Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - Europe
SAFETY DATA SHEET Europe
1. Identification of the substance/preparation and of the company/undertaking
Identification of the substance or mixture
Product name In case of emergency
VANLUBE? SL
Mixture of alkylated diphenylamines 203-853-1400
Chemical name
Chemtrec: (800) 424-9300
Not available.
Synonyms
Outside US: (703) 527-3887
Lubricant additives
Use of the
substance/mixture
51008
Code
Company/undertaking identification
R. T. Vanderbilt Company, Inc.
Supplier
30 Winfield Street
Norwalk, CT 06855
MSDS@rtvanderbilt.com
e-mail address of person
responsible for this SDS
2. Hazards identification
Liquid.
Physical state
Amber.
Color
Amine-like. [Slight]
Odor
Emergency overview WARNING!
MAY CAUSE RESPIRATORY TRACT, EYE AND SKIN IRRITATION.
Contains material which may cause damage to the following organs: blood, the
reproductive system, mucous membranes, bladder, cardiovascular system, upper
respiratory tract, skin, eye, lens or cornea.
Avoid contact with eyes, skin and clothing. Avoid breathing vapor or mist.
Keep container closed. Use only with adequate ventilation. Wash thoroughly after
handling.
The product is classified as dangerous according to Directive 1999/45/EC and its amendments.
R33
Classification
R52/53
Danger of cumulative effects.
Human health hazards
Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic
Environmental hazards
environment.
See section 11 for more detailed information on health effects and symptoms.
3. Composition/information on ingredients
Preparation
Substance/preparation
Ingredient name CAS number % EC number Classification
benzenamine, N-phenyl-, reaction products with 68921-45-9 >98 272-940-1 Not
styrene and 2,4,4-trimethylpentene. classified.
diphenylamine 122-39-4 <2 204-539-4 Xn; R22 [1] [2]
N; R50
See section 15 for the full text of the R-phrases declared above
[1] Substance classified with a health or environmental hazard
[2] Substance with a workplace exposure limit
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3. Composition/information on ingredients
Occupational exposure limits, if available, are listed in section 8.
4. First aid measures
Check for and remove any contact lenses. Immediately flush eyes with plenty of water
Eye contact
for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical
attention immediately.
In case of contact, immediately flush skin with plenty of water for at least 15 minutes
Skin contact
while removing contaminated clothing and shoes. Wash clothing before reuse. Clean
shoes thoroughly before reuse. Get medical attention immediately.
Remove to fresh air. Keep person warm and at rest. If not breathing, if breathing is
Inhalation
irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained
personnel.
If swallowed, seek medical advice immediately and show this container or label. Keep
Ingestion
person warm and at rest. Do not induce vomiting.
No action shall be taken involving any personal risk or without suitable training. It may
Protection of first-aiders
be dangerous to the person providing aid to give mouth-to-mouth resuscitation.
In case of inhalation of decomposition products in a fire, symptoms may be delayed.
Notes to physician
The exposed person may need to be kept under medical surveillance for 48 hours.
See section 11 for more detailed information on health effects and symptoms.
5. Fire-fighting measures
In a fire or if heated, a pressure increase will occur and the container may burst.
Flammability of the product
Extinguishing media
Use an extinguishing agent suitable for the surrounding fire.
Suitable
Do not use water jet.
Not suitable
Promptly isolate the scene by removing all persons from the vicinity of the incident if
Special exposure hazards
there is a fire. No action shall be taken involving any personal risk or without suitable
training.
Decomposition products may include the following materials:
Hazardous combustion
carbon dioxide
products
carbon monoxide
nitrogen oxides
Fire-fighters should wear appropriate protective equipment and self-contained
Special protective
breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode.
equipment for fire-fighters
6. Accidental release measures
No action shall be taken involving any personal risk or without suitable training.
Personal precautions
Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled material. Avoid breathing vapor or mist.
Provide adequate ventilation. Wear appropriate respirator when ventilation is
inadequate. Put on appropriate personal protective equipment (see section 8).
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
Environmental precautions
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).
Stop leak if without risk. Move containers from spill area. Dilute with water and mop up
Small spill
if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material
and place in an appropriate waste disposal container. Dispose of via a licensed waste
disposal contractor.
Stop leak if without risk. Move containers from spill area. Approach release from
Large spill
upwind. Prevent entry into sewers, water courses, basements or confined areas.
Wash spillages into an effluent treatment plant or proceed as follows. Contain and
collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite
or diatomaceous earth and place in container for disposal according to local regulations
(see section 13). Dispose of via a licensed waste disposal contractor. Contaminated
absorbent material may pose the same hazard as the spilled product. Note: see
section 1 for emergency contact information and section 13 for waste disposal.
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7. Handling and storage
Put on appropriate personal protective equipment (see section 8). Eating, drinking and
Handling
smoking should be prohibited in areas where this material is handled, stored and
processed. Workers should wash hands and face before eating, drinking and smoking.
Do not ingest. Avoid contact with eyes, skin and clothing. Avoid breathing vapor or
mist. Keep in the original container or an approved alternative made from a compatible
material, kept tightly closed when not in use. Empty containers retain product residue
and can be hazardous. Do not reuse container.
Do not store below the following temperature: 22癈 (71.6癋). Store in accordance with
Storage
local regulations. Store in original container protected from direct sunlight in a dry, cool
and well-ventilated area, away from incompatible materials (see section 10) and food
and drink. Keep container tightly closed and sealed until ready for use. Containers that
have been opened must be carefully resealed and kept upright to prevent leakage. Do
not store in unlabeled containers. Use appropriate containment to avoid environmental
contamination.
Packaging materials
Use original container.
Recommended
8. Exposure controls/personal protection
Exposure limit values
Ingredient name Occupational exposure limits
diphenylamine ACGIH (United States, 1996).
TWA: 10 mg/m?br>
ACGIH TLV (United States, 1/2008).
TWA: 10 mg/m?8 hour(s).
If this product contains ingredients with exposure limits, personal, workplace
Recommended monitoring
atmosphere or biological monitoring may be required to determine the effectiveness of
procedures
the ventilation or other control measures and/or the necessity to use respiratory
protective equipment.
Exposure controls
No special ventilation requirements. Good general ventilation should be sufficient to
Occupational exposure
control worker exposure to airborne contaminants. If this product contains ingredients
controls
with exposure limits, use process enclosures, local exhaust ventilation or other
engineering controls to keep worker exposure below any recommended or statutory
limits.
Wash hands, forearms and face thoroughly after handling chemical products, before
Hygiene measures
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Wash contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Use a properly fitted, air-purifying or air-fed respirator complying with an approved
Respiratory
standard if a risk assessment indicates this is necessary. Respirator selection must be
based on known or anticipated exposure levels, the hazards of the product and the
safe working limits of the selected respirator. Recommended: Vapor and dust
respirator.
Chemical-resistant, impervious gloves complying with an approved standard should be
Hands
worn at all times when handling chemical products if a risk assessment indicates this is
necessary.
Recommended: Protective gloves should be worn under normal conditions of use.
Safety eyewear complying with an approved standard should be used when a risk
Eyes
assessment indicates this is necessary to avoid exposure to liquid splashes, mists or
dusts. Recommended: splash goggles
Personal protective equipment for the body should be selected based on the task being
Skin
performed and the risks involved and should be approved by a specialist before
handling this product.
Recommended: lab coat
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8. Exposure controls/personal protection
Emissions from ventilation or work process equipment should be checked to ensure
Environmental exposure
they comply with the requirements of environmental protection legislation. In some
controls
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels.
Personal protective
equipment (Pictograms)
9. Physical and chemical properties
General information
Appearance
Liquid.
Physical state
Amber.
Color
Amine-like. [Slight]
Odor
Important health, safety and environmental information
pH Not available.
>198癈 (>388.4癋)
Boiling point
7癈 (44.6癋)
Melting point
Closed cup: 176癈 (348.8癋) [Pensky-Martens.]
Flash point
Open cup: 210癈 (410癋) [Cleveland.]
Not available.
Auto-ignition temperature
Not available.
Vapor pressure
1.01 g/cm3 [15.6癈 (60.1癋)]
Density
Insoluble in the following materials: cold water.
Solubility
Not available.
Octanol/water partition
coefficient
Kinematic: 11.44 cm2/s (1144 cSt) [at 25癈]
Viscosity
Vapor density Not available.
0.5% (v/v)
Volatility
Not available.
Evaporation rate
Very soluble in alcohol and toluene.
Physical/chemical
properties comments
10. Stability and reactivity
The product is stable.
Stability
Under normal conditions of storage and use, hazardous reactions will not occur.
Possibility of hazardous
reactions
Under normal conditions of storage and use, hazardous decomposition products should
Hazardous decomposition
not be produced.
products
Reactive or incompatible with the following materials: oxidizing materials.
Incompatibility with various
substances
11. Toxicological information
Potential acute health effects
Exposure to decomposition products may cause a health hazard. Serious effects may
Inhalation
be delayed following exposure.
Harmful if swallowed.
Ingestion
Irritating to eyes.
Eyes
Acute toxicity
Product/ingredient name Result Species Dose Exposure
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11. Toxicological information
diphenylamine LD50 Oral Mouse 1750 mg/kg -
LD50 Oral Rat 1120 mg/kg -
LD50 Oral Guinea pig 300 mg/kg -
VANLUBE?SL LD50 Oral Rabbit 15000 mg/kg -
Product contains diphenylamine which may contribute to irritation. Diphenylamine may
Conclusion/Summary
be absorbed through the skin in toxic amounts. Diphenylamine may cause
methemoglobinemia and red blood cell damage.
Potential chronic health effects
Chronic toxicity
Not available.
Conclusion/Summary
Irritation/Corrosion
Not available.
Conclusion/Summary
Sensitizer
Not available.
Conclusion/Summary
Carcinogenicity
Not available.
Conclusion/Summary
Classification
Product/ingredient name ACGIH IARC EPA NIOSH NTP OSHA
diphenylamine A4 - - - - -
Mutagenicity
Not available.
Conclusion/Summary
Teratogenicity
Not available.
Conclusion/Summary
Reproductive toxicity
Not available.
Conclusion/Summary
Contains material that can cause target organ damage.
Chronic effects
Over-exposure signs/symptoms
Adverse symptoms may include the following:
Eyes
pain or irritation
watering
redness
Contains material which may cause damage to the following organs: blood, the
Target organs
reproductive system, mucous membranes, bladder, cardiovascular system, upper
respiratory tract, skin, eye, lens or cornea.
12. Ecological information
Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic
Environmental effects
environment.
Aquatic ecotoxicity
Product/ingredient name Test Result Species Exposure
diphenylamine - Acute EC50 2 to Daphnia - Water 48 hours
2.46 mg/L Fresh flea - Daphnia
water magna - <24
hours
- Acute EC50 0.31 Daphnia - Water 48 hours
to 0.36 mg/L flea - Daphnia
Fresh water magna - <24
hours
- Acute LC50 3790 Fish - Fathead 96 hours
to 4140 ug/L minnow -
Fresh water Pimephales
promelas - 31
days - 18.6 mm -
0.09 g
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12. Ecological information
Not available.
Conclusion/Summary
Biodegradability
Not available.
Conclusion/Summary
No known significant effects or critical hazards.
Other adverse effects
13. Disposal considerations
The generation of waste should be avoided or minimized wherever possible. Empty
Methods of disposal
containers or liners may retain some product residues. This material and its container
must be disposed of in a safe way. Dispose of surplus and non-recyclable products via
a licensed waste disposal contractor. Disposal of this product, solutions and any by-
products should at all times comply with the requirements of environmental protection
and waste disposal legislation and any regional local authority requirements. Avoid
dispersal of spilled material and runoff and contact with soil, waterways, drains and
sewers.
The classification of the product may meet the criteria for a hazardous waste.
Hazardous waste
Disposal should be in accordance with applicable regional, national and local laws and regulations.
14. Transport information
International transport regulations
Regulatory UN number Proper shipping Classes PG* Label Additional
information name information
Not - - - -
DOT Classification
regulated.
Not - - - -
TDG Classification
regulated.
Not - - - -
ADR/RID Class
regulated.
Not - - - -
IMDG Class
regulated.
Not - - - -
IATA-DGR Class
regulated.
PG* : Packing group
15. Regulatory information
EU regulations
Classification and labeling have been determined according to EU Directives 67/548/EEC and 1999/45/EC
(including amendments) and take into account the intended product use.
R33- Danger of cumulative effects.
Risk phrases
R52/53- Harmful to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.
S24- Avoid contact with skin.
Safety phrases
S36/37- Wear suitable protective clothing and gloves.
S61- Avoid release to the environment. Refer to special instructions/safety data sheet.
All components are listed or exempted.
Europe inventory
International regulations
: All components are listed or exempted.
International lists United States inventory (TSCA
8b)
Canada inventory : All components are listed or exempted.
Australia inventory (AICS): All components are listed or exempted.
China inventory (IECSC): All components are listed or exempted.
Japan inventory: All components are listed or exempted.
Korea inventory: All components are listed or exempted.
New Zealand Inventory of Chemicals (NZIoC): Not determined.
Philippines inventory (PICCS): All components are listed or exempted.
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16. Other information
Hazardous Material Information System (U.S.A.) *1
Health
1
Flammability
0
Physical hazards
Personal protection
* Chronic Potential
The customer is responsible for determining the PPE code for this material.
National Fire Protection Association (U.S.A.)
Flammability
1
1 0
Health Instability
Special
Date of issue / Date of revision 7/13/2010.
7/13/2010.
Print date
8/20/2009.
Previous Validation Date
Information contact Corporate Risk Management
203-853-1400
Indicates information that has changed from previously issued version.
Notice to reader
Information presented herein has been compiled from sources considered to be dependable and is accurate and reliable to the best of our knowledge and belief but is not guaranteed to
be so. Nothing herein is to be construed as recommending any practice or any product in violation of any patent or in violation of any law or regulation. It is the user's responsibility to
determine for himself the suitability of any material for a specific purpose and to adopt such safety precautions as may be necessary. We make no warranty as to the results to be
obtained in using any material and, since conditions of use are not under our control, we must necessarily disclaim all liability with respect to the use of any material supplied by us.
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