ChemWatch MSDS MSDS for WATTYL ASPECTS ACRYLIC CEILING WHITE Page 1 of 13
WATTYL ASPECTS ACRYLIC CEILING WHITE
ChemWatch Material Safety Data Sheet
CHEMWATCH 5101-19
Date of Issue: Thu 11-Mar-2004
Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME
WATTYL ASPECTS ACRYLIC CEILING WHITE
SYNONYMS
Product Code: 128802
PRODUCT USE
Water base acrylic decorative interior / exterior flat
coating. Applied to timber, brick, cement, stone,
plasterboard and previously painted surfaces.
SUPPLIER
Company: Wattyl Australia Pty Limited
Address:
4 Steel St
Blacktown
NSW, 2148
AUSTRALIA
Telephone: 132101
Telephone: (+61 2) 9621 6255
Emergency Tel: 1800 039 008 (24 hours)
Emergency Tel: +61 3 9573 3112
Fax: 02 9831 2651
HAZARD RATINGS
Flammability: 0
Toxicity: 0
Body Contact: 2
Reactivity: 0
Chronic: 0
SCALE: Min/Nil=0 Low=1 Moderate=2 High=3 Extreme=4
Section 2 - HAZARDS IDENTIFICATION
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STATEMENT OF HAZARDOUS NATURE
NON-HAZARDOUS SUBSTANCE. NON-DANGEROUS GOODS.
According to the Criteria of NOHSC, and the ADG Code.
POISONS SCHEDULE
None
RISK
Harmful to aquatic organisms.
SAFETY
Do not breathe gas/fumes/vapour/spray.
Avoid contact with skin.
Wear eye/face protection.
To clean the floor and all objects contaminated by this material, use water.
This material and its container must be disposed of in a safe way.
In case of contact with eyes, rinse with plenty of water and contact Doctor or
Poisons Information Centre.
Use appropriate container to avoid environment contamination.
Avoid release to the environment. Refer to special instructions/Safety data
sheets.
Section 3 - COMPOSITION / INFORMATION ON INGREDIENTS
NAME CAS RN %
acrylic copolymer latex Not avail. 10-30
titanium dioxide 13463-67-7 5-15
diatomaceous earth, flux-calcined 68855-54-9 1-9
filler unregulated 1-9
2,2,4-trimethyl-1,3-pentanediol monoisobutyrate 25265-77-4 1-3
ammonium hydroxide 1336-21-6 <0.1
5-chloro-2-methyl-4-isothiazolin-3-one 26172-55-4 <0.1
2-methyl-4-isothiazolin-3-one 2682-20-4 <0.1
additives 1-5
water 7732-18-5 30-60
Section 4 - FIRST AID MEASURES
SWALLOWED
?Immediately give a glass of water.
?First aid is not generally required. If in doubt, contact a Poisons
Information Centre or a doctor.
EYE
If this product comes in contact with the eyes:
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?Wash out immediately with fresh running water.
?Ensure complete irrigation of the eye by keeping eyelids apart and away from
eye and moving the eyelids by occasionally lifting the upper and lower lids.
?If pain persists or recurs seek medical attention.
?Removal of contact lenses after an eye injury should only be undertaken by
skilled personnel.
SKIN
If skin or hair contact occurs:
?Flush skin and hair with running water (and soap if available).
?Seek medical attention in event of irritation.
INHALED
?If fumes or combustion products are inhaled remove from contaminated area.
?Other measures are usually unnecessary.
NOTES TO PHYSICIAN
Treat symptomatically.
Section 5 - FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA
There is no restriction on the type of extinguisher which may be used.
Use extinguishing media suitable for surrounding area
FIRE FIGHTING
?Alert Fire Brigade and tell them location and nature of hazard.
?Wear breathing apparatus plus protective gloves for fire only.
?Prevent, by any means available, spillage from entering drains or water
courses.
?Use fire fighting procedures suitable for surrounding area.
?DO NOT approach containers suspected to be hot.
?Cool fire exposed containers with water spray from a protected location.
?If safe to do so, remove containers from path of fire.
?Equipment should be thoroughly decontaminated after use.
FIRE/EXPLOSION HAZARD
?Non combustible.
?Not considered to be a significant fire risk.
?Expansion or decomposition on heating may lead to violent rupture of
containers.
?Decomposes on heating and may produce toxic/ irritating fumes.
?May emit acrid smoke.
Decomposition may produce toxic fumes of.
nitrogen oxides (NOx).
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May emit poisonous fumes.
May emit corrosive fumes.
FIRE INCOMPATIBILITY
None known.
HAZCHEM
None
Personal Protective Equipment
Glasses:
Safety Glasses.
Chemical goggles.
Gloves:
1.BUTYL 2.NEOPRENE 3.VITON
Respirator:
Type AK-P Filter of sufficient capacity
Section 6 - ACCIDENTAL RELEASE MEASURES
EMERGENCY PROCEDURES
MINOR SPILLS
? Clean up all spills immediately.
? Avoid breathing vapours and contact with skin and eyes.
? Control personal contact by using protective equipment.
? Contain and absorb spill with sand, earth, inert material or vermiculite.
? Wipe up.
? Place in a suitable labelled container for waste disposal.
MAJOR SPILLS
Moderate hazard.
?Clear area of personnel and move upwind.
?Alert Fire Brigade and tell them location and nature of hazard.
?Wear breathing apparatus plus protective gloves.
?Prevent, by any means available, spillage from entering drains or water
course.
?Stop leak if safe to do so.
?Contain spill with sand, earth or vermiculite.
?Collect recoverable product into labelled containers for recycling.
?Neutralise/decontaminate residue.
?Collect solid residues and seal in labelled drums for disposal.
?Wash area and prevent runoff into drains.
?After clean up operations, decontaminate and launder all protective clothing
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and equipment before storing and re-using.
?If contamination of drains or waterways occurs, advise emergency services.
Personal Protective Equipment advice is contained in Section 8 of the MSDS.
Section 7 - HANDLING AND STORAGE
PROCEDURE FOR HANDLING
?Avoid all personal contact, including inhalation.
?Wear protective clothing when risk of exposure occurs.
?Use in a well-ventilated area.
?Avoid contact with moisture.
?Avoid contact with incompatible materials.
?When handling, DO NOT eat, drink or smoke.
?Keep containers securely sealed when not in use.
?Avoid physical damage to containers.
?Always wash hands with soap and water after handling.
?Work clothes should be laundered separately. Launder contaminated clothing
before re-use.
?Use good occupational work practice.
?Observe manufacturer's storing and handling recommendations.
?Atmosphere should be regularly checked against established exposure standards
to ensure safe working conditions are maintained.
SUITABLE CONTAINER
?Polyethylene or polypropylene container.
?Packing as recommended by manufacturer
?Check all containers are clearly labelled and free from leaks.
STORAGE INCOMPATIBILITY
None known
STORAGE REQUIREMENTS
? Store in original containers.
? Keep containers securely sealed.
? Store in a cool, dry, well-ventilated area.
? Store away from incompatible materials and foodstuff containers.
? Protect containers against physical damage and check regularly for leaks.
? Observe manufacturer's storing and handling recommendations.
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
EXPOSURE CONTROLS
No data for Wattyl Aspects Acrylic Ceiling White.
EXPOSURE STANDARDS FOR MIXTURE
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"Worst Case" computer-aided prediction of vapour components/concentrations:
Composite Exposure Standard for Mixture (TWA) (mg/m?: 17 mg/m? If the breathing zon
ammonium hydroxide 25
Operations which produce a spray/mist or fume/dust, introduce particulates to
the breathing zone.
If the breathing zone concentration of ANY of the components listed below is exceede
titanium dioxide 2550
5-chloro-2-methyl-4-isothiazolin-3 17
2-methyl-4-isothiazolin-3-one 17
INGREDIENT DATA
For each of the following
ACRYLIC COPOLYMER LATEX:
2,2,4-TRIMETHYL-1,3-PENTANEDIOL MONOISOBUTYRATE:
WATER:
No exposure limits set by NOHSC or ACGIH
TITANIUM DIOXIDE:
TLV TWA: 10 mg/m?A4 [ACGIH]
PEL Total dust: 15)mg/m?[OSHA Z1]
TLV TWA: 10 mg/m?A4
NOTE: This substance has been classified by the ACGIH as A4 NOT classifiable as
causing Cancer in humans
ES TWA: 10 mg/m?br>
(total dust containing no asbestos and < 1% crystalline silica)
OES TWA: 10 mg/m?total inhalable dust
OES TWA: 4 mg/m?respirable dust
IDLH Level: 5000 mg/m?br>
Animal studies at 10 mg/m?show no significant fibrosis, possibly reversible
tissue reaction and the architecture of lung air spaces remains intact.
DIATOMACEOUS EARTH, FLUX-CALCINED:
None assigned. Refer to individual constituents.
AMMONIUM HYDROXIDE:
TLV TWA: 25 ppm, 17 mg/m? STEL: 35 ppm, 24 mg/m?br>
ES TWA: 25 ppm, 17 mg/m? ES STEL: 35 ppm, 24 mg/m?br>
OES TWA: 25 ppm, 18 mg/m? STEL: 35 ppm, 25 mg/m?br>
MAK value: 20 ppm, 14 mg/m?br>
MAK Category I Peak Limitation: For local irritants Allows excursions of twice
the MAK value for 5 minutes at a time, 8 times per shift.
MAK Group C: There is no reason to fear risk of damage to the developing embryo
when MAK and BAT values are observed.
MAK values, and categories and groups are those recommended within the
Federal Republic of Germany
Odour Threshold Value: Variously reported as 0.019 ppm and 55 ppm;
AIHA Value 16.7 ppm (detection)
IDLH Level: 500 ppm
NOTE: Detector tubes for ammonia, measuring in excess of 1 ppm, are
commercially available.
The TLV-TWA is thought to be protective against irritation of the eyes and
respiratory tract and minimise discomfort among workers that are not
inured to its effects and systemic damage. Acclimatised persons are able
to tolerate prolonged exposures of up to 100 ppm without symptoms. Marked
irritation has been seen in persons exposed to ammonia concentrations
between 50 and 100 ppm only when the exposures involved sudden
concentration peaks which do not permit short-term acclimatisation. The
detoxification capacity of the liver is significant since the amount of
ammonia formed endogenously in the intestines markedly exceeds that from
external sources.
Human exposure effects, at vapour concentrations of about:
----------------------------------------------------------------------
ppm Possible Effects
------------------------------------------------------------------------
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5 minimal irritation
9-50 nasal dryness, olfactory fatigue and moderate irritation
125-137 definite nose, throat and chest irritation
140 slight eye irritation
150 laryngeal spasm
500 30 minute exposures may produce cyclic hypernea, increased blood
pressure and pulse rate, and upper respiratory tract irritation
which may persist for 24 hours
700 immediate eye irritation
1500-10000 dyspnea, convulsive coughing, chest pain, respiratory spasm,
pink frothy sputum, rapid asphyxia and delayed pulmonary oedema
which may be fatal. Other effects include runny nose, swelling
of the lips, restlessness, headache, salivation, nausea,
vomiting, glottal oedema, pharyngitis, tracheitis, and speech
difficulties. Bronchopneumonia, asphyxiation due to spasms,
inflammation, and oedema of the larynx, may be fatal. Residual
effects include hoarseness, productive cough, and decreased
respiratory function
>2500 severe eye irritation, with swelling of the eyelids,
lachrymation, blepharospasm, palpebral oedema, increased
intraocular pressure, oval semi-dilated, fixed pupils, corneal
ulceration (often severe) and temporary blindness. Depending on
duration of exposure, there may be destruction of the
epithelium, corneal and lenticular opacification, and iritis
accompanied by hypopyon or haemorrhage and possible loss of
pigment from the posterior layer of the iris. Less severe
damage is often resolved. In the case of severe damage,
symptoms may be delayed; late complications including
persistent oedema, vascularisation and corneal scarring,
permanent opacity, acute angle glaucoma, staphyloma, cataract,
and atrophy of the retina, iris, and symblepharon.
Long-term exposure to sub-acute concentrations or single exposures to
high concentrations may produce chronic airway dysfunction, alveolar
disease, bronchiolitis, bronchiectasis, emphysema and anxiety neuroses
5-CHLORO-2-METHYL-4-ISOTHIAZOLIN-3-ONE:
CEL TWA: 0.1 mg/m? STEL: 0.3 mg/m?total isothiazolines [Manufacturer]
MAK value: 0.2 mg/m?br>
Designated S in List of MAK values: Danger of sensitization.
MAK Group D: Classification as to the effect of the substance on the developing
embryo/foetus is not yet possible because although data may indicate a trend,
they are not sufficient for a final evaluation.
MAK values, and categories and groups are those recommended within the
Federal Republic of Germany
2-METHYL-4-ISOTHIAZOLIN-3-ONE:
CEL TWA: 0.1 mg/m? STEL: 0.3 mg/m?total isothiazolines [Manufacturer]
MAK value: 0.05 mg/m?br>
Designated S in List of MAK values: Danger of sensitization.
MAK Group D: Classification as to the effect of the substance on the developing
embryo/foetus is not yet possible because although data may indicate a trend,
they are not sufficient for a final evaluation.
MAK values, and categories and groups are those recommended within the
Federal Republic of Germany
PERSONAL PROTECTION
EYE
?Safety glasses with side shields.
?Chemical goggles.
?Contact lenses pose a special hazard; soft lenses may absorb irritants and all
lenses concentrate them. DO NOT wear contact lenses.
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HANDS/FEET
Wear chemical protective gloves, eg. PVC.
Wear safety footwear or safety gumboots, eg. Rubber
OTHER
Use a respirator when dry sanding.
?Overalls.
?P.V.C. apron.
?Barrier cream.
?Skin cleansing cream.
?Eye wash unit.
GLOVE SELECTION INDEX
Glove selection is based on a modified presentation of the:
"Forsberg Clothing Performance Index".
The effect(s) of the following substance(s) are taken into account in the
computer-generated selection:
Substance
________________________________________
water
BUTYL A
NEOPRENE A
VITON A
PVA C
NATURAL RUBBER C
* CPI - Chemwatch Performance Index
A: Best Selection
B: Satisfactory; may degrade after 4 hours continuous immersion
C: Poor to Dangerous Choice for other than short term immersion
NOTE: As a series of factors will influence the actual performance of the glove,
a final selection must be based on detailed observation. -
* Where the glove is to be used on a short term, casual or infrequent basis,
factors such as "feel" or convenience (e.g. disposability), may dictate a choice
of gloves which might otherwise be unsuitable following long-term or frequent
use. A qualified practitioner should be consulted.
RESPIRATOR
Respiratory protection may be required when ANY "Worst Case" vapour-phase
concentration is exceeded (see Computer Prediction in "Exposure Standards").
Protection Factor (Min) Half-Face Respirator Full-face Respirator
10 x ES AK-AUS -
AK-PAPR-AUS -
20 x ES - AK-AUS
- AK-PAPR-AUS
100 x ES - AK-2
- AK-PAPR-2
^ - Full-face
The local concentration of material, quantity and conditions of use determine
the type of personal protective equipment required. For further information
consult site specific CHEMWATCH data (if available), or your Occupational
Health and Safety Advisor.
ENGINEERING CONTROLS
General exhaust is adequate under normal operating conditions. Local exhaust
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ventilation may be required in specific circumstances. If risk of overexposure
exists, wear approved respirator. Correct fit is essential to obtain adequate
protection. Provide adequate ventilation in warehouse or closed storage areas.
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
APPEARANCE
White liquid paint; mixes with water. Typical paint odour.
PHYSICAL PROPERTIES
Liquid.
Mixes with water.
Molecular Weight: Not applicable
Boiling Range (?100
C):
Melting Range (?Not available.
C):
Specific Gravity (water=1): 1.26-1.30
Solubility in water (g/L): Miscible
pH (as supplied): 9.0-9.5
pH (1% solution): Not available
Vapour Pressure (kPa): <1
Volatile Component (%vol): 50-60
Evaporation Rate: Slow
Relative Vapour Density (air=1): Not available.
Flash Point (?Non Flammable
C):
Lower Explosive Limit (%): Not applicable
Upper Explosive Limit (%): Not applicable
Autoignition Temp (?Not applicable
C):
Decomposition Temp (?Not available.
C):
State: Liquid
Section 10 - CHEMICAL STABILITY AND REACTIVITY INFORMATION
CONDITIONS CONTRIBUTING TO INSTABILITY
?Presence of incompatible materials.
?Product is considered stable.
?Hazardous polymerisation will not occur.
Section 11 - TOXICOLOGICAL INFORMATION
POTENTIAL HEALTH EFFECTS
ACUTE HEALTH EFFECTS
SWALLOWED
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The material has NOT been classified by EC Directives or other classification
systems as "harmful by ingestion". This is because of the lack of corroborating
animal or human evidence. The material may still be damaging to the health of
the individual, following ingestion, especially where pre-existing organ (e.g
liver, kidney) damage is evident. Present definitions of harmful or toxic
substances are generally based on doses producing mortality rather than those
producing morbidity (disease, ill-health). Gastrointestinal tract discomfort may
produce nausea and vomiting. In an occupational setting however, ingestion of
insignificant quantities is not thought to be cause for concern.
EYE
The liquid may produce eye discomfort and is capable of causing temporary
impairment of vision and/or transient eye inflammation, ulceration.
The vapour is.
mildly.
discomforting.
to the eyes.
The material may produce moderate eye irritation leading to inflammation.
Repeated or prolonged exposure to irritants may produce conjunctivitis.
SKIN
The material is not thought to produce adverse health effects or skin irritation
following contact (as classified by EC Directives using animal models).
Nevertheless, good hygiene practice requires that exposure be kept to a minimum
and that suitable gloves be used in an occupational setting.
Entry into the blood-stream, through, for example, cuts, abrasions or lesions,
may produce systemic injury with harmful effects. Examine the skin prior to the
use of the material and ensure that any external damage is suitably protected.
INHALED
The material is not thought to produce adverse health effects or irritation of
the respiratory tract (as classified by EC Directives using animal models).
Nevertheless, good hygiene practice requires that exposure be kept to a minimum
and that suitable control measures be used in an occupational setting.
CHRONIC HEALTH EFFECTS
Principal routes of exposure are usually by.
skin contact with the material.
and.
inhalation of vapour/spray mist.
Prolonged or repeated skin contact may cause drying with cracking, irritation
and possible dermatitis following.
As with any chemical product, contact with unprotected bare skin; inhalation of
vapour, mist or dust in work place atmosphere; or ingestion in any form, should
be avoided by observing good occupational work practice.
Wattyl Aspects Acrylic Ceiling White
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No data for Wattyl Aspects Acrylic Ceiling White.
ACRYLIC COPOLYMER LATEX:
No significant acute toxicological data identified in literature search.
TITANIUM DIOXIDE:
TOXICITY
Nil reported
IRRITATION
Skin (human): 0.3 mg/3d-I mild
DIATOMACEOUS EARTH, FLUX-CALCINED:
Not available. Refer to individual constituents.
2,2,4-TRIMETHYL-1,3-PENTANEDIOL MONOISOBUTYRATE:
TOXICITY
Oral (rat) LD50: 3200 mg/kg
Oral (rat) LD50: 3200 mg/kg ***
Dermal (rabbit) LD50: > 16 ml/kg *
Dermal (g.pig) LD50: >16 ml/kg ***
Inhalation (rat) LC50: >3.55 mg/l/6h
Inhalation (rat) LC50: 1600 mg/kg ***
Skin sensitisation (guinea pig): none. *
IRRITATION
Skin - Slight irritant *
Skin (rabbit): mild ***
Eyes - Moderate irritant *
Eye (rabbit): mild ***
in sensitisation (guinea pig): none. *
Not a skin sensitiser (guinea pig, Magnusson-Kligman) ***
Ames Test: negative ***
Micronucleus, mouse: negative ***
Not mutagenic ***
No effects on fertility or foetal development seen in the rat ***
* [SWIFT]
** [Eastman]
*** [Perstop]
AMMONIUM HYDROXIDE:
Not available. Refer to individual constituents.
ammonia
Oral (rat) LD50: 350 mg/kg Eye (rabbit): 0.25 mg SEVERE
Oral (human) LDLo: 43 mg/kg Eye (rabbit): 1 mg/30s SEVERE
Inhalation (human) LCLo: 5000 ppm/5m
Inhalation (human) TCLo: 20 ppm
Inhalation (rat) LC50: 2000 ppm/4h
Unreported (man) LDLo: 132 mg/kg
5-CHLORO-2-METHYL-4-ISOTHIAZOLIN-3-ONE:
No significant acute toxicological data identified in literature search.
Bacterial mutagen
Considered to be the major sensitiser in Kathon CG (1)
(1). Bruze etal - Contact Dermatitis 20: 219-39, 1989
2-METHYL-4-ISOTHIAZOLIN-3-ONE:
None available.
Bacterial mutagen
Considered to be a minor sensitiser in Kathon CG (1)
(1). Bruze etal - Contact Dermatitis 20: 219-39, 1989
WATER:
No significant acute toxicological data identified in literature search.
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Section 12 - ECOLOGICAL INFORMATION
Harmful to aquatic organisms.
DO NOT discharge into sewer or waterways.
Section 13 - DISPOSAL CONSIDERATIONS
?Recycle wherever possible.
?Consult manufacturer for recycling options or consult local or regional waste
management authority for disposal if no suitable treatment or disposal facility
can be identified.
?Dispose of by: Burial in a licenced land-fill or Incineration in a licenced
apparatus (after admixture with suitable combustible material)
?Decontaminate empty containers. Observe all label safeguards until containers
are cleaned and destroyed.
Puncture containers to prevent re-use and bury at an authorised landfill.
Section 14 - TRANSPORTATION INFORMATION
Shipping Name:
None
Hazard Class: None
UN/NA Number: None
ADR Number:
Packing Group: None
Labels Required:
Additional Shipping Information:
International Transport Regulations:
IMO: None
HAZCHEM
None
Section 15 - REGULATORY INFORMATION
POISONS SCHEDULE
None
Section 16 - OTHER INFORMATION
This document is copyright. Apart from any fair dealing for the purposes of
private study, research, review or criticism, as permitted under the Copyright
Act, no part may be reproduced by any process without written permission from
CHEMWATCH. TEL (+61 3) 9572 4700.
Issue Date: Thu 11-Mar-2004
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Print Date: Thu 11-Mar-2004
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