Material Safety Data Sheet
The Toro Company
8111 Lyndale Ave S
Bloomington, MN 55420
Revision Date: 30Jun2005 Issue Date: 02/02/06
Product Identification
Toro 10w30 Engine Oil
Product Name: Parts Number:
Engine oil 108-1179, 108-1180
Product type:
MSDS #
Chemtrec : 1-800-424-9300
Emergency
Contact:
1-952-888-8801
Contact Number:
Chemical Components
%
Chemical CAS # ACGIH TLV OSHA PEL Other
ZINC DITHIOPHOSPHATE 68649-42-3 < 2.5%
When mists / aerosols can occur, 5 mg/m? 5 mg/m? 10 mg/m?-
ACGIH STEL,
Physical and Chemical Properties
Characteristics Physical Properties Hazards Physical Dangers
Description
Excessive exposure may
STABILITY:
Liquid Vapor pressure < 0.013 kPa (0.1 mm
Physical
Hg) at 20癈 Material is stable result in eye, skin, or
State
pH N/A
under normal respiratory irritation. Low
Amber
Color
conditions. order of toxicity. High-
characteristic
Odor Boiling point/range: > 316癈 (600癋)
pressure
CONDITIONS TO
Melting point/range: N/A AVOID: Excessive injection under skin may
heat. High energy cause serious damage.
Relative density (at 15 癈 ): 0.865
sources of ignition.
MATERIALS TO
Log Pow (n > 3.5
AVOID: Strong
Octanol/Water
Partition Coefficient): oxidizers
Vapor density N/D
HAZARDOUS
HMIS Rating DECOMPOSITION
Evaporation rate N/D
0
Health: PRODUCTS:
Solubility in water Negligible Material does not
Flammable Limits LEL: 0.9 UEL: 7.0 decompose at
1
Flammability:
Flash Point >215癈 (419癋) [
ambient
ASTM D-92]
temperatures.
0
Physical Viscosity: 74 cSt (74 mm?sec )
HAZARDOUS
Hazard: at 40 癈 | 11.5 cSt
(11.5 mm?sec) at POLYMERIZATION:
100癈
Will not occur.
OTHER INFORMATION
Freezing Point: N/D
Melting Point: N/A
Pour Point: -33癈 (-27癋)
DMSO Extract (mineral oil only), IP-346: < 3
%wt
Health Hazards
Major Routes of Ingredients Considered Potential Health Effects:
Exposure: Hazardous to Health
Inhalation.
Inhalation
Skin contact
Skin
Eye contact:.
Ingestion
Eye Ingestion:
First Aid Measures Personal Protection
INHALATION ENGINEERING CONTROLS
Remove from further exposure. For those providing The level of protection and types of controls necessary will
assistance, avoid exposure to yourself or others. Use vary depending upon potential exposure conditions.
adequate respiratory protection. If respiratory irritation, Control measures to consider: No special requirements
dizziness, nausea, or unconsciousness occurs, seek under ordinary conditions of use and with adequate
immediate medical assistance. If breathing has stopped, ventilation. Personal Protection Personal protective
assist ventilation with a mechanical device or use equipment selections vary based on potential exposure
mouth-to-mouth resuscitation. conditions such as applications, handling practices,
SKIN CONTACT concentration and ventilation. Information on the selection of
Wash contact areas with soap and water. If product is protective equipment for use with this material, as provided
injected into or under the skin, or into any part of the below, is based upon intended, normal usage. Respiratory
body, regardless of the appearance of the wound or its Protection: If engineering controls do not maintain airborne
size, the individual should be evaluated immediately by contaminant concentrations at a level which is adequate to
a physician as a surgical emergency. Even though initial protect worker health, an approved respirator may be
symptoms from high pressure injection may be appropriate. Respirator selection, use, and maintenance
minimal or absent, early surgical treatment within the first must be in accordance with regulatory requirements, if
few hours may significantly reduce the ultimate extent applicable. Types of respirators to be considered for this
of injury. material include: No special requirements under ordinary
EYE CONTACT conditions of use and with adequate ventilation. For high
Flush thoroughly with water. If irritation occurs, get airborne concentrations, use an approved supplied-air
medical assistance. respirator, operated in positive pressure mode. Supplied air
INGESTION respirators with an escape bottle may be appropriate when
First aid is normally not required. Seek medical attention oxygen levels are inadequate, gas/vapor warning properties
if discomfort occurs are poor, or if air purifying filter capacity/rating may be
exceeded.
Hand Protection: Any specific glove information provided is
based on published literature and glove
manufacturer data. Work conditions can greatly effect glove
durability; inspect and replace worn or damaged gloves. The
types of gloves to be considered for this material include:
No protection is ordinarily required under normal conditions
of use.
Eye Protection: If contact is likely, safety glasses with side
shields are recommended.
Skin and Body Protection: Any specific clothing
information provided is based on published literature or
manufacturer data. The types of clothing to be considered
for this material include:
No skin protection is ordinarily required under normal
conditions of use. In accordance with good
industrial hygiene practices, precautions should be taken to
avoid skin contact.
Specific Hygiene Measures: Always observe good
personal hygiene measures, such as washing after
handling the material and before eating, drinking, and/or
smoking. Routinely wash work clothing and protective
equipment to remove contaminants. Discard contaminated
clothing and footwear that cannot be cleaned.
Practice good housekeeping
Fire and Explosion Hazards
Extinguishing Media Special Fire Fighting Procedures Unusual Fire and Explosion
Hazards
Use water fog, foam, dry Fire Fighting Instructions: Evacuate Hazardous Combustion Products:
chemical or carbon dioxide area. Prevent runoff from fire control or Aldehydes, Sulfur oxides, Incomplete
(CO2) to extinguish dilution from entering streams, combustion products, Oxides of
flames. Inappropriate sewers, or drinking water supply. carbon, Smoke, Fume
Extinguishing Media: Straight Firefighters should use standard FLAMMABILITY PROPERTIES
Streams of Water protective equipment and in enclosed Flash Point [Method]: >215癈 (419癋) [
spaces, self-contained breathing ASTM D-92]
apparatus (SCBA). Use water spray to Flammable Limits (Approximate
cool fire exposed surfaces and to volume % in air): LEL: 0.9 UEL: 7.0
protect personne Autoignition Temperature: N/D
Handling and Storage
Accidental Release /Spill Measures to Take Precautions for Storage Handling
Do not store in open or unlabelled Avoid contact with used
NOTIFICATION PROCEDURES
In the event of a spill or accidental release, notify containers. product. Prevent small
relevant authorities in accordance with all spills and leakage to
applicable regulations. U.S. regulations require avoid slip hazard.
Empty Container Warning
reporting releases of this material to the PRECAUTIONARY LABEL TEXT: Static Accumulator:
environment which exceed the reportable quantity Empty containers may retain residue This material is a static
or oil spills which could reach any waterway and can be dangerous. DO NOT accumulator
including intermittent dry creeks. The National PRESSURIZE, CUT, WELD, BRAZE,
Response Center can be reached at (800)424- SOLDER, DRILL, GRIND OR
8802. EXPOSE SUCH CONTAINERS TO
HEAT, FLAME, SPARKS, STATIC
SPILL MANAGEMENT
Land Spill: Stop leak if you can do it without risk. ELECTRICITY, OR OTHER
Recover by pumping or with suitable absorbent. SOURCES OF IGNITION; THEY
Water Spill: Confine the spill immediately with MAY EXPLODE AND CAUSE
booms. Stop leak if you can do it without risk. Warn INJURY OR DEATH. Do not attempt
other shipping. Remove from the surface by to refill or clean container since
skimming or with suitable absorbents. Seek the residue is difficult to remove. Empty
advice of a specialist before using dispersants. drums should be completely drained,
Water spill and land spill recommendations are properly bunged and promptly
based on the most likely spill scenario for this returned to a drum reconditioner. All
material; however, geographic conditions, wind, containers should be disposed of in
temperature, (and in the case of a water spill) wave an environmentally safe manner and
and current direction and speed may greatly in accordance with governmental
influence the appropriate action to be taken. For regulations.
this reason, local experts should be consulted.
Note: Local regulations may prescribe or limit
action to be taken.
ENVIRONMENTAL PRECAUTIONS
Large Spills: Dike far ahead of liquid spill for later
recovery and disposal. Prevent entry into
waterways, sewers, basements or confined areas
Disposal/Transportation
Disposal Method Transportation
Disposal recommendations based on material as supplied. LAND (DOT) : Not Regulated for Land Transport
Disposal must be in accordance with current applicable LAND (TDG) : Not Regulated for Land Transport
laws and regulations, and material characteristics at time of SEA (IMDG) : Not Regulated for Sea Transport
disposal. according to IMDG-Code
AIR (IATA) : Not Regulated for Air Transport
DISPOSAL RECOMMENDATIONS
Product is suitable for burning in an enclosed controlled
burner for fuel value or disposal by supervised
incineration at very high temperatures to prevent formation of
undesirable combustion products.
REGULATORY DISPOSAL INFORMATION
RCRA Information: The unused product, in our opinion, is not
specifically listed by the EPA as a hazardous
waste (40 CFR, Part 261D), nor is it formulated to contain
materials which are listed as hazardous wastes. It does not
exhibit the hazardous characteristics of ignitability,
corrositivity or reactivity and is not formulated with
contaminants as determined by the Toxicity Characteristic
Leaching Procedure (TCLP). However, used
product may be regulated.
Regulations
OSHA HAZARD COMMUNICATION STANDARD: When used for its intended purposes, this material is not classified
as hazardous in accordance with OSHA 29 CFR 1910.1200.
NATIONAL CHEMICAL INVENTORY LISTING: AICS, DSL, EINECS, ENCS, PICCS, TSCA
EPCRA: This material contains no extremely hazardous substances.
SARA (311/312) REPORTABLE HAZARD CATEGORIES: None.
SARA (313) TOXIC RELEASE INVENTORY:
Chemical Name CAS Number Typical Value
ZINC DITHIOPHOSPHATE 68649-42-3 < 2.5%
The Following Ingredients are Cited on the Lists Below:*
Chemical Name CAS Number List Citations
DIPHENYLAMINE 122-39-4 5, 9
PHOSPHORUS 7723-14-0 1, 4
ZINC DITHIOPHOSPHATE 68649-42-3 13, 15, 17
--REGULATORY LISTS SEARCHED--
1 = ACGIH ALL 6 = TSCA 5a2 11 = CA P65 REPRO 16 = MN RTK
2 = ACGIH A1 7 = TSCA 5e 12 = CA RTK 17 = NJ RTK
3 = ACGIH A2 8 = TSCA 6 13 = IL RTK 18 = PA RTK
4 = OSHA Z 9 = TSCA 12b 14 = LA RTK 19 = RI RTK
5 = TSCA 4 10 = CA P65 CARC 15 = MI 293
Code key: CARC=Carcinogen; REPRO=Reproductive
* EPA recently added new chemical substances to its TSCA Section 4 test rules. Please contact the supplier to confirm
whether the ingredients in this product currently appear on a TSCA 4 or TSCA 12b list.
Toxicology Information
ACUTE TOXICITY
Route of Exposure Conclusion / Remarks
Inhalation
Toxicity (Rat): LC50 > 5000 mg/m?Minimally Toxic. Based on test data for structurally similar materials. Irritation: No end point data.
Negligible hazard at ambient/normal handling temperatures. Based on assessment of the components.
Ingestion Toxicity (Rat): LD50 > 2000 mg/kg Minimally Toxic. Based on test data for structurally similar materials.
Skin Toxicity (Rabbit): LD50 > 2000 mg/kg Minimally Toxic. Based on test data for structurally similar materials. Irritation (Rabbit):
Data available. Negligible irritation to skin at ambient temperatures. Based on test data for structurally similar materials.
Eye Irritation (Rabbit): Data available. May cause mild, short-lasting discomfort to eyes. Based on test data for structurally similar
materials.
CHRONIC/OTHER EFFECTS
For the product itself:
Diesel engine oils: Not carcinogenic in animals tests. Used and unused diesel engine oils did not produce any
carcinogenic effects in chronic mouse skin painting studies. Oils that are used in gasoline engines may become
hazardous and display the following properties: Carcinogenic in animal tests. Caused mutations in vitro. Possible
allergen and photoallergen. Contains polycyclic aromatic compounds (PAC) from combustion products of gasoline
and/or thermal degradation products.
Contains: Base oil severely refined: Not carcinogenic in animal studies. Representative material passes IP-346,
Modified Ames test, and/or other screening tests. Dermal and inhalation studies showed minimal effects; lung
nonspecific infiltration of immune cells, oil deposition and minimal granuloma formation. Not sensitizing in test animals.
The following ingredients are cited on the lists below: None.
--REGULATORY LISTS SEARCHED--
1 = NTP CARC 3 = IARC 1 5 = IARC 2B
2 = NTP SUS 4 = IARC 2A 6 = OSHA CARC
SECTION 12 ECOLOGICAL INFORMATION
The information given is based on data available for the material, the components of the material, and similar materials.
ECOTOXICITY
Material -- Not expected to be harmful to aquatic organisms.
MOBILITY
Base oil component -- Low solubility and floats and is expected to migrate from water to the land. Expected to
partition to sediment and wastewater solids.
PERSISTENCE AND DEGRADABILITY
Biodegradation:
Base oil component -- Expected to be inherently biodegradable
Ecological Information
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