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21645-51-2 25085-99-8 25068-38-6 13463-67-7 1675-54-3 123-91-1

File Name: 21645-51-2_25085-99-8_25068-38-6_13463-67-7_1675-54-3_123-91-1.asp

                                                                                                  Material Safety Data Sheet




Revision Date: 06/01/2004 Issue date: 06/01/2004

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product name: FAST CURE MIXER CUPS 1 OZ CAN Item number: 21426_RESIN
Product type: Epoxy Resin Region: United States
Company address: Contact Information:
Henkel Corporation Telephone: 860.571.5100
1001 Trout Brook Crossing Emergency telephone: 860.571.5100
Rocky Hill, Connecticut 06067 Internet: www.loctite.com


2. COMPOSITION/INFORMATION ON INGREDIENTS


Hazardous components % ACGIH TLV OSHA PEL OTHER
Alumina trihydrate 30-60 None None None
21645-51-2

Reaction product of epichlorohydrin 10-30 None None None
and bisphenol A
25085-99-8

Epichlorohydrin-4,4'-isopropylidene 10-30 None None None
diphenol resin
25068-38-6

Titanium dioxide 5-10 10 mg/m?TWA 15 mg/m?TWA None
13463-67-7



3. HAZARDS IDENTIFICATION

EMERGENCY OVERVIEW
HMIS:
Physical state: Paste HEALTH: 2
Color: White FLAMMABILITY: 1
Odor: Mild PHYSICAL HAZARD: 1
Personal Protection: See Section 8

WARNING: MAY CAUSE ALLERGIC SKIN REACTION.
MAY CAUSE EYE, SKIN AND RESPIRATORY TRACT IRRITATION.

Relevant routes of exposure: Eye contact, Ingestion, Inhalation, Skin contact

Potential Health Effects

Inhalation: Mild respiratory tract irritation. May cause irritation to nose and throat.
Skin contact: Allergic skin reaction. Moderate skin irritation. Itching. Redness.
Eye contact: Moderate eye irritation. Redness.
Ingestion: Not expected under normal conditions of use.

Existing conditions aggravated by Skin disorders. Skin allergies. Respiratory disorders. Eye disorders.
exposure:

See Section 11 for additional toxicological information.

Item number: 21426_RESIN Product name: FAST CURE MIXER CUPS 1 OZ CAN
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4. FIRST AID MEASURES


Inhalation: Remove to fresh air. If symptoms develop and persist, get medical attention.

Skin contact: Immediately flush skin with plenty of water (using soap, if available). Remove contaminated clothing
and shoes. Get medical attention if symptoms occur.

Eye contact: Immediately flush eyes with plenty of water for at least 15 minutes. Get medical attention.

Ingestion: DO NOT induce vomiting unless directed to do so by medical personnel. Keep individual calm. Get
medical attention if symptoms develop and persist.

Notes to physician: None.

5. FIRE-FIGHTING MEASURES

Flash point: Greater than 93篊 (200篎) Tagliabue closed cup

Autoignition temperature: Not available

Flammable/Explosive limits-lower %: Not available

Flammable/Explosive limits-upper %: Not available

Extinguishing media: Foam, dry chemical or carbon dioxide.

Special fire fighting procedures: Wear self-contained breathing apparatus and full protective clothing, such as turn-out gear.

Unusual fire or explosion hazards: Closed containers may rupture (due to build up of pressure) when exposed to extreme heat.

Hazardous combustion products: Oxides of carbon. Irritating organic fragments.

6. ACCIDENTAL RELEASE MEASURES

Environmental precautions: Prevent product from entering drains or open waters.

Clean-up methods: Remove all ignition sources. Immediately contact emergency personnel. Scrape up as much material
as possible. Clean residue with soap and water. Store in a closed container until ready for disposal.

7. HANDLING AND STORAGE

Handling: Keep away from heat, spark and flame. Do not breathe mist or vapors. Keep container closed. Avoid
contact with eyes, skin and clothing. Wash thoroughly after handling.

Storage: Store in original container until ready to use. Keep in a cool, well ventilated area away from heat,
sparks and open flame. Keep container tightly closed until ready for use.

Incompatible products: Refer to Section 10.

For information on product shelf life contact Henkel Customer Service at (800) 243-4874.

8. EXPOSURE CONTROLS / PERSONAL PROTECTION

Engineering controls: Use local exhaust ventilation to maintain airborne concentrations below established exposure limits.

Respiratory protection: Use a NIOSH approved air-purifying respirator if the potential to exceed established exposure limits
exists.

Skin protection: Chemical resistant, impermeable gloves.


Item number: 21426_RESIN Product name: FAST CURE MIXER CUPS 1 OZ CAN
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Eye/face protection: Chemical splash goggles or safety glasses with side shields.

See Section 2 for exposure limits.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical state: Paste
Color: White
Odor: Mild
Vapor pressure: Nil
pH: Not applicable
Boiling point/range: Greater than 149癈 (300癋)
Melting point/range: Not available
Specific gravity: 1.68
Vapor density: Not available
Evaporation rate: Not available
Solubility in water: Slightly soluble
Partition coefficient (n-octanol/water): Not available
VOC content: 0.47%; 7.9 grams/liter 0.038% (value for resin and hardener together)

10. STABILITY AND REACTIVITY

Stability: Stable

Hazardous polymerization: Will not occur.

Hazardous decomposition products: None

Incompatability: Strong acids. Strong bases. Strong oxidizers.

Conditions to avoid: Excessive heat. Storage with incompatible materials.

11. TOXICOLOGICAL INFORMATION


Carcinogen Status

Hazardous components NTP Carcinogen IARC Carcinogen OSHA Carcinogen
Alumina trihydrate No No No
21645-51-2
Reaction product of epichlorohydrin No No No
and bisphenol A
25085-99-8
Epichlorohydrin-4,4'-isopropylidene No No No
diphenol resin
25068-38-6
Titanium dioxide No No No
13463-67-7



Literature Referenced Target Organ & Other Health Effects

Hazardous components Health Effects/Target Organs
Alumina trihydrate Irritant, Lung, Respiratory
21645-51-2
Reaction product of epichlorohydrin Allergen, Irritant
and bisphenol A
25085-99-8
Epichlorohydrin-4,4'-isopropylidene Allergen, Irritant
diphenol resin
25068-38-6
Titanium dioxide Irritant, Respiratory
13463-67-7

12. ECOLOGICAL INFORMATION

Ecological information: Not available
Item number: 21426_RESIN Product name: FAST CURE MIXER CUPS 1 OZ CAN
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13. DISPOSAL CONSIDERATIONS

Information provided is for unused product only.

Recommended method of disposal: Dispose according to EPA and local governmental regulations.

EPA hazardous waste number: Not a RCRA hazardous waste.

14. TRANSPORT INFORMATION

The shipping classifications in this section are for non-bulk packaging only (unless otherwise specified). Shipping classiciation may be
different for bulk packaging.

U.S. Department of Transportation Ground (49 CFR):
Proper shipping name: Not regulated
Hazard class or division: None
Identification number: None
Packing group: None

International Air Transportation (ICAO/IATA):
Proper shipping name: Not regulated
Hazard class or division: None
Identification number: None
Packing group: None

WaterTransportation (IMO/IMDG):
Proper shipping name: Not regulated
Hazard class or division: None
Identification number: None
Packing group: None
Marine pollutant: None known

15. REGULATORY INFORMATION

United States Regulatory Information

TSCA 8 (b) Inventory Status: All components are listed or are exempt from listing on the Toxic Substances Control Act Inventory.
TSCA 12 (b) Export Notification: Bisphenol A diglycidyl ether (CAS# 1675-54-3).

CERCLA/SARA Section 302 EHS: None above reporting de minimus.
CERCLA/SARA Section 311/312: Immediate Health Hazard
CERCLA/SARA 313: None above reporting de minimus.

California Proposition 65: This product contains a chemical known to the State of California to cause cancer. 1,4-Dioxane (CAS#
123-91-1). Acetaldehyde (CAS# 75-07-0). Ethylene oxide (CAS# 75-21-8). Benz{a}anthracene (56-55-
3).



Canada Regulatory Information


CEPA DSL/NDSL Status: Contains one or more components listed on the Non-Domestic Substances list.
WHMIS hazard class: D.2.B




Item number: 21426_RESIN Product name: FAST CURE MIXER CUPS 1 OZ CAN
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16. OTHER INFORMATION

This material safety data sheet contains changes from the previous version in sections: Revised to new format.

Prepared by: Gary Pierson, Health and Regulatory Affairs Specialist

DISCLAIMER: The data contained herein are furnished for information only and are believed to be reliable. However, Henkel Corporation
does not assume responsibility for any results obtained by persons over whose methods Henkel Corporation has no control. It is the
user's responsibility to determine the suitability of Henkel's products or any production methods mentioned herein for a particular
purpose, and to adopt such precautions as may be advisable for the protection of property and persons against any hazards that may be
involved in the handling and use of any of Henkel Corporation's products. In light of the foregoing, Henkel Corporation specifically
disclaims all warranties, express or implied, including warranties of merchantability and fitness for a particular purpose, arising from sale
or use of Henkel Corporation's products. Henkel Corporation further disclaims any liability for consequential or incidental damages of
any kind, including lost profits.




Item number: 21426_RESIN Product name: FAST CURE MIXER CUPS 1 OZ CAN
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