MATERIAL SAFETY DATA SHEET
Polyurethane 100 "A" Pigmented
SECTION I
Product Identification and General Information
Product Name: Polyurethane 100 "A" Pigmented Date Prepared: 4/21/99
Product Class: Polyester Polyol 24 Hour Emergency Assistance: Chemtrec
HMIS Codes: H F R P 1-800-424-9300
32 1 G
SECTION II
Hazardous Ingredients CAS# OSHA PEL ACGIH TLV
Propylene Glycol Mono-Methyl 108-65-6 N/E N/E
Ether Acetate
Polyester Polyol
Titanium Dioxide 13463-67-7 N/E N/E
SECTION III
Physical Data
Boiling Point: Begins at 280癋 Solubility in Water: Insoluble
Vapor Pressure: 3.7mm Hg Evaporation Rate: N/A
Vapor Density: Heavier Than Air Appearance: Viscous Pigmented Liquid
Specific Gravity: 1.43 Odor: Of Solvent, Fruity Ester-Like
Percent Volatiles: 35%
SECTION IV
Fire and Explosion Hazard Data
Flash Point: 122癋 Setaflash (ASTM D-3243)
Flammable Limits:
LEL: 1.3 @ 173癋
UEL: 13.1 @ 283癋
Extinguishing media: Dry Chemical, Carbon Dioxide, Foam, Water Spray for Large Fires
Hazardous Combustion Products: Carbon Monoxide, Carbon Dioxide
Special Fire Fighting Procedures: Full Emergency Equipment with self-contained breathing apparatus and full
protective clothing. During fire irritating, toxic gases and smoke may be present from decomposition/combustion.
Fire and Explosion Hazards: Closed containers may explode when exposed to extreme heat. Use cold spray to cool
fire exposed containers to minimize risk of rupture. Vapors may build-up and travel along the ground to an ignition
source which may result in a flash back to the vapor source.
SECTION V
Reactivity Data
Stability: Material is stable.
Hazardous Polymerization: Will not occur.
Incompatibility: Avoid oxidizers.
SECTION VI
Health Hazard Data
Primary Route of Entry: Inhalation, Skin Contact, Eye
Eye Contact: Contact is severely irritating and can cause pain, tearing, redness and swelling. If left untreated,
corneal damage can occur. Injury is slow to heal, but damage is usually reversible.
Skin Contact: Repeated or prolonged exposure may result in dry, defatted or cracked skin. Dermatitis and skin rash
may occur. May penetrate skin.
Inhalation: Vapors are irritating to eyes, nose, throat and respiratory tract resulting in itchy eyes, dryness of the
throat and tightness of the chest. Other possible symptoms include headache, nausea, narcosis, fatigue and loss of
appetite.
Ingestion: Can result in the irritation of the digestive tract. Symptoms include sore throat, abdominal pain, nausea,
vomiting and diarrhea.
SECTION VII
First Aid
Eye Contact: Flush with water for 15 minutes.
Skin Contact: Remove contaminated clothing and wash affected areas with soap and water. Wash contaminated
clothing before reuse.
Ingestion: Do not induce vomiting. Do not give anything by mouth to an unconscious person. Seek medical
attention.
Inhalation: Move to an area free from further exposure. Administer oxygen or artificial respiration as needed. Seek
medical attention.
SECTION VIII
Special Protection Information
Respiratory Protection: A respirator approved for use in organic vapor containing environments.
Ventilation: Local exhaust ventilation is recommended.
Eye Protection: Liquid chemical goggles or full-face shield.
Skin Protection: Permeation resistant gloves (Butyl rubber or Nitrile rubber). Wear long sleeved and legged
garments.
SECTION IX
Spill or Leak Procedures
Steps to be taken if material is released or spilled: Remove all sources of ignition. Ventilate area. Equip clean-up
crew with appropriate protective gear. Dike spilled material and control further spillage if possible. Cover spill with
absorbent material. Collect material in open containers. Flush spill area with water.
Waste Disposal Method: Waste disposal must be in accordance with federal, state and local regulations. Empty
containers must be handled with care due to product residue and combustible solvent vapors.
SECTION X
Shipping Data
D.O.T. Shipping Name: Paint Related Material
Technical Shipping Name: Polyester Polyol
D.O.T. Hazard Class: Flammable
UN/NA Number: UN1263
Packing Group: III
D.O.T. Labels Required: Flammable
Freight Class: 55
Polyurethane 100 Pigmented Part A p.2
MATERIAL SAFETY DATA SHEET
Polyurethane 100 Part "B"
SECTION I
Product Identification and General Information
Product Name: Polyurethane 100 Part B Date Prepared: 4/21/99
Product Class: Isocyanate Solution 24 Hour Emergency Assistance: Chemtrec
HMIS Codes: H F R P 1-800-424-9300
32 1G
SECTION II
Hazardous Ingredients Percent CAS# OSHA PEL ACGIH TLV
Propylene Glycol Mono-Methyl Ether Acetate 5-15 108-65-6 N/E N/E
Homopolymer of Hexamethylene Diisocyanate 85-95 28182-81-2 N/E N/E
SECTION III
Physical Data
Boiling Point: Begins at 280癋 Solubility in Water: Insoluble, but reacts slowly
Vapor Pressure: 3.7mm Hg Evaporation Rate: N/A
Vapor Density: Heavier Than Air Appearance: Pale Yellow Clear Liquid
Specific Gravity: 1.09 Odor: Of Solvent, Fruity Ester-Like
Percent Volatiles: 5-15
SECTION IV
Fire and Explosion Hazard Data
Flash Point: 122癋 SETA Flash (ASTM D-3243)
Flammable Limits:
LEL: 1.3 @ 173癋
UEL: 13.1 @ 283癋
Extinguishing media: Foam, Dry Chemical, Carbon Dioxide. Do Not Use Water.
Hazardous Combustion Products: Oxides of Carbon and Nitrogen.
Special Fire Fighting Procedures: Firefighters should wear full emergency equipment with self-contained breathing
apparatus. During fires irritating, toxic gases and smoke may be present from decomposition/combustion products.
Fire and Explosion Hazards: Product will burn under fire conditions. Toxic, corrosive fumes may be emitted.
SECTION V
Reactivity Data
Stability: Stable
Hazardous Polymerization: Will not occur.
Incompatibility: Water, strong bases, strong acids, strong oxidizing agents and amines.
SECTION VI
Health Hazard Data
Primary Route of Entry: Inhalation, Dermal, Eye contact.
Skin Contact: Isocyanates react with skin protein and moisture and can cause irritation. Symptoms include
reddening, swelling, rash, scaling and blistering. Cured material is difficult to remove.
Inhalation: Inhalation of mist can irritate the mucous membrane in the respiratory tract causing runny nose, sore
throat, coughing, chest discomfort and shortness of breath. Acute exposure may lead to bronchitis, bronchial spasm
or pulmonary edema. These effects are usually reversible.
Ingestion: Can result in irritation and possibly corrosive action in the mouth, stomach tissue and digestive tract.
Chronic Overexposure: May result in isocyanate sensitization.
SECTION VII
First Aid
Eyes: Flush eyes with clear water for 15 minutes. Refer individual to a physician for immediate follow-up.
Skin: Remove contaminated clothing immediately. Wash affected areas with soap and water. Wash contaminated
clothing thoroughly before reuse. Seek medical attention if irritation develops or persists.
Inhalation: Move to an area free from risk of further exposure. Administer oxygen or artificial respiration as
needed. Obtain medical attention. Asthmatic-type symptoms may develop and may be immediate or delayed up to
several hours. Treatment is essentially symptomatic.
Ingestion: Do not induce vomiting. Give 1 to 2 cups of milk or water to drink. Do not give anything by mouth to an
unconscious person. Consult physician.
Note To Physician: Eyes: Stain for evidence of corneal injury. If cornea is burned, instill antibiotic/steroid
preparation frequently. Skin: This product is a known sensitizer. Treat symptomatically as for contact dermatitus or
thermal burn. Ingestion: Treat symptomatically no specific antidote. Inhalation: This product is a known
pulmonary sensitizer. Treatment is essentially symptomatic. An individual having a sensitization reaction to this
material must be removed from any further exposure to any isocyanate.
SECTION VIII
Special Protection Information
Respiratory Protection: A NIOSH approved respiratory for organic vapor should be used. In spray applications a
supplied air respirator is recommended.
Ventilation: Possible use precautions as above.
Eye Protection: Chemical splash goggles or full-face shield.
Skin Protection: Permeation resistant gloves. Cover as much of the exposed skin area as possible with appropriate
clothing.
SECTION IX
Spill or Leak Procedures
Steps to be taken if material is released or spilled: Evacuate non-essential personnel. Remove all sources of
ignition. Put on personal protective equipment. Dike spilled material and control further spillage. Pour
decontamination solution over spill and allow to react for at least 10 min. Collect material in open containers and
further amounts of decontamination solution. Wash down spill area with decontamination solution.
Decontamination solutions: Concentrated (3.8%), detergent (2%) and water (90-95%) or Union Carbide's tergitol
TMN-10 (20%) and water (80%)
Waste Disposal Method: Waste must be disposed of in accordance with all federal, state and local regulations.
Incineration is preferred method. Empty containers will contain product residue. Decontaminate prior to disposal.
SECTION X
Shipping Data
D.O.T. Shipping Name: Paint Related Material
Technical Shipping Name: Polyisocyanate Solution
D.O.T. Hazard Class: Flammable
UN/NA Number: UN1263
Packing Group: III
D.O.T. Labels Required: Flammable
Freight Class: 55
Polyurethane 100 Pigmented Part B p.2
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