Material Safety Data Sheet Date Prepared 3/2000
Product Number: 6434
Section 1: Manufacturer Identification
Mason Color Works, Inc. Phone: (330) 385-4400
250 East 2nd Street/P.O. Box 76 Fax: (330) 385-4488
East Liverpool, OH 43920-5076
Section 2: Identification of Product
Chemical Family: Inorganic
Product Names: Yellow 6434
Chemical Abstract Number (CAS): 12036-19-3
Chemical Name: Zinc Ferrite Yellow - Spinel
Chemical Formula: Fe2O4Zn
Section 3 & Section 4: Hazardous ingredients Identity/Information and Overexposure Symptoms
ACGIH-TLVs OSHA PELs NOISHA RELs
5 mg/m3 10 mg/m3 5 mg/m3
Iron Oxide (Fe2O3)
Cas # 1309-37-1
ACGIH: Not classifiable as a human carcinogen: Inadequate data on which to classify the agent in terms of
its carcinogencity in humans/animals. The value is for particulate matter containing no asbestos and 1%
crystalline silica.
Symptoms of overexposure:
Inhalation: Repeated and prolonged exposure may cause beginnings Pneumoconiosis called
Sideordsis.
Eye Contact: May cause irritation.
Skin Contact: May cause mechanical skin irritation.
Ingestion: Expected to be non-toxic.
10 mg/m3 10 mg/m3 (total) 0.2 mg/m3
Titanium Dioxide (TiO2)
5 mg/m3 (respirable)
Cas # 13463-67-7
Symptoms of overexposure:
Inhalation: Inhalation of dust can cause irritation of the nose, throat, and lungs.
Eye Contact: Like any foreign body, particles can cause mechanical irritation.
Skin Contact: This material can cause irritation if not promptly washed form skin.
Ingestion: This material is not expected to produce adverse effects.
10 mg/m3 10 mg/m3 (Total) 5 mg/m3
Zinc Oxide (ZnO)
5 mg/m3 (Respirable)
Cas # 1314-13-2
Symptoms of overexposure:
Inhalation: High levels of dust may result in tightness of chest, metallic taste, cough, dizziness,
fever, chills, headache, nausea, and dry throat. Chronic exposure may produce symptoms known
as metal fume fever or "zinc shakes", an acute, self-limiting condition without recognized
complications. Symptoms of metal fume fever include: chills, fever, muscular pain, nausea and
vomiting. May aggravate respiratory conditions.
Eye Contact: May cause irritation.
Skin Contact: May cause irritation.
Ingestion: May cause irritation to the gastro-intestinal tract.
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Section 5: Emergency and First Aid Procedures:
Eye: flush thoroughly with water for 15 minutes.
Skin: remove contaminated clothing, wash thoroughly with soap and water.
Inhalation: remove to fresh air, may give oxygen if needed.
Ingestion: give large amounts of water to induce vomiting, only in conscious persons.
IF THESE FIRST AID MEASURES FAIL, CONSULT PHYSICIAN!!!!!!!!!!!!!!!!!!!
Principal Routes of Entry:
Inhalation: Dust from this product may cause irritation of the respiratory system.
Overexposure may cause lung damage.
Ingestion: Large amounts may cause irritation of the gastrointestinal tract, nausea, vomiting and
diarrhea.
Skin & Eye: Nuisance dust, prolonged or repeated may cause irritation.
Section 6: Special Protection Information
Respiratory Protection: Use only NIOSHA/OSHA approved respiratory protection with adequate
ventilation; avoid breathing dust. Do not exceed Occupational Exposure Limits.
Wash thoroughly after handling. No food or beverage should be consumed in
work area.
Personal Protective Equip: Wear appropriate gloves and goggles to avoid skin and eye contact. Safety
showers and eye stations must be present in work stations.
Ventilation: Use local exhaust or mechanical such as a dust collector to maintain dust levels
below Occupational Exposure Limits.
Section 7: Physical and Chemical Characteristics
Boiling Point: N/A Odor: oderless
Solubility in water: trace Specific Gravity (water=1): N/A
Vapor Pressure (mmHg): N/A Evaporation rate: None
Vapor Density (air=1): N/A % Volatile by volume: None
Appearance: yellow powder
Section 8: Reactivity Data
Stability: Stable
Hazardous Polymerization: will not occur
Incompatibility: None
Hazard Decomposition of product: N/A
Section 9: Fire and Explosive Data
Flash point: N/A Flammable Limits: None
Unusual Fire and Explosion Hazard: None expected
Extinguishing Media: Carbon dioxide, dry chemical or water
Special Fire Fighting Procedures: Wear self contained breathing apparatus when large quantities involved.
Section 10: Spill or Leak Procedures:
Contain spillage and scoop or vaccum. Avoid making dust, put in appropriate container for disposal.
Waste disposal method in accordance with Federal, State and Local Laws.
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This product is a blend of various metal oxides, salts and some compounds which are interfused by high
calcination to form the finished product. Section III, Hazardous Ingredients Identity/Information, and
Section IV, Symptoms of Overexposure, pertain to individual components. Section V through Section X
are in reference to the finished product.
**************Attention All Retailers of Mason Stains**************
ALL retailers of this product are REQUIRED by law to supply their customers with a copy of this
material safety data sheet with initial purchase.
***SARA 313
This product contains certain oxides and compounds which are subject to reporting requirements of
Superfund Amendment and Reauthorization Act (SARA) of 1986, Section 313 of the Emergency Planning
and Community Right to Know Act and of 40 CRF, Part 372.
The information contained in this Material Safety Data Sheet must be provided to every employee
who is exposed to this product in any way. We recommend the user reads and understands the
contents herein before using this material.
PLEASE KEEP ON FILE FOR FUTURE REFERENCE. DO NOT THROW AWAY ! MATERIAL
SAFETY DATA SHEETS ARE REQUIRED FOR FIRST SHIPMENT, AND WILL BE SENT
AGAIN WHEN REVISED UPON YOUR NEXT ORDER OF PRODUCT OR BY REQUEST.
DISCLAMER
Mason Color Works, Inc. believes the information contained in this material safety data sheet is believed
to be accurate and reliable as of the date of publication or revision but makes no warranty that it is.
This information provided should be made available as required by the Federal OSHA Hazard
Communication Standard 1910.1200 to ANYONE who handles, uses, stores, transports or will otherwise
be exposed to this product. Mason Color Works, Inc. Accepts no Responsibility for the health or safety
of any individual who misuses this product by not complying with manufacturer's instructions contained
herein or additional /other measures that may be required under particular conditions.
Last issued: 11/97
Updated : 3/2000
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