Shield DPA 15%
1201 3rd Avenue
Suite 5450
Super Refined
Seattle, WA 98101
800.936.6750
www.paceint.com
POSTHARVEST
MATERIAL SAFETY DATA SHEET
1. P R O D U C T & C O M P A N Y I D E N T I F I C A T I O N
Product Name: Shield DPA 15% Super Refined
Company: Pace International, LLC
Address: Office Manufacturing / Distribution
1201 3rd Avenue, Suite 5450 5661 Branch Road
Seattle, WA 98101 Wapato, WA 98951
Emergency Phone Number: 800.424.9300 (CHEMTREC)
2. C O M P O S I T I O N / I N F O R M A T I O N O N I N G R E D I E N T S
Hazardous Components
CAS # Component % Exposure Limits
3
122-39-4 diphenylamine 15 10 mg/m
67-63-0 isopropanol 20 400 ppm TLV
Other Components
proprietary
3. H A Z A R D S I D E N T I F I C A T I O N
Flammable. Harmful if swallowed or absorbed through skin or inhaled. Causes moderate eye irritation. Avoid contact
with eyes, skin or clothing. Avoid breathing spray mist. Prolonged or frequently repeated skin contact may cause
allergic reaction in some individuals. Toxic to fish and aquatic organisms.
4. F I R S T A I D M E A S U R E S
If Swallowed: Call a poison control center or doctor immediately for treatment advice. Have person sip a glass of
water if able to swallow. Do not induce vomiting unless told to do so by a poison control center or
doctor. Do not give anything by mouth to an unconscious person.
If on Skin: Take off contaminated clothing. Rinse skin immediately with plenty of water for 15 ?20 minutes.
Call a poison control center or doctor for treatment advice.
If Inhaled: Move person to fresh air. If person is not breathing, call 911 or an ambulance, then give artificial
respiration, preferably mouth-to-mouth, if possible. Call a poison control center or doctor for further
treatment advice.
If in Eyes: Hold eye open and rinse slowly and gently with water for 15 ?20 minutes. Remove contact lenses,
if present, after the first 5 minutes, then continue rinsing eye. Call a poison control center or doctor
for treatment advice.
5. F I R E F I G H T I N G M E A S U R E S
Extinguishing Media: Dry chemical, foam, CO2,
Special Exposure Hazards: Keep away from strong oxidizers.
Special Protective Equipment for Firefighters: Wear self-contained breathing equipment.
6. A C C I D E N T A L R E L E A S E M E A S U R E S
Personal Precautions: See Section 8 for personal protection measures.
Environmental Precautions: Do not allow product to enter sewers, lakes, streams or other bodies of water.
Methods for Cleaning Up: See Section 13 for disposal recommendations.
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Shield DPA 15%
7. H A N D L I N G & S T O R A G E
Handling: Good standards of hygiene should be maintained at all times. Smoking, eating, and drinking is
prohibited in the work area. For personal protection, see section 8.
Storage: Do not use or store near heat or open flames. Keep away from strong oxidizers. Avoid storing
below 40癋 (4癈). Keep container tightly closed when not in use.
8. E X P O S U R E C O N T R O L S / P E R S O N A L P R O T E C T I O N
Protective Clothing: Long sleeved shirt and long pants, shoes and socks, chemical resistant gloves such as
PVC, nitrile or butyl rubber.
Respiratory Protection: Not normally required. A NIOSH-approved respirator with solvent type canister may be
used in misty environments without proper ventilation.
Eye Protection: Chemical goggles recommended. Eye fountain and washing facilities should be present at
work area.
9. P H Y S I C A L & C H E M I C A L P R O P E R T I E S
Appearance: Light amber liquid
Odor: Alcoholic
Boiling Point: < 212癋 (100癈)
Flash Point: 74癋 (23癈) closed cup method
Flammable Limits: Not available
Explosive Properties: No data available
Oxidizing Properties: No oxidizing properties
Vapor Pressure: No data available
pH (@ 25癈): 5.26
Specific Gravity: 0.95 (H2O=1)
Solubility in Water: Dispersible
2
Viscosity: 21.48 mm /s (cSt) @ 25癈
% Volatile by Weight: 20%
10. S T A B I L I T Y & R E A C T I V I T Y
Conditions/Materials to Avoid: Heat and open flames. Strong oxidizers.
Hazardous Decomposition Products: None
11. T O X I C O L O G I C A L I N F O R M A T I O N
Acute Oral: LD50 oral (rat): 2720 mg/kg
Acute Dermal: LD50 dermal (rat): > 2000 mg/kg
Inhalation: LC50 (rat): 1.46 mg/L
Eye Irritation: Slight irritant (EPA Category III)
Skin Irritation: Slight irritant (EPA Category III)
Sensitization: Not a dermal sensitizer.
12. E C O L O G I C A L I N F O R M A T I O N
diphenylamine
Acute toxicity:
Northern bobwhite quail, LD50: > 2250 mg/kg
Mallard duck, LC50 (5-day): > 5205 ppm
Rainbow trout, LC50 (96h): 2.2 ppm
Daphnia magna, LC50/EC50 (48h): 1.2 ppm
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Shield DPA 15%
13. D I S P O S A L C O N S I D E R A T I O N S
PESTICIDE DISPOSAL: Wastes resulting from the use of this product may be disposed of on site or at an
approved waste disposal facility.
CONTAINER DISPOSAL: Triple rinse (or equivalent). Then offer for recycling or reconditioning or puncture and
dispose of in a sanitary landfill, or by incineration, or, if allowed by state and local
authorities, by burning. If burned, stay out of smoke.
14. T R A N S P O R T I N F O R M A T I O N
Proper Shipping Name: Flammable liquids, n.o.s. (Isopropanol)
Hazard Class: 3
UN Number: UN 1993
Packing Group: III
15. R E G U L A T O R Y I N F O R M A T I O N
CA Prop. 65: This product may contain a trace amount (less than 1 ppm) of ethylene oxide (CAS # 75-21-8), a
chemical known to the State of California to cause cancer, birth defects or other reproductive
harm.
Health Canada: Shield DPA 15% is registered under the Pest Control Product Act under registration number
18983.
FIFRA: Shield DPA 15% is registered with the U.S. EPA under registration number 64864-3.
SARA 313: Contains diphenylamine (CAS # 122-39-4), which is subject to SARA Title III Section 313
reporting requirements.
TSCA: All components of this product are included or exempt from inclusion in EPA's Toxic Substances
Control Act (TSCA) Chemical Substance Inventory.
WHMIS: This product has been classified in accordance with the hazard criteria of the CPR and the
MSDS contains all of the information required by the CPR.
16. O T H E R I N F O R M A T I O N
HMIS Ratings: Health ?1 Flammability ?3 Reactivity ?0
The information herein is believed to be accurate and represents the best information currently available. However,
Pace International LLC makes no warranty of merchantability or any other warranty, express or implied, with respect
to such information, and assumes no liability resulting from its use. Users should make their own investigations to
determine the suitability of the information for their particular purposes.
MSDS Revision Date: 05/18/07
Supersedes: 03/26/07
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