PMC Rubber Chemicals India Private Limited
Works & Registered Office:
103 G T Road West
PO: Rishra 712248, Dist : Hooghly
West Bengal, India
Tel : +91 33 26722515, Fax : +91 33 26721552
Committed to Service and innovation
MATERIAL SAFETY DATA SHEET
MSDS # PMC/RC/022/06
Updated on 02 - Jan - 2006
ACCINOX 100
Product Name Health Hazard : 1
+REV 08
Revision Number
Fire Hazard : 1
3077
UN Number
Reactivity : 0
68953 - 84 - 4
CAS No.
Personal Protection : X
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND
COMPANY/UNDERTAKING
ACCINOX 100
PRODUCT NAME:
Address/Phone No : PMC Rubber Chemicals India Private Limited
Works & Registered Office:
103 G T Road West
PO: Rishra 712248, Dist : Hooghly
West Bengal, India
Tel : +91 33 26722515, Fax : +91 33 26721552
2. COMPOSITION/INFORMATION ON INGREDIENTS
PRODUCT DESCRIPTION CAS No Symbol R Phrases
Diaryl-p-phenylenediamine mixture 68953 - 84 ?4 Xi, N R43, 50/53
HAZARDOUS INGREDIENT(S) CAS No. %(w/w)
Diphenylamine 122-39-4 <5
Aniline 62-53-3 < 0.1
O-Toluene 95-53-4 < 0.1
3. HAZARDS IDENTIFICATION
This health hazard assessment is based on a consideration of the composition of this
product.
Irritant to skin, eyes and respiratory tract
May cause sensitisation by skin contact (some clinical evidence of skin sensitisation has
been reported but few problems have been encountered in use)
When ignited on open flame, this product will burn.
Primary routes of entry : Dermal contact and inhalation.
Short term exposure : See: OTHER INFORMATION
Long term exposure : See: OTHER INFORMATION
- 1 of 6 - MSDS for Accinox 100
PMC Rubber Chemicals India Private Limited
Works & Registered Office:
103 G T Road West
PO: Rishra 712248, Dist : Hooghly
West Bengal, India
Tel : +91 33 26722515, Fax : +91 33 26721552
Committed to Service and innovation
4. FIRST-AID MEASURES
Inhalation Remove patient from exposure.
Obtain medical attention if ill effects occur.
Skin Contact Remove contaminated clothing.
Wash skin with plenty of soap and water.
If symptoms (irritation or blistering) occur obtain medical attention.
Contaminated clothing should be laundered before re-issue.
Eye Contact Irrigate with eyewash solution or clean water, holding the eyelids
apart, for at least 10 minutes. Obtain medical attention.
Ingestion Do not induce vomiting.
Wash out mouth with water and give 200-300 ml (half a pint) of
water to drink. Obtain medical attention.
Further Medical Treatment
Symptomatic treatment and supportive therapy as indicated.
5. FIRE-FIGHTING MEASURES
Combustible.
Combustion or thermal decomposition will evolve very toxic, irritant and
extremely flammable vapours.
Protect from sparks (dust explosion risk)
Combustion products: Nitrogen oxides, carbon monoxide, carbon dioxide
Extinguishing Media: Water spray, foam, dry powder or CO2.
Fire Fighting A self contained breathing apparatus and suitable
Protective Equipment protective clothing should be worn in fire conditions.
6. ACCIDENTAL RELEASE MEASURES
Do not allow to enter drains, sewers or watercourses.
Clear up spillages.
Transfer to a container for disposal or recovery.
Ensure suitable personal protection during removal of spillages.
- 2 of 6 - MSDS for Accinox 100
PMC Rubber Chemicals India Private Limited
Works & Registered Office:
103 G T Road West
PO: Rishra 712248, Dist : Hooghly
West Bengal, India
Tel : +91 33 26722515, Fax : +91 33 26721552
Committed to Service and innovation
7. HANDLING AND STORAGE
7.1 HANDLING
Avoid contact with skin and eyes.
7.2 STORAGE
Keep away from oxidising agents, acids, alkalis, moisture and direct sunlight.
Suitable containers: High density polyethylene (HDPE) laminated paper bags
with polythene liner inside.
Store below 500C, away from moisture and strong
Storage Temperature:
oxidising agents. Avoid dust formation (explosion
risk).
Storage Life 1 year(s)
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Wear suitable gloves and eye/face protection.
Occupational Exposure Limits
No Occupational Exposure Limit listed but 2.5 mg/m3 for total dust is
recommended
9. PHYSICAL AND CHEMICAL PROPERTIES
Form Flakes (staining)
Colour Dark brown
Odour Amine
pH (Value) No data.
Boiling Point (Deg C) No data.
Melting Point (Deg C) 90 (minimum)
Flash Point (Deg C) No data.
Flammable Limits No data.
Auto Ignition Temp (癈) No data
Explosive Properties Not applicable.
Oxidising Properties No data.
Vapour Pressure (Ps) No data.
Solubility (Water) Insoluble
Solubility (Other) Soluble in toluene
Specific Gravity 1.2 @ 25癈
- 3 of 6 - MSDS for Accinox 100
PMC Rubber Chemicals India Private Limited
Works & Registered Office:
103 G T Road West
PO: Rishra 712248, Dist : Hooghly
West Bengal, India
Tel : +91 33 26722515, Fax : +91 33 26721552
Committed to Service and innovation
10. STABILITY AND REACTIVITY
Incompatible materials oxidising agents, acids and alkalis
Hazardous Reactions : None known.
Hazardous Decomposition Product(s) : Oxides of Carbon and Nitrogen
11. TOXICOLOGICAL INFORMATION
This health hazard assessment is based on a consideration of the composition of
this product.
Acute Oral LD50 (Rat) >2370 mg/kg
Inhalation Combustion will evolve very toxic and irritant vapours.
Skin Contact May cause sensitisation by skin contact.
See: Other information
Eye Contact May cause irritation. If irritation persists, seek medical advice
Ingestion Ingestion may cause irritation of the gastrointestinal tract.
Mutagenic in the Ames test .
Long Term Exposure : See other information
12. ECOLOGICAL INFORMATION
Acute Fish Toxicity 96 hr LC50 Rainbow Trout > 0.48 mg/l
48 hr EC50 Daphnia Magna >1.8 mg/l
Acute Algae Toxicity 96 hr EC50 Algae > .20 mg/l
Octanol/Water Coefficient Log P = 4.0
Persistence and degradability Not readily biodegradable
13. DISPOSAL CONSIDERATIONS
Disposal (Incinerate/treat or landfill) should be in accordance with local, state or
national legislation.
- 4 of 6 - MSDS for Accinox 100
PMC Rubber Chemicals India Private Limited
Works & Registered Office:
103 G T Road West
PO: Rishra 712248, Dist : Hooghly
West Bengal, India
Tel : +91 33 26722515, Fax : +91 33 26721552
Committed to Service and innovation
14. TRANSPORT INFORMATION
Not Classified as Dangerous for Transport, supply and use.
UN No : 3077
Class : 9
Packing Group : III
Environmentally hazardous substance, Solid, N.O.S., (Contains diphenylamine)
Marine Pollutant Not classified as a Marine Pollutant
15. REGULATORY INFORMATION
EC Classification: Irritant, Hazard Symbol Xi
Dangerous for the Environment, N
Risk Phrases R43 May cause sensitisation by skin contact.
R50/53 Very toxic to aquatic organisms and may cause long-
term adverse effects in the aquatic environment.
Safety Phrases S24 Avoid contact with skin.
S36 Wear suitable protective clothing.
S60 This material and/its container must be disposed of as
hazardous waste.
S61 Avoid release to the environment. Refer to special
instructions/safety data sheets.
16. OTHER INFORMATION
Use : Antioxidant/antiozonant for rubbers
Other Information:
Listed by the International Contact Dermatitis Group for routine skin patch testing
in appropriate circumstances.
In animal feeding studies, diphenylamine at 1% (10,000 ppm) of the diet, has
been reported to effect the heart, blood, bladder and kidney.
The concentration of the residual monomers are less than 0.1%. At this
concentration, this product is not regulated as a potential carcinogen by the
OSHA Hazard Communication Standard or the WHMIS legislation.
- 5 of 6 - MSDS for Accinox 100
PMC Rubber Chemicals India Private Limited
Works & Registered Office:
103 G T Road West
PO: Rishra 712248, Dist : Hooghly
West Bengal, India
Tel : +91 33 26722515, Fax : +91 33 26721552
Committed to Service and innovation
HMIS rating: Health: 1
Flammability: 1
Reactivity: 0
PPI: X
Legend : 0(HMIS) Minimal hazard
1(HMIS) Slight hazard
2(HMIS) Moderate hazard
3(HMIS) Serious hazard
4(HMIS) Severe hazard
X(HMIS) Personal protective rating to be supplied by user
depending on the use conditions
.
Information in this publication is believed to be accurate and is given in good faith, but it is for the Customer to satisfy itself of the
suitability for its own particular purpose. Accordingly, PMC Group Rubber Chemicals gives no warranty as to the fitness of the
product for any particular purpose and any implied warranty or condition (statutory or otherwise) is excluded except to the extent of
such exclusion is prevented by law. The trade mark "ACCINOX" is registered in the name of ICI India Limited and assigned
to : PMC Rubber Chemicals India Private Limited.
- 6 of 6 - MSDS for Accinox 100
|