canada)
CLASS E: Corrosive solid.
Section 16. Other Information
Fire Hazard
HMIS (U.S.A.) National Fire Protection
2
Health Hazard
0
Association (U.S.A.)
0
Fire Hazard Reactivity
0
2
Health
0
Reactivity
Specific hazard
A
Personal Protection
NFPA Aerosol Level Not applicable.
Validated by Product Safety on 10/27/2004. Printed 10/27/2004.
Notice to Reader
To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained
herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee
that these are the only hazards that exist.
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