Material Name: PVC Adhesives Material Safety Data
Sheet ID: 2006
Section 1 - Chemical Product and Company Identification
Product Name PVC Adhesives
CAS# Mixture/None Assigned
Generic Name Adhesive
Formula Mixture
Chemical Name: Mixture
Hazard Label SOL-XF
Manufacturer Information
Johns Manville Telephone: 303-978-2000 8:00AM-5:00PM M-F
Performance Materials Division Internet Address: http://www.jm.com
P.O. Box 5108 Emergency: 800-424-9300 (Chemtrec, In English)
Denver, CO 80127 USA
Trade Names: Ceel-Co?and/or Ceel-Tite?Adhesive, Clear or White; Zeston?Perma-Weld Adhesive, Clear or White
Section 2 - Composition / Information on Ingredients
CAS # Component Percent
109-99-9 Tetrahydrofuran 45-60
78-93-3 Methyl ethyl ketone 20-30
9003-22-9 Vinyl chloride-Vinyl acetate copolymer 20-30
13463-67-7 Titanium dioxide (colorant) 1-5*
67-63-0 Isopropyl alcohol 1-5
67-64-1 Acetone 1-5
108-05-4 Vinyl acetate 0.1-5
Additional Component Information
* In white adhesive only.
Section 3 - Hazards Identification
Emergency Overview
APPEARANCE AND ODOR: Clear or white liquid. Solvent odor.
Extremely flammable liquid and vapor. Vapor may cause flash fire. Use water spray to cool materials in or near a fire. Fire may
be difficult to extinguish. Vapors may travel, and can be ignited by a remote source.
Inhalation of vapors may cause upper respiratory irritation or central nervous system depression - remove affected individuals
to fresh air.
HMIS Ratings: Health = 2* Fire = 3 Reactivity = 0
* indicates a chronic effects
Potential Health Effects
Summary
Vapors from this product may cause eye and upper respiratory irritation, dry throat and mouth, nausea, headache, dizziness,
drowsiness, and coma in extreme cases. Prolonged exposures may lead to liver and kidney injury.
Inhalation
Excessive inhalation of vapors may cause nasal and respiratory irritation and central nervous system effects including
dizziness, weakness, fatigue, nausea, headache, and possible unconsciousness.
Skin
Irritation may occur with burns if not removed.
Absorption
Can pass through skin and cause symptoms similar to those resulting from swallowing or inhalation.
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Material Name: PVC Adhesives Material Safety Data
Sheet ID: 2006
Ingestion
This product in not intended to be ingested or eaten under normal conditions of use. If ingested, it may cause gastrointestinal
(GI) irritation, nausea, vomiting, and diarrhea.
Eyes
Irritation may occur with burns if not removed.
Primary Routes of Entry (Exposure)
Inhalation, skin, and eye contact.
Target Organs
Upper respiratory passages, central nervous system, skin, eyes, liver, kidney.
Medical Conditions Aggravated by Exposure
Pre-existing chronic eye, skin, respiratory, liver, or kidney diseases or conditions
Section 4 - First Aid Measures
First Aid: Inhalation
Remove to fresh air.
First Aid: Skin
Remove contaminated clothing. Wash exposed areas with soap and water. If irritation develops or persists, seek medical
attention. Launder contaminated clothing before reuse.
First Aid: Ingestion
Product is not intended to be ingested or eaten. If this product is ingested, do not induce vomiting and seek medical attention.
Do not make an unconscious person vomit.
First Aid: Eyes
Flush eyes with large amounts of water for 5-15 minutes. If irritation develops, or persists, seek medical attention.
First Aid: Notes to Physician
Treatment for inhalation of vapors should be symptomatic with supportive therapy. Skin and eye contact may be treated by
washing the exposed area. Removal from exposure will generally result in complete recovery.
Section 5 - Fire Fighting Measures
Flash Point: -14.4篊/6篎 Method Used: TCC
Upper Flammable Limit (UFL): Not determined. Lower Flammable Limit (LFL): 1.9%
Auto Ignition: Not determined Flammability Classification: Not determined
Rate of Burning: Not determined
General Fire Hazards
EXTREMELY FLAMMABLE liquid and vapor. May cause flash fire. Keep away from heat, sparks and flame. Keep container
closed. Use with adequate ventilation. Containers exposed to elevated temperatures (such as heat or flames) may develop
pressure build-up and rupture. Vapors may travel, and can be ignited by a remote source.
"Empty" container warning: "Empty" containers retain residue (liquid and/or vapor) and can be dangerous. Do not pressurize,
cut, weld, braze, solder, drill, grind, or expose such containers to heat, flame, sparks, or other sources of ignition. They may
explode and cause injury and death.
Extinguishing Media
Dry chemical, foam, carbon dioxide.
NFPA Ratings: Health = 2 Fire = 3 Reactivity = 1
Fire Fighting Equipment/Instructions
Firefighters should wear full-face, self contained breathing apparatus and impervious protective clothing. Firefighters should
avoid inhaling any combustion products.
Section 6 - Accidental Release Measures
Containment Procedures
Remove all sources of ignition. Evacuate and ventilate spill area. Dam spill area with sand, earth, or other suitable absorbent.
Prevent entry of material into sewers, other water sources, or land areas. Wear full protective clothing and respiratory
protection during clean-up as required to maintain exposures below the applicable exposure limit. Shovel absorbed material
into containers in well-ventilated area.
Clean-Up Procedures
No additional information available.
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Material Name: PVC Adhesives Material Safety Data
Sheet ID: 2006
Section 7 - Handling and Storage
Handling Procedures
Use protective equipment as described in Section 8 of this material safety data sheet when handling uncontained material.
Keep this material and vapors from this material away from ignition sources, such as heat, sparks, pilot lights, static electricity,
and open flames. Containers exposed to elevated temperatures (such as heat or flames) may develop pressure build-up and
rupture. Keep containers sealed when not in use and clean spills promptly to reduce air concentrations and floor hazards.
Storage Procedures
No additional information available.
Section 8 - Exposure Controls / Personal Protection
Exposure Guidelines
A: General Product Information
Protective equipment should be used as necessary to prevent irritation of the throat, eyes, and skin, and to keep exposures
below the applicable exposure limits identified in Section 8.
B: Component Exposure Limits
Tetrahydrofuran (109-99-9)
ACGIH: 50 ppm TWA
100 ppm STEL
Skin - potential significant contribution to overall exposure by the cutaneous route
OSHA: 200 ppm TWA; 590 mg/m3 TWA
250 ppm STEL; 735 mg/m3 STEL
Methyl ethyl ketone (78-93-3)
ACGIH: 200 ppm TWA
300 ppm STEL
OSHA: 200 ppm TWA; 590 mg/m3 TWA
300 ppm STEL; 885 mg/m3 STEL
Acetone (67-64-1)
ACGIH: 500 ppm TWA
750 ppm STEL
OSHA: 750 ppm TWA; 1800 mg/m3 TWA
1000 ppm STEL; 2400 mg/m3 STEL (The acetone STEL does not apply to the cellulose acetate
fiber industry. It is in effect for all other sectors)
Titanium dioxide (colorant) (13463-67-7)
ACGIH: 10 mg/m3 TWA
OSHA: 10 mg/m3 TWA (total dust)
Isopropyl alcohol (67-63-0)
ACGIH: 200 ppm TWA
400 ppm STEL
OSHA: 400 ppm TWA; 980 mg/m3 TWA
500 ppm STEL; 1225 mg/m3 STEL
Vinyl acetate (108-05-4)
ACGIH: 10 ppm TWA
15 ppm STEL
OSHA: 10 ppm TWA; 30 mg/m3 TWA
20 ppm STEL; 60 mg/m3 STEL
PERSONAL PROTECTIVE EQUIPMENT
Personal Protective Equipment: Eyes/Face
Safety glasses with sideshields or chemical splash goggles are recommended to prevent splashing of material in eyes.
Personal Protective Equipment: Skin
Solvent-resistant gloves are recommended, such as polyvinyl alcohol.
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Material Name: PVC Adhesives Material Safety Data
Sheet ID: 2006
Personal Protective Equipment: Respiratory
If vapor levels are above the applicable exposure limits, a NIOSH-approved organic vapor respirator must be provided and
worn.
Ventilation
Local exhaust ventilation should be provided at areas of use to remove gases & vapors from work area. General dilution
ventilation should be provided as necessary to keep gases & vapors below the applicable exposure limits and guidelines. The
need for ventilation systems should be evaluated by a professional industrial hygienist, while the design of specific ventilation
systems should be conducted by a professional engineer.
Personal Protective Equipment: General
An apron or coveralls impervious to chemicals can be used to protect clothing. Wash exposed skin after contact, before breaks
and meals, and at end of work period.
Section 9 - Physical & Chemical Properties
Appearance: Odor:
Clear or white solvent odor
Physical State: pH:
liquid Not determined
Vapor Pressure: Not determined
Boiling Point: Melting Point:
62.8-68.3篊/145-155篎 Not determined
Solubility (H2O): Specific Gravity:
Not soluble 0.95-0.975
Freezing Point: Evaporation Rate:
Not determined Faster than ether
Viscosity: Percent Volatile:
Not determined 79%
VOC: 726 g/L (clear), 720 g/L (white)
Section 10 - Chemical Stability & Reactivity Information
Chemical Stability
This is a stable material. This product is not reactive.
Chemical Stability: Conditions to Avoid
Keep away from heat, ignition sources and incompatible materials.
Incompatibility
This product may react with strong oxidizing agents.
Hazardous Decomposition
Carbon monoxide, carbon dioxide, hydrogen chloride, and other partially oxidized hydrocarbons.
Hazardous Polymerization
Will not occur.
Section 11 - Toxicological Information
Acute Toxicity
A: General Product Information
Vapors from this product may cause irritation of the eyes, and upper respiratory tract including the nose, mouth, and throat.
B: Component Analysis - LD50/LC50
Tetrahydrofuran (109-99-9)
Inhalation LC50 Rat: 53.9 mg/L/4H; Inhalation LC50 Rat: 180 mg/L/1H; Oral LD50 Rat: 1650 mg/kg
Methyl ethyl ketone (78-93-3)
Inhalation LC50 Mouse: 32 g/m3/4H; Oral LD50 Rat: 2600 mg/kg; Dermal LD50 Rabbit: 6400 mg/kg
Acetone (67-64-1)
Inhalation LC50 Rat: 76 mg/L/4H; Oral LD50 Rat: 1800 mg/kg; Dermal LD50 Rabbit: 20000 mg/kg
Titanium dioxide (colorant) (13463-67-7)
Oral LD50 Rat: >10000 mg/kg
Isopropyl alcohol (67-63-0)
Inhalation LC50 Rat: 72.6 mg/L/4H; Oral LD50 Rat: 4396 mg/kg; Dermal LD50 Rat: 12800 mg/kg; Dermal LD50 Rabbit: 12800
mg/kg
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Material Name: PVC Adhesives Material Safety Data
Sheet ID: 2006
Vinyl acetate (108-05-4)
Inhalation LC50 Rat: 11.4 mg/L/4H; Inhalation LC50 Rat: 3200 ppm/4H; Oral LD50 Rat: 2920 mg/kg; Dermal LD50 Rabbit:
2320 mg/kg
Carcinogenicity
A: General Product Information
No additional information available.
Tetrahydrofuran was associated with an increase in liver cancer in female mice and a slight increase in kidney cancer in male
rats. However, in the same study, it had no effect on cancer incidence in male mice or in female rats. The relevance of this
finding to humans is uncertain.
B: Component Carcinogenicity
Tetrahydrofuran (109-99-9)
ACGIH: A3 - Confirmed animal carcinogen with unknown relevance to humans
Vinyl chloride-Vinyl acetate copolymer (9003-22-9)
IARC: Group 3 - Not Classifiable (IARC Supplement 7 [1987], Monograph 19 [1979])
Acetone (67-64-1)
ACGIH: A4 - Not Classifiable as a Human Carcinogen
Titanium dioxide (colorant) (13463-67-7)
ACGIH: A4 - Not Classifiable as a Human Carcinogen
IARC: Group 2B - Possibly Carcinogenic to Humans (IARC Monograph 93 posted, Monograph 47
[1989])
Isopropyl alcohol (67-63-0)
ACGIH: A4 - Not Classifiable as a Human Carcinogen
IARC: Group 3 - Not Classifiable (IARC Monograph 71 [1999], Supplement 7 [1987], Monograph 15
[1977])
Vinyl acetate (108-05-4)
ACGIH: A3 - Confirmed animal carcinogen with unknown relevance to humans
IARC: Group 2B - Possibly Carcinogenic to Humans (IARC Monograph 63 [1995], Supplement 7
[1987])
Chronic Toxicity
Prolonged, excessive exposures to vapors of this product may produce liver and kidney injury. Methyl ethyl ketone has shown
possible reproductive risks in one animal study; a second study was negative. Individuals exposed to high levels of
Tetrahydrofuran have elevated circulating liver enzymes and have complained of nausea, tinnitus, and occipital headache.
Section 12 - Ecological Information
Ecotoxicity
A: General Product Information
No data available for this product.
B: Component Analysis - Ecotoxicity - Aquatic Toxicity
Tetrahydrofuran (109-99-9)
96 Hr LC50 Pimephales promelas: 2160 mg/L [flow-through]; 96 Hr LC50 Pimephales promelas: 2700-3600 mg/L [static]
24 Hr EC50 Daphnia magna: >10000 mg/L
Methyl ethyl ketone (78-93-3)
96 Hr LC50 Pimephales promelas: 3220 mg/L [flow-through]; 96 Hr LC50 Lepomis macrochirus: 1690 mg/L
5 min EC50 Photobacterium phosphoreum: 3426 mg/L; 30 min EC50 Photobacterium phosphoreum: 3403 mg/L
48 Hr EC50 water flea: 520 mg/L; 48 Hr EC50 Daphnia magna: 5091 mg/L
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Material Name: PVC Adhesives Material Safety Data
Sheet ID: 2006
Acetone (67-64-1)
96 Hr LC50 Oncorhynchus mykiss: 5540 mg/L [static]; 96 Hr LC50 Pimephales promelas: 6210 mg/L [flow-through]; 96 Hr
LC50 Lepomis macrochirus: 8300 mg/L [static]
15 min EC50 Photobacterium phosphoreum: 14500 mg/L
48 Hr EC50 water flea: 0.0039 mg/L; 48 Hr EC50 water flea: 12700 mg/L [Static]; 48 Hr EC50 Daphnia magna: 12600 mg/L
Isopropyl alcohol (67-63-0)
96 Hr LC50 Pimephales promelas: 9640 mg/L [flow-through]; 96 Hr LC50 Pimephales promelas: 94900 mg/L [flow-through]
(29 days old); 96 Hr LC50 Pimephales promelas: 61200 mg/L [flow-through] (31 days old)
96 Hr EC50 Scenedesmus subspicatus: >1000 mg/L; 72 Hr EC50 Scenedesmus subspicatus: >1000 mg/L
5 min EC50 Photobacterium phosphoreum: 35390 mg/L
48 Hr EC50 Daphnia magna: 13299 mg/L
Vinyl acetate (108-05-4)
96 Hr LC50 Pimephales promelas: 31.0 mg/L; 96 Hr LC50 Lepomis macrochirus: 31.0 mg/L; 96 Hr LC50 Pimephales
promelas: 14-15 mg/L [static]; 96 Hr LC50 Lepomis macrochirus: 18 mg/L [static]
5 min EC50 Photobacterium phosphoreum: 2080 mg/L
24 Hr EC50 water flea: 52.0 mg/L
Section 13 - Disposal Considerations
US EPA Waste Number & Descriptions
A: General Product Information
Comply with state and local regulations for disposal. If you are unsure of the regulations, contact your local Public Health
Department, or the local office of the EPA.
B: Component Waste Numbers
Tetrahydrofuran (109-99-9)
RCRA: waste number U213 (Ignitable waste)
Methyl ethyl ketone (78-93-3)
RCRA: waste number U159 (Ignitable waste, Toxic waste)
200.0 mg/L regulatory level
Acetone (67-64-1)
RCRA: waste number U002 (Ignitable waste)
Disposal Instructions
Dispose of waste material according to Local, State, Federal, and Provincial Environmental Regulations.
Section 14 - Transportation Information
International Transportation Regulations
DOT: Consumer Commodity, ORM-D
Packaging must not exceed 5 L (1.3 gal) inner; 30 kg (66 lb) outer
IATA: UN 1133, Adhesives, 3, PGII.
CARGO AIRCRAFT ONLY
FLAMMABLE LIQUID label required
1 qt plastic cans, 6/box only:
Inner packagings must not exceed 10 L (2.6 gal) each (depending on the type of inner packaging used) and the outer package
may not exceed 60 L (15.8 gal).
1 gal steel can, 1/box only:
Inner packagings must not exceed 5 L (1.3 gal) each (depending on the type of inner packaging used) and the outer package
may not exceed 5 L (1.3 gal)
IMDG: UN 1133, Adhesives, 3, PGII
Inner packagings must not exceed 5 L (1.3 gal) and outer packagings must not exceed 30 kg (66 lb)
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Material Name: PVC Adhesives Material Safety Data
Sheet ID: 2006
Section 15 - Regulatory Information
US Federal Regulations
A: General Product Information
SARA 311 Status. The following SARA 311 designations apply to this product: Immediate (acute) health hazard. Delayed
(chronic) health hazard. Fire hazard.
B: Component Analysis
This material contains one or more of the following chemicals required to be identified under SARA Section 302 (40 CFR 355
Appendix A), SARA Section 313 (40 CFR 372.65) and/or CERCLA (40 CFR 302.4).
Tetrahydrofuran (109-99-9)
CERCLA: 1000 lb final RQ; 454 kg final RQ
Methyl ethyl ketone (78-93-3)
CERCLA: 5000 lb final RQ; 2270 kg final RQ
Acetone (67-64-1)
CERCLA: 5000 lb final RQ; 2270 kg final RQ
Isopropyl alcohol (67-63-0)
SARA 313: 1.0 % de minimis concentration (only if manufactured by the strong acid process, no supplier
notification)
Vinyl acetate (108-05-4)
SARA 302: 1000 lb TPQ
SARA 313: 0.1 % de minimis concentration
CERCLA: 5000 lb final RQ; 2270 kg final RQ
State Regulations
A: General Product Information
Other state regulations may apply. Check individual state requirements.
B: Component Analysis - State
The following components appear on one or more of the following state hazardous substances lists:
Component CAS # CA FL MA MN NJ PA
Tetrahydrofuran 109-99-9 Yes No Yes Yes Yes Yes
Methyl ethyl ketone 78-93-3 Yes No Yes Yes Yes Yes
Acetone 67-64-1 Yes No Yes Yes Yes Yes
Titanium dioxide (colorant) 13463-67-7 No No Yes Yes Yes Yes
Isopropyl alcohol 67-63-0 Yes No Yes Yes Yes Yes
Vinyl acetate 108-05-4 Yes No Yes Yes Yes Yes
Other Regulatory Information
A: General Product Information
No information available for the product.
B: TSCA Status
This product and its components are listed on the TSCA 8(b) inventory.
The following components listed in this product are listed on the TSCA Export Notification 12(b) list.
TSCA 12(b)
Component CAS TSCA 12 (b)
Tetrahydrofuran 109-99-9 Yes
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Material Name: PVC Adhesives Material Safety Data
Sheet ID: 2006
C: Component Analysis - Inventory
Component CAS # TSCA DSL EINECS
Tetrahydrofuran 109-99-9 Yes Yes Yes
Methyl ethyl ketone 78-93-3 Yes Yes Yes
Vinyl chloride-Vinyl acetate copolymer 9003-22-9 Yes Yes No
Acetone 67-64-1 Yes Yes Yes
Titanium dioxide (colorant) 13463-67-7 Yes Yes Yes
Isopropyl alcohol 67-63-0 Yes Yes Yes
Vinyl acetate 108-05-4 Yes Yes Yes
Component Analysis - WHMIS IDL
The following components are identified under the Canadian Hazardous Products Act Ingredient Disclosure List:
Component CAS # Minimum Concentration
Tetrahydrofuran 109-99-9 1%
Methyl ethyl ketone 78-93-3 1%
Acetone 67-64-1 1%
Isopropyl alcohol 67-63-0 1%
Vinyl acetate 108-05-4 1%
Section 16 - Other Information
Other Information
Prepared for:
Johns Manville
Performance Materials Division
P.O. Box 5108
Denver, CO USA 80217-5108
Prepared by:
Johns Manville Product Stewardship
P.O. Box 625005
Littleton, CO USA 80162-5005
As of the date of preparation of this document, the foregoing information is believed to be accurate and is provided in good
faith to comply with applicable federal and state law(s). However, no warranty or representation with respect to such
information is intended or given.
Date MSDS # Reason
08/01/00 2006-1.0000 New MSDS authoring system.
10/27/00 2006-1.0100 LOLI update, minor. Also transportation update (Sect. 14).
11/17/00 2006-1.0101 Delete "300" from trade names (Section 1.)
06/18/02 2006-1.0102 Sect. 15: Updated TSCA 12B, Tetrahydrofuran no longer listed.
Other minor edits.
06/30/03 2006-1.0103 Sect. 1, 2, 6, 9. Minor adjustments to composition. New JM division
name (Performance Mtrls.). Changed Ceel-Tite to Ceel-Co Perma-
Weld.
01/07/04 2006-1.0104 Sect. 1 added Ceel-Tite to product names and revised material
name.
02/10/05 2006-1.0105 Minor edits throughout
12/30/05 2006-1.0106 Section 14 Transportation addition of IATA and IMDG info.
01/15/07 2006-1.0107 Minor edits throughout.
This is the end of MSDS # 2006
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