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SECTION 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
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CHEMICAL PRODUCT IDENTIFICATION:
PRODUCT ID . . . . . . . . . . : 71-WHT/CLR
PRODUCT CLASS . . . . . . . . . : PAINT, SOLVENT BASE
TRADE NAME . . . . . . . . . . : SUPERKOTE ZONE MARKING PAINT
FORMULA ID . . . . . . . . . . : 71-WHT/CLR
MSDS PREPARATION DATE . . . . . . : 09/12/2005
MANUFACTURER IDENTIFICATION:
NAME . . . . . . . . . . . . . : INSL-X PRODUCTS CORPORATION
ADDRESS . . . . . . . . . . . . : 308 OLD COUNTY ROAD
EDGEWATER FL 32132
TELEPHONE . . . . . . . . . . . : 386-428-6461
EMERGENCY CONTACT . . . . . . . : CHEMTREC
EMERGENCY TELEPHONE . . . . . . : (800) 424-9300
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SECTION 2 - COMPOSITION/INFORMATION ON HAZARDOUS INGREDIENTS
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1 VM & P NAPHTHA
CAS# 64742-89-8
ALIPHATIC PETROLEUM DISTILLATES
PCT BY WT: 10 - 15 VAPOR PRESSURE: 10.200 MMHG @ 68F
EXPOSURE LIMIT:
ACGIH TLV/TWA: 300 ppm TWA
OSHA PEL/TWA: 300 ppm TWA
OSHA STEL: 400 ppm
LC50: Inhalation (Rat) - 3400 ppm/4H
LD50: Oral (Rat) - > 8 ml/kg
CA PROPOSITION 65: No
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2
CAS# 100-41-4
ETHYLBENZENE
PCT BY WT: .1300 VAPOR PRESSURE: 7.000 MMHG @ 68F
EXPOSURE LIMIT:
ACGIH TLV/TWA: TWA 100 ppm
ACGIH TLV/STEL: STEL 25 ppm
OSHA PEL/TWA: TWA 100 ppm
OSHA STEL: 125 ppm
LD50: Oral, Rat - 3500 mg/kg
CA PROPOSITION 65: Yes
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3 PETROLEUM SPIRITS
CAS# 8032-32-4
VM & P NAPHTHA
PCT BY WT: 5 - 10 VAPOR PRESSURE: 5.000 MMHG @ 68F
EXPOSURE LIMIT:
ACGIH TLV/TWA: TWA 300 ppm
OSHA PEL/TWA: TWA 300 ppm
OSHA STEL: 400 ppm
LC50: Inhalation, Rat - 3400 ppm/4H
LD50: Intravenous, Mouse - 40 mg/kg
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4
CAS# 13463-67-7
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INSL-X PRODUCTS CORPORATION
MATERIAL SAFETY DATA SHEET
71-WHT/CLR 1
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TITANIUM DIOXIDE
PCT BY WT: 5 - 10
EXPOSURE LIMIT:
ACGIH TLV/TWA: 10 mg/cu m(Total Dust) - TWA
OSHA PEL/TWA: 10 mg/cu m(Total Dust) - TWA
LD50: Oral (Rat)- >7500 mg/kg (TiO2)
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5 GROUND LIMESTONE
CAS# 1317-65-3
CALCIUM CARBONATE
PCT BY WT: 20 - 25
EXPOSURE LIMIT:
ACGIH TLV/TWA: 2 mg/cu m (Respirable Dust)
OSHA PEL/TWA: 15 mg/cu m (Total Dust)
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6 CALCINED KAOLIN
CAS# 1332-58-7
ALUMINIUM SILICATE
PCT BY WT: .5 - 5
EXPOSURE LIMIT:
ACGIH TLV/TWA: 2 mg/cu m (Respirable fraction)
OSHA PEL/TWA: 10 mg/cu m (Total dust)
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7 HYDROUS KAOLIN
CAS# 1332-58-7
ALUMINUM SILICATE
PCT BY WT: 10 - 15
EXPOSURE LIMIT:
ACGIH TLV/TWA: 2 mg/cu m - TWA
OSHA PEL/TWA: 10 mg/cu m (Total dust) - TWA
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This product contains one or more reported carcinogens or suspected
carcinogens which are noted in Section 3, Hazards Identification,
CARCINOGENICITY.
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This product contains one or more Hazardous Air Pollutants.
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This product contains pigments, which may become a dust nuisance when
removed by abrasive blasting, sanding, or grinding.
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SECTION 3 - HAZARDS IDENTIFICATION
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POTENTIAL HEALTH EFFECTS
EYES: May cause eye damage and pain.
SKIN: May irritate skin.
INHALATION: Anesthetic. Nervous system depression characterized by
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INSL-X PRODUCTS CORPORATION
MATERIAL SAFETY DATA SHEET
71-WHT/CLR 1
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the following progressive steps: headache, dizziness,
staggering gait, confusion, unconsciousness or coma.
May irritate nose, throat and respiratory tissue.
INGESTION: Swallowing small amounts of this product during normal
handling is not likely to cause harmful effects, but
swallowing large amounts may be harmful.
CHRONIC EFFECTS
NOTICE: Reports have associated repeated and prolonged occupational
exposure to solvents with permanent brain and nervous system damage.
Intentional misuse by deliberately concentrating and inhaling the contents
may be harmful or fatal. May cause respiratory and/or skin sensitization.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE
Any pre-existing respiratory or eye/skin conditions.
POSSIBLE ROUTES OF ENTRY
Inhalation, ingestion, skin absorption.
CARCINOGENICITY
Ethylbenzene has been shown to cause cancer in laboratory animals.
The relevance of this finding to humans is uncertain. IARC has
classified ethylbenzene as a possible human carcinogen, Group 2B.
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SECTION 4 - FIRST AID MEASURES
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EMERGENCY FIRST AID:
EYE CONTACT: Flush at once with large amounts of lukewarm water for at
least 15 minutes and get medical attention.
SKIN CONTACT: Remove from skin with soap and water. Remove drenched
clothing. If irritation persists, consult a physician.
INHALATION: If affected by inhalation of vapor or spray mist, remove to
fresh air. If necessary, restore breathing; in this case
contact physician at once.
INGESTION: If victim is conscious, give 2 glasses of water to dilute.
Do not induce vomiting. Consult physician or poison control
center at once.
NOTE TO PHYSICIAN:
Not Applicable.
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SECTION 5 - FIRE FIGHTING MEASURES
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FIRE AND EXPLOSIVE PROPERTIES OF THE CHEMICAL:
Flammability Classification . . . . . : Class 1B
Flashpoint . . . . . . . . . . . . . : 50.0 癋
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MATERIAL SAFETY DATA SHEET
71-WHT/CLR 1
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Explosion Level . . . . . . . . . . . : Low - .9
High - 7.0
EXTINGUISHING MEDIA
Use National Fire Protection Association (NFPA) Class B extinguisher
(carbon dioxide, dry chemical or foam) designed to extinguish NFPA
Class 1B flammable liquid fires.
FIRE-FIGHTING PROCEDURES AND EQUIPMENT
Clear fire area of unprotected personnel. Do not enter confined space
without helmet, face shield, bunker coat, gloves, rubber boots, and a
positive pressure NIOSH-approved self-contained breathing apparatus.
Water spray may be used to cool closed containers to prevent pressure
build-up and possible explosion when exposed to extreme heat. Water
may be ineffective in extinguishing a paint fire. Therefore, use
caution not to spread flames with stream of water. If water is used,
fog nozzles are preferable.
UNUSUAL FIRE AND EXPLOSION HAZARDS
Keep containers tightly closed. Isolate from heat, electrical
equipment, sparks and open flame. Vapors may be heavier than air and
may travel along the ground to distant ignition sources, then flash
back to the vapor source. Keep welding or cutting equipment away
from product. Containers may explode when exposed to extreme heat.
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SECTION 6 - ACCIDENTAL RELEASE MEASURES
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STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED
Remove all sources of ignition (flame, hot surfaces and sources of
electrical, static or frictional sparks). Avoid breathing vapors.
Ventilate area. For large spills in a confined area, use self-contained
non-sparking tools. Keep out of drains, sewers and waterways.
CLEAN-UP
Contain and remove with inert absorbent and non-sparking tools.
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SECTION 7 - HANDLING AND STORAGE
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HANDLING
Keep away from heat, sparks and open flame. Use only with adequate
ventilation. Keep from contact with oxidizing materials. Comply with
all national, state, and local codes pertaining to the storage, handling
dispensing and disposal of flammable liquids.
STORAGE
Do not store above 120 Degrees F. Close container after each use.
SPECIAL COMMENTS
Do not take internally. Wash with soap and water before eating,
drinking, smoking or using toilet.
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INSL-X PRODUCTS CORPORATION
MATERIAL SAFETY DATA SHEET
71-WHT/CLR 1
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SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
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VENTILATION
Provide general dilution or local exhaust ventilation in volume and
pattern to keep TLV of the most hazardous ingredient in Section 2, below
acceptable limit, and LEL in Section 5 below stated limit, during
application of this product, and to remove decomposition products
during welding or flame cutting on surfaces coated with this product.
RESPIRATORY PROTECTION
If personal exposure cannot be controlled below applicable limits by
ventilation, wear a properly fitted organic vapor/particulate respirator
approved by NIOSH for protection against chemicals in Sections (2 &/or 15).
EYE PROTECTION
Use safety eyewear with splashguards and side shields.
SKIN PROTECTION
For operations where prolonged or repeated skin contact may occur,
impervious gloves should be worn.
OTHER PROTECTIVE EQUIPMENT
None required.
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SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES
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Physical State . . . . . . . . . . . .: LIQUID
Vapor Pressure . . . . . . . . . . . : 10.20
Vapor Density . . . . . . . . . . . . : 3.80
Boiling Point Range . . . . . . . . . : Lower - 240.0 癋
Higher - 300.0 癋
Specific Gravity . . . . . . . . . . : 1.500
Weight per Volume . . . . . . . . . . : 12.4878 LB/GL
VOC - Total (lbs./gal). . . . . . . . : 2.864
Evaporation Rate . . . . . . . . . . .: 1.200 (n-Butyl Acetate = 1)
Volatile by Weight . . . . . . . . . : 22.9382
Volatile by Volume . . . . . . . . . : 45.9977
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SECTION 10 - STABILITY AND REACTIVITY
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STABILITY
This product is stable.
INCOMPATIBILITIES (Materials to Avoid)
This product can react violently with strong oxidizing agents such
as chlorine, oxygen, or strong oxidizing acids, such as, nitric and
sulfuric.
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INSL-X PRODUCTS CORPORATION
MATERIAL SAFETY DATA SHEET
71-WHT/CLR 1
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HAZARDOUS POLYMERIZATION
Will not occur.
CONDITIONS TO AVOID
High temperatures.
HAZARDOUS PRODUCTS OF DECOMPOSITION
Heating to decomposition, as in a fire or welding, may produce
hazardous fumes. Fumes may contain carbon monoxide, carbon dioxide
and oxides of nitrogen.
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SECTION 11 - TOXICOLOGICAL INFORMATION
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No data at this time.
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SECTION 12 - ECOLOGICAL INFORMATION
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No data at this time.
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SECTION 13 - DISPOSAL CONSIDERATIONS
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WASTE DISPOSAL
Dispose of this product in accordance with applicable local,
county, state and federal regulations, by incinerating, or treating and
disposing in approved facility. Do not incinerate closed containers.
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SECTION 14 - TRANSPORT INFORMATION
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DOT HAZARD CLASS . . . . . . . . : 3
DOT PACKAGING GROUP . . . . . . . : PG II
DOT LABEL . . . . . . . . . . . . : FLAMMABLE LIQUID
DOT SHIPPING NAME . . . . . . . . : PAINT
DOT PLACARD . . . . . . . . . . . : FLAMMABLE LIQUID
UN/NA NUMBER . . . . . . . . . . .: UN1263
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SECTION 15 - REGULATORY INFORMATION
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U.S. FEDERAL REGULATORY INFORMATION
TSCA SECTION 8(b) - INVENTORY STATUS:
All components of this product are either listed on the U.S. Toxic
Substances Control Act (TSCA) inventory of chemicals or are otherwise
compliant with TSCA Regulations.
SARA 313 TOXIC CHEMICALS:
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INSL-X PRODUCTS CORPORATION
MATERIAL SAFETY DATA SHEET
71-WHT/CLR 1
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This product contains the following substances subject to the
reporting requirements of Section 313 of Title III of the Superfund
Amendments and Reauthorization Act of 1986 and 40 CFR Part 372:
ETHYLBENZENE
CAS# 100-41-4 PCT BY WT: .1300
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SECTION 16 - OTHER INFORMATION
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Prepared by . . . . . . . . . . . . . :
Date of issue . . . . . . . . . . . . : 09/12/2005
Last Revision Date . . . . . . . . . : 02/18/2004
MSDS Prepared for . . . . . . . . . . :
MSDS Last Prepared . . . . . . . . . : NONE
HMIS Rating: Health- 2* Flammability- 3
Reactivity- 0
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This Material Safety Data Sheet conforms to the Hazard Communication
Standard, 29 CFR 1910.1200(g)(4).
The above information pertains to this product as currently formulated
and is based on the information available, as of this date. Addition of
reducers or other additives to this product may substantially alter the
composition and hazards of the product. Since conditions of use are out-
side our control, we make no warranties, express or implied, and assume
no liability in connection with any use of this information.
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Abbreviations used: int.- interior; ext.- exterior; MSDS - Material Safety
Data Sheet; HMIS - Hazardous Materials Information System; CAS - Chemical
Abstracts Services; pct - percent; wt - weight; mm Hg - millimeters of
mercury; F - Fahrenheit; ACGIH - American Conference of Governmental
Industrial Hygienists; TLV - Threshold Limit Value; OSHA - Occupational
Safety and Health Administration; PEL - Permissible Exposure Limit; TWA -
Time-Weighted Average; STEL- Short Term Exposure Limit; N/A- Not applicable
IARC - International Agency for Research on Cancer; NE - Not established
NTP - National Toxicological Program; CFR - Code of Federal Regulations;
OSHA - Z 29CFR 1910, Subpart Z; VOC - Volatile Organic Compounds; TCC -
Tag Closed Cup; LEL - Lower Explosive Limit; Mg/m3 or Mg/Cu M - milligram
per cubic meter; mppcf - millions of particles per cubic foot; ppm - parts
per million; NIOSH - National Institute of Occupational Safety and Health;
MSHA - Mine Safety and Health Administration; CNS - Central Nervous System.
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