Page 1/6
Safety Data Sheet
according to 1907/2006/EC, Article 31
Printing date 11.03.2010 Revision: 04.02.2010
* 1 Identification of substance:
?Product details:
?Trade name: Certanium 715 3.2mm 22625
?Article number: 22625
?Application of the substance / the preparation Metal-working product
?Manufacturer/Supplier:
Barnes Group KENT Limited
Pitreavie Crescent
Pitreavie Business Park
Dunfermline
Fife
KY11 8UQ
Tel: 01383 737393
Fax: 01383 620079
Monday - Thursday 8.30am - 5.30pm, Friday 9.00am - 3.00pm
?Informing department: Product Safety Department
?Emergency information: fullertonj@kenteurope.com
* 2 Hazards identification
?Hazard designation:
@
?
F T Toxic
?Information pertaining to particular dangers for man and environment
R 40 Limited evidence of a carcinogenic effect.
R 43 May cause sensitisation by skin contact.
R 48/23 Toxic: danger of serious damage to health by prolonged exposure through inhalation.
?Classification system
The classification is in line with current EC lists. It is expanded, however, by information from technical literature and by information
furnished by supplier companies.
?GHS label elements
~
Warning
H351 - Suspected of causing cancer.
H373 - May cause damage to organs through prolonged or repeated exposure.
~
Warning
H317 - May cause an allergic skin reaction.
?Prevention:
P201 Obtain special instructions before use.
P202 Do not handle until all safety precautions have been read and understood.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P272 Contaminated work clothing should not be allowed out of the workplace.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
* 3 Composition/information on ingredients
?Chemical characterization
?Description: Mixture of the substances listed below with harmless additions.
(Contd. on page 2)
GB
Page 2/6
Safety Data Sheet
according to 1907/2006/EC, Article 31
Printing date 11.03.2010 Revision: 04.02.2010
Trade name: Certanium 715 3.2mm 22625
(Contd. of page 1)
?Dangerous components:
@
? T, ? Xi; R 40-43-48/23
F G
@
CAS: 7440-02-0 nickel 20-40%
Warning: ~ 3.6/2; ~ 3.4.S/1
EINECS: 231-111-4
CAS: 7440-47-3 chromium 9-19%
EINECS: 231-157-5
G
@
? Xn; R 48
CAS: 7439-96-5 manganese 3-13%
EINECS: 231-105-1
CAS: 13463-67-7 titanium dioxide 1-11%
EINECS: 236-675-5
? Xi; R 36/38
G
@
CAS: 1344-09-8 Silicic acid, sodium salt 1-11%
Warning: ~ 3.2/2, 3.3/2
* 4 First aid measures
?After inhalation Supply fresh air or oxygen; call for doctor.
?After skin contact
Instantly wash with water and soap and rinse thoroughly.
If skin irritation continues, consult a doctor.
?After eye contact Rinse opened eye for several minutes under running water. Then consult doctor.
?After swallowing
In case of persistent symptoms consult doctor.
Rinse out mouth and then drink plenty of water.
* 5 Fire fighting measures
?Suitable extinguishing agents
CO2, extinguishing powder or water haze. Fight larger fires with water haze or alcohol-resistant foam.
?Special hazards caused by the material, its products of combustion or resulting gases:
Formation of toxic gases is possible during heating or in case of fire.
Carbon monoxide and carbon dioxide
?Protective equipment:
Wear self-contained breathing apparatus.
Wear full protective suit.
* 6 Accidental release measures
?Person-related safety precautions:
Avoid causing dust.
Wear protective equipment. Keep unprotected persons away.
?Measures for environmental protection:
Do not allow product to reach sewage system or water bodies.
Inform respective authorities in case product reaches water or sewage system.
(Contd. on page 3)
GB
Page 3/6
Safety Data Sheet
according to 1907/2006/EC, Article 31
Printing date 11.03.2010 Revision: 04.02.2010
Trade name: Certanium 715 3.2mm 22625
(Contd. of page 2)
?Measures for cleaning/collecting:
Collect mechanically.
Send for recovery or disposal in suitable containers.
Dispose of contaminated material as waste according to item 13.
* 7 Handling and storage
?Handling
?Information for safe handling: Prevent formation of dust.
?Information about protection against explosions and fires: No special measures required.
?Storage
?Requirements to be met by storerooms and containers: Store in cool location.
?Information about storage in one common storage facility: Not required.
?Further information about storage conditions: Store in cool, dry conditions in well sealed containers.
* 8 Exposure controls and personal protection
?Additional information about design of technical systems: No further data; see item 7.
?Components with limit values that require monitoring at the workplace:
nickel
WEL Long-term value: 0.5 mg/m?br>
as Ni
chromium
WEL Long-term value: 0.5 mg/m?br>
titanium dioxide
WEL Long-term value: 10* 4** mg/m?br>
*total inhalable **respirable
copper
WEL Short-term value: 2** mg/m?br>
Long-term value: 0.2* 1** mg/m?br>
*fume **dusts and mists (as Cu)
carbon
WEL Long-term value: 10* 4** mg/m?br>
*inhalable dust **respirable
?Additional information:
The lists that were valid during the compilation were used as basis.
Overexposure to welding fumes may result in dizziness, nausea or dryness or irritation of nose, throat and eyes. Chronic excess
welding fumes above OES or OEL may be hazardous. Prolonged and repeated inhalation may be harmful to respiratory system.
?Personal protective equipment
?General protective and hygienic measures
Take off immediately all contaminated clothing
Keep away from foodstuffs, beverages and food.
Do not inhale dust / smoke / mist.
Avoid contact with the eyes and skin.
Wash hands during breaks and at the end of the work.
?Breathing equipment:
In case of brief exposure or low pollution use breathing filter apparatus. In case of intensive or longer exposure use breathing
apparatus that is independent of circulating air.
?Protection of hands:
Welders protective gloves
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation
?Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from
manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be
calculated in advance and has therefore to be checked prior to the application.
?Penetration time of glove material
The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed.
(Contd. on page 4)
GB
Page 4/6
Safety Data Sheet
according to 1907/2006/EC, Article 31
Printing date 11.03.2010 Revision: 04.02.2010
Trade name: Certanium 715 3.2mm 22625
(Contd. of page 3)
?Eye protection: Welders face shield and coloured absorbing lenses
?Body protection: Heat-resistant protective clothing
* 9 Physical and chemical properties:
?General Information
Form: Solid.
Colour: According to product specification
Odour: Odourless
?Change in condition
Melting point/Melting range: 1000-1500癈
Boiling point/Boiling range: Not determined
?Flash point: Not applicable
?Self-inflammability: Product is not selfigniting.
?Danger of explosion: Product is not explosive.
?Density at 20癈 5-8 g/cm?br>
?Solubility in / Miscibility with
Water: Unsoluble
* 10 Stability and reactivity
?Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications.
?Materials to be avoided: Acid
?Dangerous reactions No dangerous reactions known
?Dangerous products of decomposition:
Formation of toxic gases is possible during heating or in case of fire.
Carbon monoxide and carbon dioxide
* 11 Toxicological information
?Acute toxicity:
?LD/LC50 values that are relevant for classification:
titanium dioxide
Oral LD50 >20000 mg/kg (rat)
Dermal LD50 >10000 mg/kg (rabbit)
Inhalative LC50/4 h >6.82 mg/l (rat)
aluminium trisodium hexafluoride
Oral LD50 143 mg/kg (rat)
?Primary irritant effect:
?on the skin: Irritant to skin and mucous membranes.
?on the eye: Irritant effect.
?Sensitization: Sensitization possible by skin contact.
?Additional toxicological information:
Harmful
The product shows the following dangers according to the calculation method of the General EC Classification Guidelines for
Preparations as issued in the latest version:
?Sensitisation May cause sensitisation by skin contact.
GB
(Contd. on page 5)
Page 5/6
Safety Data Sheet
according to 1907/2006/EC, Article 31
Printing date 11.03.2010 Revision: 04.02.2010
Trade name: Certanium 715 3.2mm 22625
(Contd. of page 4)
* 12 Ecological information:
?Additional ecological information:
?General notes: Do not allow product to reach ground water, water bodies or sewage system.
* 13 Disposal considerations
?Product:
?Recommendation Must not be disposed of together with household garbage. Do not allow product to reach sewage system.
?Uncleaned packagings:
?Recommendation: Disposal must be made according to official regulations.
* 14 Transport information
?Land transport ADR/RID (cross-border)
?ADR/RID-GGVS/E Class: n/a
?Maritime transport IMDG:
?IMDG Class: n/a
?Marine pollutant: No
?Air transport ICAO-TI and IATA-DGR:
?ICAO/IATA Class: n/a
?UN "Model Regulation": n/a
* 15 Regulatory information
?Designation according to EC guidelines:
The product has been classified and labelled in accordance with EC Directives / Ordinance on Hazardous Materials (GefStoffV)
?Code letter and hazard designation of product:
@
F
? T Toxic
?Hazard-determining components of labelling:
nickel
aluminium trisodium hexafluoride
?Risk phrases:
40 Limited evidence of a carcinogenic effect.
43 May cause sensitisation by skin contact.
48/23 Toxic: danger of serious damage to health by prolonged exposure through inhalation.
?Safety phrases:
36/37 Wear suitable protective clothing and gloves.
45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).
60 This material and its container must be disposed of as hazardous waste.
* 16 Other information:
These data are based on our present knowledge. However, they shall not constitute a guarantee for any specific product features
and shall not establish a legally valid contractual relationship.
?Relevant R-phrases
10 Flammable.
20/22 Harmful by inhalation and if swallowed.
36/38 Irritating to eyes and skin.
40 Limited evidence of a carcinogenic effect.
(Contd. on page 6)
GB
Page 6/6
Safety Data Sheet
according to 1907/2006/EC, Article 31
Printing date 11.03.2010 Revision: 04.02.2010
Trade name: Certanium 715 3.2mm 22625
(Contd. of page 5)
43 May cause sensitisation by skin contact.
48 Danger of serious damage to health by prolonged exposure.
48/23 Toxic: danger of serious damage to health by prolonged exposure through inhalation.
48/23/25 Toxic: danger of serious damage to health by prolonged exposure through inhalation and if swallowed.
51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
?Department issuing data specification sheet: Environment protection department.
?Contact: Marketing Department
?Abbreviations and acronyms:
ADR: Accord europ閑n sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage of Dangerous Goods by Road)
RID: R鑗lement international concernant le transport des marchandises dangereuses par chemin de fer (Regulations Concerning the International Transport of Dangerous
Goods by Rail)
IMDG: International Maritime Code for Dangerous Goods
IATA: International Air Transport Association
IATA-DGR: Dangerous Goods Regulations by the "International Air Transport Association" (IATA)
ICAO: International Civil Aviation Organization
ICAO-TI: Technical Instructions by the "International Civil Aviation Organization" (ICAO)
GHS: Globally Harmonized System of Classification and Labelling of Chemicals
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
GB